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By D R. Peacor, J L. Mauk

Dioctahedral clay minerals in the volcanic-hosted Golden Cross epithermal Au deposit, New Zealand, have been investigated by petrography, X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy/analytical electron microscopy (TEM/AEM) to determine the nature of these minerals in a hydrothermal ore deposit. Heterogeneity in the distribution of dioctahedral clays is observed from the hand-specimen scale to the TEM scale, indicating that primary rock textures and fluid pathways (related to rock type, porosity/permeability and fluid/rock ratios), in addition to temperature, are important factors controlling the distribution. As the proportion of illite in mixed-layer illite/smectite (I/S) decreases, TEM observations show decreasing layer stacking order, parallelism of packets, and packet size, and increasing apparent porosity. AEM structural data show a corresponding decrease in AlIV, AlVI, and K+, and an increase in Si, Ca2+, and Fetotal. The observations of this study indicate that local dioctahedral clay mineral reaction progress is controlled mainly by permeability and structure, but that this is superimposed on a predictable, system-wide clay mineral distribution that is controlled by temperature and fluid/rock ratio.

Jan 1, 1999

By P. C. Guillaume

Global plant modernizations or expansions cannot be considered in the same light as any other industrial investment project. Relationships between the partners, relationships and communications with the client, structure and organisation of the teamwork, schedule of the work, and a lot of other tasks and missions devoted to external contractors have to be defined considering one fundamental input: an operating plant. For an engineering company expert in processing, like UM Engineering, such a context requires a specific approach as well as specific procedures able to efficiently challenge the generated constraints. First of all, even if a detailed audit had been conducted at the beginning of the conceptual engineering phase, new elements will be discovered during the preparation and realization of the project, and must be continuously integrated. Consequently, a close proximity to the site is necessary. This is one reason why UM Engineering, most often, works in partnership with a local engineering company. The second important point for the client is that the operation must not be interrupted during the realization. In order to make that possible, UM Engineering has defined a specific project structure and organisation, integrating on a permanent basis the operators (the "users") in the project teams. This paper presents the way UM Engineering copes with this type of "multi-constraints" context with reference to the recent copper cellhouse modernization under realization for the CCR Refinery of Noranda Inc. in Canada.

Jan 1, 1999

By C. Anderson

Most applications of copper metallurgy are geared towards primary production. However, as recycling of materials is a growing industry, one future facility will rely on copper metallurgy as a means of processing precious metals. This paper will discuss the derivation of the proposed copper pyrometallurgical and electrometallurgical unit operations to be utilized in industrial recycling of secondary precious metals.

Jan 1, 1999

By C. J. Webb, C. J. Paterson, A. Davis

This work focused on identifying, examining and ranking the physical and environmental hazards at inactive and abandoned mine sites in the Black Hills of South Dakota. Earlier inventory projects in the Black Hills concentrated on federal lands, while more recent efforts have examined abandoned mines on state and private lands. The more recent efforts are a result of passage of legislation by the State of South Dakota requiring a comprehensive inventory. The inventory information provides criteria for identifying those sites that require further investigation or characterization of the physical safety or environmental hazards. For most AML sites in the Black Hills, location information is all that is typically needed, because the majority of sites pose little environmental or physical hazard.

Jan 1, 1999

The Elgas Underground Storage Facility at Port Botany, Sydney, is the first purpose-built cavern of its kind in Australia and allows large capacity, safe and environmentally benign storage of Liquefied Petroleum Gas (LPG). The facility provides Elgas with the flexibility to source product at competitive prices and will ensure long-term security of supply. Construction has provided Orica Australia, formerly ICI Explosives, with a unique opportunity to provide a bulk explosive delivery system specifically designed to meet the exacting demands of the site (see Figure 1) and of the project.

Jan 1, 1999

By Andrew S. Lain

Before you begin mining aggregates in Oklahoma, you must first look at the market and ask these questions: (1) Is there a need for additional aggregate production? (2) Can we produce the aggregate efficiently enough to compete? (3) Is the deposit close enough to the market? If you can answer "yes" to each of these three questions, then you are ready to start the process for mining aggregates in Oklahoma. The first consideration to be made is whether the aggregates produced will need to meet state specifications. If you do not want to meet state durability standards, there are numerous formations you can mine and produce aggregates. We will deal only with the formations that will meet state durability standards. These formations are located in the southern half of Oklahoma and in the Tulsa area. Some of the formations that contain limestone, dolomite, and sandstone that will meet state durability tests are West Springs Creek, Kindblade, McKenzie Hill, Butterly-Royer, and Rush Springs Formations. Granite and rhyolite also are found in Oklahoma and can be used as construction aggregates. Once an area has been identified as having durable material, and drilling has verified its properties, a permit must be secured from the Oklahoma Department of Mines, Oklahoma Department of Environmental Quality, and any other applicable agency before construction of a plant occurs. There are many different brands of crushers available, but all work on one of two crushing principles-either compression breakage or impact breakage. Each type has its application in different industrial-mineral types and the desired end product. A typical small crushing plant would start with a jaw crusher for primary reduction, and then employ one standard cone and one shorthead cone for secondary reduction. One grizzly would be in the circuit with one finished-product screen and three to four finished-product stackers. Natural sands and gravels are found in rivers and old river channels. These too need to be tested to see if spec product can be produced. All of our sand operations have very little gravel; thus, we do not process the gravel. The sand is processed through classifying tanks for gradation.

