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By Frank Rausche

Since the early 1980s, when the Road Construction Authority of Victoria authorized the dynamic proof testing of roughly 100 drilled shafts of 1.5 m diameter and typically 60 m length in Melbourne Australia, dynamic load testing has been applied worldwide for quality control of drilled shafts. Today, test capacities of 4000 tons or more are not unusual. On numerous occasions the authors have been involved in similar tests in the United States and test engineers from other countries have reported on experiences in many different countries. Without doubt, generating high test loads is most economically accomplished by dynamic load testing and this method is particularly well suited for testing piles founded in rock because of the rocks low energy dissipation. However, deep foundation professionals have on occasion expressed reservations about subjecting a drilled shaft to impact loadings fearing, for example, a degradation of the shaft ? rock interface properties or potential error sources due to uncertain concrete properties or shaft geometry. This paper will present numerous case studies, demonstrating the performance of rock socketed drilled shafts under dynamic loads. It will discuss the mechanics of the dynamic tests and the method of data interpretation, addressing the concerns stated above and investigating the limitations of the test method. The paper will formulate a set of recommendations for the design and execution of these tests.

Jan 1, 2006

By John P. Davis

The use of conventional, circulatory air rotary and fluid rotary, cased and uncased drilling methods in the vicinity of sensitive infrastructure can have deleterious effects on the ground conditions surrounding and supporting structures and the structure itself. Furthermore, the use of these conventional methods offers the engineer or contractor little information about the condition of the subsurface during geotechnical applications. Conversely, sonic drilling measurements and samples can be used to evaluate actual conditions during the progress of exploration and construction across a given site. This paper will discuss the history and properties of sonic drilling and explore case histories of geotechnical applications for the advancement of boreholes within vulnerable structures and on sensitive sites for several recent infrastructure projects ? a tunnel and railroad project, a dam grout curtain project, a bridge micropile exploration project and a tunnel instrumentation project. Project summaries will discuss the advantages realized when the application of sonic drilling techniques demonstrated superior accuracy, quality control, efficiency, productivity, penetrability, waste minimization and adaptability when drilling adjacent to or within existing infrastructure. Finally, the discussion will address the current testing and application of sonic drilling to the installation of micropiles, earth retention anchors, grout injection and instrumentation installation where the quality control benefits provided by the inherent soil cores, measurement while drilling systems, accuracy and non-destructive production drilling features will be advantageous.

Jan 1, 2006

By Lewis Martin

Spokane Research Center personnel are currently conducting research on cable bolts to assess their material and support properties, to provide design criteria for roof control systems under various types of underground mining conditions, and to provide background data for computer models of cable bolt supports. Laboratory studies of cable bolts made of conventional steel cables with Garford bulbs and collars resulted in recommendations on characteristics such as embedment length, hole diameter, cable bolt diameter, and configuration of cables. A completed series of laboratory tests has determined the minimum embedment length of resin required for resin-grouted, cable bolt ground support.

Jan 1, 1996

By Patrick Frenette

The Goldex Mine is an underground gold mine using a unique mining method where a single very large stope is being created. In order to maintain stability of the walls and roof of the stope which is 450m, 250m high and up to 120m thick, ore is left in the stope as long as possible and acts as backfill would do. At many occasions during the mining sequence, the walls will be exposed on height ranging from 30 meters up to 250 meters. A monitoring system comprising in-stope laser surveys, a seismic system and an array of extensometers and sloughmeters all remotely connected to surface is used to observe the shape and evolution of the stope. This paper will focus on the results obtained following some of the large blasts and on the long term monitoring of the stope.

May 1, 2011

This paper sets out to examine the possible relationships between three factors, they are, the rate of growth of world production of minerals, the growth of Australian production and the growth of scientific and engineering knowledge.The first two are quantified, in terms of tonnes and value. The third, an abstract concept "knowledge", requires to be quantified, in terms of manpower.A mathematical model, which has general application, was derived to demonstrate certain axiomatic premises and to define, more precisely, basic concepts related to the philosophy of knowledge.Finally a summary is made of education-cum-industry issues.

