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By C. J. Pritchard

Controlled recirculation of ventilation air in underground metal and nonmetal mines has the potential to improve airflow and the health and safety of miners when implemented properly. Previous research by Robinson, Marks, Cecala and others concluded that the success of a district recirculation system is predicated upon an adequate supply of fresh air and the use of a reliable monitoring system for safe operation. This recent research also showed that contaminant levels will not exceed pre-recirculation levels, and that district recirculation can improve the dilution of face contaminants, especially methane gas. To illustrate the process of implementing controlled recirculation and also to promote and give guidance to mine operators in consideration of this tool to improve mine airflow, Office of Mine Safety and Health Research (OMSHR) researchers acquired baseline airflow and contaminant data from a multi-level room-and-pillar nonmetal mine and used commercial ventilation network software to simulate base case conditions and recirculation of mine air. Mine return air baseline contaminants of dust and diesel particulate matter were at lower levels than intake air, providing the potential for improved face air quality. A ventilation model implementing controlled recirculation was developed and analyzed, showing an increase in air quantity at the face, improved intake air quality, and contaminant exposure levels below those set by statutory requirements. These results, along with conclusions reached by previous researchers, provide the basis for examining the safe and effective implementation of controlled recirculation in metal and nonmetal underground mines using this mine as an example.

By Zvi Rivlin

Classical nucleation theory states that in first order phase transformations, such as liquid to solid transition, nucleation of the product phase starts with the formation of small, unstable clusters (embryos). When the thermodynamic barrier to nucleation is overcome, the embryos grow and attain a critical size, beyond which they are stable, i.e. they become nuclei. If nucle- ation does not occur, the parent, liquid phase remains in metastable equilibrium. At temperature lowers, undercooling increase and atomic mobility decreases. The viscosity change in the undercooled liquid may result in the formation of glassy state. As demonstrated in previous papers [I-21, in solidification involving surface nucleation of the product phase, as the case is in rapid quenching by melt-spinning, both nucleation temperature and nucleation time depend upon the number of atoms available at the isothermal surface in contact with the substrate. As a result of the thinness of the melt-spun ribbons, the embryo clusters that form at the freezing temperature may not be supplied by the amount of atoms necessary for their growth to critical nuclei sizes. In such extreme conditions, the liquid does not crystallize, it forms a metallic glass. A numerical simulation method is proposed for the reactions involved in embryo cluster formation and growth, at the atomic level. The simulation enables the caIcuIation of either the nucleation or the glass transition temperatures. Calculations made for the well-known glass forming CuZr and FeB systems afford prediction of the geometrical and thermodynamically conditions necessary for the formation of either crystalline or amorphous ribbons in melt-spun ribbons.

Jan 1, 1994

By K. E. Hjelmstad

Solution mining operations often encounter difficulty maintaining adequate leach solution flow into the ore formation because of loss of formation permeability near the injection well. Permeability loss caused by swelling and breakup of clays and fine particle migration can often be the cause of the problem.

Jan 1, 1989

By Lim Thi Duong, Du Duy Bui, Thuat Ngoc Pham, Chuc Ngoc Pham, Que Anh Nguyen, Hoa Anh Bui, Chi Thi Ha Nguyen, Hoan Thanh Nguyen, Bac Quang Nguyen, Kien Trung Nguyen, Dung Trung Doan, Nhiem Ngoc Dao

