Search Documents

By Y. Sako, E. Nomura, K. Muraguchi, K. Shibata

In 1998, Mitsui Mining & Smelting Co., Ltd. (MMS) produced 70,000 tonnes of lead, 231,000 tonnes of zinc and 214,000 tonnes of copper. MESCO, Inc. has been in charge of the automation and mechanization of smelting facilities promoted by MMS as well as the construction of facilities for chemical production and electronics materials plants, by which MESCO has contributed to the development of MMS. Initially, MESCO developed a casting machine for refined lead in the early 1960's, and thereafter, it developed a casting machine for refined zinc, a stripping machine for zinc tankhouses and energy saving facilities. In the field of copper smelting, it has also developed automation and mechanization facilities.

Jan 1, 2000

By B. K. Rath

The Industrialization of a country depends on its mining activities to a great extent. In mineral production, India has a top rank not only in South Asia, at the global level too. Quantum of mineral production is almost directly proportional to the quantum of explosive production. Mining sector consume more than 80% of country’s explosive production. Due to rapid growth of mining activities in the country, the explosives industry has been developing very fast in terms of quantity, quality and types. , In this paper, India’s post independent chronological date regarding use of explosives, their types, their constraints and a profile of well-known manufacturers has been meticulously presented. A production figure for three years with system analysis has been presented. The paper also deals with present consumption pattern while making a futuristic forecast. In view of the anticipated changes that are to take place in mining industries in near future, the manufacturers of explosives have to pay a vital role. The paper highlights some concrete and valuable suggestions and recommendations. Small scale Companies have to limit their production to Slurry and Emulsion types of Cartridged explosives whereas the large manufacturing units have to concentrate on Bulk explosives, specialized explosives and better initiating systems. The large manufacturing units have also to make all concerted efforts to compete with global market for significant export. The Country for its rapid growth needs basic raw materials like Coal, Iron Ore and Limestone. So, the extraction of these minerals is of prime importance. The more we produce and consume, the more will be Industrialization. The Industrial growth rate has been around 6% during the last few years. As the Industrial growth rate is moderate, there is moderate increase in mineral extraction in the Country. Additional mineral extraction demands additional explosive production (Annexure-1).

Jan 1, 2000

By W. J. Pennstrom, J. R. Arnold

This paper focuses on solution-balance management around heap-leach operations. Experience has shown that increased leach recoveries can be achieved by utilizing various leach-solution recirculation techniques. The most prominent solution-recirculation technique is intermediate leaching. The net effect of intermediate leaching is to increase recovery plant performance by increasing solution concentration tenors, to increase metal recovery by increasing the total leach time and to decrease the overall capital expenditures required for metal-recovery facilities. The adverse effect on the flow of cash from increased metal inventories in the recirculating solutions is offset by increased metal recovery and lower operating costs per unit produced.

Jan 1, 2000

By Yoshinobu Fukumori, Testuya Watanabe, Futoshi Shikata, Hiroyuki Tokumitsu, Hideki Ichikawa, Masahito Miyamoto

Nano-particulate systems have attracted much attention recently in pharmaceutical field as drug carriers and functional components of pharmaceutical dosage forms. This paper describes our approaches in design and preparation of nano-particulate systems, including lipid nano-emulsions, chitosan nanoparticles and thermosensitive acrylic nanoparticles, for certain pharmaceutical applications mentioned below. The lipid nano-emulsions with their particle size smaller than 100 nm were prepared for gadolinium neutron-capture therapy (Gd-NCT) of cancer by a thin-film hydration method with sonication, and intraperitoneally injected into Greene's melanoma (melanotic No. 179)-bearing Syrian hamsters. This provided such a high gadolinium concentraton in tumor as 107 µg/g tumor (wet basis) at 48 h after administration. As an alternative gadolinium nano-carrier for Gd-NCT, biodegradable and highly gadopentetate-loaded chitosan nanoparticles (Gd-nanoCPs, 426 mTI in particle diameter and 9.3% in Gd content) were prepared by a novel emulsion-droplet coalescence technique. A significant tumor-killing effect could be obtained when Gd-nanoCP suspension was injected intratumorally twice 24 and 8 hours before neutron irradiation into B 16Fl O melanoma-bearing mice and subsequently thermalneutron was irradiated toward tumor site with a flux of 2 x 109 n/cm2/sec for 60 min. As one another application of nanoparticles, a novel acrylic composite latex with a hydrophobic core and a thermosenstively swellable shell was designed for fabricating microcapsules showing thermosensitive mode of drug release. The microcapsules with the composite latex-dispersing membranes exhibited an exceptionally rapid on-off response of drug-release in a thermosensitive manner.

