Search Documents

By William R. Yernberg

The Fifth International Conference on acid rock drainage (ICARD 2000) was held May 21-24, 2000, in Denver, CO. The three-day conference consisted of about 150 oral presentations and poster sessions that described the state-of-the-art of acid-rock-drainage (ARD) science and technology. The conference also featured a trade show. It included representatives from consulting companies and government agencies with interests in ARD, as well as other environmental issues related to mining. The conference also included field trips to ARD treatment sites and short courses on acid rock drainage issues. ICARD 2000 was planned and promoted by the ICARD 2000 Organizing Committee and the Society for Mining, Metallurgy, and Exploration, Inc. (SME). Financial support was provided by Barrick Gold, BHP Copper, Homestake Mining, Noranda, Phelps Dodge, PlacerDome, the US Bureau of Land Management, the USEnvironmental Protection Agency and the US Geological Survey. Since the original ICARD was held in Roros, Norway, in 1988, knowledge has improved of the behavior of mine wastes as have methods of environmental mitigation. The ICARD 2000 presented the latest advancements in the field of acid drainage.

Jan 1, 2000

By Alain Dorval

"''Purification of marine sands from Les Iles-de-la-Madeleine''This paper presents the results of the work that has been done at CRM pilot plant for «Les Silices du Golfe Inc.». Essentially the purpose of this piloting was to demonstrate, on a semi-industrial scale, the process of purification of marine sands from Les Iles-de-la-Madeleine; that had been developed by CRM Process Development Service. This purification is necessary to produce silica suitable for the glass sand and the foundry sand markets.Introduction«Les Silices du Golfe Inc.» is a company who intends to dredge marine sands around the «Les Iles-de-la-Madeleine» coasts. The material will be transported to Gaspesia where electricity, water supply, and a convenient site is available to treat it. A high purity silica intended for glass sand and foundry sand markets will be produced. The objectives of this purification process are to remove organics, calcium, feldspars and iron.Material ReceivedCRM received 50 tons of sand with Si02 varying between 80,6 and 99,3 % (see Figure.1). The highest variations in impurities were the calcium and lost on ignition. We notice direct relation between% SiO2, % CaO and % L.O.I. as you can see on the following Figures 2, 3 and 4."

Jan 1, 1994

Zircon producers are often required to lower impurity levels to meet customer specifications as most of these impurities adversely effect the end use. For example, zircon sand in foundry applications needs to be free of any surface impurities (eg clay, gibbsite and goethite) which otherwise could cause sintering or fusion between cast metal and the zircon mould. Light coloured ceramic grade zircon, typically low in iron oxides and titania, is preferred in ceramics applications. The presence of impurities in zircon sands is a problem in the magnetic and electrostatic separation stages of their concentration. Previous work (Aral et al, 1997) showed that impurities in zircon sand concentrates occurred in the form of stains on grain surfaces, discrete gangue minerals and in the mineral grains. The gangue minerals such as rutile, garnet, xenotime, monazite, spinels, ilmenite, and aluminium silicates in the concentrate in some cases (Aral et al, 1997) contribute significantly to the impurity content of the concentrate. A careful hand picking of the impurity grains from a Western Australian zircon sand showed that the impurity content of the concentrate could be lowered significantly as a result of the removal of the surface stained grains and gangue minerals. The hand-picked ædirtyÆ fraction, comprised about eight per cent by weight of the concentrate, and consisted mostly of iron-oxide/hydroxide-stained zircon, silica grains and rutile, and occasionally ilmenite, monazite, gahnite and other (unidentified) coloured grains. The chemical analysis of the remaining æcleanÆ fraction showed that the major impurities (Fe and Ti) were reduced significantly (Table 1). The reduction in the uranium content was about 30 per cent. The other measured impurities, P, Mg, Al, Th, and Ca remained mostly unchanged as shown in Table 1. The contribution of ilmenite to the overall iron content of æcleanÆ zircon was insignificant as it comprised about 0.1 per cent weight of the æcleanÆ zircon. Rutile was the major source of titanium contamination (about one per cent by weight). Recent work (Aral and Calle, 1999) on zircon sand concentrates from the Murray Basin showed that, under the electron microprobe, the bulk of the impurities occurred in the dark back scattered electron (BSE) regions of the zoned zircon grains. The impurity contents of the light BSE regions and unblemished (unzoned) grains were low. The impurity content in zoned zircons has been investigated on single, relatively large, crystals (McLaren, Gerald and Williams, 1994; Smith et al, 1991; Romans, Brown and White, 1975). These studies generally aimed to investigate the incorporation of U in zircon as zircon is used extensively for U-Pb geochronology owing to its relatively high content of uranium. Smith et al (1991) identified a striking difference in composition between the areas of lower (dark BSE) and higher (light BSE) average atomic number in the zoned zircon. Their work showed in particular that the zones of lower atomic numbers contained very significant amounts of trace metals such as Y, REE, Nb, U, Al, Fe, Ca, Ba and, by difference H2O. In this paper the impurity distribution in zoned zircon grains was investigated on statistically significant number of grains before and after a leach treatment. The distribution of impurities was also measured in unblemished areas to compare the results.