The microstructures and kinetics of a rich iron ore ( TFe = 65.84%) of Na Rua mine, Vietnam, used for the iron production were investigated in this study. Thermal behaviors of iron ores were well-examined by heating microscopy, thermogravimetric analysis, and differential thermal analysis. After being pelletized and then oxidatively fired at 500–1200 °C for 2 h, the pellets fired at 1200 °C (P1200) displayed a hard and dense structure with a decent compressive strength of 317.9 kg/pellet whereas those fired at 500 °C (P500) had a soft and spongy structure. The reduction of iron pellets conducted in a flow of a 60–100% CO2/ Ar gas mixture at 900–1100 °C showed significantly higher efficiency than the reduction using coal. The spongy pellets showed superior performance for the reduction in the CO/Ar gas mixture compared to the dense ones, compatible with the production of sponge iron. When mixed with an amount of coal, P1200 designed for iron production in the blast furnace demonstrated an impressive reduction activity compared to P500 and previous studies. The kinetics of pellet reduction was determined by the diffusion of substances through the solid product layers having the mathematical model of 1 − 2 3 f − (1 − f )2∕3 = kt . The microstructures of pellets during the oxidative firing and reduction were also examined by X-ray diffractometry; scanning electronic microscopy; energy-dispersive X-ray spectroscopy; and Brunauer, Emmet, and Teller method.

Jun 7, 2022

A spectrochemical procedure applicable to the determination of iron, manganese, and magnesium in titanium metal and to the determination of alloying constituents in three types of titanium alloys is presented. Acid solutions of samples and standards are excited with a spark-type discharge and porous-cup electrode arrangement. The method is particularly applicable for analyzing samples for which a self-electrode method cannot be used. Calibrations are accomplished with synthetic standard solutions, resulting in a primary method that makes calibrations based upon results of other analytical methods unnecessary. Replicate determinations are reproduced to within 5 percent, and the average percentage deviations from reliable chemical values are less than 6 percent. The method can be extended readily to determine additional elements that are similarly soluble and have similar spectral sensitivities. It also can be used as a starting point to establish standards for a direct sparking procedure for analyzing titanium alloys. In view of the absence of established reliable analytical methods in the titanium industry, the spectrochemical method described here should prove to be a timely contribution.

Jan 1, 1956

By Alexander R. Troiano, Taylor Lyman

Studies of the transformation of aus-tenite at constant subcritical temperatures have been numerous since the work of Davenport and Rain.' Considerable information has been obtained on low-alloy steels and on high-carbon alloys containing undissolved carbide or graphite at the austenitizing temperature. Little is known of the isothermal transformation of aus-tenite containing in solution large amounts of both carbon and a single alloying element. In this investigation four steels containing one per cent carbon and with chromium in the range 3 to 9 per cent have been examined with the view to establishing the fundamental character of the isothermal reactions when all carbon and chromium are initially in solution in austenite. Experimental Procedure Alloys The chemical compositions of the steels investigated are given in Table I. The 4 per cent Cr alloy is a commercial steel. The other steels were made by the Carpenter Steel Co. as 50-lb., induction-furnace heats and rolled to 5/8 -in. round bars. Bars were softened at 650' to 700°C. before the specimens were cut. Most of the lines on the transformation diagrams presented here have been placed on the basis of the microscopic examinatioll of partially reacted specimens, Thees specimens were approximately 1/2 by 1/4 by 1/8 in. ill size, specimens of the 9 per cent cr steel were held 10 to 12 hr, at 1200°to 1225°C. before quenching to the various subcritical temperatures. The other steels were held for 2 to 2 1/2 hr. at 12ooOC. before quenching. These treatments, carried out in an atmosphere of purified nitrogen, produced an austenite grain size larger than A.S.T.M. So. I, some grains being 1 to 2 mm. in diameter. There were a few undissolved carbide particles in some specimens of the 9 per cent Cr steel. It is believed, however, that any errors in the results due to incomplete solution of carbon and chromium in austenite are negligible; that is, austenite compositions may be considered as being those listed ill Table I. X-ray Methods Constituents were identified and mar-tensite axial ratios determined from Debye