Jan 1, 1981

By H. S. Price, J. C. Cavendish, R. S. Varga

A numerical formulation of bigh-order accuracy, based on variational methods, is proposed for the solution of multidimensional diffusion-convection-type equations. Accurate solutions are obtained without the difficulties that standard finite difference approximations present. In addition, tests show that accurate solutions of a one-dimensional problem can be obtained in the neighborhood of a sharp front without the need for a large number of calculations for the entire region of interest. Results using these variational methods are compared with several standard finite difference approximations and with a technique based on the method of characteristics. The variational methods are shown to yield higher accuracies in less computer time. Finally, it is indicated how one can use these attractive features of the variational methods for solving miscible displacement problems in two dimensions. INTRODUCTION The problem of finding suitable numerical approximations for equations describing the transport of heat or mass by diffusion and convection simultaneously has been of interest for some time. Equations of this type, which will be called diffusionconvection equations, arise in describing many diverse physical processes. Of particular interest here is the equation describing the process by which one miscible liquid displaces another liquid in a one-dimensional porous medium. The behavior of such a system is described by the following parabolic partial differential equation:

Jan 1, 1969

Experiment of Improving the Quality and Decreasing the Impurity of Titanium Concentrate in Panzhihua Mine in China

Sep 13, 2010

By McHenry Mosier

The Bureau of Mines, United States Department of the Interior, has established a testing adit on the Government reservation at Mount Weather, Virginia, to facilitate research on the fundamentals of mining under actual metal-mining conditions. A number of sites in several Eastern States were investigated, but Mount Weather was selected because the rock seemed best suited for rock drilling and other mining tests and because the ground was already owned by the Federal Government, the site having been acquired in 1902 for use of the Weather Bureau. The testing adit has an advantage over an active metal mine for certain investigations because variable conditions affecting any particular research problem can be controlled and maintained in a fixed status, whereas in an operating mine this seldom is feasible. Operations were begin in September 1936, with a crew of four laborers under a resident engineer. The laborers were recruited from nearby farms, and although they had no previous mining experience, they have developed into satisfactory miners.

Jan 1, 1939

By D N. B Skinner, R L. Brathwaite, M S. Rattenbury

The Institute of Geological and Nuclear Sciences Ltd has carried out a mineral resource assessment of the Coromandel region, one of the most mineral-rich regions of New Zealand. The assessment focussed on metallic minerals and clays, because these are the main commodities that have potential for increased production and export from the region (and from New Zealand).   Three steps were used in the assessment: 1) development of mineral deposit models, 2) comparison of the models with regional geology, structure, geochemistry and past mineral production to estimate the number of undiscovered mineral deposits, and 3) application of grade-tonnage models to determine the quantity and value of the known and undiscovered resources. In step 1, descriptive and grade-tonnage mineral deposit models were developed for 11 different types of mineral deposits: ò     Low-sulphidation andesite-hosted epithermal Au-Ag ò     Low-sulphidation rhyolite-hosted epithermal Au-Ag ò     High-sulphidation quartz-alunite epithermal Au ò     Porphyry Cu-Au-Mo ò     Andesite-hosted polymetallic veins adjacent to mineralised porphyry stocks ò     Zn-Pb-Ag skarn ò     Cu-Ag skarn ò     Hot spring Hg ò     Shoreline placer Ti ò     Rhyolite-hosted halloysite clay ò     Volcanic-related kaolinite clay   Step 2 was aided by a geographic information system (GIS) assembled from a number of digital spatial data sets including: a digital elevation model, an aeromagnetic map (from open file mining company data), a geological map (from the GNS QMAP project), location of areas of hydrothermal alteration, locations of mineral deposits (from the GERM database), stream sediment geochemical analyses (from the REGCHEM database), and a lineament map derived from satellite remote sensing data and the digital elevation model.   Based on May 2001 commodity prices, potential resources estimated for the 11 mineral deposit and grade-tonnage models total NZ$22 806 million for the metallic minerals, NZ$1000 million for halloysite clay deposits and NZ$57 million for kaolinite clay deposits.