Jan 1, 2000

By T. O. Allen, J. H. Atterbury

Laboratory and field tests during the past five years indicated considerable variation in the penetrating power of commercially available gun perforators. Many of the guns which achieved inadequate penetration in these tests have since been improved. However, recent productivity tests indicated the possibility of inadequate penetration or, at least, ineffective penetration in some wells. Laboratory experiments under simulated well conditions have demonstrated considerable plugging of the perforations, apparently as a result of factors associated with the shooting process and/or the drilling mud in the well at the time of perforating. The restrictions to flow per unit of hole depth caused by this plugging appears to be greater for jet perforators than for bullet guns of comparable diameter; however, because of the greater depth of penetration obtained with the jet guns, the total flow rates appear to he approximately equal. Limited testing with an experimental shaped charge suggests that less shot hole restriction and greater flow rates may result from larger-diameter perforations or other factors related to charge design. INTRODUCTION Gun perforating has been accepted for a number of years as a routine well completion method which is often preferred since it permits more selective operation of producing zones. Nevertheless, questions have continued to arise as to the effectiveness of the communication paths established between the productive formation and the interior of the casing. The basis for these questions has generally been failure to obtain anticipated fluid production rates through gun perforated completions in specific wells. These low productivities, together with the frequent recovery of bullets from well bores, were considered strong evidence of inadequate penetration. Laboratory investigations of the penetration performance of many of the bullet guns available as late as 1948 gave support to these indications. Subsequent electrical analog studiesl,2,3 indicated that the depth of penetration required to provide productivities equivalent to open hole was beyond the capacity of most bullet perforators evaluated in the early laboratory penetration tests. These results, together with the advent of the shaped charge in the field of oil well perforating, stimulated the interest of both oil operators and service companies in gun development. Improvements in gun design resulted in jet and bullet guns which appeared to be capable of providing sufficient penetration for most perforating jobs. However, some wells failed to yield satisfactory fluid production even after being perforated with the more powerful guns, again raising the question as to the effectiveness of the perforating operation. This fact, together with preliminary shooting into targets prepared with formation cores, indicated that factors associated with the perforating process and/or the fluids in the well bore at the time of shooting may reduce effective formation penetration and thereby decrease well productivity. These laboratory and field data prompted another phase in the investigation of the effectiveness of gun perforating: a program to determine the extent and seriousness of perforation plugging under simulated well conditions.

Jan 1, 1955

Continuous pH and Pulp Potential Measurements During Complex Sulfide Ore Flotation

Sep 13, 2010

By R. L. Andrew

The southwest Pacific has produced at least four of the world’s premier porphyry copper-gold deposits, and the current level of exploration is likely to produce even more. An appreciable amount of gold is being produced with this copper, with obvious economic advantages. Gold content, in addition to their large size, makes the southwest Pacific’s porphyrycopper-gold deposits very attractive exploration targets. The recognition of telescoping and overprinting of porphyry systems has produced a greater awareness of the likely surface expressions, in particular the significance of advanced argillic lithocaps in porphyry exploration. The recognition of the spatial and genetic association of porphyry copper and epithermal gold systems (Sillitoe, 1972), as in other parts of the world, has had important implications for exploration in the Asia Pacific region.

