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Safety is the No. 1 concern of any drill contractor or mine operator. Everyone in the industry knows a safe site helps stabilize operational costs and enables higher productivity. When it comes to exploration drilling, research has proven a majority of injuries are caused by the mishandling of coring rods. A driller helper will typically handle up to 50 rods per shift or up to 15,000 rods per year. With an annual 340 t (750,000 lb) in rods managed by hand, the risk of serious injury is extremely high. Because of this, the top request from the exploration industry is diamond rod handling. The Boart Longyear 4200 surface exploration drill, slated for release in 2009, will give the industry a hand-free, operationally safe rig.. Developed through the collaboration of its global drilling services and products divisions and targeted at the 1,200-m (3,900-ft) NQ market, the upcoming Boart Longyear 4200 surface exploration drill features the safest and most flexible rod management sys-tem in its class. The rig includes the industry?s first, truly hands-free rod handling system. This increases operator safety on the jobsite. In addition to the rod handler, the rig also features many new innovations that boost productivity and rig efficiency while minimizing the risk of downtime due to component failure or operator error. Boart Longyear has also included an intelligent PC-based operating system designed to allow complete drilling control as well as diagnostics reporting for the rig.

Jan 1, 2009

By H. R. Hanley

The characteristics of alloyed anodes and their influence on the products of electrolysis and power consumption have been noted previosly ously in the literature.' This paper presents data in continuation of the subject given in an earlier paper by the authors.2 As noted in the authors1 previous paper, the objectives of this work are the reduction in the cell voltage and the purity of the cathode product resulting from the use of alloyed lead anodes. The fundamental facts developed in the previous paper were: (I) that the presence of a small amount of calcium lowers the anode potential approximately 50 per cent. below that of pure lead; and (2) that thallium when present to the extent of 4 per cent. rendered the anode practically stable, thereby lowering the contamination of the cathode by lead to a very insignificant amount. The specific features determined in this recent work are as follows: 1. The lowest limit of calcium in the lead which will still give maximum lowering of the anode potential. 2. The characteristics of the thallium-calcium-lead anode. 3. The characteristics of the silver-calcium-lead anode. 4. The characteristics of the thallium-silver-calciurn-lead anode. It was determined that 0.1 per cent. calcium in the anode was sufficient to lower the anode potential approximately 50 per cent. Table 1 shows the characteristics of alloyed anodes tested. The anode composed of 0.1 per cent. calcium, 4 per cent. thallium, and 95.9 per cent. * Professor of Metsllurgy, Missouri School of Mines. t Professor of Metallurgy and Ore Dressing, Hea.d of Department, Missouri School of Mines. Assistant Professor of Metallurgy, Missouri School of Mines. 1 Among others, see C. G. Fink and Li Chi Pan: Insoluble .Anodes for the Electrol-ysis of Brine [Trans. Amer. Electrochem. Soc., (1926) 49, 83-1341 and other papers by these authors. U. CJ. Taintori, 8. G. Taylor arid H. P. Ehrlinger: Lead Alloys for Anodes in Electrolytic Production of Zinc of High Purity. Truns. A. I. M. E. (1929) 192-200. 2 H. R. Hanley, C. Y. Clayton, D. F. Walsh: Investigation of Anodes for Production of Electrolytic Zinc. Trans. A. I. M. E. (1930) 275

Jan 1, 1931

By Fred Delabbio

There are presently several issues that the mining industry is facing, such as underground air quality, deep mining and green house gas emissions, which could be addressed by the application of alternate energies. Several aspects must be considered by the industry in any drive to introduce new technologies within the context of a producing underground mine. This article presents several operational and support aspects that will evaluate the relevance of alternate energies, with emphasis on hydrogen power systems: operational drivers, commercial supply of technology, site supply system requirements, health and safety, capital and operating costs, mine production, corporate philosophy, and role of government. It is concluded that introduction of alternate energy technology requires a step-wise progression: Applicability to the industry, proof of concept testing, development of generic infrastructure, power systems and regulations, whole system studies and detailed studies of cost and risk versus benefits. The current initiative to apply fuel cells is at the proof of concept stage, entering the generic infrastructure stage.