Jan 1, 2001

IN the recent monograph on Broken Hill, N.S.W., by E. C. Andrews,* two independent petrological reports appear as Appendices 1 and n, by W. R. Browne and F. L. Stillwell respectively. In these considerable differences of opinion occur. Andrews contributes to some of the questions at issue, but no analytical review of the differences appears in the body of the report. Their development may invite question, and the following notes have been prepared partly in explanation and partly as a summary of some of the divergences. The soope of Browne's report extends over the whole district of Broken Hill, while Stillwell's deals with the rocks within 25 chains of the main lode. The more difficult and important rock-types occur in both areas, raising similar questions. In both cases observations extended beyond the limits of the prescribed areas. Broadly, Browne faces his problem as a study of a series of primary igneous rooks, acid and basio, whioh are intrusive into a series of sillimanite gneisses. The development of the sillimanite gneisses is regarded as belonging to an earlier period than the intrusion of the igneous rooks, while the gneissio structures of the latter are features which are incidental to their orystallization, and are not acquired subsequent to their consolidation. He finally produoes a picture in which his views of igneous injection and differentiation takes a prominent place. One direct result is the claim that three separate periods of metamorphism have oocurred in the Broken Hill area. Stillwell primarily examines the rooks as schists and gneisses since their present dominating features have been acquired during metamorphism. The effort is made to understand suoh differences as might arise from differing conditions of metamorphism upon rocks of similar and different oonstitution. The aim is to divest the rocks of those oharaoters which are due to metamorphism before approaching the questions of intrusive relatio'nships between igneous rocks andsediments.

Jan 1, 1924

By R Handfield, G Kary, Frieda Project

Recent exploration by the Cyprus Amax-Highlands Pacific-OMRD Joint Venture at the Frieda River project, PNG has demonstrated the extent of igneous phases, alteration and mineralisation, and the relationships between the various mineralisation styles in this major Cu-Au porphyry-epithermal system. The project area is in the obducted volcano-sedimentary section of the New Guinea mobile belt 78 km NE of Ok Tedi. It is between two major NNE dipping faults interpreted to have undergone thrusting then sinistral shear in the Late Miocene to Recent. The Frieda River Igneous Complex is a 15 km +7 km ovoid area with a central pod of basaltic andesite volcanics with cogenetic diorite to quartz diorite subvolcanic intrusions, and flanking clastic sediments. A series of late-stage, hornblende quartz diorite plugs ring the main igneous mass. The igneous rocks have a normal K calc-alkaline character with a very limited compositional variation. The intrusives are exposed on the eastern flank of the complex and have five mappable units and numerous defined phases. The southeastern quarter of the complex is host to a cluster of at least seven stockwork porphyry copper and skarn-hosted deposits within an area of 4.5 +3.5 km. The Horse-Ivaal and Koki deposits have identified resources totalling 804 mt @ 0.46 per cent Cu and 0.3 ppm Au, and the other deposits are in various stages of exploration. All these deposits are related to the Horse Microdiorite phase of the Complex and are outlined by a zone of potassic-propylitic-SCC alteration. Local overprinting argillic and advanced argillic alteration is related to a separate, post-porphyry mineralisation intrusive phase. The recent emphasis has been on the identification of higher-grade zones using ideas of structural control and specific intrusive-alteration-mineralisation relationships within the known resource areas. An elongate area 13 km x 4 km in the centre of the Complex has advanced argillic alteration in the volcanic rocks. This alteration zone hosts the Nena deposit (52.8 mt @ two per cent Cu and 0.7 ppm Au) and approximately 20 prospects of high sulphidation type. These deposits are distributed along two prominent NW-trending siliceous ridges interpreted as regional scale structures. Nena is a pod of vein and replacement sulphides hosted in a tectonically controlled multiphase breccia that overprints the advanced argillic alteration. The Nena deposit is 4 km from the nearest of the major porphyry occurrences. It is underlain by basemetal veins and minor porphyry mineralisation that are related to the Flimtem Trachyandesite intrusive phase. The recent search for additional Nena-type ore has focussed on the siliceous ridges using detailed structural and geochemical ore control criteria. Widespread, but poorly mineralised, basemetal-bearing carbonate and sulphate veins form a ring around the mineralised area. These veins have sericitic selvages, cut the porphyry mineralisation, but are cut by and locally underlie the silica-alunite phase of the advanced argillic alteration. The current model is that there are discrete intrusive phases responsible for each of major hydrothermal events at Frieda. These include from oldest to youngest:the Koki phase has no related alteration or mineralisation; the dominant Frieda phase has the hornfels, early skarn and minor magnetite-chalcopyrite mineralisation; the Horse phase has the bulk of porphyry copper and skarn-hosted mineralisation and minor basemetal veins; the peripheral Knob phase is barren; and the Flimtem phase has the high sulphidation epithermal deposits and minor porphyry and vein mineralisation. The intrusive phases span the interval 17 to 11.5 Ma and are co-magmatic. They represent discrete batches off the parent magma, rather than simple fractionation products.

