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By Z. R. Llanos

This paper presents a review of industrial and experimental processes for the recovery of molybdenum, vanadium, nickel, cobalt and aluminum from spent hydrotreating or hydrodesulfurization catalysts. Numerous processes have been developed in a laboratory and pilot scale. However, worldwide, there are only four well established commercial facilities currently in operation. The installed capacity of these facilities exceeds the availability of spent catalysts and may be sufficient to assimilate future increases of spent catalysts. Despite liability risks; significant quantities of spent catalysts are still being landfilled. Changing regulations that may affect the future handling and disposal of spent catalysts are also reviewed.

Jan 1, 1995

Investigation of the Effect of N-Substituents on Performance of Thioureas as Special Collectors for Copper Sulfides by ab Initio Calculations

Sep 13, 2010

By M. Karmis

Subsidence planning and control must be an integral part of mine design in order to minimize the economic impact of underground mining on the surface. Pre-calculation of surface deformations which may cause damage to surface structures must be performed and dam-age criteria must be established, if the response of structures to such movements is to be determined and the extent of damages to be assessed. In this paper the Surface Deformation Prediction System (S.D.P.S.), which can be used to predict accurately the vertical and horizontal parameters of surface movements due to underground mining, is discussed. The Subsidence Response Modeling Program (S.R.M.P.). which can be applied to evaluate the response of buildings to subsidence-induced movements, is also reviewed. Finally, an example is presented demonstrating the applicability of these techniques for subsidence design and control.

Jan 1, 1990

By R Byrnes, P Hensley

The outstanding environmental management initiatives undertaken by Novacoal at its Western Main Site near Lithgow in New South Wales over the past five years are detailed in this paper. These initiatives have been based on a combination of proven and innovative investigation and implementation techniques, close consultation with regulatory authorities and full support by colliery management. The results of these initiatives have enabled the colliery to exceed its pollution control obligations from a base well below industry standards. The initial poor condition of the mine was the result of over 50 years of traditional mining which paid little regard to environmental management. The transformation of the colliery within such a short period, with limited capital, is considered a model for the N.S.W. coal industry.

Jan 1, 1995

By H. R. Babitzke

The purpose of this investigation was to develop an alloy of columbium for use at high temperatures and for nuclear applications. The properties of possible alloys were determined, and the more promising ones were selected for further improvement. Criteria for selection were machinability, hardness, workability, tensile strength, and oxidation resistance. Thirteen 100-gram ingots, ranging from 100 percent columbium to 100 percent vanadium, were prepared and subjected to various tests. Also included for comparison were zirconium and the zirconium alloy, zircaloy-2. Test results showed that a columbium alloy, containing 10 atomic percent vanadium merits further development. Besides being workable at room temperature, the columbium-10 atomic percent vanadium alloy has oxidation resistance superior to the other alloys of the series and is also superior to zirconium or zircaloy-2. The latter two materials have comparable neutron-absorption cross sections. The strength and hardness values of the alloys tested were found to increase with increasing vanadium content, reaching a maximum at 50 atomic percent vanadium and decreasing with further increase in vanadium. This behavior is typical of binary alloys wherein each element will retain any proportion of the other in solid solution. INTRODUCTION There is an increasing need for alloys for service at high temperatures. Since current world reserves of columbium metal approximate 1,500,000 tons (1),4 this metal is now readily available. Columbium can ties; be considered a practical base material for high-temperature alloys required in nuclear reactors and in aircraft and space vehicles. General requirements chosen are: (1) Workability, (2) satisfactory mechanical properties at temperatures approaching 1,000° C., and (3) resistance to oxidation at such temperatures.

