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By Eleanora I. Robbins, Motoaki Sato

Many problems associated with acid mine drainage (AMD) are caused by the complex way molecular oxygen (O2) oxidizes reduced matter at surface temperatures. In aqueous solution, O2 kinetically "prefers" to go through the formation of hydrogen peroxide (H2O2) as an intermediate. Being innately unstable, H2O2 is quickly decomposed back to water and oxygen in the presence of dissolved Fe and Mn, both catalysts for the decomposition. Direct addition of H2O2 to AMD produced similar results. Ozone (O3) is a much faster and stronger oxidizer than either O2 or H2O2. In the laboratory, O3 rapidly precipitated Mn, Fe, Ni, Co, Pb, and Ag even in acidic solutions. The experiments indicate that AMD can probably be processed with ozone and metal oxides/hydroxide recovered in flow systems using only septic-tank-size reactors and small sedimentation ponds.

Jan 1, 2000

By J. P. H. Steele, T. Vincent, C. Debrunner, M. Whitehorn

For a variety of reasons, the need for automation of underground mining equipment is growing dramatically, e.g., improved safety and health, availability of labor, deeper mines, and desire for more focused excavation. While there has been tremendous progress made in this direction, much needs to be done to reach the holy grail of an autonomous mining machine. This paper reviews a number of technological developments and presents research and development needs for future development. A report on our current project for the Western Mining Resource Center at CSM is included.

Jan 1, 2000

By P J. Terbrugge

Many ore deposits have considerable vertical extent which is not always known at the time of commencement of mining. In many of these cases, initial mining is by opencast methods, and as ore reserves are proved to greater depths, the pits are often planned to go deeper than had been originally envisaged. In such cases, surface plants and critical underground facilities such as conveyer tunnels, access ramps, ore passes, hoisting shafts and ventilation shafts are often located much closer to the pit rim and the orebody than is desirable for the deeper mining situation. This usually raises the question of the stability of such underground excavations, which may be critical for the viable longer-term mass underground operation of the mine. In this paper the key considerations in the evaluation of the stability of the overall mining environment for ædeepened minesÆ are defined. Aspects which are dealt with are: open pit stability, shaft stability, dilution, mudrushes and airblasts, and selection of mining method. The necessary stability evaluations are put into the appropriate context by considering two case histories. Critical parameters and considerations which need to be addressed during the evaluation of excavation interaction are also discussed.

Jan 1, 2000

By Cindi Byrns, Andy Davis, Amy Tisdale

The Robinson district, Ely, Nevada is a hydrogeologically complex system with several distinguishable geologic blocks, each with a distinct background groundwater chemistry. To discriminate between background and mine-impacted groundwater, background wells, monitoring wells, pit lakes, waste rock seeps, and surface water samples were analyzed for a suite of major cations and anions, together with trace and precious metals, rare earth elements, 2H-deuterium and 18O/16O. The data allowed identification of groundwater flow paths, verification of hydrochemical source areas and characterization of natural attenuation mechanisms (e.g., mixing, dilution and mineral precipitation) that control the concentration and migration of metals at the site.

Jan 1, 2000

By T. Brady, J. Johnson, J. Whyatt, B. Pariseau, M. Stahl

An elastic-viscoplastic material model allows for time-dependent rock mass motion in proportion to excess stress above the elastic limit. The model produces rounded stair-step curves of displacement versus time that are similar to those obtained from recent borehole extensometer measurements made in the central portion of the Ross shaft pillar at the Homestake mine. The work in progress, including two- and three-dimensional finite element analyses using the UTAH2/3 codes, indicates that the model is a step towards more realistic safety and stability analysis, but that inclusion of rock mass damage may be desirable.