May 1, 2007

By Ching L. Wu, Joseph Penzien

An analytical procedure is presented for evaluating the stresses in linings of bored tunnels caused by kinematic soil-lining interaction. Three cases of interaction as produced by the following conditions are treated: (1) relaxation of in situ soil stresses near a lining following its installation; (2) overburden pressure at the soil surface; and (3) free-field soil response resulting from an earthquake. Non-dimensional formulas and graphs resulting from parametric studies are presented for practical tunnel design applications. The procedure is applied separately to a steel lining and a concrete lining for a site located at the lower end of Market Street in San Francisco through which a BART (Bay Area Rapid Transit)tunnel passes.

Jan 1, 1997

By Brian Stump, David Anderson, D. Craig Pearson, Robert Martin

Mining explosions designed to move, bulk or fracture rock are often composed of a number of explosions arranged in a complex spatial and temporal pattern. The effects of the explosions are strongly dependent upon the design and implementation of this blasting pattern. This paper describes the collection, combination and visual display of multiple types of data from these explosions for the purposes of understanding the relationships between the blast design, implementation, and observations. Data sets consist of three-component ground motion, acoustic, video and high speed film, three-dimensional topography, geological and geophysical properties, design blast pattern and timing, and velocity of detonation in the explosive for individual borehole detonation times. The explosions studied include simple single-fired contained explosions, ones designed to bulk and fracture rocks and those that cast material.

Jan 1, 2000

Recovery of Fine Gold Particles from Philippine Gold Deposits by Enhanced Gravity Concentration and Flotation The objective of the study is to determine the applicability of enhanced gravity concentration (EGC) and flotation for gold recovery. While gravity concentration methods have long been applied to gold ores, especially to free-milling types that requires minimal beneficiation, flotation for gold recovery has not yet taken hold as a major operation in the Philippine setting. In this study, the application of EGC and flotation for gold is applied and compared to the existing methods for gold recovery. Two samples, with assays of 7.315 and 5.333 g Au/MT (samples 1 and 2, respectively) are used for this study. These samples are subjected to mineralogical studies and is found to have a gold-particle size ranging 10 to 200 microns. To verify the separation size, the mesh-of-grind (MOG) is used as the primary parameter for experimentation. Initially, the samples are stage-crushed, ground, and subjected to EGC using a Falcon SB40 Concentrator. Based on the results, the two samples showed that recovery increases with a finer MOG. The ratio of concentration (K) decreases with a finer MOG. This shows that there should be sufficient liberation of the gold values for EGC to be effective. The effect of the enhancement is to pronounce the difference in specific gravity of the minerals, promoting better separation. This is validated by the high recovery values of 86.97 per cent and 98.73 per cent exhibited respectively for samples 1 and 2 (at 54 microns). For the flotation runs, sample 2 with an average particle size of 80 per cent passing 74 microns is examined using thiocarbamate-based collectors for roughing and subsequently exhibited a recovery of 96.32 per cent. At this point, the concentration ratio (K) is noted as an important efficiency indicator for flotation process since it yielded a very low-mass and high-metal content concentrate.

