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By K. J. Heale, G. G. Richards, D. J. Rioux, R. L. Stephens

Slag fuming has remained a key process for the recovery of Zn, Pb, and minor elements in the integrated flow sheet at Teck Cominco's Trail Operations for more than 75 years. Since the start-up of the KIVCETTM process and the #3 slag fuming furnace in 1997, a range of process intensification projects have been completed to improve metals recoveries and throughput based on improved process control, mechanical modifications, and, most recently, the implementation of oxygen enrichment of the blast air. This latter project, initially named 'nitrogen depletion' and now 'nitrogen oxygen performance enhancement' (NOPE), is the primary focus of this paper. NOPE reduces the amount of heat required to heat the inert nitrogen gas, and therefore more of the energy input can be used for reduction. It also frees up boiler capacity because the inert nitrogen gas does not then have to be cooled down. A dynamic METSIMTM model was developed to determine the opportunities to improve the process capacity and heat balance to both assist with justifying the project and to verify the observed furnace behaviour. Several process safety management issues were also addressed and a few key minor mechanical modifications were made to allow the project to proceed to commercial implementation at 25% blast air oxygen enrichment. Short term plant trials have confirmed the model predictions. The first three months of a long term, continuous trial showed a 6% increase in zinc fuming rate from average furnace performance despite the implementation of a KIVCETTM fluxing change to assist with minor element recovery that was expected to negatively impact the zinc fuming rate by 3 to 5%. This encouraging result is also in line with the model predictions.

Jan 1, 2008

By R. C. Dunne

As ore grades of existing and new ore deposits continue to decrease there is ever increasing pressure to decrease operating costs to maintain profitabitabitiy at existing mine sites and for new projects. The accepted solution to this dilemma in most cases is to increase treatment rate, leading to a coarser grind, at the expense of marginal decreases in recovery. The recovery loss is usually associated with losses of liberated and composite coarse material. This paper will review the practice of coarse particle flotation, including the reagent chemistry, cell hydrodynamics, froth stability, entrainment and flotation cell design, all parameters important to the recovery of coarse liberated and composite particles. This will provide a better understanding of opportunities to improve the recovery of coarse particles. Some examples will be provided.

Sep 1, 2012

By R. C. A. Minnitt, A. Akpabio

This study presents a rigorous comparison between ordinary kriging and commonly used machine learning algorithms, those being, linear regression, support vector regression, decision trees, random forests (RF), and k-nearest neighbours for spatial interpolation of platinum grade estimates in a complex ore body within the Bushveld Igneous Complex. Using only X and Y coordinates as predictors, both ordinary kriging and machine learning models were evaluated at point and block supports under traditional and spatial block cross validation frameworks. While naive validation results suggested superior performance for k-nearest neighbour and random forest (R² = 0.92 and 0.86, respectively), these were revealed to be overly optimistic under spatial dependence. Spatial block cross validation results demonstrated substantial declines in model performance, with R² often falling below zero, particularly for decision trees and k-nearest neighbour, indicating strong overfitting and limited generalisability. Ordinary kriging exhibited more stable, albeit modest, performance under spatial validation, reflecting its strength in geostatistical interpolation when contextual geological variables are unavailable. The study underscores the critical importance of spatially aware validation in resource estimation and highlights that machine learning models constrained to spatial coordinates behave as interpolators rather than true learners of geological variability. Recommendations are provided for future work incorporating geological information to enhance predictive robustness.