Jan 1, 1945

By Ulrich Kerney

In 1996, bath smelting technology for lead recovery from concentrates and secondary materials was introduced in Nordenham to replace the common sinter plant/shaft furnace operation. Since start-up, a continuous improvement of equipment and operation lead to a steady increase of capacity and plant availability. The decision to skip the reduction stage for slag treatment now allows the treatment of 200000 t/a feed materials with a secondary fraction of up to 70 %. The main feed source for the furnace is automotive battery recycling, which offers oxide paste and metallics to be molten under oxidizing conditions in the lance fired furnace. The lead bullion is transferred to the refinery, where copper, silver and other impurities are removed. Silver is recovered as doré quality. All loopings are recycled to the BSF. Inert feed material is collected in a so-called lead concentrate of metallurgical origin, the primary slag, which is sold. It is rather a valuable feed material for further processing than a slag The off-gas is cooled in a flux-flow system, entering then an electrostatic dust precipitator. Having passed a further washing and cooling system, SO2 is oxidized and collected and sold as concentrated sulphuric acid. The presentation will cover a review of the start-up phase, the development of significant production parameters over the last years and actual production routes and figures. A comparison of environmental data between new and old applied technology is made.

Jan 1, 2006

By N. J. Themelis

Autogenous grinding, broadly defined as the self-comminution of ore in a cylindrical tumbling mill without using auxiliary grinding media, was first applied in the early thirties in the so-called Hadsel mills (Figure 1) mainly used in gold mines on the U.S. West Coast. A number of these mills were built in sizes of 20 to 24 ft. in diameter and five-six feet in length but were later abandoned because of operating and maintenance problems. Further development of autogenous grinding led to the Hardinge wet grinding mill (Figure 2), the Aerofall dry grinding mill and others. A tabulation of all known autogenous and semi-autogenous installations around the world was sent recently to the authors by Hr. G. J. Kushner of the Koppers Mineral Processing Division. In the size range of 24 to 32-ft. in diameter, it lists a total of thirty mills used in the processing of copper ores. An additional 120 units are listed in the same size range for the processing of iron ores and other minerals. The largest mills in existence are 36-ft. dia X 15-ft. long mills in Minnesota, powered by 12,000 hp. motors and used in taconite beneficiation. It is indicative of the phenomenal growth of this technology that none of the above one hundred and fifty mills was in operation prior to 1964.

Jan 1, 1978

By Taciana Rezende Pereira

O aço 10B06 é utilizado na produção de fio máquina para trefilação. Por ser produzido em aciaria elétrica, o teor de nitrogênio desse aço tende a ser elevado, o que pode causar o fenômeno de envelhecimento, resultando em aumento de resistência e queda de ductilidade. Os dois principais fatores que influenciam na microestrutura e propriedades mecânicas do material são a composição química e o processo produtivo. A análise metalográfica realizada com Nital revelou microestrutura composta de 88% de ferrita e 12% de perlita, enquanto o reagente Le Pera identificou ilhas de martensita e/ou austenita retida (MA). Através das análises de raio x foi possível identificar a presença das fases a e cementita e manganês em solução sólida. A análise fractográfica mostrou que o modo de fratura observado no material foi dúctil, entretanto pequenas regiões de ruptura frágil também foram identificadas. Com o objetivo de melhorar as características de trefilabilidade do material, sugere-se a redução do teor de nitrogênio e consequente queda do boro adicionado, e/ou aumento da temperatura inicial de resfriamento do material, dificultando o enriquecimento da austenita em carbono e a consequente formação do microconstituinte MA.

Oct 30, 2017

By D. Harrington

Before the present century there existed a fairly persistent demand for the establishment of a Federal Department of Mines, but relatively little was done about it until a considerable number of very serious coal-mine disasters in 1906, 1907, 1908, and 1909 created what might almost be termed a national scandal and virtually forces the Federal. Government to take action to try to solve the problem of the cruse and prevention of such disastrous occurrences. Instead of a Department of Mines, the mining people had to accept a bureau, which was created on July l, 1910; and while the Bureau of Mines was given numerous functions, unquestionably the promotion of safety in the mineral industries was and continues to be one of its main "jobs." The Bureau's organic act was approved in 1910 and amended in 1913. Both the original and amended acts indicated that promoting; the health and safety of the mine workers constituted the chief function of the Bureau, and that this was the construction placed on its activities by those put in charge in 1910 is shown very definitely by the fact that as soon as the Bureau came into existence on July 1, 1910, both health end safety activities were started in its Mine Accidents Division. Before the end of the first fiscal year (June 30, 1911) 6 mine safety stations had been established in various parts of the United States, add 6 nine safety cars had been put into the field; by October 1910 first-aid-training work was being done in mining regions. The Bureau eras able to function so promptly in its safety work largely because sections of the Geological Survey, which had been doing some coal-mine safety work since 1907 or 1905, were transferred into the Bureau when it began to operate in July 1910. On October 30, 1911, a national First-Aid Meet was held at Pittsburgh, Pa., at which first aid and mine rescue were demonstrated. During the fiscal year 1910-11, the first year of the Bureau's existence, 509 persons were given certificates indicating completion of the Bureau's training course in first aid.