Jan 1, 2000

By M Hino, D R. Swinbourne

The thermodynamic properties of arsenic in metal, speiss, matte, slag and gas phases are first summarised in this paper. Arsenic associates with sulphide minerals and generally has compounds of high volatility, but it has a weak affinity for sulphur and a strong affinity for metals, especially copper and iron. In the initial stage of the oxidation of sulphide concentrates arsenic is volatilised easily prior to the oxidation of FeS, although it tends to be fixed in the condensed phase as FeAsO4 if the concentrate is over-oxidised. Thermodynamic simulation of oxidative copper smelting reveals the distribution of arsenic between matte, slag and gas, and the possibility of condensation of arsenic from the resulting waste gas is discussed. In reductive smelting more arsenic remains in the metal or matte, and is sometimes concentrated as a separate speiss phase. The phase relations and thermodynamic properties of speiss are also summarised briefly. Arsenic refining from smelted copper metal is shown, from an examination of the basic principles of arsenic removal into slags, to be difficult. Owing to its weak affinity for lead however, arsenic refining from lead bullion is seen to be much easier.

Jan 1, 2000

Tracey Khanna, Assistant Editor of UK?s Mining Magazine discusses some of the new and important environmental challenges, physical and social, that are facing mining companies. The tide of public opinion has turned strongly against those companies which are unable to show that they are practising responsible environmental stewardship. This is, no doubt, in part due to the recent focus of the international media on environmental issues and constantly improving means of communications, which has brought the whole subject of mining and the environment to those who, in the past, had only a limited awareness of the industry. Mining companies today face new and important challenges with regard to the environment, both physical and social. New technology and a greater understanding of waste management techniques has helped to bring about improved handling and disposal of mines wastes, so reducing some of the impacts. However, improved technology has also brought about the economic viability of exploiting increasingly lower-grade ore from open pits, resulting in a greater visual impact.

Jan 1, 2000

By Uchil Jayagopal, P. V. Krupakara, S. Manjunath

"This paper deals with the corrosion characterization of quartz particlate ZA-27 alloy metal matrix composites (MMCs). Quartz particles of size 50-80 microns are used as reinforcement. MMC's are prepared according to ASTM standards. Composites containing. 2, 4, and -6% by weight of quartz and unreinforced matrix were tested using 1 -N hydrochloric acid: The composite was found to be more corrosive resistant than matrix alloy. In each test the corrosion resistance of both alloy and composites were found to decrease with the exposure time.1. IntroductionMetal matrix composites- (MMCs) offer designers many added benefits, as they are particularly suited for applications requiring good strength at high temperature, good structural rigidity, dimensional stability, and light weight 1-5. The trend is towards safe usage of the MMC parts in the automobile engine, which work particularly at high temperature and pressure environments Particles reinforced MMCs has been the most popular over the last two decades.ZA alloy MMCs have most popular families being represented by. ZA-27 alloy reinforced with ceramic particulate. Although the incorporation of the second phase into a matrix material can enhance the physical and mechanical properties of the base metal, it could also significantly change the corrosion behavior.ZA alloys have been used extensively in industry. This is attributed to their excellent fludity, castability and good mechanical properties. Among the zinc-based foundry alloys, the ZA family of alloy have been widely used during the past few years. ZA alloys have many advantage over aluminium based ones, especially high strength with a low casting temperature 8."

Jan 1, 2000

By J L. Kanau

In this study some drawbacks of using Bond grindability as a measure of grindability characteristics for mill control have been discussed. After reviewing the merits of alternative methods of determining the Bond grindability published in the literature, a new alternative method has been proposed.