Jan 1, 2000

By K. S. Han, M. Yoshimuura, H. Fujita, Y. Sato, S. W. Song

"Film of LlCoO2 as cathode material for rechargeable lithium microbatteries has been fabricated on the platinum metal substrate by electrochemical-hydrothermal method in concentrated LiOH solution at 200 °C as Soft Solution-Processing. The film fabrication has been understood in terms of dissolution of cobalt metal powders and subsequent oxidative deposition on the substrate. The film structure was characterized using scanning electron microscope, X-ray diffraction analysis; X-ray photoelectron spectroscopy and micro-Raman spectroscopy.IntroductionRapid growth of wireless communications and emerging integrated optoelectronic circuits caused the miniaturization· cif electronic devices, thus the demand for high energy density microbatteries as a power source for the microelectronics increases. In this regard, all solid-state lithium microbatteries including LiCoO2 and LlMn2O 4 [l-4], the most promising intercalation cathode material, have been developed. However, major difficulty of .fabrication of a lithium microbattery arose from the preparation of cathode film, according to a· recent report on Rare Metal News [5]. Although many attempts have been made to deposit the cathode films, all those methods are mostly chemical vapor deposiiton (CVD), various evaporation, sputtering techniques and spray pyrolysis. These methods require preparation of bulk cathode materials cir its precursor, then deposition with complicated instruments including high· vacuum system, and even postsynthesis annealing to obtain desire electrochemical 'properties. It is clear that all of these techniques are neither economic nor environmentally friendly. Compared to those methods, film form.ation from an aqueous solution is thought to be simpler and more economical, and requires much· less energy consumption. Our .group has demonstrated the utility of Soft SolutionProcessing [6,7], which is defined as environmentally friendly processing using (aqueous) solutions, to produce films of a variety of functional solid materials. According to the Pourvaix's diagram [8], some metal can be dissolved in an alkaline solution and consequently combined with hydroxyl group or oxygen anion forming metalate or metalite. Cobalt also seemed to form cobaltite, HCoOi in strong alkaline solution in the Pourvaix's pH-potential diagram. Based on this information, it was expected that LiCoO2 could be prepared using the cobalt metal in Li OH solution by Soft Solution-Processing. Recently, we reported the successful single step fabrication of electrochemically active LlCoO2 films on the cobalt metal substrate by hydrothermal methods without any post-synthesis annealing as Soft SolutionProcessing [9,10]. Film formation mechanism could be elucidated by the following evidences. . As expected from Pourvaix's diagram, cobalt metal was dissolved in concentrated LiOH solution forming dissolved cobalt species which was detected by an observation of absorption band in UV-VIS absorption spectrum [10]. Thus the reaction was assumed to be started from dissolution. Time dependent potential of Co electrode exhibited only one-step evolution with 0.6 eV from Co metal to LiCoO2 [10]. Another strong evidence was the finding of LiCoO2 powder precipitates at the bottom of tetlon beaker after the reaction [11]. Based on those experimental findings, it was understood that film is formed by dissolution-precipitation mechanism [9-11]."

Jan 1, 2000

By K Inoue

The pressure oxidation of molybdenite concentrates in acidic and alkaline media has been studied. The conditions of the selective oxidation of copper and iron sulphide minerals with a quantitative copper leaching by ferrous-ferric-sulphate solution have been found and explained from the point of view of electrochemical kinetics. The partly oxidised residue consisting of molybdenite and (hydro-) oxide of iron (III) was then decomposed by oxygen in alkaline media. Effects of the main parameters, such us oxygen pressure, leaching temperature, solid-liquid phase ratio, autoclave stirring speed as well as lixiviants nature on the molybdenite oxidation rate have been established.

Jan 1, 2000

By D R. Lueking

A technology involving separate unit processes for the generation and use of ferric ions for the oxidation of sulphidic minerals has been developed. The technology utilises a stand-alone automated bioreactor for ferric-ion generation (termed SAAB-FIG) and produces a low pH, ferric ion-rich leach liquor with a high oxidation potential. This leach liquor is then employed, in a separate unit process, to oxidise sulphidic minerals and regenerate ferrous iron that may subsequently be recycled to the bioreactor for the continual generation of ferric ions. The technique was successfully applied for the recovery of copper from chalcocite (Cu2S) and chalcopyrite (CuFeS2), as well as other ores and concentrates containing copper sulphide minerals. Coarse ore, ground ore and concentrates were treated with acidic solutions containing 8 to 12 (g/L) Fe(III) ions at a variety of temperatures. This process yielded over 50 per cent of the contained copper from both chalcopyrite and chalcocite samples. Maximum reaction rates and copper recoveries were found to be highly dependent upon temperature and pH and leach liquors containing bacterial cells displayed little difference in their leaching efficiency when compared to cell-free leach liquors.