Sep 13, 2010

Sluiceboxes can provide a much higher concentration ratio than most other gravity concentrators (up to 50 000:1) at very high overall placer gold recoveries (greater than 99 per cent). They are also very reliable, inexpensive and simple to operate. This combination is very difficult to beat and explains why the sluicebox is still the most important placer gold concentrator in northwestern Canada, Alaska and the rest of the world. A sluicebox is a rectangular fl ume containing riffles on matting, through which a dilute (<12 per cent) slurry of water and alluvial gravel flows. Sluiceboxes are actually centrifugal concentrators with settling velocity playing a minor role in gold recovery. Due to their higher density, gold particles tend to segregate to the bottom of the slurry flow where they form a streamline that is diverted by a low pressure zone into a riffle. Under ideal conditions, this ribbon of slurry will be overturned as it flows down the rear of the following riffle and will continue fl owing in a circular path to form a vortex. At the bottom of this vortex, centrifugal and gravitational forces combine to drive gold particles into or beside the matting. To remove the gold concentrates, sluiceboxes are shut down and the riffles and matting are taken apart and cleaned. The slurry velocity provides the energy that powers the vortex. If the velocity of the slurry is reduced through overloading with solids, insufficient water flows or shallow gradients it may not sustain a full size vortex. If the riffles are too close, too far apart, too tall, or if there is not enough energy available to the vortex, the vortex will not be formed properly and gold recovery will be reduced. If the slurry velocity is too high, extreme turbulence and the resulting scouring will also cause gold losses. Testing sluiceboxes with conventional sampling and evaluation techniques is very costly, time consuming and problematic. Most placer gold ores contain a very small number of gold particles in a large volume of pay gravels. Sluiceboxes can lose coarse gold particles. The presence or absence of one of these particles in a tailings sample can lead to high unpredictable errors (nugget effect) even when large sample volumes are processed with care. Every time conventional samples are upgraded, additional errors are introduced due to the inefficiency of recovery equipment. Nuclear tracer tests are more accurate, faster, cheaper and safer than conventional sampling. In 1989 through 2002, the recovery efficiency of dozens of sluicing systems was determined by mixing radioactive gold particles (tracers) into the feed streams of dozens of placer mines in the Yukon Territory, British Columbia, Alaska and Guyana. Four distinct sizes of nuclear tracers were used and their recovery was related to the design and operational characteristics of the individual sluiceboxes and their pay gravels. At clean up, scintillometers were used to detect the very low level X-ray and gamma ray radiation emitted by these tracers and locate them in the sluice runs. The effectiveness of any given section of riffles was easily diagnosed by the presence or absence of tracers. At every mine the gravel feed rates, water flows, equipment dimensions and riffle performance were measured. After the gold tracers were removed from the fi nal concentrate and counted, the concentrate was sieved and weighed. These gold recovery, weight and sieve data were used to calculate the quantities and size distributions of the gold particles in the original pay gravels and those lost in the tailings. The expired tracers were stored in a lead lined container until their radioactivity was near background levels (about two months). The standard errors from these radiotracer tests were estimated from binomial probability theory with the equation: SE = {(n + p + q) ^ 0.5}/n. Where n was the total number of radiotracers added, p is the proportion recovered and q was the proportion lost. Each overall recovery estimate would be within one standard error of the true recovery value (14 times out of 20) and almost always within two standard errors of the true recovery (19 times out of 20). The maximum standard error with 100 tracers was five per cent and occurred when the recovery approached 50 per cent. With higher recoveries, standard errors usually ranged from one to two per cent.

Aug 1, 2010

Silver is one of the three major metals produced from the Broken Hill mines. The accurate determination of the silver in these ores, therefore, is of economic importance.With due appreciation of the divergence of opinion of many who are interested in the subject of the determination of silver, the writer has been prompted to present the results of some recent experiments on silver losses during cupellation and conclusions from these experiments in the present paper. The losses of silver in the fire assay for this metal are due to silver retained in the slag during the fusion or scorification of the ore, and to silver volatilized from, and absorbed by the cupel during the process of cupellation.The literature describing the results of experimental work on silver losses due to the above causes is extensive, and the general conclusion of these experiments is that the silver lost in the slag is small, but that lost by cupellation is larger and more variable.The term cupellation loss in this paper refers to the total cupellation loss, no distinction being made between the absorption and volatilization losses.Volatilization loss is shown by King to be 0.5% of the total cupellation loss and, as it is generally accepted among assayers as being only a small fraction of the cupellation loss (3) (5), it will not receive further consideration in this paper.The factors causing the loss of silver by cupellation and the precautions to be obs~rved to reduce the loss in this operation are described in (1), (2), (3), (4) and (5). The...