Jan 1, 2000

By Graeme G. Strathdee

"IntroductionThis paper presents an overview of the industry status, describes current potash industry practices at three mills, and summarizes developments that have taken place since the previous review by Banks (1985).The commodity potash is produced in both New Brunswick and Saskatchewan from the evaporite ore sylvinite. This ore is a mixture of co-crystallized halite, NaCl, and sylvite, KCl, and a minor assortment of silica, carbonate, sulphate, and clay minerals. Carnallite, KMgCl3.6H20, is also dispersed throughout the bedded deposits and can affect the recovery of sylvite for fertilizer and industrial uses.Canada continues to be a principal source of supply of agricultural and industrial potash products. Figure 1 shows the sector performance between 1989 and 1997 in the context of the world supply and demand situation as reported by Prud'homme (1997) of Natural Resources Canada.Potash industry output is traditionally measured as the quantity of potassium nutrient and reported as tonnes ofK20. Mineralogically, the principal form of potash produced in Canada is sylvite, KCl, and 1 nutrient tonne K20 corresponds to approximately 1.64 tonnes of sylvite of agricultural grade, about 95% KCI. In 1997, the Canadian industry milling capacity was 13.4 million metric tons (Mt) ofK20 (22 Mt KCl) while the actual production was 9.0 Mt K20 (14.8 Mt KCl). Worldwide milling capacity in 1997 was 35.9 Mt K20 (58.8 Mt KCl) and global consumption was 25.3 Mt K20 (41.6 Mt KCl). Canadian producers can deliver about 35% of the global demand for potash commodities"

Jan 1, 2000

By John A. Herbst

Mineral processors have evolved from "handbook-based" decision makers to "model-based" decision makers. With this evolution have come significant improvements through increasing productivity, decreasing capital and operating costs and increasing product quality. This paper traces the development of model-based decision-making technology over the last 40 years and documents the benefits resulting from systems optimization using these tools. Some speculation is ventured concerning the future of model-based decision-making tools and their use in the field of mineral processing.

Jan 1, 2000

By Jun Iwai, Osamu Takai, Yasushi Inoue, Hiroyuki Sugimura

"Infrared reflection absorption measurement was performed during plasma-enhanced chemical vapor deposition of silicon dioxide films at room temperature. Hydrocarbon contaminants adsorbed onto growing film surface are oxidized by oxygen radicals in plasma resulting functional groups which include C=O and C-O bondings. These groups exist only near the surface and are hydrolyzed rapidly after exposure to air.IntroductionRecently low-temperature silicon dioxide (SiO2) deposition has been in a growing industrial demand in pa1ticular, polymelic substrates such as polycarbonate and polyethylene telephthalate, which have poor heat resistance, need low process temperature (near room temperature) in coating of SiO2 which is a suitable material to improve optical and mechanical properties of polymenc products. Plasma enhanced chemical vapor deposition (PECVD) using organosilicon reactants is one of the most promising technique for lowering process temperature, so that it has been extensively studied1-12. In the present; however, hydrocarbon contaminants and a plenty of Si-OH termination in Si-O-Si networks tend to exist in the films, which degrade mechanical, optical and electrical properties of the films. It is necessary to understand the deposition mechanism at, low temperature in order to solve the problems. We have studied the low-temperature PECVD of Si02 by spectroscopic diagnosing techniques such as optical emission and mass analysis6-7, 11- 12Infrared reflection absorption spectroscopy (IR-RAS) has been a well-established technique for characterization of thin films on metals as· well as on semiconductors and insulators13-17. In this paper, we report on' the surface reaction of room-temperature PECVD of Si02by using in situ IR-RAS."

Jan 1, 2000

By P. Klut, D. Groult, R. Marechalle, B. T. H. Bonnema

In the past 5 years, Compagnie Europeenne de Dezingage (CED) has developed a successful dezincing process and the St. Saulve pilot plant has evolved into a commercially successful production plant. Currently the plant meets all the required standards for scrap and zinc quality, output capacity, availability, and meets the prescribed environmental emissions standards. The initial process problems relating to zinc recovery, uncontrollable explosions and sodium hydroxide aerosol emissions have all been solved. Presntly, the yearly production of dezinced scrap is around 50.000 tonnes/year; this capacity is enough to supply the local market. This capacity can be increased easily to 65.000 tonnes/year or more. The market for dezinced material is growing due to the increased consumption of galvanized material on one hand and on the other hand the higher demand for high quality scrap. The proven technology of CED is currently patented worldwide, but CED is inviting licensees to implement the dezincing technology in other parts of the world.