Jan 1, 1962

By Donald V. Currie

"The Alberta and Northwest Chamber of Mines was founded in Edmonton, Alberta in 1935. The organization represented private sector mining explorers and developers in the province and north west Canada. The Chamber aided and abetted the establishment of the two territorial mining associations. Because of corporate human resource department creation by north of sixty mine operators, the Chamber refocused on Alberta and broadened its perspective to include activities beyond mining. In 1977 the name changed to the Alberta Chamber of resources. The slogan (in more modern terms vision, mandate, goal, etc) remains as Orderly Development of Canada's Resources.The sixty-three year reputation of the Chamber, built on volunteer rather than staff contribution, is the principal reason for any success. The key has truly been the reputation, not an image, as all activities have been solution oriented.This presentation provides insight into the structure and methodology applied by the organization, and reviews some of the successes and failures during the period 1985 to present. Examples discussed include:• Canada-Alberta Partnership on Minerals 1992-1995• Regional Upgrader Business Plan• National Oil Sands Task Force• Lakeland and Waterways Railway"

Jan 1, 1998

By Benjamin C. Pollard

The location and production potential of a large block of strippable reserves in North Dakota were determined by using published data as a base and adding new drill hole data or other data contributed by companies that presently own or lease coal lands. Only beds exceeding 5 feet in thickness, under less than 120 feet of overburden, and in large blocks of 5 million tons or more were included in the estimates. All such reserves are in the Fort Union Formation of western North Dakota and are lignite in rank. Sixteen large blocks of reserves evaluated in this study are estimated to contain a total of 4.1 billion tons of strippable lignite.

Jan 1, 1972

By J. J. de Barbadillo

This report describes a process for recovering chromium and other metals from superalloy scrap. Part I contains the results of laboratory scale experiments which were conducted to test a complex flowsheet utilizing a wide range of extractive metallurgical operations. The novel basis for the process is the formation of a sulfide matte in which chromium is concentrated in a discrete chromium sulfide phase. Mineral processing and hydrometallugical procedures are used to separate chromium sulfide from the other matte constituents. The products of the process are a chromium-nickel alloy suitable for reuse in the superalloy industry, electrolytic nickel, electrolytic cobalt, and an iron-molybdenum residue. Recovery of the principal elements contained in the scrap are chromium(Cr)-93 percent, nickel(Ni)-99 percent, cobalt(Co)-96 percent, molybdenum(Mo)-92 percent. Part II encompasses a preliminary engineering design of a pilot plant capable of treating 100 pounds(lb) of superalloy scrap per hour. Also included is an economic analysis of the operation of the pilot plant.

Jan 1, 1980

By A. H. Anderson

THE travelling grate coking process was developed by Shawinigan Chemicals, Limited, at their Shawinigan Falls plant. The first production unit went into operation a month prior to the outbreak of the war. Since then a substantial part of the coke used in the manufacture of calcium carbide has been produced by this process. In the following will be given a short account of the development work, a description of the process and the equipment, a discussion of the properties of the coke, the economics of the process and its future possibilities. EXPERIMENTAL WORK The carbide industry is a large consumer of coke, one ton of commercial carbide requiring for its production 1,200 lb. This coke must meet certain specifications in order to be acceptable. It should have a low ash content, preferably below 8 per cent, and the sulphur and phosphorus content must not be above specified limits. The size of the coke is also important. If it is too large it has to be crushed before it can be used in the furnaces, and if it is too fine it may have to be screened and briquetted. In addition, it must be dry. Although it was generally possible to purchase coke, including petroleum coke, and coke fines, in the quantities required, it became increasingly more difficult as time went on to obtain coke of a suitable quality at an attractive price. It was therefore natural for us to look to coal carbonization as a means of basing the supply of the fundamental raw material for carbide manufacture on something more solid than the shifting conditions of the coke market.

Jan 1, 1944

By Donald J. Knight

HEAT Treatment at 1500' F of a mild steel containing 0.1 pct C, in an atmosphere which is oxidizing to both carbon and iron, results in the progressive oxidation of the metal surface with little or no change in the carbon content of the underlying metal. Further heat treatment of the scaled metal in either a neutral atmosphere or in a vacuum may or may not result in the decarburization of the metal depending upon the physical nature of the scale. It is apparent that if a continuous layer of oxide is present on the steel surface, the reaction OScale + Cmetal Cogas cannot progress since the SO formed gas would be unable to leave the oxide/metal interface. Thus, in order for the reaction to progress, the oxide must be cracked or porous. Vacuum heat treatment at 1500" F of samples with a thick continuous oxide scale showed no decarburization of the steel. However, when cracks were introduced mechanically into the scale prior to the vacuum heat treatment notable decarburization of the metal resulted and a structure as shown by Fig. 1 obtained, i.e., reduction of the crack walls to ferrite. With reference to the diagram of Fig. 2, it would appear that a mechanism of the following type takes place. Carbon atoms arriving at an oxide/metal/void interface, such as 'A', Fig. 2(a), can combine with oxygen atoms from the scale and leave the reaction site as Cogas thereby reducing the oxide to metal. On a greatly magnified scale, Fig. 2(b),this will appear as a ferrite projection along the crack wall. Carbon atoms entering this projection can react with oxygen atoms at point 'C', which is a new interface, and so on leading to a progressive growth of the ferrite along the crack wall and to the surface, Figs. 2 (c) and 1. It would appear that the only means by which thickening of the ferrite film can take place is by a diffusion of oxygen through the ferrite film to react with carbon at the newly formed ferrite/ void interface. Since the diffusion rate of carbon is reportedly much greater than that of oxygen, and since there is a low probability factor of oxygen and carbon atoms arriving simultaneously at the same site on the ferritehoid interface, there will be a tendency for more rapid lengthening than thickening of the ferrite layer, as is observed.