Jan 1, 2000

By M. Vallée

Several reviews of mineral project performance in the past 35 years indicate a pattern of occasional, but recurrent, mining project failures due to shortcomings in geological information and estimation, mineral processing and metallurgical testing, feasibility study objectives and requirements, and project start-up methods. A commitment to quality assurance and continuous improvement methods and to obtaining “ENOUGH DATA, OF APPROPRIATE QUALITY” is essential. Recent international and Canadian proposals for mineral resource and ore reserve definitions have taken a nonprescriptive stance that will undermine the formulation of requirements, guidelines and industry standards for efficient deposit delineation and estimation, and for the determination of project feasibility. To help reduce problems, every feasibility study supporting a mine development and production decision should be based on objectives and methods adequate to reach completion targets similar to the bankers’, as a good business target for a profitable project. In a resource/reserve system, the use of reserve should be restricted to a project that meets required technical, economic and legal feasibility requirements for successful project implementation, and the definitions of these categories should provide explicit limits. Current shortcomings will limit the ability of the Qualified Person to provide “adequate professional practice,” fulfill his/her professional responsibilities to his employer or client and provide adequate information to the investing public. We must take advantage of present opportunities for Setting New Standards for the new Millennium.

Jan 1, 2000

By K. Hanumantha Rao, P. K. Sharma

A pure strain of Paenibacillus polymyxa and mineral- adapted strains are used to bring about surface chemical changes on pyrite and chalcopyrite and, thus, theirflotation. Paenibacillus polymyxa was adapted by repeated subculturing in the presence of pyrite and chalcopyrite. The surface chemical changes of bacteria due to adaptation and of minerals after their interaction with bacterial cultures are evaluated by electrokinetic and infrared spectroscopy and are discussed with reference to their flotation responses. Interaction of bacterial cells, bacterial metabolites and whole bacterial cultures affected the Hallirnondflotation behavior of the sulfide minerals. The Xanthate flotation results show that pyrite, but not chalcopyrite, is depressed when the tests are carried out after interaction with chalcopyrite-adapted Paenibacillus polymyxa. This investigation demonstrated that the surface chemical properties of bacteria can be manipulated successfully to achieve the desired effects in the flotation process.

Jan 1, 2000

By André Vien, Pedro Gonzalez, Julio Palomino, Rob Perry

"In many mineral processing plants ore is reclaimed from a stockpile using multiple feeders. The discharge from these feeders is combined onto a single conveyor from which total tonnage is measured. Typically, operators set feeder output ratios to adjust the proportion of total tonnage drawn from each feeder. From a process control perspective, this system is not easy to control because the response time of each feeder depends on the distance from the feeder to the weightometer. This paper proposes a simple and elegant process control strategy to manage feeder ratio changes and the associated long and varying process dead-times. Changes in feeder speed are delayed and filtered to compensate for transport delays between feeders. The strategy was evaluated by simulation and installed on a mill feed system.ResumenEn numerosas plantas procesadoras de minerales, el mineral es extraido desde una pila de almacenamiento usando varios alimentadores. La descarga de estos alimentadores es recibida por zinica correa transportadora, en la cual se mide el tonelaje total. Comzinmente, los operadores colocan un valor determinado en cada controlador de razdn para ajustar la proporcidn del tonelaje total extraido por los alimentadores. Desde el punto de vista del control automatic0 de procesos, este sistema es dijkil de manejar debido a que el tiempo de respuesta de cada alimentador depende de la distancia de este respecto a la ubicacidn del pesdmetro. Este trabajo, propone una estrategia de control, simple y elegante, para compensar los cambios de razdn a cada alimentador y los tiempos muertos del proceso largos y variables. Los cambios en la velocidad de los alimentadores son retardadas y filtradas para compensar los retardos del transporte entre alimentadores. La estrategia fue evaluada por simulacidn, instalada y probada en un sistema de alimentacidn a molino."