Jan 1, 1995

Viscosity measurements were carried out on slags in the CaO-Cu2O-CuO-MgO-SiO2systemcontaining ~ 63 wt% SiO2in air. The experimental work was carried out over a range of temperatures where the slags were completely liquid. Initial measurements were on a binary CaO-SiO2slag to which incremental additions of CuxO-MgO-SiO2slag with the same silica mole fraction were made. The viscosity-temperature relationship was measured for slags with‘Cu2O’contents of 0.02, 0.19, 0.38, 0.79, 1.69, 2.47, 3.01, 5.31 and 10.0 wt%. The proportions of Cu+and Cu2+in the slags were determined. The oxidation state of Cushifted from predominantly Cu+to Cu2+, with the Cu+/Cu2+ratio of approximately 0.3 for slag with a Cu content above 2 wt%. This is equivalent to Cu1.13O. The trends observed for changes of Cu2+/Cu+redox ratio with slag chemistry were consistent with the literature. Decreasing the CaO content by substituting copper oxide resulted in a decrease in the Cu+/Cu2+redox ratio. The change in ratio corresponded to a shift of the value of x in CuxO from an initial value of 1.8 to 1.1,when the slags contained 10% ‘Cu2O’. In this study, the SiO2content of the slags varied between 64 and 60 wt% as the Cu content increased. The viscosity of the slag containing 10 wt% CuxO was nearly 4.5 times lower than the binary CaO-SiO2slag. As the silica mole fraction (xSiO2) actually stayed constant (0.61±0.009),the results show that CuxO acted as a network breaker. Comparison with other ternary slags with similar silica mole fractions suggest that that addition of CuxO to silicate slags has a stronger effect on lowering the viscosity than FeO or MnO has on a molar basis. Keywords: viscosity, copper, silicate, slags

Jan 1, 2004

By L. M. Anisdahl

Ventiflex is a flexible ventilation duct system with a global market within mine and tunnel ventilation. The system is distributed in a wide range of qualities and dimensions. It is very important that ventilation systems are designed correctly in mines and tunnels. An incorrectly dimensioned system might result in bad air quality and too high costs. The objective of this study has been to assess some important design parameters for ventiflex comprising the friction loss factor for the duct wall itself, as well as the shock loss factors and the leakage factors for the different couplings systems. This has been obtained by carrying out a large scale experimental program on ducts with all the three different couplings: Velcro, zip and steel-ring. Pressure profiles and air flow rates have been measured, and based on these data the different factors have been calculated. The following results have been obtained: A friction factor l = 0,012 (K = 10) for the duct wall, a shock loss factor z = 0,0125 for velcro- and zip couplings, a shock loss factor z = 0,005 for steel-ring couplings, and a leakage factor f* = 0 mm2/m2 for all three coupling types. The latter result proves that no leakage is possible for a correctly installed duct with proper alignment. The results also confirm that ventiflex complies with class S, or better, according to the SIA-norm. However, whether ventiflex should be designed as class S, A or B according to the SIA-norm, depends on the particular application.

Jan 1, 2009

By G. Stokreef, B. R. Davis, M. Kadiyski, Alvear Montenegro, H-P. Loock, V. Montenegro

An optical probe for burner monitoring in copper flash smelting, first developed at the University of Concepcion, is being industrially tested in a collaboration between Kingston Process Metallurgy, Aurubis AG, and Queen’s University. The sensor uses fibre-optics and optical emission spectroscopy to analyze the light emitted from combusting particles in the furnace reaction shaft. Information that can be extracted from the emission spectrum includes the temperature and brightness of the flame, as well as emission lines or bands from excited atomic and/or molecular species. Laboratory proof of concept testing of the sensor was first completed in a continuously fed drop tube reactor using O2/S stoichiometric ratios between 0.8–4.0. These O2/S stoichiometries capture the industrial operating condition, which is typically less than 1. The results from lab testing justified a plant trial of the optical probe, which was done in the Aurubis Hamburg flash furnace in September 2018. From this trial, approximately 31 hours of spectral data were collected and synchronized with furnace operating data. The results from both drop tower test work and the plant trial are discussed with implications for process monitoring in the commercial furnace. INTRODUCTION Flash furnace smelting is a continuous feed, batch tap, pyrometallurgical process. It is used to treat copper sulphide concentrates and small amounts of secondary materials, such as dust generated by the process. O2 enriched air and the concentrate blend are fed into the furnace reaction shaft through the concentrate burner. As the particles fall through the reaction shaft, they heat up and ignite, causing rapid, exothermic reactions that oxidize the iron sulphide, some copper sulphide and impurities in the feed. Reacted particles fall into the settler of the furnace, melt and separate into a matte and slag, while the SO2 enriched off-gas is carried out of the furnace for heat recovery and H2SO4 production. Operation of the furnace is achieved by adjusting a limited number of control variables. The main variables are the blast feed rate, blast oxygen enrichment, SiO2 flux feed rate and CH4 combustion rate (CH4 is used when the chemical energy of the concentrate is low) all measured relative to a set feed throughput. (Davenport & Partelpoeg, 1987; Davenport, King, Schlesinger & Biswas, 2002) The batch tapping nature of flash furnaces makes operation difficult because these control variables impact each other, and product quality can only be measured when matte and slag are tapped from the furnace. This means that operation of a furnace is based on feedback control from matte and slag assays. Because of the time-delay associated with understanding product quality, there is interest in using technology to monitor the combustion reactions that happen in the furnace reaction shaft.