Jan 1, 1962

By Walter W. Kaufman

This report summarizes a study conducted to determine the state of the art of various rock removal systems and their capabilities. The objective of the study was to determine if currently manufactured equipment can adequately accomplish rock removal in surface mine reclamation applications. Evaluations of state reclamation regulations, with regard to topsoil rock content, were made to determine the rock removal requirements. The major categories of equipment studied are rock pickers and rock rakes. The impact of rock removal implementation on the reclamation operations is discussed in detail.

Jan 1, 1979

By Bruce I. Thomas

Reconnaissance studies of beach sands along the eastern part of the Gulf of Alaska were conducted by the Bureau of Mines to determine if any of these coastal areas warranted investigations as possible sources of valuable minerals. Because of difficult access and limited transportation facilities only a minimum of sampling, surveying, and camping equipment is utilized to obtain spot samples from key areas as well as information indicating the location, size, and character of the deposits. Such data were obtained from beaches located along approximately 247 miles of the Gulf of Alaska coastline during parts of the 1957 and 1958 field seasons. A total of 201 3-inch-diameter auger holes, spaced roughly at 1 mile intervals, were bored by hand methods to depths ranging from 3 feet to 27 feet; also 33 shovel samples were collected from selected localities. Samples were reduced to a rough concentrate in the field by panning; the rough concentrates were shipped to the Bureau of Mines laboratory at Juneau for further concentration and for petrographic and chemical analyses. Particular attention was given to the heavy-mineral content of the concentrates, although the types and relative amounts of rock-forming minerals were also determined. The reconnaissance indicated that, generally, the valuable mineral content of the beach deposits was too low to be of further interest except in the vicinity of Yakutat and Lituya Bays where erratic but possibly significant concentrations of magnetite and/or ilmenite were found. At Yakutat, about 20 miles of beachline extending southeasterly from Ocean Cape, yielded samplas containing from 1 pound to over 300 pounds of iron and from a trace to over 100 pounds of titanium dioxide (TiO2) per cubic yard of beach material. However, the higher grade samples represented local concentrations of minor importance. The general tenor of the Yakutat beach, as indicated by the airthmetical average of 27 auger-hole samples, is about 35 pounds of iron and 20.5 pounds of titanium dioxide per cubic yard of beach material. Ilmenite is the predominant heavy mineral of the beach deposits in the vicinity of Lituya Bay, but it was found in concentrations only in limited areas near the

Jan 1, 1962

By Ray Patterson

A planned modification to a cement kiln at the Holnam Portland Cement Plant near Florence, Colorado required the removal of a ring of cast-in-place (CIP) refractory lining. The CIP lining was approximately 14 inches wide, 12 inches thick and 38 feet in circumference.

Jan 1, 1999

By Andrew M. Leszcykowski

This report represents the first comprehensive accounting of lode mining sites in the Sheep Mountain mining district, Custer County, Idaho. Twenty-one mine and prospect locations have been added to the Bureau's Mineral Industry Location Subsystem (MILS) data base as a result of initial phases of a mineral appraisal of the River of No Return Wilderness; previously known locations were checked and the updated information added to the data base. The district's deposits are mainly confined to metasedimentary xenoliths in granodiorite and quartz monzonite. Those deposits in the north and west parts of the district are lead-silver-zinc replacement veins in dominantly calcareous facies; those in the southern part of the district are polymetallic fissure-veins containing pyrite, chalcopyrite, arsenopyrite, galena, and sphalerite hosted by micaceous schist and phyllite. The dominant structural trend in the southern part of the district is northwesterly and on strike with major deposits in the adjacent Seafoam mining district.