Jan 1, 1940

By Enrique Fernandez

M-30, Madrid’s inner ring, covers 42 sq km of the city centre where one million people reside. It was constructed in several phases during the sixties and the eighties. The design criteria applied to those phases were different and were not always homogeneous with urban roads with lighting regulation as well as speedways. These areas had a heavy concentration of access and exits and there had been made many changes on the number of traffic lanes which has caused heavy traffic congestions and high accident rates. The environmental impact and noise pollution in residential areas are also consequences of M-30. The Madrid Major took a decision at the beginning of the present legislation, based on socio economic and environmental evaluation; rebuild the M-30 with the following sustainable mobility principles: Underground transfer of a considerable portion of the main ring and some of its links replacing some parts of the surface with new green areas in order to reduce the environmental impact. Increase the traffic capacity, improving the traffic continuity and fluidity and eliminating the lighting regulation areas, which is one of the main congestion problems currently. Increase the traffic safety with clear signalling information panels and avoiding difficult maneuvering. Redesign the links with the high capacity radial highways and other connecting lanes of the city. The project is worth 3.7 billion Euros. In 2007, when the construction is completed, it is expected will save 14 million of journey hours that represent 4.5 million Euros saved in fuel consumption per annum, There will be a very significant reduction of 35,000 tons of CO2 in terms of pollution and 400 less car accidents. Those values will increase even more in the following years. The areas beside Manzanares River, running parallel to the M-30 on the western side of Madrid, will be highly enhanced. Better water quality and the recovering of the green areas existing in old times will also return for the citizen’s enjoyment. TUNNEL CROSS SECTION OF CALLE 30 SOUTH BY PASS One of the major challenges of the new Calle 30 is actually not only the related to the main road but also to the link with the A-3, with highway to Valencia. This link is currently the most congested area and has one of the highest traffic densities of Spanish roads, with more than 250,000 vehicles/day. The remodelling of this area is the principle objective of the South by-pass. The tunnel is the only answer for this by-pass as the road alignment will go among buildings. A twin tube design, one for each direction, with three lanes allowing the circulation of both, light cars and heavy trucks, is the solution that has been

Jan 1, 2007

The latest Draft MPRRB was released for public comment in October 2006. The main purpose of the Bill is to collect royalties at mines developed in terms of new-order mineral rights granted through the MPRDA process. The transition phase stipulated in the MPRDA will be completed by 1 May 2009, on which date mineral royalties will become payable to the state. The royalty rates stated in the MPRRB differ from mineral to mineral and also depend on the degree of refinement. Gold is the subject of this paper, where the royalty rate ranges from 1.5% (for refined gold) to 3% (for unrefined gold) of sales revenue. This royalty is payable regardless of profit, with a maximum 75% relief for loss-making mines. The purpose of this paper is to establish whether or not it would be necessary for gold mines to adjust their mineral reserve statements as a result of this Bill. The methodology is to add the royalty costs stipulated in the MPRRB to the actual quarterly information for the past ten years as reported by the gold-mine members of the COM. The rationale is to investigate the impact this Bill (in its current form) would have had on gold reserves that must be left unmined in the ground because of a higher pay limit. The results of the study point to a significant impact on reserves available for mining with the subsequent shortening of mine lives and retrenchment of workers. Had the MPRRB been effective for the 10 years prior to 1996, it would have resulted in 46 tonnes of gold being sterilised. Stated alternatively, 30 700 workers at COM gold mines alone would have lost their livelihoods.