Mar 30, 2026

By Michael von Seebach

High-pressure grinding rolls subject the feed material to pressures of 200 N/mm? During this process considerable size reduction and the Formation of flakes occur. This paper describes the basic consideration For design and operating of this type of mill. It is also shown that the particle size distribution resulting from this process is typical for grinding processes but untypical for crushing processes. High pressure grinding rolls are designed in size of up to 2.8 m roll diameter allowing feed material top sizes of 250 mm. The rigid frame, bearing and drive - train design allows a broad application of the high-pressure grinding rolls operating the machine in open or semi-closed and closed circuit for dry and moist feed materials. Operating results show that capacity increases of up to 100 % can be accomplished with this technology. The high-pressure grinding roll also, allows for lower operating and maintenance costs due to energy savings of up to 20 L and reduction of wear to less than 1 76 for dry and less than 0.1 5 for wet grinding. Other advantages of the high-pressure grinding rolls are smaller equipment sizes than a ball or SAG-mill for a given capacity resulting in lower building sizes with reduced capital in- vestment costs.

Jan 1, 1987

By Sumit Kumar Biswas, Moyukh De, Sibapriya Mukherjee

"The piles often are also subjected to lateral (horizontal) forces and moments. In fact, there are some structures where the primary function of piles is to transfer lateral loads to the ground. Proper analysis of laterally loaded piles is very important to the geotechnical and civil engineering profession.In the present investigation an experimental study has been carried out with free head short model cast iron hollow piles of outer diameter of 24 mm and L/d ratios of 8, 10, and 15. The experimental results have been supplemented by numerical techniques using PLAXIS-3D Foundation version 2.1 software. The results have been found to agree reasonably well with the experimental results. Further finite difference approach has been adoptedto reduce the computational time and to calculate the coefficient of modulus of subgrade reaction (?h) from the load- deflection data obtained from PLAXIS output at different pile depths. The parametric study has been extended for the non-dimensional form defined as flexibility ratio (F.R.),where ?h, L, Ep and Ip are the coefficient of modulus of sub-grade reaction, the embeddedlength of model pile, elastic modulus of pile material and the moment of inertia of model pile about the central axis respectively).The variation of coefficient of horizontal modulus of sub-grade reaction (?h) has been studied with respect to the following parameters for homogeneous soil system: relative density andL/d ratio. It has been found that the logarithm of flexibility ratio increases with increase inrelative density and increase inL/d Ratio. The values of ?h obtained by the proposed method have been, found to be close to the numerical results.As output of this research, graphs have been generated in respect of different parametric variations to gain an insight into behavior of piles under lateral load for short piles."

Jan 1, 2015

By Martin Dirks

Nowadays the sinter cooler often becomes the bottleneck of the sinter production, with outdated equipment leading to low productivity and high operation and maintenance costs. Furthermore valuable energy is simply destroyed in the cooler, which is not compatible anymore with a cost efficient and environmentally friendly sinter production. Paul Wurth has developed and improved two types of coolers, the annular cooler and the shaft cooler which offer flexible solutions to the specific situation of each client. The classic design of the annular cooler was completely revised and is now composed of a rigid ringframe construction as opposed to the traditional design with individual sintering cars, avoiding the typical problems of centering. Additional features of the PW annular cooler are the low air leakage rate and the increased effective cooling surface due to the removal of dead areas. This leads, in addition to the lower weight, to lower operating costs and a smaller space requirement. The shaft cooler stands out with an even smaller space requirement and a lower sinter outlet temperature because of a very long residence time of the sinter inside the shaft. Its development into a pure counter flow cooler aims at maximizing its energy efficiency, as it is designed as a system with a very low demand for cooling air, high air discharge temperatures and highly reduced dust emissions. For both cooler types flexible heat recovery solutions can be offered. These solutions include the supply of hot combustion air to the ignition hood burners and the sinter strand, the production of steam for the clients steam grid or the production of electric energy.