Jan 1, 1999

By R. D. Prengaman

Wrought lead-calcium-tin anodes developed by RSR Corporation have improved the performance compared with the other lead alloy anodes. These anodes have been in continuous service at various locations around the world for as long as fourteen years. Calcium provides mechanical strength to the anode to prevent the deformation while tin increases the mechanical strength, reduces the rate of corrosion, prevents the formation of non-conducting layers on the anode surface, and dramatically improves the conductivity of the anode. Tin is also instrumental in developing the unique rolled structure of the anode which leads to the reduced rates of corrosion, longer life, and improved oxygen evolution. Cobalt additions to the electrolyte further enhance the oxygen evolution and improve the anode life. Higher current densities and higher operating temperatures reduce the anode life. The unique patented method of attaching the rolled anode sheet to the bus bar substantially reduces the resistance of this important joint and offers the substantial savings in power over the life of anode.

Jan 1, 1999

By Sergio Demetrio

Based on the current reality of the copper smelters industry, besides the advances that have been and are expected for the next few years, the authors present a futurist vision of the processing of copper concentrates and copper smelters in the years 2000. Outlined new development strategies and ways of improvement in this business, including research, development and management of the works that today posses characteristics of a profitable operation, as well as the changes expected with respect to the entry of new actors and the creation of new products The authors finally bet for small or tailor-made smelters with ad hoc technology for their raw materials and few units to coordinate -devoted to specific concentrates using high technology and low manpower. Considering the in-situ hydrometallurgical route, as well as the pyrometallurgical route in works or conversion facilities that buy or process white metal and produce copper and other metals associated with this such as gold and silver, besides sulfuric acid, plants which should be strategically located in zones with high sulfuric acid price to make this a product which contributes to the profitability of the business.

Jan 1, 1999

By Mark D. Cocker

Georgia?s Coastal Plain contains important sediment-hosted deposits of kaolin, bauxite, heavy minerals, sand and gravel, silica sand, carbonate rocks, and fuller's earth. Genesis, location, size, and quality of these deposits are related to terrestrial, marginal-marine, and shallow-marine depositional environments that evolved during development of the southeastern North American continental margin. From the Cretaceous to Eocene, kaolin and aluminous sediments, which contained mica and feldspar, were deposited in marshes, ponds, and bays located in deltas or behind barrier islands or spits. In the Cretaceous sediments, subsequent, intensive, in situ chemical weathering converted mica and feldspar to kaolin. Kaolin eroded from deeply weathered granitic rocks in the Georgia Piedmont was deposited in Paleocene to Eocene sediments. Subaerial exposure during the Paleocene and Eocene desilicated kaolin sediments to form bauxite. Sand and gravel, silica sand, and heavy-mineral deposits are found in Cretaceous to Eocene fluvial and shoreline sediments, some of which are associated with the kaolin and bauxite deposits. Source areas, intensive chemical weathering in the source areas, transportation by the major river systems, and deposition of these clastic sediments in similar or nearby depositional environments are common elements in the genesis of these resources. Eocene fuller's-earth deposits are opaline claystones in near-shore to shelf-marine sediments, which overlie the kaolin-bearing strata. These claystones consist of montmorillonite and opal/ cristobalite derived from alteration of diatom frustules. Favorable ocean currents provided nutrients for extensive planktonic growth. Oligocene and Miocene carbonate rocks were deposited principally in shallow-marine embayments. Miocene fuller's- earth deposits in south-central Georgia and adjacent parts of Florida contain palygorskite that formed through alteration of montmorillonite/bentonite clays. Deposition and subsequent alteration occurred in shallow, brackish-water lagoons under relatively high temperature and subtropical conditions. Middle and late Miocene phosphorites were deposited on a shallow carbonate-shelf platform and were concentrated proximal to anticlinal highs. Numerous marine transgressions and regressions since the beginning of the Pleistocene resulted in shoreline detrital deposits containing aggregate sand, silica sand, and heavy minerals on the Coastal Plain and on the Continental Shelf. Major river systems transported sand and heavy minerals from source areas in the Piedmont and Upper Coastal Plain. Deltaic deposits of heavy minerals were redistributed and concentrated by longshore currents, shoreline processes, and aeolian processes. River-terrace sediments, correlative with the Pleistocene shoreline deposits, contain sand-and-gravel and silica-sand deposits. Aeolian dune sands are associated with both Pleistocene fluvial and shoreline detrital deposits.

