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By R. L. Grayson

Following lip on a USBM-sponsored research project, the authors have utilized the knowledge-base structure and system concepts from the Sun Sparcstation-based worker scheduling system of the Mine Management Support System to develop a PC-based application. The new software adopts the nested-window concept to facilitate data collection and modification on personnel, their availability on a shift, and work priorities for a shift as well as to allocate manpower optimally on a work shift and delineate supervisory training responsibilities. The various components of the software are described in detail, along with enhancements made to the original system.

Jan 1, 1996

By Wei Han, Zhenwei Liu, Jianhong Yang, Qingwei Qin, Tiejun Chen, Zili Huang

The preparation of industrial ammonium molybdate from molybdenum concentrate was conducted according to the process of roasting—leaching—purification—precipitation—crystallization. The optimum technological conditions were determined: the roasting temperature was 680 degrees C, the roasting time was 2.5 h; in the leaching process the alkali excess coefficient was 1.2, the reaction temperature was 80 degrees C, the liquid-solid ratio was 3:1, the leaching time was 3 h; the amount of (NH4)2S added into the solution was 1.1 times of the theoretical amount, the temperature was 80-85 degrees C, and the terminal pH was 8.5-9 in the purification process; the density of the solution was 1.4-1.6 g/mL, the pH was 1.5-2 in the precipitation process; temperature of dissolution was controlled at 80-90 degrees C. The recovery of the preparation of ammonium molybdate can reach 85.18%.

Mar 1, 2017

By D. P. Patil, B. K. Parekh

Water is the mainstay for beneficiation of fine size coal and minerals; however, it is also the least desirable constituent in the final product. The basic concept of the novel process described in this paper is based on the differential surface heat conduction/ absorption capacity of individual particles, which differs for different species of minerals. When a mixture of fine material is exposed to a radiant energy source, the various solids present in the mixture will absorb heat energy depending on their heat-conducting properties and there will be a difference in the surface temperature of the particles. When this differentially heated solid mixture is placed on a moving belt, which is coated with a low temperature melting resin, the hotter component of the mixture will stick to the belt and relatively cooler particles will stay free on the belt and fall off at the end of the belt run. Experiments were conducted with pyrite, coal, and quartz of 6 × 18 mesh particle size. The goal of the test program was to find the optimum conditions at which there exists a required temperature difference between minerals and coal particles by controlling the operating system variables. Preliminary tests results showed that there is a potential for separating mineral matter from coal using the thermo-adhesive separation technique.

Jan 6, 2022

Arsenic bearing minerals such as enargite (Cu3AsS4) and tennantite (Cu12As4S13), which may associate with major copper minerals such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and bomite (Cu2FeS4), usually report to the copper concentrate in conventional flotation due to their similar flotation properties. Arsenic in a copper concentrate causes environmental problems and also problems in the subsequent pyrometallurgical process. Voltammetric studies were carried out to investigate the oxidation characteristics of enargite, tennantite, chalcopyrite, chalcocite and bomite. Contact angle measurements and micro-flotation tests were conducted to examine the flotation characteristics of enargite and chalcopyrite under controlled pulp potentials. Selective flotation of enargite from chalcopyrite under varied pulp potentials was conducted to investigate the feasibility of arsenic removal from a copper concentrate. The test results indicate that the non-arsenic bearing copper minerals ( chalcopyrite, chalcocite and bornite) were easier to oxidise than arsenic bearing minerals ( enargite and tennantite) in an alkaline solution. Enargite floated well at a potential as high as +0.45 V vs. SCE while chalcopyrite was completely depressed at a potential higher than +0.43 V vs. SCE. Selective flotation revealed that enargite can be successfully removed from chalcopyrite through controlling the pulp potential at +0.30 ~ +0.50 V vs. SCE.