Jan 1, 1939

By Martin J. Gavin

[The theory of fractional "eduction" of oil from oil shale has been used by several inventors as the basis for the design of retorts for the production of oil f roan the oil shales of the United States. The term fractional "eduction" gives expression to the rather common belief that when an oil shale is he-test et produces light, low-boiling oils at to temperatures, and increasingly heavier, higher-boiling oils as the temperature of retorting rites. The theory evidently had its is origin in the fact that crude petroleum may be fractionally distilled, yielding light oils at low distillation temperatures, and heavier oils as the distillation temperature increases. Thus, gasoline is produced from petroleum at relatively log: temperatures, kerosene at a higher temperature, and heavier products such as gas-oil and lubricating distillates at still higher temepratures, The writers have examined several oil-shale retorts designed to take advantage of the belief that crude, and en some cases refined, gasoline can be recovered from the shale at low temperatures; kerosene at higher temperatures, and so on. Such retorts are usually designed to operate continuously, and. have several vapor-pipes lending from them at differing intervals and passing to separate condensers. Designers of such retorts expect that the distillate from the low-temperature parts of the retort will be gasoline, and that as the shale basses to zones of increasingly higher temperatures, the vapor lines leading from these zones will remove increasingly heavier products such as kerosene, gas-oil, etc.]

Jan 1, 1924

By Barnes R. G, Agostini A, Lewis P. C

The Mineral Resources Audit is a five-year Program established to produce a comprehensive and objective assessment of the mineral resources of New South Wales, including prospective resources. The goals of the Program are to improve planning and land use decision-making; attract exploration and minerals related investment; help the Department to identify and fill gaps in knowledge; and develop methods to identify and quantify resource potential and prospectivity. To achieve the goals of the Audit it is necessary to assemble and enhance a large amount of information and it is necessary to spatially analyse this information using computer-based Geographic Information Systems (GIS) which allow the collection, storage, transformation and display of large quantities of spatial data. An extensive range of both map-based and textual data can be employed in spatial analysis and resources and geoscience modelling. In order to use this information, data sets have to be corrected and standardised. Many data sets need to be classified. An objective of the Audit Program is the spatial analysis of the State, region-by-region, and the release of cleaned-up multiple digital data sets as packages which include upgraded mineral deposit information, 'seamless' geological map layers showing lithology, structures and stratigraphy, and processed and classified geophysical map layers. These regional packages are important reference sets for the mineral resources industry and will assist delineation of regional exploration targets.

Jan 1, 1995

By Eric Klaffenbach

Valorization of slag from metallurgical industrial processes becomes ever more important as this may help optimizing and reducing the use of natural resources such as rock and sand. In view of this objective, metallurgical processes have to be analyzed in order to modify the slag composition so that it will meet the expected requirements of potential users of these resources. This paper gives the results of a thermodynamic analysis of the flash smelting process to understand the impact of operational parameters on slag chemistry and elemental partitioning in the process. It is shown that an increase of the matte grade and temperature leads to higher deportment of Pb, Zn and As to the slag. With increasing matte grade the volatilization of these elements decreases. Furthermore, the results indicate an increasing solubility of Cu and S in slag at higher temperatures.