Jan 1, 1999

By I. S. Escobar

Copper, particularly the oxygen-free grade Cu-OFP, is a candidate material for containers for the long-term isolation and disposal of high-level radioactive waste (HLW) in underground repositories. After having been buried for a few hundred years, all oxygen will have been consumed in the repository, and corrosion of the copper will be caused entirely by contact with dissolved sulfides. Chloride is another potential corrodant, but in deep repositories where groundwater is neutral or slightly alkaline, the effect of chlorides can be ignored on thermodynamic grounds. Thus, the corrosion of copper in the presence of sulfide ion and under reducing conditions has been studied using cyclic voltammetry and Tafel slope measurements. It is possible to determine the effect of sulphide ion on copper corrosion resistance which is minimized at low temperature and also at low sulphide concentration. The presence of anions such as HCO3 under environmental conditions produces a beneficial effect because these ions are inhibitors.

Jan 1, 1999

By John W. Brown

"Adequate dust control in and around rock drills is a problem that must be solvedfor the health and safety of workers running the drill as well as those working around thedrilling operation This paper will discuss the designs available from most drill manufacturers todayand the effort ‘nvolved in keeping them effective on a productive basis."

Jan 1, 1999

By John Hartlen

"The 19th century was an ""age of gold"" and Nova Scotia experienced its share of early gold rushes. Gold mining activity in the province was focussed into three ""rushes"" which occurred, approximately, in the 1860s, 1890s and 1930s; a total recovery of 1.1 million oz. Au has been recorded. The purpose of this note is simply to chronicle the technical development of gold mining and processing in the province and to comment briefly on the recently renewed interest in this precious metal. The first public discovery of gold in Nova Scotia was made by a farmer in 1860 at Old Tangier or Mooseland, and this find sparked the province's first gold rush. The mining and milling methods of the 1860s were ingenious. Initially, arrastras, crude stone-hewn grinding mills, drawn by men, mules or horses, were widely used. Nova Scotia's first conventional stamp mill was installed at Mooseland by 1862; it was comprised of four wooden stamps and is believed to have been imported from Scotland. One of the largest waterwheels of the 1860s, reportedly 16 feet in diameter and 8 feet wide with a SO-horsepower rating, was used in the Renfrew Gold District to drive gold stamps. Steam power was also employed, and many of the engines were of native construction, as was the unit at Waverley's Lake Major Company, which had a piston 1 foot in diameter by 12 feet long and was connected to a 16-ftdiameter flywheel."

Jan 1, 1999

By J. S. Lee

A new high performance adsorbent is synthesized by the sol-gel method and applied to the removal of cadmium and mercury ions from aqueous solutions. Adsorbents based on metal oxides have been developed by immobilizing chelating molecules on the surface of the existing metal oxide networks and show ability for selective metal extraction from aqueous solutions. However, efficiencies of such adsorbents are limited due to low ligand density, and difficulty in pore accessibility. These difficulties are circumvented by synthesizing adsorbents using the sol-gel technique. In one example to be discussed, the sol-precursor possesses an organic moiety that binds cadmium, mercury, and copper ions. The capacities of 1.98mmol Cd(II-/gm and 6.40 mmol Hg/gm of this adsorbent are considerably higher than those of adsorbents prepared by the ligand immobilization technique. The scope of this paper is to discuss the development of the new adsorbent and its applications for cadmium and mercury removal from aqueous solutions.

Jan 1, 1999

By J. F. Leroux

The Gaspé smelter at Murdochville, Quebec, Canada introduced concentrate injection into elongated Peirce-Smith converters sized 1.96m x 12.5m (13 ft. by 41 ft.) in 1996, and commissioned a large, converter-like bath smelting vessel in April 1998. The new vessel, which is sized 4.27m x 16.1 5m (14ft. by 53ft.) has several interesting features designed to effectively utilize bath smelting technology for the requirements of the Gaspé smelter. For example, the vessel can operate on concentrate injection at upwards of 60-80 tph rate on an instantaneous basis, can operate as a large Peirce-Smith converter, while it is also fitted with matte and slag tapholes much akin to Noranda Process reactor, and includes a novel cold charge addition system. The new technology will eventually allow the capacity of the plant to increase from about 300,000 tonnes of concentrate per year to over 350,000 tonnes of concentrate per year while improving sulfur capture.