Jan 1, 2007

By Larissa Agrizzi Ronqueti

The effect of coiling temperature on selective oxidation behaviour of binary and ternary iron-based model alloys containing different contents of Si or Mn were investigated by SEM and SIMS. The experiments were carried out with a temperature ranging from 450 °C to 700 °C, under N2-5%H2 gas flow with a Dew Point of -3.3°C, for different durations. SEM images of binary iron-based model alloys revealed a decrease of grain boundary oxidation depth with increasing Silicon or Manganese content. At 530°C and 600°C SIMS results showed no Silicon diffusion toward surface, contrary to the results analyzed for Fe-x%Mn. Tests results and Wagner’s theory application (specific cases Fe-0.2%Si and Fe-0.5%Si) showed that grain boundary oxygen diffusion coefficient “DoGB” is almost 60 to 70 times faster than oxygen bulk diffusion coefficient. These results helped to broaden knowledge of single-element effects on grain boundary oxidation, in addition, will contribute of the future works in new steels with complex alloy compositions.

Aug 17, 2017

By Zainab Nasrullah, MontanaFrank Agyemang, Mehran Sadat, Richard LaDouceur

Rare earth elements (REEs) are valuable for various modern technological applications, including metallurgy, machine building, radio electronics, instrument engineering, nuclear engineering, and manufacturing. The extraction and separa-tion of rare earth elements (REEs) from their complex ores is challenging due to their distinct physical and chemical properties, contributing to their market scarcity. At present, REE recovery utilizes traditional pyro- or hydrometallurgi-cal processes. The overall process in the recovery and sepa-ration of individual elements from complex REE systems suffers from high energy demands and the use of many haz-ardous chemicals that negatively impact the environment. With the growing trend toward a circular economy aim-ing to balance sustainability, efficiency, and environmental impacts, this research is focused on using deep eutectic sol-vents (DESs): a combination of a quaternary salt: Choline Chloride and five organic acids: Oxalic Acid, Urea, and Ethylene Glycol, Lactic acid and Glycerol for the selective leaching of REEs from their complex ore which is proven to be green, selective, non-toxic, biodegradable, and cheap. The effects of different DESs and leaching time on the REE leaching efficiency were determined, and the optimum DES media were found to be Oxaline and Lactic Acid at which a leaching efficiency of 25% and 15% was achieved at 80°C respectively for cerium.