Jan 1, 2000

By M P. Sandy, J B. Simpson

The empirical stope design techniques developed by Mathews et al (1981) and refined by Potvin (1988) and others, have gained rapid acceptance in Australia in the 1990s as a simple, æfirst-passÆ means of designing primary stopes. However, it is recognised that these æstability graphÆ methods can only provide broad design guidelines. Recently published stability graphs (Hutchinson and Diederichs, 1996) encompass a wide range of geological environments, which are not discussed, and the influence of time and blasting practices cannot be easily reviewed. The æscatterÆ in the graphs must reflect, to some degree, different operating practices as well as subtle but important differences in the pre-mining conditions that are not adequately accounted for in the æmodified stability numberÆ. Development of a ælocalÆ, site-specific stability graph may overcome some of these problems. At NormandyÆs Golden Grove Operations, Western Australia, detailed reviews of stope stability performance, including Cavity Monitoring System (CMS) surveys, are undertaken for every stope, with the objective of developing a series of local stability graphs, customised to site conditions and calibrated in terms of æAverage Falloff ThicknessÆ (AFT). Cablebolting of stope hangingwalls is used to develop reinforced æbeamsÆ on each sublevel, effectively dividing the full span into smaller, more stable æsubspansÆ. By analysing stope stability performance in terms of fall-off, cost-benefit studies can be undertaken of the effect of cablebolting and other options for modifying stope spans. The approach used to develop the local stability graphs, and their integration into routine stope design procedures at Golden Grove, is described. The experience gained during stope extraction in the Scuddles orebodies has been successfully applied to the Gossan Hill æC-PanelÆ orebody. This methodology should be applicable to other underground mining operations.

Jan 1, 2000

By D. M. Lane, J. M. Berkoe

Engineers and Owners share a common desire to build reliable, efficient plants on schedule at reasonable costs. This paper describes one tool that Bechtel finds can integrate these objectives by “putting innovation into practice”. Examples of such innovative engineering practice include the use of computational fluid dynamics (CFD) to determine efficient designs. This paper outlines several examples of CFD applications on actual Mining and Metals Projects from around the world. The focus here is to highlight the modeling objectives, analysis strategy, actual benefit obtained from the work, lessons learned to improve future efforts and the common mistakes that can obscure the correct or best results, despite impressive graphics. The tools are powerful, and the results are more powerful when applied with skilled and well-directed human effort and ingenuity.

Jan 1, 2000

By O. E. Etheridge Jr., R. A. Lowe, C. I. Basilio, J. M. Randolph, S. W. Sheppard

The low-shear viscosity of kaolin slurries is one of the principal characteristics that determine whether a clay can be utilized for paper and ceramic applications. In this work, the causes of high low-shear viscosity and methods for improving the rheological behavior of the slurries were investigated. The presence of fine-grained smectite impurities within the kaolin was shown to detrimentally affect the low-shear rheology of the slurries produced from these clays. It was also shown that mechanically working (i.e., pugging) a crude kaolin followed by desliming to remove these impurities can reduce the low-shear viscosity.

Jan 1, 2000

By P. Massacci, F. La Marca, G. Bonifazi

Some deposits of inhomogeneous materials, which occur near the surface and are exploitable by open-pit mining, may he characterized in real time prior to mining through groundsurface imagery. If the slice to be stripped is not overly thick, surface texture and color properties may be extrapolated to its entire thickness. Image-analysis techniques for processing ground-surface images acquired in situ or in the laboratory shortly after their acquisition have been developed. These images yield pattern vectors representative of red, green and blue (RGB) color component distributions and hue, saturation and brightness (HSB) texture parameters. The techniques were applied to a sandy ore deposit containing three lithotypes. Geostatistical analysis indicated that the data used to characterize the lithotypes were reliable. The correct recognition of the lithotypes was carried out using a multibarycenter classification algorithm. Such in situ image-analysis procedures provide a means for selecting the ore to be mined, selecting the proper ore-processing method and determining the appropriate blend to he processed. This can be done either before or during mining.

