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By Ray H. S, Galgali R. K

It is well accepted that the blast furnace will continue as the main route for iron-making for many more years. However, its limitations have motivated researchers to look for alternative routes, particularly, those where non-coking coal is used for liquid iron production. Smelting reduction (SR), where coal and oxygen are used to produce liquid iron and power is now receiving serious attention. Several smelting reduction reactors are now operating in pilot plant scale and one or two have reached commercial status.

Jan 1, 1999

By Akira Yazawa

The composition of ferrous calcium silicate slag is located on the tie line between FeOx and calcium silicates in ternary FeOx-SiO2-CaO system. This slag has never been used as copper smelting slag because of high sulfidic copper solubility. However, when the dissolved copper in slag is just oxidic, as in direct white metal production or in converting process, this slag is quite attractive and can be regarded as the third copper smelting slag after fayalite and calcium ferrite slags. Based on the authors' studies on phase separation thermodynamics and laboratory experiments, it was clarified that the oxidic copper loss in this ferrous calcium silicate slag become the minimum not only %Cu in slag but also the total copper loss when the amount of slag is taken into account. It has been proven that calcium ferrite slag is suitable for continuous converting where the dissolved copper is oxidic, but there exist some drawbacks such as limited solubility of silica, low lead removability and too high fluidity. To overcome these difficulties accompanying traditional slags, ferrous calcium silicate slag is the hopeful alternative. In view of the general trends of modem copper smelting processes, the interesting features of this new slag system are discussed.

Jan 1, 1999

By Fathi Habashi

Nitric Acid has been used for over 50 years in the uranium industry and in phosphate fertilizer manufacture. Its application in the treatment of sulfide concentrates is relatively recent. A review of recent developments is given.

Jan 1, 1999

By F. Begazo

The most common approach to increase production in copper refineries is to increase current densities. However, if these increases are not well thought out beforehand and are not properly and effectively controlled, the end results could be reduced plant performance and a deterioration in cathode quality. Both of these factors result in lower efficiencies and increased costs. At the Ilo Refinery of Southern Peru Copper Corporation, a modernization and expansion program was implemented shortly after the Refinery was purchased from Minero Peru, in 1994. This program was intended to increase production from 195,200 mtpy of cathode to 227,000 mtpy over a 3-year period. Part of this production increase would come from increasing current density. During the period from 1994 to 1997, current density at the Ilo Refinery was increased from 218 A/m2 to 230 A/m2, while plant efficiencies were maintained at consistently high levels. The current efficiencies were maintained at >97.5% and time efficiencies were maintained at >98%. During 1998, additional increases in current density were implemented while the high plant performance was maintained at the same levels. By the end of 1998, the current density was 241 A/m2, while current efficiency and time efficiency of 98% were maintained. This paper describes the control processes used at the Ilo Refinery to maintain high plant performance levels while increasing the current density. Additionally, expected plant performances from extended test programs at current densities up to 280 A/m2, for future production increases, are reviewed and discussed.