Feb 1, 2025

By R. C. Gifkins, K. U. Snowden

The value of the index n in power ktivs for the stress sensitivity of minimum creep rale at lead is derived front results drawn from lite literature and from previously unpublished nork on commercial (99.99 pel) and high-purity (99.999 pel) lead polycryslalline and hi crystal specimens. In tests al 0.5Tm (22 to 50'C) for slvesses below 250 psi, n fulls to mily for poly-cr,yslullirle specimens, single crystals, and bicrystals, and toy grain boundary sliding in bicrystals. Between 250 and 500 psi there is a tyansilion range and, for the polycrystalline specimens al least, u high-stress regime for 500 to 1500 psi where n is 5 or 6. These results are such that none of the suggested stress taws can he used to extrapolate to very loir stresses. Meclianisms for deformation in Ike grains and toy grain boundary sliding in the low-strcss regime are outlined. In particular, the mechanism for grain boundary sliding involves sliding controlled by diffusion from tensile to compressire Ledges. predictions based on this model give promising numerical agree-nicul with experiment. II is suggested that the mechanism for grain boundary sliding may he important in other circumstances, e.g., in creep of ceramic materials or superplaslicity, because it can operate with lille or no dislocation aclirity. WhEN the stress dependence of secondary creep rate is represented by a power law the values taken by the stress exponent n are found to vary between 1 and 7, see, c.g., Garofalo.' In Eq. 1 11 u is the applied stress and A a constant. The case for accepting values of v = 1 rests principally upon tests at high temperatures (>0.9Tm) and there have only been isolated tests at lower temperatures (rather than plots of creep rate against stress) for which the creep rates are such that some form of Nabarro-Herring creep with n = 1 is applicable. Hanson5 and Greenwood and cole6 plotted creep rate against stress for tests made in the vicinity of 0.5Tw, and found a "creep yield", so that below a certain low stress the creep rate was linearly related to stress: these observations appear to have been subsequently ignored. Various models have been proposed which agree with a large body of experimental results in which n equals -5 at high stresses (e.g., weertman7 and McLean8). Various alternatives to Eq. [1] have been proposed principally as a means of unifying creep data, but sometimes, it seems, in order to obviate the necessity for assuming a series of regimes of deformation associated with the various values of n; further refer- ence to these will be made in the section on stress laws. This paper calls attention to extensive results which show n = 1 for the creep of lead at room temperature (0.5 T,). RESULTS Fig. 1 is a composite diagram based on figures in the literature6,9,10 with additional results obtained by the present authors and their colleagues11,12 in the course of a number of investigations not directly concerned with stress sensitivity. In Fig. 1 In creep rate is plotted against In stress. The curves show results for two kinds of material. Lead I is of commercial purity (99.99 pct Pb) and lead IT a specially refined material, hydrogen-purified to remove oxygen; it contains 99.999 pct Pb. Curve A is for lead I in polycrystalline form (grain diameter 0.02 to 0.05 cm) at room temperature (22' to 26°C). Curve B1 is for lead I, polycrystalline, tested at 50C. Curve B2 is for lead 11, polycrystalline (grain diameter 0.02 cm), tested at room temperature (22 O- Curves C to F relate to tests made of bicrystals of lead 11: all of the same nominal orientation ("Y" in Ref. 12). Curves C and V are for creep within the component crystals of the bi crystals at 22°C (AB and CD in Fig. 2). Curve E is for creep measured in a gage straddling the boundary, approximately 0.15 mm either side (BC in Fig. 2). Curve F shows rates of grain boundary sliding (as distinct from strain rates in the other curves), obtained by averaging the offsets of six marker lines on the bi-crystal boundaries. The principal feature of the results is that the stress sensitivity falls into two distinct regimes, according to whether the stress is below approximately 250 or above 500 psi (there is a transitional range between 250 and 500 psi). The new result is that below -250 psi two of the curves (A and BI) give a value of n 1, and the other curves also drop below n - 2 to -1.5 but do not extend to low enough stresses to show clear evidence of n 1. At very high stresses the curves tend to give values of n - 6, as previously determined in other investigations. Curve R2 for the high-purity lead in polycrystalline form at room tenlperature almost merges with B, and thus gives new significance to the values for stresses of 150 and 200 psi; previously'3 these points had seemed to fall away from the curve of slope -3, but they now can be seen as almost completing a transition to n = 1. It should be noted that there was originally considerable apparent scatter in the results for the high-purity lead. However, this was found to be associated with annealing conditions or variations in residual content of oxygen and curve B2 was constructed using the highest rate (i .e., the rate for the purest lead) determined for each stress during the course of various investigations over the years: altogether, some forty tests were used in constructing curve R2.

Jan 1, 1968

By Frank A. Peters

With the current renewed interest in advancing the technology for producing alumina from domestic raw materials, revisions of previous cost estimates to provide planning data are urgently needed. Completely new cost estimates on a 1973 basis are included for four alumina-from-clay processes and one alumina-from-anorthosite process. These estimates are based on new or previously calculated material balances, recalculated heat requirements, and new equipment designs. The use of larger and more modern equipment has permitted a significant reduction in labor requirements as well as equipment costs. Chemical prices, labor rates, and utility rates typical of late 1973 are used in these cost estimates. In addition to the revised cost estimates, all 21 previously published alumina evaluations compiled by the Bureau of Mines were updated to show the effect of inflation using an inflation index and late 1973 chemical prices, labor rates, and utility rates.