Jan 1, 1999

By P. H. Williams, D. J. Morris

The co-disposal of coarse and fine coal wastes by combined pumping through a pipeline to subaerial deposition was pioneered in Australia in 1990 by Jeebropilly colliery in Queensland. Significant segregation of fines is found to occur in its co-disposal delta, leading to the formation of distinct mainly coarse upper and fine-dominated lower segments; the upper delta drains rapidly and is able to support traffic on its surface immediately after deposition. An existing theory of subaerial deposition, originally developed for mine tailings alone and later extended to trial co-disposal, is shown to apply also to the upper segment of the full-scale Jeebropilly delta

Jun 19, 1905

By David Newman

Multiple seam underground coal mining is ubiquitous in Appalachia. Many coal properties have from two to ten or more economically mineable coal seams. Because of the ability to penetrate 600-feet to 1,000-feet or deeper into the mountainside leaving panels of web pillars separated by barrier pillars, highwall mining is a hybrid between surface and underground mining. As a result, many of the ground control problems commonly associated with multiple seam underground mining exist with multiple seam highwall mining. These include: i) superjacent mines, subsidence and caving propagating to overlying seams and ii) mines, pooled water and the potential for inundation resulting from a iii) breakthrough between an active highwall mine and abandoned underground mines in the same or superjacent seams, the presence of overlying or underlying mine workings where iv) pillar columnization in the active mine is not possible, and v) the question of whether to mine ?top-down? or ?bottom-up.? Case histories are presented from southeast Ohio where the Middle Kittanning No. 6 and Lower Kittanning No. 5 seams are successfully highwall mined with 20-feet to 40-feet of largely shale interburden. A highwall miner was caught in a highwall collapse in the Middle Kittanning No. 6 seam when it was overmining auger workings in the Lower Kittanning No. 5 seam. Multiple seam interaction caused by the overmining transferred overburden stress onto the Lower Kittanning No. 5 seam. The overburden concentrated through web pillars initiated auger web pillar failure, resulting in roof collapse and subsidence in the Lower Kittanning No. 5 seam that propagated up to the Middle Kittanning No. 6 seam. A second case history involves multiple seam highwall mining in southeast Kentucky. The A3 Rider, A3, B2, and C1 seams are being highwall mined around abandoned underground mines in the A3 and B2 seams and augering in the A3 Rider. Because of spoil storage constraints for the surface contour mines, the highwall miner follows the active pits in each seam so a standard sequence of ?top-down? or ?bottom-up mining does not exist. The planning and engineering design considerations associated with each case history is presented along with geotechnical information. In the case of the highwall collapse a back analysis is presented of the stability and safety factors for the auger webs, highwall miner web pillars, and barrier pillars.