Jan 1, 1999

By L. Cui

X. Huang (1997) recently suggested a poroelastic model for simulating the hydraulic fracturing breakdown pressure. His paper began with a discussion questioning Haimson and Fairhurst's (H&F) model. He claimed that the H&F model failed to lead to the Hubbert and Willis (H&W) model as[ a --> 0.] Huang also tried to explain why the H&F model could only work for special types of rock conditions. He pointed out that one possible reason could be that the Terzaghi's effective-stress concept had been adopted. The H&F model (Haimson and Fairhurst, 1969) was derived under the conditions that the borehole wall is fully penetrated (pp = pi) and a drained state is realized (steady pore-pressure field). Cui et al. (1997a) demonstrated that, under drained conditions, the total stresses in the penetrating poroelastic model (identical to the H&F model) degenerate into their counterparts in the elastic model (identical to the H&W model) as [a -- 0.] However, the effective-stress conditions are different for both of these models, because different pore-pressure conditions at the borehole wall were adopted. In the H&W model, p = po was assumed, i.e., the pore pressure field is not disturbed; but pp = pi was assumed in the H&F model. Assuming that Terzaghi's effective-stress controls tensile failure (that was the hypothesis adopted in both the H&F and the H&W models), only the following two special drained poroelastic cases may degenerate into the H&W model for very small a: • when the pore pressure at the borehole wall remains at the same level as the virgin pore pressure for a penetrating model and when the borehole wall is simply impermeable (i.e., the nonpenetrating model, Cui et al., 1997b). Therefore, simply setting a = 0 in the H&F model generally does not lead to the same problem described by the H&W model. On the other hand, when the porepressure boundary conditions do not correspond to the ones in the H&W model, a degeneration of the poroelastic model to the H&W model as [a – 0] should be questionable. The pore pressure at the borehole wall is generally dependent on the injection-fluid pressure and the penetrating conditions at the borehole wall, such as the existence of a filter-cake. For an impermeable wall, pp is independent of Pi, and it is basically an unknown [(how¬ever, pp -- po as t --oo).] For a fully permeable wall, pp is the same as Pi. Between these two extremes, pp should be a function of p; and the permeable condition of the borehole wall, which may be dependent of the leak-off coefficient cf. (the range of cf is from 0 to 1). Theoretically, for a rock with low permeability, a penetrating borehole wall is still possible. For saturated porous materials with very low values of a, poroelasticity shows that a pore pressure will be built up due to the stress concentration subjected to a nonhydrostatic in situ stress field (Cheng et al., 1993). This phenomenon is known as the Skempton effect. The variation of the pore pressure may be evaluated by [AP = 3 B(A rr + 06ee + A (Y,,)] (1) where B is the Skempton pore pressure coefficient. This pore pressure variation dissipates as time increases (it is totally gone as the drained state is approached). The rate of the dissipation mainly rely on the permeability of the formation. The dissipation is very slow for tight formations because their permeability is very low, and it is fast for rocks of high permeability. According to our analyses, the time period for this process could be from seconds (for sandstone's) to a couple of days (for stales). One possible reason that the H&C model did not agree well with the experimental results for rocks with low permeability might be that the time interval between the application of the loading and the fluid injection had not been long enough for the dissipation of the Skempton effect. The effective-stress law basically defines how much pore pressure contributes to the total stress. The difference between Terzaghi's effective stress and Biot's effective stress is that 100% of the pore pressure contributes to the total stress in Terzaghi's definition, while only a certain portion of the pore pressure ((ap) goes to the total stress in Biot's definition. Therefore, when the pore pressure at the boretole wall (pp) is determined according to Biot's effective-stress law, app in the total tangential stress is attributed to the pore pressure. In other words, Terzaghi's effective tangential stress is expressed

Jan 1, 1999

By M. Urda-Kiel

Stainless steel is increasingly used as a cathode starting sheet. It was shown earlier that even when depositing copper on copper, a substrate-influenced zone appears in the deposit structure, followed by a transition zone and finally by the electrolysis-influenced structure. On copper, the substrate-influenced zone has a thickness of twenty micrometers and on titanium, eventually more than fifty micrometers. Initial nucleation and growth have a considerable influence. In this paper, copper was deposited in a channel cell on four different 304 stainless steel substrates: mechanically polished and anodized, respectively, at 0, +400 and +800 mV/SHE in 1M H2SO4 at 20°C. Copper was deposited under electrowinning conditions after solvent extraction (SX) (40 g/l Cu++, 180 gh/l, H2SO4, 20 or 60°C). The results showed that, although Auger surface analyses of the substrates were only slightly different one from another including the oxide thickness, nucleation and initial stages of growth were very sensitive to the surface treatment of the substrate. Potential step and current step methods gave similar results : progressive nucleation followed by 3D diffusion controlled growth. The highest nucleation frequency was observed on stainless steel anodized at 0 mV/SHE, under various electrolysis conditions. The potential influence of these findings on industrial practice is discussed.

Jan 1, 1999

By J. H. de. Visser

The transfer of molten metal in smelting or refining operations is typically performed in open trough-type launders that are constructed of either water-cooled copper troughs or refractory lined steel jackets. This transfer can be either continuous or batch. Batch operations transfer metal through an open launder. The uncovered launder has many operational and environmental drawbacks. In order to improve workplace hygiene, designs have evolved toward ventilated launder covers that .are connected to secondary exhaust systems that use negative pressure under the cover removing fume and hot gases to secondary fume control devices. In smelting operations, a variety of covers have been employed which insulate the launder and contain the fumes and also provide additional heat along the length of the launder through a series of premix or inspiration-type burners that add combustion products to the normal fume load in the launder. Cover designs have proven to be inadequate in that hinged unventilated covers hinder convenient access while heated ventilated covers are costly to maintain. Covers that employ refractory bricks and overhead enclosure-type exhaust hoods have been somewhat successful, but restrict operator movement and require large volumes of exhaust air. An example is given of a cover and off-gas system for launders that is designed to provide superior insulation and heating capabilities, as well: as better control of the fume gases-and ease of maintenance. The cover system must maintain the balance between maintaining launder heat and fume removal. The construction of the covers must be able to withstand high internal temperatures and maintain its structural properties.