Jan 1, 2019

By S. Klein, D. Crouthamel, D. W. Farmer, S. H. Phillips

Groundwater inflows during construction pose one of the greatest risks to the successful completion of tunnel projects. Inflows can result in safety concerns, difficulty in mining and ground support, impact sensitive environmental habitats, create surface settlement and increase costs. Adequately planned pre-excavation grouting programs benefit both the Owner and Contractor in reducing risks and controlling project costs and potential schedule delays. This paper outlines strategic guidelines for assessment of site conditions for pre-excavation grouting hard rock tunnels. It also describes the design of pre-excavation grouting programs with respect to project requirements.

Jan 1, 2005

By Christa Overby

As part of the City of Portland, Oregon?s East Side Combined Sewer Overflow Tunnel Project, nine separate 2,130 mm (84-inch) diameter reinforced concrete pipe microtunnel drives totaling approximately 2,380 m (7,808 ft) are being constructed to divert flows from several of the existing outfalls to the main tunnel. The drives were constructed in challenging ground conditions that include soft soils under the ground-water table, large amounts of wood and metal debris, and close proximity to sensitive structures. While all of the drives will be addressed, the focus of the paper will be on the 931 m (3,055 ft) continuous drive connecting Outfall 46, currently the longest microtunnel driven in North America.

By B Powell

Coastal acid sulfate soils (ASS) are wetland soils and unconsolidated sediments that contain iron sulfides which, when exposed to atmospheric oxygen in the presence of water, form sulfuric acid. ASS form in protected low energy environments such as barrier estuaries and coastal lakes and commonly occur in low lying coastal lands as Holocene marine muds and sands. When disturbed, the iron sulfides in these soils can oxidise and produce large volumes of sulfuric acid (essentially similar chemistry to acid rock drainage with mines) resulting in the subsequent release of toxic levels of iron, aluminium, manganese and possibly heavy metals. This results in detrimental effects on aquatic biota, plants, animals and steel/concrete structures and on human health in the surrounding environment. There are an estimated 2.3 million ha of ASS located along 6500 km of the Queensland coastline. In contrast to many mineral sulfides encountered in the mining industry, the pyrite crystals in ASS can be as small as 2 mm and commonly occur as framboids with extremely large surface area per unit mass, substantially increasing their reactivity if exposed to air (oxidation). Highly reactive iron monosulfides can also occur, particularly in drains and shallow lakes. Many coastal areas, where some 80 per cent of the population of Queensland reside, are coming under pressure for agricultural and urban development. Construction of canal estates, marinas, housing/industrial estates, roads, golf courses, aquaculture ponds, sand/gravel extraction and drainage for sugar cane can disturb ASS and release sulfuric acid, which may then drain into adjacent waterways with heavy rain. As development continues to encroach on coastal lowlands, the identification, quantification and management of ASS must be addressed as part of a commitment to the principles of Ecologically Sustainable Development (ESD). ASS can be successfully managed by adopting best practices and following guidelines, but government, community and industry must collaborate to raise awareness, avoid æhot spotsÆ and develop more cost-effective solutions. Scientists led the education and public awareness program showing infrastructure and environmental damages arising from ASS in Queensland. Using results from mapping and research, they convinced policy makers, industry and polititians to accept the need for legislation founded on good science. The resulting æState Planning Policy 2/02: Planning and Managing Development Involving Acid Sulfate SoilsÆ identifies the StateÆs interest in acid sulfate soils. The Queensland Government considers that development involving acid sulfate soils in low-lying coastal areas should be planned and managed to avoid potential adverse effects on the natural and built environment (including infrastructure) and human health. SPP 2/02 states where the policy applies and when a development application will trigger the policy. It can also be used to assist local governments in preparing their planning schemes under the æIntegrated Planning Act 1997Æ. The SPP 2/02 comes with a æState Planning Policy 2/02 GuidelineÆ to provide advice and technical information on interpreting and implementing the SPP 2/02. This guideline has legal status in assisting in the interpretation of SPP 2/02. Those seeking more detailed technical information can now also access the æSoil Management GuidelinesÆ and ASS æSampling GuidelineÆ, available from the Department of Natural Resources and Mines website. These are some of a series of chapters being developed for the æQueensland Acid Sulfate Soil Technical ManualÆ.