Aug 16, 2017

By K C. Runge, E Tabosa, A Jankovic

Flotation recovery in geometallurgical modelling is usually predicted based on relationships developed from batch flotation testing of different ore types. These batch flotation tests are usually performed at a constant set of operating conditions and at a fixed feed grind size P80. Usually the laboratory feed grind P80 is that which is expected to be produced in the full-scale flotation circuit for that particular ore type.Flotation recovery will be a strong function of the valuable mineral particle size distribution, with lower recovery of ultra-fines due to poor flotation kinetics, optimum recovery for the intermediate sized particles and lower recovery for the coarser particles due to poorer liberation of this fraction. This valuable mineral particle size distribution is not characterised by the solids P80 parameter alone. The proportion of material in each class will also be a function of the slope of the size distribution and the degree of preferential grinding of the valuable mineral in comparison to the total mass of the ore.This paper will demonstrate (through example) how these other size distribution parameters can change with a change in grinding technology, the size and operating conditions used in a grinding unit and the characteristics of the classification technology used in conjunction with the grinding unit. Case studies will be presented that demonstrate how this can result in these parameters being very different in laboratory testing to that produced in the full-scale comminution circuit. A rule of thumb that laboratory rod milling rather than ball milling produces a size distribution most similar to that of the full-scale grinding circuit will be challenged. These differences can result in a significant change in flotation recovery. It is therefore important to consider these parameters when developing a laboratory geometallurgical program, to enable more accurate prediction of the flotation recoveries that will be achieved in the full-scale process.CITATION:Runge, K C, Tabosa, E and Jankovic, A, 2013. Particle size distribution effects that should be considered when performing flotation geometallurgical testing, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 335-344 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By E. H. Smith

St. Joe Minerals Corp., a subsidiary of Fluor Corp., treats high-grade gold, silver, and copper ore at its El Indio plant at an altitude of 4 km in the Chilean Andes. The ore is complex, being a mixture of massive pyrite-enargite and quartz, both containing very fine gold and silver. Treatment produces a copper flotation concentrate containing high levels of gold, silver, and arsenic, and also dore bullion. Part of the flotation concentrate is roasted to remove the arsenic content, and arsenic trioxide is collected as a by-product.

Jan 1, 1987

Semisoluble salt minerals are characterized by their ionic bonding and are distinguished from soluble salt minerals by their limited solubility in water. One group of semisoluble salt minerals being considered is the alkaline earth salt minerals, including fluorite (CaF2), calcite (CaCO3) and apatite (Ca5F (PO4)3), as well as celestite (SrSO4) and barite (BaSO4). Another group of semisoluble salt minerals being considered is the rare-earth salts, which include bastnaesite ((Ce, La) CO3F), monazite (CePO4) and xenotime (YPO4). Surface chemistry features of these selected semisoluble salt minerals are discussed with respect to flotation separations. First, the surface chemistry features of alkaline earth semisoluble salt minerals are reviewed, and then the surface chemistry features of rare-earth semisoluble salt minerals are examined. The discussion includes electrokinetic behavior, wetting characteristics and collector adsorption.

By G. E. McElroy

This report discusses the construction and use of an all-pressure psy- chrometric chart in which the requirements of simplicity of appearance and absolute accuracy have been waived, to a certain extent, to provide for the rapid determination of psychrometric data and for the rapid solution of air- conditioning problems of major interest to the mining industry. Many mines in which air-conditioning problems are important are situated at elevations far above sea level and embrace great differences in elevation - in excess of 8,000 feet in certain mines → throughout their airflow circuits. Under these conditions, the effects of variations in the pressure of the at- mosphere upon the physical properties of the mixture of air and water vapor of which it is composed are considerable and should be taken into account in the solution of problems. The simple types of psychrometric charts in common use, such as the Carrier, Bulkeley, Hill, and Goff (American Society of Heat- ing and Ventilating Engineers Guide), are not generally suitable, in that they are drawn for a single barometric pressure 29,92 inches mercury.