Jan 1, 1999

By D. G. E. Kerfoot

In September 1945, when the Lynn Lake nickel orebody was discovered Sherritt Gordon Mines was a small copper mining company with rapidly depleting ore reserves at its single producing mine at Sherridon in the Cold Lake area of Manitoba, 100 miles north of The Pas. The company has been formed in 1927, largely through the efforts of Eldon L. Brown, a 27-year old mining engineer, with the financial backing of Thayer and Halstead Lindsley and the Gordon family. The Lindsleys were American mine promoters who had been successful in the Sudbury area, and the Gordons had extensive interests in the lumber industry in northern Ontario. Carl Sherritt, who gave his name to the company, was an American trapper and prospector who had staked the copper property and sold his interest to the new company. Carl Sherritt died in a flying accident at The Pas in 1928. The Sherritt Gordon Mine started production in 1931, shipping copper concentrate to the new Hudson Bay copper smelter at Flin Flon, Manitoba. In 1931 the price of copper was 18¢/lb. Within a year the price had fallen to 5¢ /lb and the mine was forced to close. It remained closed through the Depression years.

Jan 1, 1999

By F. A. Fasoyinu

The mechanical properties of yellow brass (C85800), high strength yellow brass (C86300), and high manganese brasses (C99700 and C99750) cast in permanent molds have been studied. The tensile properties as well as fracture and impact toughness of these alloys are strongly dependent on the chemical composition. Alloys and/or compositions exhibiting relatively high zinc equivalent often exhibited high ultimate tensile strength and yield strength with significant reduction in ductility (% elongation). In order to achieve optimum properties with a good balance between strength and ductility, a calculation of the zinc equivalent before alloy preparation can be useful.

Jan 1, 1999

By W. Persson

The first installation at a copper smelter of a Semtech OPC System for continuous, on-line production control of copper converting in PS converters took place in 1994. At present OPC systems are installed at 19 PS converters. The technology presents to the operator real-time information on the progress of the process he is controlling in the form of optical process parameters, thus facilitating dynamic process control. The optical process parameters are based on time- and wavelength resolved registrations of the light emitted by the off-gas flames and identification of correlation between these parameters and characteristic metallurgical process data. The present paper provides a description of the technology as seen by the furnace operators and a summary of operating experiences made during five years of full-scale, operation at various smelters, reviews influences from the technology on smelter operational practises and comments on recent developments as regards new applications of the technology.

Jan 1, 1999

By René Bustamante

The subject of this paper is a comparative evaluation of different copper smelting gas cooling techniques, using "productivity and quality" criteria. The first section presents a brief description of the operation of the radiant and the evaporative cooling systems, focusing on the differences between each other, in particular regarding. a) mass and energy balances; b) gas flow, temperature and composition; c) dust concentration and recovery. This section includes a brief discussion of the "client-server chain", i.e. the links between the cooling equipment and the down-and up-stream operations. More in particular, the up-stream server relationship impacts on the operating stability of the furnace, and in turn on furnace down-time and Cu production losses; and the down-stream client relationship affects the operation of the electrostatic precipitators, in terms of workload and cost of handling larger quantities of dust of a given dust size The second section deals with the development of indexes to measure and compare value added through the "utilization, productivity and quality" that can be expected of both cooling methods at the physical and economic levels, and the impact on the overall smelter productivity and the final cost composition of copper. The final section presents the results and includes a discussion of the comparative advantages and disadvantages of both cooling systems.

Jan 1, 1999

By Nathaniel Arbiter

The first ammonia leaching plants, applied to copper carbonate and native copper tailings in 19 15, were followed more recently by research and development of flowsheets for ammonia leaching of sulfide concentrates. These were applied to two commercial plants. Anaconda's Arbiter Plant started up in 1974 with a design capacity of 36,000 tons/year of cathodes, to be produced by ammonia leaching with oxygen, followed by solvent extraction and electrowinning. The plant shutdown in late 1977 as a result of high maintenance and operating costs, partly due to harsh winters; to complications associated with sulfate disposal; and to changes in mineralogy. BHP's Coloso plant in Chile was designed to produce 80,000 tons/year of cathodes by leaching part of Escondida's concentrate production. Using a similar flowsheet but with air and low temperatures to avoid sulfate production, it started up in late 1994 and shutdown in mid-1998, after failing to reach cathode design capacity, and experiencing problems with its technology. The paper reviews the technologies and also alternative methods for overcoming the problems.

Jan 1, 1999

By B. E. Zeigler

This bi-product from a nickel smelter has been manufactured over the last 30 years for the abrasive and roofing industries. This paper discusses a new development for this material a foundry aggregate used for molding sand in both ferrous and non ferrous casting industries. Test data, marketing strategies, manufacturing, and case studies will be presented from the first concept, to current production, marketing and the end use of this product.