Jan 1, 2003

By M. J. Nicol

The kinetics of the dissolution of colloidal silver in aerated cyanide solutions has been investigated with the aim of developing a relatively rapid and convenient method for monitoring the ?leaching power? of solutions typically used in the cyanidation process. Experimental results obtained are consistent with an electro-chemical model, in which the mixed potential is set up in the active region of the polarization curve for the anodic dissolution of silver, giving rise to a rate of dissolution which is controlled by the rate of mass transport of either cyanide or oxygen to the surface of the silver. The rate of dissolution of colloidal silver was found to respond to variations in the reactant concentrations in a similar manner to gold (and silver) in a typical free-milling ore. The use of this technique for the monitoring and control of the cyanide leach process is discussed.

Jan 1, 1998

Study on Separation Technology for Copper-Molybdenum Collective Concentrate

Sep 13, 2010

By Thomas C. Anderson

Thirty-four retaining walls are part of the $46 million upgrade of a 1942 depressed highway in Highland Park, Michigan near Detroit. This project will close a missing link between two newer roadways, I-75 and the John Lodge Freeway. The existing 75 ft. wide, six lane Davison Freeway is being replaced by a eight to ten lane, 200 ft. wide depressed highway in a limited right of way. The highway will be 20-25 ft. deep and 1.5 miles long. A design/build decision by the Michigan DOT saved about 37% of the engineers estimated cost of $19 million for the walls. The successful pre-qualified specialty contractor utilized an innovative solution for the walls consisting of tiedback/cantilevered walls on the north side and mechanically stabilized earth walls on the south side. All of the walls have an identical cast-in-place architectural facing.

Jan 1, 1999

By J. Ronald Lawter

The purpose of the work described in this report was to measure the effects of diesel engine emissions on the air quality of work areas in a coal mine. Concentration measurements of a number of diesel related air contaminants were made at the Martin County Coal Corporation Mine in Inez, Kentucky. Compounds measured included carbon dioxide, carbon monoxide, formaldehyde, nitric oxide, and nitrogen dioxide. In addition, concentrations of the two classes of odorous compound;, aromatic hydrocarbons, and oxygenates were obtained along, with aldehyde concentrations. Surveys were made of the mine by odor analysts to determine the perceived intensity of diesel-produced odors. It was found that the concentrations of the measured species were well below their Threshold Limit Values. Odor intensity levels in the moderate to strong range were observed in the mine.

Jan 1, 1977

By Samuel Canchaya Moya

Si bien en las últimas décadas se aplicó el estudio de la geoestadística en la minería, el uso de la técnica no ha logrado una mayor difusión. En ese sentido, el presente texto señala la aplicación de los paquetes de software en la minería a través de los módulos de geoestadística. En este punto, la optimización del muestreo, se convierte en un problema tanto en la etapa de exploración como de producción. Por ello, es necesario conocer y comprender los conceptos y métodos geoestadísticos que se apliquen a la medida de muestreo de la veta, ver distancia y ubicación de taladros, costos de campaña de exploración, entre otras medidas, etc.