Jan 1, 2009

By A A. Ndiaye, A Galli

In a companion paper on current hedging practices in the mining industry (Armstrong et al, 2009) we showed that contrary to popular belief, mining groups are still using financial derivatives to hedge against foreign exchange risk and interest rate risk, and more recently against adverse changes in energy prices, notably the oil price. This paper presents a case study on a hypothetical gold mine to illustrate the impact that hedging policies could have on its profitability by reducing the downside risk due to adverse changes in the exchange rate and increases in fuel prices. The characteristics of the hypothetical mine have been set to reproduce those of a real gold deposit, the Kisladag mine that is currently being exploited by open pit methods in Turkey. This mine was selected because its feasibility study was available to the public. Geostatistical simulations are used to reproduce the inherent uncertainty on the recoverable reserves û stochastic simulations are used to generate the variability of the other three key sources of uncertainty: the gold price, the cost of energy and the exchange rate. A simple strategy based on straightforward vanilla options (puts and calls) was developed for hedging the last two risks, on the assumption that the company sells its production at the prevailing spot price.

Jan 1, 2009

By K. Loutet, A. Guenkel, K. Nikolaisen

"The INCO SO2/air process was patented by INCO in 1985. Well over 80 mining operations worldwide are using this process to oxidize cyanides to cyanates in the tailings from gold, silver and copper mining operations. The sulphur dioxide (SO2) for this process can be supplied either as liquid SO2, SO2 gas or as a sulphite-based salt. The majority of SO2/air operations have used sulphite-based salts as the ‘SO2’ equivalent probably due to low capital cost. Liquid SO2 has also been used frequently, but due to concerns with safety and availability, this option is often not preferred. The solid salt sodium meta-bisulphite (SMBS) is commonly employed, but its cost is an order of magnitude higher than that of sulphur. Due to the high cost of SMBS, the increased capital cost for a sulphur-burning SO2 gas plant (green field or retrofit) usually has a pay-back of less than three years. In addition, a SO2 gas plant offers potential for significant heat recovery from the sulphur burning process. In terms of safety, the SO2 gas plant only requires the storage of relatively benign sulphur and the site inventory of SO2 will be limited to the plant gas volume. Therefore, a SO2 gas plant will not trigger the Canadian Environmental Protection Act (CEPA) E2 Regulations or the US Clean Air Act Section 112(r) accident prevention regulations, as may be the case for liquid SO2.Most existing mining operations using ‘SO2’ are gold operations, but in recent years there has been an increased interest in larger sulphur dioxide gas plants for hydrometallurgical facilities that employ leaching of cobalt/manganese minerals or precipitation of manganese/iron (e.g. Tenke Fungurume and El Boleo).This paper focuses on the production of sulphur dioxide gas generated on site and on demand for the use in hydrometallurgical processes. The capital and operational costs of a SO2 gas plant is compared to conventional process alternatives using sulphite-based salts or liquid SO2."

Jan 1, 2016

By Green P. F

Apatite Fission Track Analysis (AFTA) is a thermal history reconstruction tool that enables determination of magnitude and timing of maximum paleotemperature and paleo-geothermal gradient at the time of maximum paleotemperatures. From this information, the amount of section missing at major unconfornities can be estimated and incorporated into basin models. The Gippsland Basin has a number of distinct problems that can be tackled using AFTA. 1. The nature of the regional break between the Late Cretaceous-Tertiary Latrobe Group and the underlying Early Cretaceous Strzelecki Group. 2. The tectonic history of the basement flanking the basin and its effect on sediment composition. 3. The age of igneous activity in the basin, as typified by the widespread basaltic plugs and dykes intruding the outcropping Strzelecki Group. Major uplift and erosion within, and adjacent to, the early Cretaceous rift basin in the Mid-Cretaceous, at -95 to 100 Ma, initially constrained the Latrobe Group depositional area to the central deep of the Gippsland Basin and provided an elevated source of quartz-rich detritus for the Latrobe Group reservoirs. This is in marked contrast to the preceding period in the early Cretaceous when contemporaneous volcanism dominated as a source of detritus, producing quartz-poor lithic sandstones, in which a host of attendant diagenetic reactions destroyed their reservoir potential. Initial uplift and erosion of the volcanogenic Strzelecki Group also occurred in the mid-Cretaceous as revealed by a number of distinct inversion structures, and erosion of this material will have locally provided very poor quality sand to the basal Latrobe Group.