Jan 1, 1983

By O. F. Oxtoby, J. E. Olsen, M. W. Erwee, Q. G. Reynolds

"The extraction of molten products and wastes through smelting furnace tap-holes during the tapping process is a complex procedure involving many coupled thermophysical effects. Insight into the fluid flow behaviour in such systems can be gained by using computational mechanics tools to build highfidelity models of the fluid flow and other relevant physics. Previous work using such models indicates that the nature of the flow in the tap-hole, as well as operational parameters such as the tapping flow rate, depends strongly on the properties of the material being tapped and the geometry of the tap-hole channel. Additional complications arise when multiple fluid phases (for example, slag and metal) are present simultaneously, when porous coke beds hinder flow to the tap-hole entrance, and when the geometry of the tap-hole changes over time due to cycles of wear and repair. In the present work, challenges with the coupling of phenomena such as multiphase flow and porosity into computational fluid dynamics methods for tap-hole modelling are discussed in the context of electric furnaces used for ferromanganese production. Qualitative and quantitative results of computational models of flow through tap-holes are presented and compared as a function of material parameters to determine sensitivity effects, and in response to operational parameters to determine typical process behaviour over the duration of a tap. IntroductionPyrometallurgical production using electric furnaces accounts for substantial portion of the world supply of ferroalloys and other strategic materials (Degel et al., 2015). A range of different furnace designs may be used depending on the metallurgical process, with circular three-electrode submerged arc furnaces (SAFs) powered by alternating current being the most common for commodities such as ferromanganese and silicomanganese (Olsen, Tangstad, and Lindstad, 2007).As shown in Figure 1, manganese furnaces typically operate with a deep charge consisting of an upper layer of loose burden (onto the upper surface of which is fed solid raw material), a molten slag layer partially or completely filled with unreacted carbonaceous reductant (generally metallurgical coke), and a molten metal layer which settles to the bottom of the furnace due to its high density. The solid particles present in the slag and burden layers form porous beds which hinder the fluid flow of molten process material and gases inside the furnace (Olsen, Tangstad, and Lindstad, 2007).In order to remove material from the furnace during normal operations, a single tap-hole is built into the sidewall of the vessel near to the level of the hearth. Tapping involves removing both slag and metal phases through the same tap-hole channel, which makes tap-hole design, operation, and maintenance particularly complex. In the case of processes such as ferromanganese, which operate with no external gas injection or open arcs present at the furnace electrodes, flow of material out of the tap-hole is driven primarily by the hydrostatic pressure generated by the weight of the solid and liquid phases above the tap-hole."

Jun 1, 2019

May 1, 1997

By G. B. Shea

Among the many engineering problems directly related to conservation in the petroleum industry, that of crude-oil emulsions continues to be important. Emulsions of water and oil always have constituted one of the most serious forms of waste in the oil fields, and the necessity of dehydrating emulsified crude petroleum to obtain marketable or pipe-line oil confronts operators in many fields with a major operating problem. In 1926 the Bureau of Mines published a comprehensive treatise s on oil-field emulsions dealing with field conditions, practical methods of dehydration, and physicochemical characteristics of the formation and resolution of emulsions. Although this bulletin is still available and may be obtained from the Superintendent of Documents, Washington, D. C., and although its contents are a valuable reference on the subject of emulsions, knowledge regarding the physical properties of emulsions and the phenomena of dehydration has increased greatly within the last decade. With the information gained through continued scientific research, substantial improvements have been made in the art of resolving petroleum emulsions. Moreover, in recent years there has been a growing realization of the importance of emulsion-preventive measures that has led to more critical examination of the causes of emulsions and methods of eliminating or at least reducing the degree of emulsification. Conditions causing agitation and commingling of oil and water and the formation of "cut oil" often are within the control of the producer, thereby making it possible to utilize preventive or remedial measures by which emulsification may be minimized or avoided. In fact, many companies have materially reduced their treating costs as a result of careful studies in emulsion prevention and proper handling of "wet" production. Of course, in many instances preventive measures or the correction of conditions causing emulsification cannot be achieved practically or economically, and the emulsions that form must be treated regardless of the care exercised or the money spent in attempting to prevent their formation.