Dec 1, 1947

By J. F. Adams, V. G. Papangelakis

Chemical modelling is becoming increasingly useful in the development, analysis, design, and control of hydrometallurgical processes. The paper presents the development of reliable databases for chemical modelling of selected hydrometallurgical systems using state-of-the-art software, such as OLI. The modelling strategies are also demonstrated. The high pressure acid leaching (HP AL) of laterites, oxygen solubility in the oxidative leaching process of zinc sulfide, gypsum solubility and lead chemistry in mixed sulfate-chloride solutions are presented as case studies. This on-going work attempts to bridge the gap between theoretical research and industry needs. Computational Analysis in Hydrometallurgy 35th Annual Hydrometallurgy Meeting held in conjunction with the 44th Annual Conference of Metallurgists ofCIM Calgary, Alberta, Canada Edited by

Jan 1, 2005

By R. M. Geisenheyner

We are in the midst of a transportation revolution. From the Wright Brothers to the SST. From the Toonerville Trolly to the 120-mile-an-hour Northeast Corridor train. From Christopher Columbus to Neil Armstrong. There is another side to this revolution and it is going on every day at our mines and factories. We call it bulk distribution. Perhaps ordinary sounding, but every bit as exciting as those other transportation innovations. Basically, we have gone from bag to bulk, and in the process reached that Last Frontier in manufacturing cost savings. By revitalization of our distribution system, we have made it possible for our mines and factories to realize fully the vast economies of spage-age manufacturing techniques and accomplishments. The pacesetters in this distribution revolution have been you gentlemen, the producers and shippers of dry mineral products. In this area bulk distribution grew up. And here most of the current innovations are being introduced. Management of your industry was early to realize the economic advantages of bulk distribution. Distribution costs of your products comprises a sizeable, portion of the selling price and management is sensitive of any developments which may even slightly reduce the cost of transportation, marketing or the exploration of new frontiers.

Jan 1, 1969

By Michael J. Friedel

The permeability and flow capacity in unsaturated media is investigated by the Bureau of Mines for application to in situ copper leach mining at the Cyprus Casa Grande mine site. Moisture retention properties are derived and combined with scanning electron microprobe data to characterize the mineralogy, texture, pore size, distribution, and permeability of the host rock. Finite element modeling is used to derive a saturated permeability, ambient degree of saturation, and assess various injection-recovery schemes. Recommended design modifications for optimization of solution distribution and maximum recovery from the rock matrix requires either (1) the injection pressures on the order of 1500 psi and recovery wells operating in a suction mode, or (2) performing permeability enhancement, through rubblization. By producing a maximum block diameter of 4 m, injection pressures can be reduced to 500 psi with improved recovery and containment of solutions.

Jan 1, 1991

By Andrea Pedroza da Rocha Santos

Neste trabalho, amostras de aço Lean Duplex UNS S32304 foram submetidas à temperatura de 800°C em um forno acoplado a um difratômetro de raios-x durante intervalos de tempo de 30, 60 e 90 minutos. Com o objetivo de analisar em tempo real a transformação das fases constituintes, foram realizadas várias varreduras insitu durante os diferentes tempos de permanência em 800°C deste material. Assim, observou-se a formação da fase sigma neste aço, tanto nos contornos de grão da ferrita como nas interfaces ferrita/austenita. Os valores de fase sigma obtidos para cada tempo de exposição foram calculados através do método de Rietveld sobre cada difratograma obtido e variaram de 11% a 17%. Notou-se que a fase sigma exibiu crescimento contínuo até 60 minutos e variação após este período. Todavia, observou-se que a formação de fase sigma a 800°C ocorre de forma significativa neste material após 30 minutos de aquecimento, o que pode comprometer as propriedades do mesmo.