Jan 1, 2007

By Nikolaus Schneider

"Abstract: The combination of failure in joints of diaphragm walls and their exposure to water pressure may have far reaching effects ranging from water leakage to the risk of catastrophic loss of stability for the retaining wall and civil structures behind it. Investigations of imperfect joints in diaphragm walls have led to the development and testing of a quality tool to monitor the joint integrity of diaphragm walls during construction. By applying independent mechanical sensors (“joint inspector”) to the steel frame of hydraulic or mechanical grabs, it is now possible to record the surface conditions of exposed primary joints during the construction of secondary panels. This allows for the implementation of corrective action during the construction process should joint quality not indicate a watertight connection to the adjacent panel. The joint inspector, used for different types of stop ends, was tested on a full scale test field at several construction sites. The implementation of this new quality tool drives a new quality standard for deep excavations in inner city areas.General introduction to diaphragm wallsDiaphragm walls are reinforced concrete elements constructed using bentonite slurry to temporarily support an open trench in the ground. They are used in two main fields of application in civil construction, as foundation elements for vertical and horizontal loads (barrettes) and as retaining walls for excavation pits.Particularly for deep excavation pits in inner city areas, diaphragm walls are used as temporary or permanent walls of retaining walls. Alternative retaining wall systems would be secant pile walls, sheet piles or soldier piles, but these have disadvantages in structural strength when compared to diaphragm walls. If the vertical load of existing buildings next to the excavation pit has to be accommodated, the most practical solution can be found using diaphragm walls supported by prestressed anchors, steel struts or slabs."

Jan 1, 2014

A detailed study of the capital investment and production cost for copper electrowinning plants shows that significant savings in both can be achieved by increasing the current density. From the economic analysis it is determined that the optimum current density which will result in lowest capital investment and lowest operating cost is between 60 A/sq. ft. and 70 A/sq. ft., or at least three times as high as the Conventionally employed current density. The specific investment, expressed as $/ton-year, is found to be a function of both the current density and plant capacity and has a minimum value at the optimum current density. Empirical equations are developed for the purpose of estimating the capital investment and operating cost for plants of any production capacity operating at any current density.

Jan 1, 1972

By Paul Semple

"In 2007, Noront Resources Inc. discovered the high grade nickel copper PGE deposit in northwestern Ontario in a region now known as the Ring of Fire. Since the initial discovery, Noront has advanced the Eagle¹s Nest Project and in September 2012 released a feasibility study for the development of the Eagle¹s Nest Project. This paper summarizes the results of this recent study and outlines additional work planned in the next stages of project development. INTRODUCTIONThe following paper summarizes the findings of the recently completed feasibility study on Noront Resources Ltd.’s Eagle’s Nest Project. The feasibility study was compiled into a NI 43-101 report by Micon International. This paper is intended to summarize the major technical findings and for complete information, interested parties can find the entire NI 43-101 report at www.norontresources.com or on SEDAR.LOCATIONThe McFaulds Lake project area, which includes the Eagle’s Nest deposit, is located at approximately UTM 5844000 N and 547000 E, and between approximately 52º42’ and 52º50’ N latitude and 86º06’ and 86º24’ W longitude, approximately 250 km west of the community of Attawapiskat on James Bay and 575 km northwest of Timmins. The closest all-season accessible community to the McFaulds Lake project area is Nakina, 300 km to the south, where there is a paved airstrip, in addition to all weather road and railroad access (see Figure 1).The First Nations communities of Webequie and Ogoki/Marten Falls are located 90 km west and 120 km south southeast of McFaulds Lake, respectively. Both communities are served by regularly scheduled air service, primarily from Thunder Bay; both Thunder Bay and Timmins serve as support centres for the James Bay communities and the exploration projects in the area."