Jan 1, 1974

By Ottmar Burghardt

Sintering of iron ore has undergone a dramatic development world-wide. Today, the annual world production amounts to approximately 600 million tons. At present, the sintering process in competition with pelletizing, seems to offer certain advantages inasmuch as it allows the use of solid fuels. Also, its charging behaviour in the blast furnace is, in general, considered as being better than that of pellets. This is true, in particular, for the charging behaviour and the gas permeability in relation to the grain size. Moreover, instead of charging limestone into the blast furnace, for instance, the basic components which are necessary for the burden materials can generally be supplied in a simpler and more cost-effective way by using basic sinter instead of basic pellets. While in sintering, with basicity rising to the range of 1.6 to 1.8 CaO : SiO2, the capacity increases and the sinter quality shows improvements in most of its characteristics, the pro¬duction of basic pellets generally requires a higher fuel rate, when compared to acid pellets, while production capacity decreases and some of the quality characteristics deteriorate.

Jan 1, 1982

By H. A. Pearse

The history of the flotation process, as applied to the practical field of ore dressing, dates back somewhat less than twenty years; yet this fact may be overlooked in view of the present universal dependence on this process in the concentration of almost all classes of ore. It is therefore interesting to recall that Britannia was the scene of some of the earliest experiments with flotation on a commercial scale. In 1911, sixteen years ago, an Elmore vacuum machine was operated for several months with encouraging results. In 1913, some time before flotation was very generally adopted elsewhere, a Minerals Separation plant, capable of treating 600 tons daily, was operating successfully at Britannia. Considering how little was known of the theory and practice of flotation at that time, the recovery was remarkably good, but it was not until the present mill was completed in 1923 that any attempt was made to raise the concentrate grade by differential flotation, or, in other words, to float the chalcopyrite while rejecting the then worthless pyrite with the tailings. The first ore passed through the present concentrator in March, 1923. As originally designed, the rated capacity was for 2,000-2,500 tons, but this has been increased year by year, until at the present time 4,000 tons daily can be treated economically. During the first few months of operation the concentrate grade averaged only 10-11 per cent Cu, but by the end of 1923 this had been raised to over 20 per cent, due to the elimination of the pyrite by differential flotation. In 1923 the tailings averaged approximately 0.25 per cent Cu, but also in the matter of recovery a considerable improvement has been effected, for during the year 1926 an average tailing of 0.15 per cent Cu was maintained.

Jan 1, 1927

By F. Garcia, J. Cervik

Recent advances in the commercial separation of gases using membranes have renewed interest in the possibility of applying this technology to the recovery of methane ( CH4 ) from mining operations . This Bureau of Mines report briefly reviews the history of the development of membranes for gas separation , the theory of how they work , and their application to the separation of methane from air and associated problems . However , methane -air mixtures are difficult to separate with membranes because the pertinent gas couples , 02 - N2 , 02 - CH4 , and N2 -CH4 , have poor separation characteristics , as indicated by their separation factors of about 3 or less . Even if these separation factors were substantially higher , there is doubt that methane could be recovered economically from the low concentrations in mine ventilation exhaust ( 2 vol pct or less ) . The exhaust pressures are not sufficient for adequate separation . The power cost of compressing the methane recovered . these mixtures would far exceed the value of New discoveries could make separation of gob hole methane - air mixtures practical . These mixtures have much higher concentrations of methane (from 30 to 100 vol pct ) ; however , for safety reasons , be limited to gob gas with 60 vol pct CH4 or more .

Jan 1, 1988

By T. D. Barkand

A recent coal mine elevator accident resulted in serious injuries to four passengers. The miners struck the ceiling of the elevator car as it collided into the overhead structure at an estimated speed four times faster than normal. In response to mine hoisting accidents, safety authorities have required additional protective devices on new and existing mine hoists and elevators. This paper examines supplemental safety circuits and new devices designed to provide ascending car overspeed protection on mine hoists and elevators. These devices provide needed protection that eliminates the hazard or significantly reduces the potential of a mine hoisting accident.