By Wolfgang Kern

More and more coke oven plants worldwide face the task to improve their emission reduction at their coke oven batteries. In the 90’s PROven® was invented and developed by DMT to regulate the inner pressure of a single coke oven chamber. Generally, most of the coke oven chambers can only close and open their connection to the collecting main but without the possibility to regulate the pressure during the carbonization time. Through the installation of PROven® the load on the coke oven door sealing system and the charging lids will be decreased and so does the emissions of crude COG as well. The current PROven® system, installed in the collecting main, does not only regulate the chamber pressure, it replaces the valve between the goose neck and the collecting main, too. This variable pressure control allows decreasing the leakages at the emissions sources to a minimum and allows operating the collecting main under optimum pressure. Subsequently, this will lead to enhanced emission reduction. PROven® proved its value with more than 2,100 units installed by licensee worldwide. Nevertheless, DMT is always focused on its client’s needs and therefore enhance PROven® to provide the Best Available Technique (BAT). Among the main features of the now available system is the plain arrangement with a higher reliability and the possibility to install the system outside of the collecting main without modifying it. Hence, upgrading coke oven plants during operation is possible without any noticeable impact on the plant operation.

Aug 1, 2018

By C. G. Roache

Mining legislation in Jamaica dates back to only 1947 when, on August 30 of that year the Minerals (Vesting) Act was promulgated. None of the exploratory and trial-mining projects over the preceding 450 years were regulated or controlled by law. It was the seriousness of the intent of the North American Aluminum Companies to establish a bauxite mining industry in Jamaica which led to the development of the first piece of mineral legislation. It is of note that the incoming mineral industrialist was more anxious than the Government to see that a legislative framework was in place. It was relevant then as it is today for good mining legislation to be in place for the Government to regulate and control the exploration and exploitation of mineral resources. It was also necessary for the industry to know their rights and obligations so that they could plan, explore and exploit with some assurance that their capital was secure. One of the main reasons that the mining of bauxite did not begin in Jamaica until 1952 was that no legislational framework existed prior to 1947. The Jamaican dollar is tied to the US Dollar at a rate of J$35.00 to US$1.

Jan 1, 1998

By George L. Gates

This report presents is an evaluation by the Federal Bureau of Mines of the effect of clay-water, brine, and oil-base drilling fluids on the productivity of test wells drilled on the Umiat anticline in U.S. Naval Petroleum Reserve No. 4 in northern Alaska. Eleven, wells were drilled on the Umiat structure as part of the U.S. Navy's extensive exploration of the Reserve during 1944-53 to determine the possibilities for oil production. The Federal Geological Survey cooperated in the exploration program and has published a comprehensive report3/ on the geology of the area and case histories of the wells. The re¬port also includes the results of special studies by the Bureau in connection with the drilling and coring of well 9 with oil-base mud in hole and was the source of much of the information used in preparing this publication. Of the eleven wells, four were drilled with rotary tools and water-base mud (one of the water-base muds was an oil-in-water emulsion mud), five were drilled with cable tools with brine in the hole, one was drilled with cable tools with brine in the hole and later reamed with rotary tools and crude oil, and one was drilled with rotary tools and oil-base mud. Although all of the wells penetrated sandstones that contained oil and gas, some were productive and others were not. The latter two wells, one completed with crude oil in the hole (with some added brine) and the other with oil-base mud, had the greatest productive capacities. The wells drilled with cable tools and brine in the hole had lower productive capacities. In contrast, two of three wells completed with rotary methods and fresh-water drilling mud and the well com¬pleted with rotary and emulsion mud were unproductive.