Jan 1, 1992

By JeffreyS. Vipperman, Daniel R. Babich, EricR. Bauer

In response to the continuing problem of noise induced hearing loss NIHL among mine workers, the National Institute for Occupational Safety and Health NIOSH has conducted numerous noise surveys in coal preparation plants. The research, consisting of worker dose monitoring, task observations, and equipment noise profiling, was completed in eight separate preparation plants. Worker dose monitoring was conducted for three shifts in most cases. Workers experiencing higher than allowable doses were task-observed for one full shift to correlate dose to noise source(s). Finally, noise levels on all floors, and in lunchrooms and control rooms, were characterized. Results indicate that only workers who routinely spend a significant portion of their shift in the plants (away from the control rooms) are susceptible to overexposure from noise. Certain pieces of equipment (screens, centrifuges, sieve bends) are the loudest primary noise sources responsible for the worker noise exposures.

THE furnace described in this paper was installed and has been used by the writer for the melting of rich gold-bearing material, and has given complete satisfaction. It may, therefore, prove of interest to other metallurgists who are faced with a similarproblem. A furnace of this type should be most suitable for the reduction of "cyanide preeipitate," "charcoal ash," "anode sludge," &c. formerly the melting was done in fire-clay crucibles, using coke or crude oil as fuel, but this method is costly, slow, and unsatisfactory. A small water-jacketed blastfurnace was also tried on this material after briquetting it, but was discarded in favour of the electric furnace. The furnace may be described as a simple form of the Heroult resistance furnace, with an adjustable upper electrode and a fixed bottom electrode. This is in accordanee with Stansfield's classification of electric furnaces. The heating is mostly due to the resistance offered the current by the molten slag. The melting chamber consists of a steel drum 14 in. in diameter and 21 in. high, and is lined with silica bricks specially made to fit the shell. The internal diameter is G in. The bricks contain 92 % silica, are made from calcined quartzite bonded with fireclay, and are similar in composition to those used for lining steel converters. They are set in a mixture of finely-ground quartzite and clay, and well dried out. The shell is bolted to a steel plate, which forms the decking of a truck running on rails, so that the furnace can be moved under ahood for carrying off the fumes. A cast-iron slag spout is bolted to the shell below the tapping hole, which is 4 in. from the bottom of the shell. Opposite this another hole 1 in. in diameter is drilled through the shell and lining for the passage of the lower...