Jan 1, 1995

By Stephen V. Thompson

Within recent years portable seismic refraction units have found their place in the industry for shallow investigations, Completely portable, relatively inexpensive and of proven accuracy, the portable refraction seismograph is an electronic tool in an electronic age. The age of electronic instrumentation has seen the development of seismic reflection and refraction equipment for deep exploration, especially in the petroleum industry. Large, expensive units, normally truck-mounted and utilizing explosives, are being used successfully for this type of sub- surface investigation. The portable seismograph utilizes the same theory for shallow work as that applied to deep refraction seismology.

Jan 1, 1964

By Márcio Nascimento Cunha

A presença de inclusões não metálicas em aços inoxidáveis é uma das possíveis fontes de defeitos superficiais, especialmente em produtos laminados a frio. Uma das alternativas para evitar as inclusões de óxido de alumínio em aços inoxidáveis é o rígido controle dos níveis de alumínio presentes nas matérias primas adicionadas ao aço. O presente trabalho tem como objetivo apresentar melhorias de qualidade superficial obtidas no aço ferrítico 430 estabilizado ao nióbio (0,20%Nb a 0,40%Nb) produzido pela Aperam através do uso de ferro-nióbio contendo menores teores de alumínio em relação ao produto padrão, desenvolvido especialmente para essa aplicação pela empresa fornecedora do material. Através de resultados industriais constatou-se uma evolução da qualidade com a redução no índice de desvios por esfoliação de 29%, enfatizando não só a importância do controle do teor de alumínio incorporado aos aços inoxidáveis como também um controle rigoroso de processo especialmente em aplicações de alto apelo estético, caso do uso em equipamentos da linha branca.

Jul 30, 2018

By Benjamin W. Haynes

This Bureau of Mines publication comprises a compilation of the state of the science in Pacific Ocean manganese nodule mineralogy and elermental composition. The report is divided into three sections: morphology, mineralogy and elemental composition. The nodule morphology section defines what is considered a nodule for the study, and details the external characteristics and internal structure. Nodule mineralogy is discussed in three sections: manganese minerals, iron oxide minerals, and accessory minerals. The major manganese minerals discussed are todorokite, birnessite, and vernadite. The iron oxide minerals are less well known and include feroxyhyte, goethite, and lepidocrocite. Accessory minerals present include quartz, clays, and other silicates and nonsilicates. A discussion on moisture content is also included. The elemental composition section presents data on 74 elements occurring as cations or anions. Summary data, histograms, and interelement correlation coefficients are presented. The elements are grouped as follows: major and minor elements of potential economic interest (8), other major and minor elements (9), elements of environmental interest (8), rare-earth elements (15), precious-metal-group elements (6), radioactive elements (3), other trace elements (17), and anion-forming elements (8). Cross sectional determinations of Ni, Cu, Zn, Co, Pb, Fe, Ce, and Ba are given for a single nodule to show the general tendency of different growth patterns within a nodule because of different element associations and composition.

Jan 1, 1982

By Izabela Diniz Duarte

O controle da temperatura do aço líquido desde o refino secundário até o lingotamento é condição essencial para alcançar alto nível de qualidade do produto final e economia de energia, o que permite ressaltar a importância de se determinar as perdas térmicas na panela. Entre outros fatores este trabalho buscou identificar a importância relativa das perdas térmicas para o revestimento refratário e através da escória. A temperatura, espessura da camada de escória, temperatura do revestimento refratário, propriedades físicas e características de convecção foram os fatores considerados. Cálculos numéricos que quantificam essas perdas.