Jan 1, 2013

By S. J. Frank

Ferroalloy furnaces are well known to be extremely difficult to control from a metallurgical perspective. Mostly metallurgical control is still reactive in nature, causing a significant amount of reworking and product blending to achieve a proper product specification. Despite numerous efforts towards the model based control of primary smelting operations, actual metallurgical feed forward control seems to remain elusive. One of the key reasons in the failure to model these metallurgical reactors well, is that fundamentally orientated pyrometallurgists, statisticians, data miners and control engineers very often have diverging ideas how to model these systems. Furthermore, metallurgists have often come to rely on their ability to develop empirical regression models of furnace behaviour, as they have lost their faith in the ability of thermochemical and metallurgical engineering fundamentals to accurately predict the outcomes from furnaces. This paper shows how good thermochemical modelling can be combined with proper technological and systems analysis, as well as a proper inventory model, to predict the alloy and slag chemistry with good accuracy one tap into the future, at a time horizon of typically around 4 to 6 hours. For this modelling approach, a number of tools will be used, such as data reconciliation, thermodynamic modelling using Fact Sage®, inventory and heel estimation, neural networks and statistical data exploration. Furthermore, systems identification theory will be combined with the approaches given above to develop a truly dynamic predictive model. This paper seeks to demonstrate the need for a hybrid approach, which incorporates plant data and readily accessible thermodynamic data to develop a proper dynamic model.

Jan 1, 2004

By Dale S. Preece, Lee M. Taylor

Accurate computer prediction of the muck pile produced by a conventional blast requires modeling of the physics that occurs during the rock motion phase of a blast. The ability to predict the motion and the subsequent muck pile can have a significant economic impact on the mining industry.

Jan 1, 1990

By Steve Signer, Ed Mchugh

Recent studies by researchers from the National Institute for Occupational Safety and Health indicate that shear loading contributes significantly to failure of bolts used for rock reinforcement in coal mine roofs, Laboratory tests on 17 bolts were conducted to study the behavior of roof bolts subjected to shear loading over a range of axial bolt loads, Fourteen strain gauges were attached to each bolt to measure axial and bending loads at seven locations along its length. The instrumented bolts were grouted through two high-strength concrete blocks, and axial tension was applied to as much as 75% of yield strength. With the block interface acting as a failure plane, shear loads were applied to the blocks at a constant rate of displacement to the ultimate strength of the bolts. The tests characterized the relationship of axial bolt loads to shear forces across a rock bedding plane and measured the distribution of axial and bending strain along the length of the bolts. 'These results will improve the selection of roof reinforcement in mine areas where high shear stresses are present, thus improving the safety of miners working in these areas.

Greater use should be made of lineations in investigations of the engineering properties of rock masses and in structural studies guiding prospecting programmes.A prominent alignment of elongate mineral grains and stretched pebbles usually marks the primary direction in which metamorphic rocks have been extended by flow. In local adjustment zones separating masses that have extended different amounts, this lineation has been a direction of slip. Kinks and crumples resulting from this slip lie in secondary lineation directions transverse to the primary mineral lineation.During deformation relatively mobile materials move into dilatant zones caused by irregularities in primary flow directions. This secondary movement transverse to lineated, primary-flow directions is the cause of crenulations and folds with axes parallel to flow lineations.INTRODUCTIONThe arrangement of inequidimensional particles in rocks is rarely statistically random. Platy minerals tend to be parallel to bedding and foliation planes. Elongate particles and linear structures lie most frequently in certain lineation directions. The types of elongate particles in lineated rocks include needle and blade shaped mineral grains, sheared out segregations, and stretched pebbles, amygdules, and aolites.Crenulations and kinks are the most common of the linear structures involved.Faint lineations are readily overlooked. Even strong lineations have been ignored. This is unfortunate as even weak lineations may be important.Use of lineation information Well-developed lineations influence the mechanical properties of rocks. Quarry workers have long known that the mechanical properties of rock masses vary directionally...

Jan 1, 1965

By Edgardo Torres Hernández

El Proyecto Optimización de Ángulos de Taludes en Explotación de Minas es un proyecto desarrollados por E-Mining Technology (EMT), socio estratégico de Prodimin en Perú, para Codelco Chile en uno de sus yacimientos del Norte de Chile. El desarrollo de este proyecto estuvo enmarcado en el Programa de Proveedores de Clase Mundial; programa que tiene como misión desarrollar un sector de proveedores intensivo en conocimiento, mediante la generación de soluciones tecnológicas empujadas desde la demanda de la minería y desde la propuesta del sector de proveedores que puedan ser escaladas a otros sectores y mercados.