Jan 1, 1960

By Thomas Fraser

"El objetivo del presente texto es describir las características del lavado del carbón bruto producido actualmente en La Galgada, Ancash. Para ello, se revisa el registro y la comparación comparación de datos de prueba realizados entre 1945-1955. Desafortunadamente no se tuvo información de los lugares de trabajo para la selección de muestras, por lo cual no se las considera representativas de la producción obtenida en una operación a gran escala. Empero, los datos de las muestras en conjunto permiten una mayor índice de representación, y muestran la fluctuación en consumo que una nueva planta tendría que ser capazde manejar. Asimismo, se sugiere que dentro del diseño de plantas definitivas, el diagrama de tratamiento, indica un plan que pudiera ser adoptado ventajosamente, si surge el caso de que el carbón de Ancos y La Galgada sea empleado principalmente para la producción de combustible para altos hornos. En este caso, se supone que la planta lavadora estaría situada en Chimbote, como parte integrante del horno de coke y planta de sub-producción, y que el lavado daría un producto uniforme de no más de 10% de contenido de cenizas. Esto es solo una solución posible, que ofrece grandes posibilidades en la actualidad, en vista de los planes corrientes para una expansión eventual de la industria del acero, basada en el funcionamiento convencional de altos hornos que utilizan un combustible fabricado a base de antracita."

Jul 20, 1956

By T. Estelle Gardner

Heat-capacity measurements were made over the range 8° to 350° K on beryllium sulfate dihydrate and beryllium sulfate tetrahydrate using an adiabatic calorimeter. No anomalies were noted in the curve for either compound. Smooth values of heat capacity, entropy, enthalpy function, and free-energy function were calculated from the heat-capacity data at 10° K intervals and at 273.15° and 298.15° K. The entropy values calculated at 298.15° K were 39.01 ± 0.12 entropy units (eu) for the dihydrate and 55.68 ± 0.17 eu for the tetrahydrate.

Jan 1, 1967

By P Yß±ez, G Ferguson

The El Teniente mine produces more than 340 000 tonnes of fine copper per year from an industrial complex of underground mine, concentrator and smelter. Mass caving methods are employed to deliver approximately 95 000 tpd of ore to the mill, from a number of sectors underground, each sector being in effect a large-scale mine in its own right. This mining activity has faced challenges over the course of the last century such as:the capacity of the underground mine has been expanded to maintain and increase output of fine copper; the increasing size of the ore fragmentation forced to change the mining method to achieve the high productivity and profitability required in the business; and to modify the mining methods to continue mining at depth with safety. Fundamental activities in these mining methods, for the successful initiation of caving and subsequent draw, are:undercutting the base of the block or panel by blasting; and excavating of drawbells. The undercutting design evolves mainly on the height of the blasting to manage the change on ore fragmentation. The methodology move away from incorporating massive areas, typical of the block caving method, to a continuos blasting, typical of the panel caving method. Drawbell design changes on geometry, dimensions and sequence of excavation to deal with a corse ore fragmentation and the resolution of mining difficulties in the form of major rock bursts and collapses of production facilities. This paper focuses upon the evolution of the undercutting and drawbell design used at El Teniente mine and techniques under consideration to deal with future caving operations to provide the bulk of the daily production for the foreseeable future.

Jan 1, 2000

By Charles Austin

IT has long been known that plain high-carbon steels may be susceptible to graphiti-zation below the A, critical, but no data have been available to indicate what factors cause and tend to inhibit graphite formation. Two recent publications1,2 have shown that the factors controlling graphitization below the A, are different from those operating above the A, inversion where commercial graphitization of malleable iron begins. Furthermore, for plain high-carbon steels graphitization below the critical point does not appear to be related to ordinary chemi-cal analyses. Many years ago it was recorded' that the rate of graphitization at subeutectoid tem-perature is not a maximum just below the A, critical, but at some lower temperature, which Austin and Norris have shown to be about 670°C. Indeed, work done in our laboratory has demonstrated that it is im-possible to spheroidize certain steels in the temperature range of 650° to 710°C. with-out the formation of considerable amounts of graphite. However, if the temperature is maintained just below the A, (720°°C,) these same steels may be completely sphe-roidized at constant temperature. In previous studies1,2,4 on 1 per cent plain carbon steels graphitization was en-countered during prolonged tempering. The limited number of steels studied did not provide sufficient data to permit adequate study of the factors controlling this graphi-tization. Accordingly, a limited statistical investigation was undertaken, utilizing 18 steels of similar chemical analyses, fur-nished by four steel companies, who also supplied information regarding the history of manufacture.

Jan 1, 1940