Jul 30, 2018

By John A. Ames

Limestone for portland cement must be beneficiated to produce uniform raw material for the kiln. Careful quarrying and selective recovery are factors in this process, but the chief aspects of beneficiation are "in plant" processes, such as crushing and screening, washing, grinding, flotation, and heavy-media separation. Numerous technical and economic problems exist. Detailed studies of the limestone deposit and the stone itself are required for intelligent beneficiation. As used in this paper, beneficiation is defined as the improving of limestone composition so as to produce an economically usable raw material A limestone deposit is defined as a mass of limestone which can be recovered, by quarrying or mining, for sale or for use in a commercially profitable operation. The stone may require elaborate processing, or it may qualify with little or none. Obviously, the "commercially profitable" qualification may change as the economy changes. Potentially commercial deposits may be of much better quality than actually developed deposits, and yet may be denied development for various economic reasons.

Jan 1, 1966

By Richard O. Kneisley

An empirical method, based on U. S. Bureau of Mines field studies in several Western U.S. coal mines, is presented for sizing gate road yield pillars. Discriminant analysis was used to generate functions separating successful from unsuccessful case studies. These functions relate the pillar width-height and extraction ratios and a pillar development factor to the Coal Mine Roof Rating System (CMRR), and are assumed to establish three criteria that other entry systems, under similar conditions, must satisfy. A program, Pillar Sizer, from user-provided inputs, generates a range of pillar sizes that meets the proposed criteria. Although the analysis is based on a sample consisting primarily of two-entry systems, the derived expressions generate pillar sizes closely agreeing with observed, two-entry and three-entry in situ pillars. It is concluded that the proposed approach should assist mine operators estimate entry system yield pillar dimensions.

Jan 1, 2010

By M. Hayashi

The Bureau of Mines conducted laboratory studies on low-grade vanadiferous silicates from the Pumpkin Buttes and Nine Mile Lake deposits of Wyoming to examine techniques for extracting vanadium and uranium. Recovery from low-grade sources such as these could contribute to future vanadium production and reduce reliance on vanadium imports. The Pumpkin Buttes samples contained 0.03 to 0.04 pct V205 and 0.06 to 0.12 pct U308; the Nine Mile Lake samples contained 0.02 to 1.0 pct V205 and 0.06 to 0.19 pct U308" Leaching the Pumpkin Buttes samples for 18 h at 800 C with addition of 200 lb/ton H2S04 resulted in recoverey of 80 pct of the vanadium contained in the samples. The Nine Mile Lake samples were readily leached, yielding 78 to 94 pct of the vanadium after 3 h at 800 C with addition of 100 lb/ton H2S04, A solvent extraction procedure was used to selectively recover urani-um from Pumpkin Buttes and Nine Mile Lake leach solutions and to recover vanadium from the raffinates. In batch shakeout tests, Alamine 336 recovered over 95 pct of the uranium from leach solution adjusted to pH 1. Di-2-ethylhexyl phosphoric acid and Cyanex 272 recovered vanadium from the uranium raffinate after reduction and adjustment to pH 2; vanadium extractions of up to 96 pet and 92 pct, respectively, were achieved.

Jan 1, 1985

By Jessica M. Wempen, Dallan J. Coons, Bailey S. Simmons, Michael K. McCarter

Gate-road yield pillars are subject to increases in stress as the longwall face advances toward the pillars. Increases in pillar stress can be inferred by measuring roof/floor convergence surrounding the pillar. This paper presents a case study of convergence measurements surrounding a two-entry gate-road yield pillar in the head gate of a coal mine. Convergence was measured over a six-month period, as the longwall face approached and passed the pillar. Measurements were collected at eight locations surrounding the pillar: four locations in the travelway and four locations in the beltway. In addition to convergence stations, the pillar was instrumented with an array of seismometers. In future analysis, convergence measurements will be compared to seismic interpretations. This study reports on the geology and geometry of the longwall panel, the roof and rib support, the change in convergence over time, and the physical properties of coal and parting. Additionally, the convergence measurements are compared to pillar safety factor distributions derived from a finite element model. The convergence measurements contribute to the knowledge of when yield pillar abutment loading, caused by the encroaching longwall, is first detected. Knowing when abutment loading begins to yield the pillars can help define when standing secondary roof supports are required for head gate entry support.