Aug 16, 2017

By N. S. Dalal, Xianglin Shi

"The mechanism of vanadium(V) V ) toxicity is still not fully understood in spite of extensive current effort (1-3). The presence of a vanadium(V) V ) -dependent NAD ( P )H oxidase in cell membranes suggests that at least one of the pathways involves oxidation of NAD(P)H (1-3). Considerable effort has therefore been devoted to finding the mechanism of NAD ( P ) H-oxidation by va¬nadium( V ) (1-19). Recently Liochev and Fridovich (4, 16) provided a critical review of vanadium( V) -stimulated NAD (P )H oxidation by plasma membranes. They out¬lined a mechanism in which vanadium(V) V )-stimulated oxidation of NAD ( P )H by biomembranes involves an O2 - initiated free radical chain reaction (4 ). While the above may be the major pathway for the vanadium-me¬diated NAD (P )H oxidation in membrane-related sys¬tems, some recent results suggest that in the presence of NADPH the flavoenzyme glutathione reductase can function as a vanadium(V) V ) reductase (18). Because of the significance of this result in relationship to the mech¬anism of vanadium( V) metabolism and the novelty of the metal-reductase behavior of a flavoenzyme, we have car¬ried out additional studies on one-electron reduction of vanadium( V) by two other, related flavoenzymes: lipoyl dehydrogenase and ferredoxin-NADPH oxidoreductase. These two enzymes were selected because they are known to catalyze a one-electron reduction of Cr ( VI ) (19-21 ), which is isoelectronic with vanadium( V ).The present study also reports on the generation of hydroxyl ( • OH) radicals in the vanadium( V) -flavoen-zyme redox system without exogenous H2O2. The • OH study was undertaken because • OH radicals are known to be generated in reactions of vanadium( IV) with H2O2 (17,18,22-27). For example, Piette and co-workers (17, 22) have studied effects of vanadium(IV) IV ) on lipid per-oxidation and NADPH oxidation and suggested that va-nadium( IV) -induced • OH radical formation may play an important role in vanadium( V) toxicity. Carmichael (25, 26) investigated the reaction between a RNA /VO 2' complex and H2O2 with a view to probe the possible re-lationship between vanadium( IV) -mediated • OH radical generation and DNA damage. He has suggested that in this reaction the • OH radical adds to the C (5) carbon of uracil, causing nucleotide damage, similar to what occurs in the nucleotide /Fe2+ / H2O2 reaction (28) and in y-irradiated aqueous solutions of nucleic acids (29 ). To our knowledge, however, there is as yet no report on ·OH radical generation in any reaction involving the reduction of vanadium ( V) by a well-characterized enzyme, without exogenous H20 2 • The present study provides evidence that ·OH radicals can form in a flavoenzyme-mediated reduction of vanadium( V) to vanadium( IV) and that this process involves also the reduction of molecular oxygen ( 0 2 ) to H20 2 • The H20 2 thus generated reacts with vanadium( IV) to produce ·OH radical, in analogy with the Fenton reaction ( Fe2 + + H20 2 - Fe3 + + OH- + ·OH)."

Mar 1, 1992

By B. Samanta

This paper highlights the use of an innovative mine production scheduling scheme for grade-control planning tasks that take into consideration grade-model uncertainty. The scheduling exercise has been carried out with the help of a multiobjective genetic algorithm (MOGa) for the production scheduling operations. The underlying motive behind the use of MOGa has been the generation of a set of pareto optimal solutions to meet the goals of the target-grade specifications for the considered multiple grade attributes. Several new concepts related to MOGa formulation, in particular the mutation operation and the convergence criteria of this algorithm, are proposed in this paper. The modeling of grade uncertainty into the scheduling outputs has also been incorporated through a set of conditional simulated grade maps. The proposed scheme of production scheduling operations has been applied for the grade-control planning operations in an iron ore mine to meet the targeted grade specifications of iron, silica and alumina, and a risk analysis has been performed to this end.

Jan 1, 2013

A brief description of the hydro-gen reduction of nickel from ammoniacal solutions by the Sherritt process is given, indicating how this procedure can now be used to coat a great number of materials -particularly powders -with nickel or cobalt, whereby so-called composite powders are produced. The technique for the production of composite powders is described, particularly with regard to the surface activation of noncatalytic powders, whereby it is possible to coat core powders uniformly with nickel or cobalt. The properties of some of the more interesting composite powders, such as Ni/ AI, Ni/WC, Co/WC, Ni/Graphite and i/P, are discussed as well as possible fields of application for these new products. INTRODUCTION DURING the last decade, no-table advances have been made in pressure hydrometallurgy, so that large quantities of three of the more com1r.on metals, copper, cobalt and nickel are now produced on a commercial scale by hydrometallurgical processes.