Jan 1, 1918

By David B. Paul

"ABSTRACTThe US Army Corps of Engineers (USACE) has 704 dams in their inventory and over 100,000 miles of levees with a capital value of over $150 billion. Currently, there are 319 dams that are classified as high hazard and have actionable failure modes that will require structural modifications. The most frequent actionable failure mode associated with the inventory is seepage and piping. One of the most effective engineering solutions is the installation of a cutoff to limit seepage. Currently, USACE has over $1.5 Billion of cutoff wall projects under construction and/or design. Given the magnitude of the dam and levee safety issues, USACE is developing a new Engineering Manual (EM) titled “Seepage Control Cutoffs for Dams and Levees.” This EM covers all of the methods to construct cutoff walls. USACE has partnered with the Deep Foundation Institute (DFI) in preparation of the EM to ensure that it is comprehensive and draws from the expertise of the specialty foundation engineering companies that design, manufacture, and construct seepage control cutoffs around the world. The EM contains case histories as well as a comprehensive project statistical summary and guide specification paragraphs. The goal of USACE was to make the EM a state of the art document for use by Districts.HISTORYSlurry wall construction techniques were developed in the late 1940’s in Italy by ICOS. The first use of the slurry trench method of construction in the United States was by the USACE Memphis District in September 1945, to form a partial cutoff along the Mississippi River levee on the Arkansas side of the river just below Memphis, Tennessee. The idea for the project probably evolved from the use at that time of puddle clay trench cutoffs combined with the use of drilling mud for advancing borings. A paddle wheel mixing device was constructed for making slurry from native clays. Trenches were dug to a 20-ft depth using a trenching machine and to a 35-ft depth using a dragline with a 100-ft boom and 2-cu-yd bucket. Backfill was mixed in windrows at the site from hauled-in clay gravel and native materials and pushed into the trench by a bulldozer when the length of the trench was equal to about twice the trench depth. It is amazing that after almost 70 years, the technique is still about the same as it was when first developed by the Memphis District. A soilbentonite cutoff was constructed under the Kennewick Levee adjacent to the Columbia River as part of the McNary Dam Project in Washington by the Walla Walla District in 1952 The first application of a soil-bentonite slurry trench cutoff for control of underseepage at a major earth dam was at Wanapum Dam on the Columbia River in Washington in 1959.The first cement- bentonite cutoff in the United States was constructed at the Tilden Tailings Project to store tailings from the Tilden Mine in Michigan in 1976. The first cement-bentonite cutoff constructed at a dam on a river retaining a reservoir in the United States was completed in 1978 at the Elgo Dam (formerly the San Carlos Dam) in Arizona.The USACE has designed and constructed some of the deepest and most complex cutoff walls for dams since the 1970’s. The first major concrete panel cutoff wall constructed in a dam in the United States was at Wolf Creek Dam (Nashville District) by the ICOS Corporation between 1974-77. The dam has a long history of seepage issues associated with the karst geology that comprises the foundation. In 1968, about 17 years after first being impounded, wet areas, muddy flows in the tailrace and sinkholes in the downstream toe adjacent to the switchyard occurred."

Jan 1, 2014

By L. E. Lynd

Ilmenite concentrates prepared from beach and dune sands of Florida, India, Australia, and other localities deviate to varying degrees from the theoretical composition of pure ilmenite, and generally contain more TiO2 than the formula FeTi03 would indicate, and some Fe2O3. This variation in composition is due to different amounts of altered ilmenite in the concentrates. (') The alteration has been shown to take place by oxidation and leaching of the iron in ilmenite, to yield residual products consisting of amaphous or very finely crystalline titanium dioxide and ferric oxide. Other studies(2) have stressed that ilmenite may alter first to an amorphous titanium-iron oxide, or to an amorphous mixture of titanium and iron oxides, with later alteration to crystalline titanium dioxide. There has been some speculation as to whether alteration of ilmenite is usually caused by weathering or by hydrothermal pr0cesses.(3,4,5 Three main methods of approach were used to study the mechanism and rate of ilmenite weathering. (1) Etch tests were used to learn the relationship between crystallographic orientation and the rate of chemical attack on ilmenite. (2) Altered ilmenites in New Jersey sands were compared with ilmenite in rocks of the area from which the sands were probably derived. (3) Experiments were carried out to determine at what rate, and by what agents, originally fresh ilmenite could be altered in the laboratory under simulated weathering conditions. ETCH FIGURES ON ILMENITE CRYSTAL PLANES A rather large ilmenite crystal from Sannidal, Norway, about 11/2 x 11/2 x 2 inches, bearing a few natural faces with imperfect surfaces, was prepared for etching by grinding and polishing crystal planes whose Bravais-Miller indices (referred to hexagonal axes) had been determined by X-ray methods to be 00.1, 10.0, and 10.2. Metallographic examination showed that the crystal was homogeneous, and uniform in orientation, except for the presence of twin lamellae which were oriented with their broadest surfaces parallel to the 00.1 planes of the large crystal. Since ilmenite is rather inert to standard etch reagents, strong solutions of hot sulfuric acid and cold hydrofluoric acid were used. Preliminary tests established that better etch figures were obtained using HF than with H2So4 solutions. The etch figures produced on 00.1 and 01.0 planes of ilmenite by etching 3 to 5 minutes in cold concentrated HF solution are shown in Figures 1, 2, and 3. The figures on 00.1 are "etch hillocks", rather than pits, and according to Honess(6), this phenomenon

Jan 1, 1961