Sep 1, 2017

Triboelectric Charge and Separation Characteristics of Industrial Minerals The basic principles of triboelectric charge and separation of minerals and the factors affecting the entity of the charges developed on mineral surfaces are discussed and the surface pretreatment methods by which the electrophysical properties and thereby triboelectric charging and separation of minerals can be artificially altered/modified are reviewed. Furthermore, the triboelectricfication theory of materials is envisaged from the chemical concept of acid-base donor-acceptor and an attempt is made to correlate the physical concept of triboelectrification with the donor-acceptor properties. The triboelectric charge characteristics of the quartz, calcite and wollastonite mineral samples for different size classes were defined using different tribocharging medium. Based on the triboelectric charges acquired by mineral samples their energetic work function values are estimated. In addition, the main electrophysical properties, ie dielectric constant and electrical conductivity, of different size fractions of the mineral samples are measured and their donor-acceptor chemical properties were defined. A series of triboelectric separation tests were conducted to explore the possibilities for separation these mineral from each others. The results from the triboelectric charge and separation of the single mineral systems showed promising prospect in separating quartz, calcite, and wollastonite from each others. Finally, attempts were made to explore the possibilities to implement triboelectric charge and separation process to real ores. Promising results achieved when separation of calcite from silicate impurity was sought from a carbonate ore. A very high purity (99 per cent) calcite product was obtained at a recovery of 80 per cent. Interesting results were also achieved to concentrate wollastonite from a complex silicate ore containing quartz, different feldspars, wollastonite and other Mg-Fe silicates. In this case conditioning of the ore with salicylic acid at defined temperature and relative humidity was found to be essential to concentrate wollastonite. The outcomes indicate despite the fact that triboelectric charge and separation process has not been completely perceived, it pronounced to be an environmentally friendly and economically viable technique for minerals and wastes beneficiation. Being a dry beneficiation technique the process has special appeal, which must be explored further in particular for treating industrial minerals.

Sep 13, 2010

By B. A. Wilcox

ThERE are several reports in the literature which indicate that both solid-solution hydrogen and hydride precipitates can promote low-temperature em-brittlement of tantalum.1-3 For example, Imgram et al.2 showed that hydrogen additions in the range of 140 to 580 ppm promoted a ductile-to-brittle transition at slightly above room temperature in both wrought and recrystallized tantalum. This contrasts with the observation that tantalum of norma1 purity is very ductile, even at liquid-nitrogen temperature. Imgram et al. also found that hydrogen additions caused a deterioration of notch tensile properties of tantalum. The purpose of this communication is to present some limited evidence that hydrogen can also cause fatigue embrittlement of tantalum. The material used in this investigation was wrought, stress-relieved (1000°C, 1 hr), are-melted tantalum rod (5/8-in. diameter) containing the following impurities in weight percent: 0.005 C, 0.007 02, 0.0005 H2, 0.003 N2, 0.08 Cb, 0.01 W, and 0.01 Fe. Hydrogen charging was done in an atmosphere of flowing dry hydrogen for 3 hr at 600°C, followed by an homogenizing anneal in purified argon for 15 min at 600°C, and cooling in an argon atmosphere. Typical micro-structures of the hydrogen-free and the hydrogen-charged materials are shown in Fig. 1(a) and Fig. 1(b), respectively. Fig. 1(b) shows the appearance of hydride precipitates which, in many cases, formed preferentially parallel to the rod axis. The hydride dispersion was uniform across the diameter of the specimen. The fact that the precipitate was a tantalum hydride was tentatively confirmed by X-ray diffraction on a metallographically prepared surface. After hydrogen charging, chemical analyses by vacuum fusion revealed the hydrogen content to be 0.0295 wt pct. In addition, the oxygen and nitrogen contents were slightly raised to 0.0095 O2 and 0.005 N2.

Jan 1, 1964