Jan 1, 1963

By R. O. Pynnonen

This circular is a study by the Bureau of Mines of 346 accidents in underground iron-ore mines of the Lake Superior district from June 1949 to August 1954. These accidents caused 354 lost-time injuries, including 28 fatalities and 2 permanent-total disabilities. The accident reports were analyzed by the Bureau to show the causes of injuries and the time charges and unsafe practices or conditions that caused the accidents. Also shown are the times of occurrence, ages of the injured by job classification, and experience of the injured in mines and on the job being performed when hurt. Detailed information is presented on approximately 14 percent of the total number of Lake Superior district underground mine accidents that resulted in lost-time injuries during the period covered. These facts are presented to aid accident-prevention measures in underground mines and as a record for measuring future safety accomplishments.

Jan 1, 1956

By William G. Pariseau

A small displacement-small strain finite element technique utilizing the constant strain triangle and incremental constitutive equations for elastic-plastic media that are nonhardening and obey a Coulomb yield condition has been applied to the analysis of gravity flow initiation in a V-shaped hopper containing a powder under lunar environmental conditions. Three methods of loading were examined. Of the three, the method of computing the initial state of stress in a filled hopper prior to drawdown by adding material to the hopper layer-by-layer is superior (as expected). Results of the analysis of a typical hopper problem show that the initial state of stress, the elastic moduli, and the strength parameters have an important influence on material response subsequent to the opening of the hopper outlet.

Jan 1, 1971

By H. J. R. Way

THE work to be described was undertaken at various periods from 1937 to 1939 on the Busia gold field, in the eastern province of Uganda. It was decided to examine the possibility of reef prospection by the resistivity method, for it was not known how far the usually disintegrated nature of most reefs in the ubiquitous laterite near the surface would obscure indications obtained by resistivity traverses. The work at the commencement was therefore largely experimental, but the results obtained thereby were satisfactory, and a survey was started at the Government closed area at Amonikakine. With the limited time and resources at the writer's disposal, it was not possible to complete the survey to his satisfaction or to follow up exhaustively all the geophysical indications, but some of the results of the experimental work and the survey were of sufficient interest to be worth recording; in particular the relation between the width of reef, electrode separation and shape of the curve, and the interference effect of constant separation curves over zones of float are significant and useful. Three new veins were located, but only one contained sufficient gold to warrant detailed prospection. This was called the Geophysical reef, and was uncovered over a strike distance of 1140 ft., and there are indications that it extends over a distance of 1990 ft. These results and the recommendations consequent therefrom were embodied in a special report to the Uganda Geological Survey. HISTORY OF THE FIELD The Busia field is in the southeastern corner of Uganda near the Kenya-Uganda border, and is about 17 miles north of the northeastern corner of Lake Victoria. Gold was first discovered in the area in the stream beds by Davies1,2 in 1932. Subsequently numerous small alluvial claims were worked by prospectors and the area was prospected for reef by a company for periods varying from three to nine months, but was finally abandoned, as the results were considered unfavorable. Further prospecting by the Geological Survey in 1935-1936 under Davies3 and later under the writer4 uncovered three reefs with sufficient gold values to be of economic interest. These were finally taken over by a company known as Borderland Syndicate, which still owns the area, and from September 1937 to the end of 1941 about 13,000 oz. of gold was extracted from reefs of the area proved by the Geological Survey. Opencast mining operations are still proceeding (February 1943). The Amonikakine area lies to the immediate north of that of Borderland Syndicate. A certain amount of prospecting had been done when the writer started work there. As a result of his report, this area was taken over by another syndicate, but little further work was accomplished before it ceased operating because of difficulties of wartime working.

Jan 1, 1944