Jan 1, 2000

By M. J. Collins, L. C. Trytten, K. R. Buban, I. M. Masters

Both pressure leaching of zinc concentrate, in an autoclave, and atmospheric leaching, in stirred tanks, have been employed in the expansion of zinc production at plants employing roast-leach-electrowin technology. These direct leaching methods result in the conversion of the sulphur in the feed to the elemental form, rather than to sulphur dioxide, decoupling zinc production from acid production. Atmospheric and pressure leaching methods are also readily implemented over a wide range of production rates. In choosing the best technology for expansion, capital and operating costs, zinc recovery, byproduct quality and the compatibility of recycle streams with the existing refinery must be compared. Leach testwork with several zinc concentrates using both methods has been performed by Dynatec. Recent results are presented, along with a discussion of their implications for process selection.

Jan 1, 2000

By P. J. Uggowitzer, H. Kaufmann

"New Rheocasting is a novel route of semi-solid casting, in which the globular semi-solid precursor material is produced by controlled cooling of only slightly superheated melts in conventional steel crucibles. The resulting semi-solid slugs are placed into the sleeve of a vertical Squeeze Casting Machine and then filled into steel dies. Solidification occurs under hydraulic pressures up to 100 MPa Due to the reduced cost of precursor material, reduced investment cost and easier recycling, the New Rheocasting process offers cost reductions of up to 25% over conventional semi-solid casting · routes. The New Rheocast products are pore free, pressure tight, weldable and heat treatable castings.In the present work the New Rheocasting Process is introduced and the influence of heat treatment on mechanical properties of the New Rheocast alloy A356 is discussed.The alloy A356 is cast under ideal New Rheocasting conditions into a step die on an UBE HVSC 350 Squeeze Casting machine. As-east, TS and T6 heat treatment conditions with variations in solutionizing and aging time/temperature parameters are applied and the samples are tested by tensile testing. Alternatively, the same heat treatment conditions are applied to conventional Squeeze Casting parts and compared with New Rheocasting.Questions of potential cost savings due to modified heat treatment conditions are also addressed in this paper."

Jan 1, 2000

A series of stemming confinement tests were conducted at a test site near Vernal, Utah. The purpose of the study was to determine the relative performance of various stemming enhancement “plugs”, stem types and loading configurations. The stemming performance was quantified in terms of: . Stem confinement time . Stem ejection velocity . Ground swell velocity . Ground vibration . Air blast . Crater formation Of primary interest was the performance of a new spherical stemming enhancement plug. The initial findings indicate that the hard plastic spheres improved blast performance when used appropriately. Their ability to improve blast performance is reduced when used in over confined or severely underconfined conditions. The study also evaluated the effects of air decking on stemming confinement and explosive performance.

Jan 1, 2000

By Ernest K. Yanful, Paul H. Simms

The lysimeter is a useful tool for evaluating the performance of mine waste covers or liners. A major problem with its application is the possibility for preferential flow into or away from the lysimeter, if the lysimeter soil is finer or coarser than the barrier soil or sub-base soil. Analysis of a field lysimeter using a two-dimensional unsaturated-saturated liquid flow model suggested that preferential flow would occur and little or no water would be collected; however, in the field, the lysimeters collected significant amounts of water. A similar discrepancy was found between the observed and predicted water balance of a simple laboratory test simulating the lysimeter design. Vapour flow and partial flow, two phenomena not generally simulated in conventional flow models, are possible explanations for the difference between field and laboratory observations.