Jul 31, 2003

By N. Yamazaki

The supply of clean copper ores, which have high copper concentration and low impurities like arsenic, has declined year by year. Therefore, both mine and smelter sides have to consider how to remove impurities like arsenic. We focus herein on arsenic as an impurity because it is an extremely important issue from the environmental point of view. Approximately 150,000 t of arsenic is input into the copper industry every year. A small part of it is mainly treated in the smelting side. For instance, Ministro Hales Limited, which is a mining corporation in Chile, has performed the calcination process to remove arsenic from ore with high-arsenic content. In the process, flue gas is washed by water, and the final residue is treated by a hydrometallurgical process. Many processes for arsenic removal in various stages have been proposed, and several bottlenecks exist to achieve it. One of the difficulties encountered is getting an assessment of the process, which depends on the countries and/or areas of operation. The standardization of the assessment procedure will be desired in the near future to keep the same environment standards all over the world, and now is the time to start making discussions on this matter. This will be the first step in making an international assessment procedure for arsenic treatment in the copper industry. INTRODUCTION Using the term “sustainable development” without any scientific basis can give people a false sense of security. Engineers and scientists must analyze the total mass flow of energy and materials and estimate local drain on the environment as well as the global impact of a particular industrial activity to ensure sustainability on this planet. The operations of the mining and smelting industries have a strong effect on the environment even if they provide useful materials for human beings. The copper mining and smelting industries have brought about serious environmental problems in the past. For example, the Ashio mine pollution caused big damage to the agricultural sector near the Ashio area in Japan in the late 19th century. One of the most serious problems at that time was SO2 emission because copper ore is sulfide, and the smelting process basically results to sulfur oxidation. The resource balance from a copper smelter in a year, assuming a total production of 16 million tons, can be summarized as follows: discarded minerals, 30 billion tons; sulfur, 16 million tons; iron oxide, 8 million tons; additional smaller amounts of other metals, electricity, and fuel.

Jan 1, 2019

By J. B. Dyess

TARNISH films on some of the common metals (particularly on copper and silver) have been of much scientific and commercial concern for a long time, but before the development of the electrical method1 of measuring film thicknesses there was no satisfactory quantitative approach by which to study the separate parts of these complex films. This method has been adapted to the measurement of duplex (cuprous-cupric) oxide films on copper .2 In the present work it has been used to measure tarnish films on copper when they were mixtures of cuprous oxide and cuprous sulphide, and also when they contained cuprous oxide, cupric oxide and cuprous sulphide, each component part being measured at a different potential value. Oxide-coated copper specimens, prepared by heating copper in air at chosen temperatures for given periods, were exposed to moist hydrogen. sulphide in air to form the various oxide-sulphide films studied. The comparative resistances afforded by (1) different thicknesses of oxide films, and also (2) equal thicknesses of oxide and sulphide films, against severe attacks of hydrogen sulphide were measured. The electrical method requires that the time be observed for the cathodic reduction of each part of the film substance, and these respective time values multiplied by the constant current give the corresponding quantities of electricity expended. Then each millicoulomb per square centimeter represents a film thickness of T= MX10 8 2D X 96,494 X 103 (a) where M is weight of oxide (or sulphide) giving one gram-atom of oxygen (or sulphur) for cathodic reduction, D is density of the oxide (or sulphide) and t is the thickness in Angström units per millicoulomb per square centimeter. The value of t for cuprous sulphide (cubical) is 14.27, and is obtained by substituting 5.78 for D and 159.20 for M in equation a. Previous values2 of t for cuprous and cupric oxides (12.36 and 6.39, respectively) were used in the present work.

Jan 1, 1939

By R. Grimard, M. Gamache, L. -P. Bigras, P. Cohen

This paper describes a real-time fleet management system for an undergroun mine. Dispatching, routing and scheduling are handled simultaneously, taking into account the mine status, operational constraints and vehicle location information. Each assignment decision takes into account the traffic on the road segments of the mine network, whether road segments are bi-directional or uni-directional, and ensures that each LHD (load-haul-dump) vehicle arrives at loading and dumping points with the correct orientation. Such a system can be used either as a simulation tool for strategic planning or as a real-time managing and optimizing system for operations. In the simulation mode, the system can accurately estimate the impact on productivity of decisions such as the development of waiting areas (bays, sidings), or the addition (elimination) of vehicles to the fleet in operation. When used for real-time dispatching, routing and scheduling of vehicles, the system can optimize production with respect to various assignment criteria such as cycle-time minimization or deviation from a target production plan.

Jan 1, 2004