Jan 1, 1999

By Dale S. Preece, Stephen H. Chung

"In bench blasting, the distribution of loaded explosives with respect to the burden rock has strong effects on digging especially at the toe area. Blast design often focuses on other results such as percent-cast or fragmentation, sometimes leaving a diggability problem at the toe of the blast that is not discovered until excavation. A method for assessing the influence of blast design on diggability has been developed. This method relates the kinetic energy and rock displacement experienced by the material in the muckpile to its diggability. Simulation of the blast along with the calculation of kinetic energy and diggability is done with the discrete element computer program DMC_BLAST(DMC: Distinct Motion Code)."

Jan 1, 1999

By A. W. Laughlin

Analytical costs are a major part of exploration programs in developing nations which may lack adequate laboratories. Laser-Induced Breakdown Spectroscopy (LIBS), a variant of atomic emission spectroscopy, can reduce exploration analytical costs and can provide the analytical results in <1 minute. CPI is now marketing battery-powered, backpack mounted analyzers, using LIBS to analyze for many elements of interest to the explorationist. LIBS is well suited to the analysis of elements in industrial minerals. Limits of detection in ppm for some of these are: Li-1, Be-2, Na-100, B-33, Sr-10, Ba-300, Cs-1, K-500, Fe-500, Mg-500, and Ti-500.

Jan 1, 1999

By D. Kump

The Bullfrog Mine is an underground goldmine that uses the underhand-cut-and-fill mining method. The portal was established on June 18, 1991. Mining is expected to be completed by the summer of 1999. This paper starts by discussing what it took to get from nothing to 2000 tons-per-day backfill, and ends with a hindsight commentary on things that did and did not help.

Jan 1, 1999

By G. Biles

The Eskay Creek Mine, a high-grade gold and silver underground mine in northwestern British Columbia started operations in late 1994. For the first three years of operation, ore was crushed to minus 2 inch; blended to satisfy smelter terms and direct shipped to smelters in Japan and Canada. Before commencing the above operations, preliminary evaluations had indicated that an extremely complex metallurgical facility, requiring a large capital investment, would be required to recover the precious and other economic metals. Subsequently markets for raw ore were identified and underground mining and ore transportation operations, at a nominal production rate of 300 tonnes per day, were commenced. Exploration diamond drilling in 1995 and 1996 discovered additional lower grade mineralized zones, which are less economic or uneconomic as direct shipping ore. Testwork demonstrated that these lower grade zones could be upgraded to marketable concentrates in a simple flotation mill. The mill was built in 1997 and has been in operation since late 1997. The mining rate now has increased to 400 tonnes per day including 250 tonnes per day of the direct shipping ore and ISO tonnes per day of the mill ore. Prime Resources Group Inc. wholly owns the Eskay Creek Mine. Homestake Canada Inc. owns 50.6% of Prime&apos;s shares and manages and operates the mine on Prime&apos;s behalf. This paper discusses the mining and milling operations as well as ore shipment and smelter contracts&apos; administration.

Jan 1, 1999

By A. K. Kyllo

The use of Composite Furnace Module cooling systems has been shown to give improved refractory performance in a number of above bath locations in WMC flash furnaces. To test the behaviour of modules in contact with a melt, a set of instrumented modules have been installed in the reaction shaft of a. nickel flash furnace. The location was chosen to provide a suitably harsh environment to ensure rigorous testing, while still allowing relatively easy access for module installation. The modules were continuously monitored to provide information on the module performance, as well as the temperature in the shaft itself. The shaft temperature showed significant transient behaviour, which resulted in heat fluxes through the modules ranging from 10 to 92 kW m-2. The modules were capable of handling the highest heat flux with no risk of the coolant boiling. This paper details the design and operation of the modules over a period of seven weeks.

Jan 1, 1999

By S. Uihteenmaki

Pyhasalmi is a massive sulfide orebody located in central Finland. The mine has been in operation since 1962. The flotation concentrator produces Cu, Zn, Pb and pyrite concentrates. The plant has used an on-stream analyzer for process control since 1968. The original analyzer has overlived a few generations of minicomputers, but the analytical parts are essentially unchanged. The on-stream analyzer is a critical component in plant process control system, which has made Pyhasaltni one of the pioneers in the art of computer control and optimization of flotation plants. The paper summarizes the experiences gained from the use of the high performance elemental analyzer system and the proven benefits from the use of on-stream analyzers at a complex sulfide flotation. The aging analyzer is approaching the end of its useful life. A new state of the art analyzer system is undergoing testing at Pyhasalmi.

Jan 1, 1999