Jan 1, 1999

By Jonkion M. Font

As a comprehensive contribution to the understanding of oxygen-blowing of matte smelting, the copper and nickel solubilities between the FeOx SiO2-MgO slag with saturated SiO2 and the Cu2S-Ni3S2 FeS matte with the NCu/(NcU+NNi) of 1, 0.75, 0.5, 0.25 and 0, in a MgO crucible were investigated at 1573 K under controlled partial pressures of SO2 at 0.1, 0.5 and 1 atm. The partial pressures of SO2, S2 and O2 were controlled by using an Ar-SO2-S2 gas mixture after passing through a sulfur reservoir. It was clarified that, at a given matte grade, the solubility of copper in the slag was independent of pso2 while that of nickel increased with increasing pso2. This notable difference was considered to be ascribable to the chemical formulas of the mono-metallic sulfides in which one copper atom combines with ½ sulfur atom while one nickel atom combines with 2/3 sulfur atom. It was also clarified that, at a given iron content in the matte, the pot and ps2 were independent of the matte species. This was ascribable to aFeS in the matte, which was independent of the matte composition, Ncu/(Ncu+NNi), at a given iron content in the matte.

Jan 1, 1999

By M. M. Botz

Cyanidation tailings which are disposed in a surface impoundment experience a loss of cyanide due to natural degradation, frequently reducing the cyanide concentration to very low levels. Quantifying cyanide losses in terms of pond geometry, local weather conditions and feed solution chemistry has been largely empirical though in many cases mining operations rely on surface impoundments to reduce cyanide to below an internally regulated concentration or an effluent limitation. To permit a more quantitative evaluation of cyanide losses in an impoundment, a computer simulation was developed to estimate the losses of free, WAD and total cyanide due to dissociation, photolysis and volatilization. Results of the model are compared against data collected for a North American tailings impoundment during 1998.

Jan 1, 1999

By D J. Gray

The 4 km long Huguenot Toll Tunnel in the Western Cape region of South Africa celebrated its tenth anniversary on 18 March 1998. At present a single (South) bore with bi-directional traffic flow is operational. The North bore was originally excavated but not lined and equipped.The tunnel is fitted with a semi-transverse ventilation system comprising 45/350 kW two speed fresh-air and 1 MW exhaust air fans at each of the portals. These provide ventilation through fresh and exhaust air ducts above the ceiling separated by movable partition doors. Secondary air ducts deliver air at low level. The fan control depends on the levels of CO pollution or visibility measured at six positions along the tunnel.The system performed well during initial tests and under conditions of low traffic volumes. As traffic volumes increased, and user complaints of bad air in the tunnel were received on several occasions, we realised that we had a problem. Tests confirmed that natural airflow within the tunnel induced by prevailing meteorological conditions outside the portals affected the performance of the ventilation system causing a plug of bad air to be trapped at varying positions along the operating tunnel.The control systems in the tunnel are presently being upgraded as described by Gray, Rieckert and Bullock (1998). As part of the retrofit we are implementing a new control strategy for the ventilation system which takes into account the external weather conditions. This paper discusses the 24 month long meteorological data gathering exercise, which is on-going, and explores the philosophies planned for controlling the ventilation system. The correlation between winds external to the tunnel and induced airflow inside the tunnel are examined. The effects of the weather induced airflow on the existing ventilation system are considered and proposals given for taking these effects into account in the new control strategy. These include the implementation of an expert system to predict ambient airflow from prevailing weather conditions, and the use of airflow measurements taken in the uncompleted North bore as a cross-check.The paper highlights the need to take cognisance of external weather conditions when designing tunnel ventilation systems.

Jan 1, 1999

By Michael F. Barber

"Highway slopes are intended to remain stable over a long period of time. Unexpected slope failures can be costly in terms of human life and property damage or loss. Cleanup of failures can prove to beextremely expensive."

Jan 1, 1999

By M. L. Young

Hindered settling columns are used throughout the minerals industry for both size and density separations. In this study, the performance of a continuous, laboratory-scale hindered-settling column was evaluated for various particle systems. The test variables included solids composition, water rate, and column height column performance was evaluated using partition curves and corresponding performance parameters.

Jan 1, 1999

Deep level block caving as a mining method is becoming more popular due to the fact that it is the lowest cost per ton underground extraction system. However, many block caves do not achieve their full potential due to draw horizon instability. In this paper five design rules are given to overcome this problem. The design rules described are applicable for slusher and trackless block caves where the operational depths exceed 500 metres.

Jan 1, 1999

By Vânia L. L. Andrade

Igarapé Bahia Mine is located in Carajás area, northern Brazil. Currently Companhia Vale do Rio Doce operates there a CIP / heap leaching plant treating an oxide gold ore containing about 4 g Au /t and 0,2% Cu, which produces 11 t of gold per year. Recent geological survey has identified a signifcant copper-gold reserve underneath the oxide gold ore. The processing aspects of this copper-gold sulphide ore are described in this paper. It includes ore characterization studies, grinding and flotation tests, orebody variability assessment, flowsheet selection and preliminary economical evaluation Emphasis is given to studies aimed at depressing fluorine bearing minerals to achieve a clean and marketable flotation concentrate.

Jan 1, 1999