Jan 1, 2000

By Dany Pelletier, Yeves Breau, Ahmed Bouajila, Claude Gagnon

"In flotation circuits, direct measurement of the volumetric flow rate delivered by electromagnetic flowmeters is often difficult to obtain particularly due to piping and flow constraints. However, on-line material balance calculation could offer a reliable alternative to flow rate sensing. This paper describes an on-line material balance software package as applied to a copper flotation circuit for mass flow rate estimation mainly based on the output of an x-ray fluorescence onstream analyser. Rule-based procedures for the management of the main calculation modules are designed and integrated to a Comdale expert system. Attempts to diagnose the flotation process from mass flow rate data are also discussed.INTRODUCTIONThe need for improved process diagnosis, control and optimisation has become more evident for the mineral processing industry in the last decade. Therefore, new process variables need to be inferred or measured particularly in highly multivariable processes such as flotation. This process is subject to a wide variety of disturbances mainly generated by frequent and sometimes abrupt changes in physical and chemical characteristics of the ore and due to some irregularities in manual process operating procedures.A flotation circuit scheme is always a complex network counting more than two dozens of slurry streams. Information about those streams (%solids, metal content analysis, and flow rates) are important for process diagnosis, performance evaluation control and optimization (1,3).On-line sensing instruments such as x-ray fluorescence (XRF) on-stream analysers (OSA), gamma density gauges and electromagnetic flowmeters have been developed for the measurement of those variables. Unlike the other variables, stream flow rates could be determined by different ways:"

Jan 1, 2000

By Roger Beckie, Leslie Smith, Craig Nichol

To study the hydrogeological processes that control the movement of water through unsaturated waste rock, an intermediate-scale (8m x 8m x 5m) waste rock pile has been constructed and instrumented. The constructed pile is monitored for moisture content, matric suction, temperature, matrix water chemistry, gas chemistry, gas pressure, rainfall, evaporation, discharge volume and discharge chemistry. The pile is built upon a grid of 16 contiguous lysimeters. The experiment is designed to investigate the mechanisms that create rapid water flow through a pile and its exchange with slower-moving matrix water.

Jan 1, 2000

Mining companies around the world are seeking methods to coordinate operations between the mine and the concentrator to achieve an overall improvement in enterprise performance. In several instances very significant increases in productivity (more than 20 per cent) and profitability (more than $US 10M per annum) have resulted from such efforts. The key to realising these large benefits has for the most part arisen from improved communication between mining operations and plant operations personnel and the judicious use of new tools to evaluate alternatives for improvement and to minimise the risk of implementation. This paper presents a systematic approach to mine-to-mill optimisation . The importance of systemic thinking and systems optimisation methodologies is emphasised. New tools for evaluating operational performance are discussed. Recently reported benefits are summarised. Finally current research is discussed and projections for the future are given.

Jan 1, 2000

By D. J. Turk

Stillwater Mining Company’s, Nye Operation has been producing PGM concentrate since 1987.Several expansions have allowed for increasing capacity from the initial rate of 500 tons per day, to its present capacity of 3,000 tons per day. The expansions were performed with minimal impact upon production and maximum utilization of the existing equipment. The latest expansion incorporates a 6’ X 18’ SAG mill, 13’ X 20’ Ball mill, pebble crusher, rougher flotation cells, 1250 Hp tertiary grinding mill, middling and scavenger flotation cells, and cleaner column flotation cells. This paper will describe the concentrator flow sheet, and controls for improved concentrator performance.

Jan 1, 2000

Komatsu America International has introduced two new hydraulic excavators. They can work in congested and confined areas. The tight tail swing radius of the PC128US-2 and PC22-8USLC-2 enables the excavators to minimize the work space. The units can operate in confined work settings that are inaccessible or counterproductive to traditional machines. Even the door is designed for tight working conditions. A convex door slides open along the exterior curve of the cab, rather than swinging out on hinges past tracks. And the excavators’ tight tail swing design allows them to load within the track width of the machine.

Jan 1, 2000