Jan 1, 1939

By R. A. Cummings

Certain roof shales in coal mines deteriorate upon exposure to the atmosphere, causing difficulties in the mining operations and adding to the cost. This report presents the results of both field investigations, in a West Virginia mine, and laboratory studies on the effects of atmospheric moisture on roof shales. Based on these observations a conceptual procedure is presented on how shale deterioration might be predicted during exploration, and guidelines are given as to how air tempering or conditioning chambers may be designed to reduce moisture effects. Recommendations for further studies are included. An annotated bibliography of the literature constitutes the second volume.

Jan 1, 1981

By Thys B. Johnson

The mine system analysis and evaluation study presented in this report was part of the U. S. Bureau of Nines' Tertiary channel project conducted under the Heavy Metals program. The Badger Hill pit, located on the west end of the San Juan Ridge area, near Nevada City, California, was the site of the Bureau's field work. The objectives of this study were: (1) Determine potential alternative mining systems for some of the large tertiary channel gold-bearing gravel deposits, and (2) Identify areas of technology where further investigation would be merited because of their potential inclusion in a mining system for such deposits, The study involved the development of a mineralized block inventory, an economic block inventory, determination of optimum ultimate mining limits and a preliminary economic mining system evaluation. Computer programs were developed and utilized for each of the study phases stated above. The sampling program conducted at Badger Hill by the Bureau Delineation Group together with confidential drill hole data provided by the San Juan Gold Co. formed the basic gold values and distribution information from which a deposit model was developed. The deposit was divided into minable block units and net economic values were assigned to each block for various configurations of both open-pit and underground mining methods based on cost and performance data provided by the various Bureau of Mines Research Centers. A number of controllable variables such as: (1) Mining method (open-pit and underground), (2) depth of mining cut, (3) production rate and (4) equipment type and capacity were evaluated. The prime measures of effectiveness on which the mining systems where judged were discounted cash flow rate of return and maximum utilization of natural resources. The analysis showed that underground mining of the Six-Mile Tertiary channel gold-bearing gravel deposit under consideration was uneconomical and did not permit maximum recovery of the resources within the channel. It was also apparent that mining the Six-Mile Deposit for gold alone is uneconomical or at best marginal at a gold price less than $80 per ounce. The analysis showed that the potential for an economic mining operation within the Six-Mile Deposit exists when the gravel resources of the channel are considered together with the gold. It was determined that the highest rate of return would be realized with a 20-year open-pit mining operation yielding 745,000 ounces of -gold and 55 million cubic yards of usable gravel.

Jan 1, 2012

By J Crosbie, M Lord, R Bitencourt, P Defferrard

The MMG Century mine, which is the largest zinc/lead mine in Australia, began operating in 1999 and ceased mining from the open pit in July 2015, with processing completed in early 2016. Closure plans were developed from 2006, and detailed planning for closure commenced in early 2011 with the appointment of a dedicated closure planning resource. The site will continue to be managed during the active and passive closure phases to complete rehabilitation commitments and demonstrate that closure completion criteria have been achieved.Completion of the mining/processing phase of the project provides an opportunity to reflect on successes, missed opportunities and lessons learnt with respect to planning and execution of mine closure. This paper highlights examples of success at Century and also identifies key learnings and areas for improvement in progressive closure outcomes. Specific examples examine mine planning and execution involving bulk movement of waste rock and construction of permanent waste encapsulation landforms. The paper also provides recommendations for other sites that are planning for closure.Decisions made during the operational phase of the project life can result in a significant increase in closure liability and reduce the likelihood of achieving lease relinquishment. Likewise, it is of paramount importance to assess the consequences and thoroughly understand the risks associated with changes or deferral of closure plans, progressive rehabilitation targets and closure related key performance indicators.CITATION:Lord, M, Bitencourt, R, Crosbie, J and Defferrard, P, 2016. Closure planning lessons Learnt from the Century mine, in Proceedings International Mine Management Conference, pp 207-216 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 22, 2016