Jan 1, 2000

By R. W. Smith, D. L. Taylor, K. A. Altman

Recent research has shown that traditional sensitivity, what if and best case/worst case analysis of metallurgical data has the potential to over estimate the value of mining projects. Use of simulations, which rely on the input of statistical information, may provide more realistic predictions of the value of future projects. Actual metallurgical data is used to demonstrate that analyzing the data from a statistical perspective can give insight into completing an optimum amount of metallurgical testing and a mechanism to determine that samples used for the testing are truly representative of the ore that will be processed.

Jan 1, 2000

By M. Okido, R. Ichino, K. Kuroda

"Compound semiconductor, ZnTe, was electrodeposited in an acidic solution with K2TeO3, ZnSO4 and Na2SO4 solution. Since the reduction potential Te(IV)/Te(O) is remarkably noble from the solution comparing to Zn(II)/Zn(O), code position of Te and Zn was thought to be difficult from this solution. Resulting from EQCM analysis, furthermore, Te(IV) reduced to Te(O) and Te(-II) in this order so that Te catholically dissolved from the electrode surface at more negative potential. But ZnTe alloy were formed by the UPD of Zn at -0.7V at 298K on Te surface in lmM K2TeO3, 100mM ZnSO4 and 100mM Na2SO4 solution adjusted at pH 4. Content of Te in the deposits is, however, more than 80%.Electrolytic temperature is well known to affect on the deposits characteristics. The higher bath temperature was, the better ZnTe crystal was detected in this study. Thermal electrode method is a. process of heating only substrate by flowing ac current in substrate. This process makes the surface temperature of substrate higher than boiling point of the solution, 373K. From EDX analysis, deposits without thermal current were Te-rich, Te content in the deposits with thermal current decreased with increasing of thermal current. Te content was 62% for 5A ac current, 51 % for I OA and 45% for 20A, respectively. The deposits that produced with ac current of IOA were closed to the stoichiometric ratio, i.e. ZnTe.Consequently, thermal electrode method is more effective to obtain a good crystallized ZnTe without heat treatment after deposition.IntroductionThe current subject of solar cell materials is silicon. Compound semiconductors including GaAs and II-VI group are generally used in the developing field of digital information such as the rapid cellular phone and car telephone. Compound semiconductors consist of more than 2 kinds of element. There are many materials for these compound semiconductors such a SiC, InSb, CdS for binary system and CuinSe2 for ternary system. It becomes generally difficult, to produce high quality crystal with increasing of kinds of element due to a complicated structure and a compound ratio of element. Semiconductor materials as a device are usually simple binary compounds and/or these mixed crystals. Properties of compound semiconductors have variety of the forbidden band and lattice constant and that can be change easily by addition of another element for the usage of the solar cell. Since most compound semiconductors are direct interband transition type, which has steep optics absorption edge and large light absorption coefficient."

Jan 1, 2000

By J. A. Oraniscak

Longwall mining operations continue to increase extraction rates and the potential to generate higher amounts of airborne respirable dust (ARD). The National Institute for Occupational Safety and Health (NIOSH) has gathered data from underground longwall surveys and laboratory crushing tests to identify the important factors influencing the amount of ARD levels generated. Coal-seam characteristics, operational parameters (i.e.,cut sequence, mining height, etc.), extraction rates and dust-control parameters (i.e., airflow, water flow, etc.) were examined to determine their influence on ARD levels measured at longwalls during actual mining operations. ARD generated by a laboratory crusher while crushing bituminous coal samples collected from underground longwalls was also examined to determine if there were cor relations with coal-seam properties. Results from the longwall and laboratory data collected indicated that low-ash, high-volatile coals (low moist fuel ratio or MFR coals) generate higher amounts of ARD. It was found that face ventilation and water application to the coal product are essential elements to controlling longwall ARD levels.

Jan 1, 2000

By A. Burger Pintér

To be meaningful the sharing of ideas about the National Environmental Management Act (NEMA) and social issues within the context of Mining and Metallurgy (M&M) requires an honest scrutiny of the M&M/social environment relationship, both past and present. It is not a secret that this relationship has been and is fraught with difficulties. Thus from all perspectives (M&M, society and environmental and social consultants) such a dissection, that highlights the realities, both good and bad, is uncomfortable. For this section of the colloquium to have any value, the honest but difficult approach needs to be taken.

Jan 1, 2000