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By M. L. Free, L. Anthian

Electrochemical, chemical, and image analysis techniques were utilized together with statistical analysis methods to determine the effect of various anode impurities on copper electrorefining performance. Results indicate that arsenic is a beneficial anode impurity. Anode lead and sulfur are shown to decrease electrorefining performance. Specific emphasis is given to the influence of individual elements on current efficiency, slime particle generation, and cell voltage parameters.

Jan 1, 2000

By I. A. Ibrahim, A. K. Ismail, A. A. I. Afifi

"Synthetic rutile for paints industry is conventionally produced by a combined smelting and leaching process. Smelting process is an energy intensive step and represents economic burden in view of the increasing energy costs. Egyptian ilmenite ore containing 40% TiO2 and 38% total Fe was thus directly leached with sulphuric acid to produce eventually synthetic rutile. The process-involves digestion of the ore with sulphuric acid whereby both TiO2 and Fe are dissolved. The solution was then treated with iron powder to convert Fe3+ to Fe2+ to avoid co-precipitation of iron during the hydrolysis step. After solid/liquid separation and clarification, Fe was crystallized as ferrous sulphate hydrate by chilling. The titanium pregnant liquor was concentrated by evaporation and then hydrolyzed to precipitate hydrated titanium dioxide which was then calcined to produce synthetic rutile containing 98.6 TiO2 and 0.58% Fe2O 3. The optimum conditions of all the processing stages were determined.IntroductionSynthetic rutile for paints, welding rods and other industries could be produced from ilmenite ore by sulfuric acid leaching process. This process is a batch process and nearly 80% of all TiO2 produced in the world is made by this process [1]. Figure l shows simple block flowsheet of the process. The process involves the following stages.Digestion: In this stage, ilmenite ore is treated with concentrated sulfuric acid where both iron and titanium are converted to their respective sulfates according to the following equations:"

Jan 1, 2000

By Robert R. McDougal, Anne E. McCafferty, Bruce D. Smith

Magnetic, electromagnetic, and radiometric airborne survey data have been used in regional and local (drainage basin) scales. In a regional geoenvironmental assessment of the state of Montana, magnetic and radiometric data compiled from airborne surveys were used along with other digital geologic and geochemical data to prioritize mining districts for potential acid water generation. Probability ratio mapping was done in order to integrate the interpretation of many different digital data sets. On a more local scale, the Animas (CO) and Boulder Basin (MT) watersheds have been studied using helicopter geophysical surveys. The airborne geophysical surveys show many more structural features than the geologic maps. Combined interpretation of the geophysical data sets using the probability ratio method has resulted in identification of areas of alteration. Airborne radiometric data in the Boulder Basin area suggests that rocks with high potassium and thorium also have a high acid water buffering capacity.

Jan 1, 2000

By C. G. Buttleman, W. C. Brice

In Minnesota, reclamation of active aggregate mining sites is primarily regulated through local permits issued at the county, township, or municipality. However, for abandoned or depleted aggregate mining sites, a responsible party for reclamation is often no longer available. Since 1995, the Minnesota Department of Natural Resources has reclaimed several abandoned aggregate sites using innovative public/private partnerships and emphasizing native plant materials. The purpose of these projects is to demonstrate cost effective reclamation methods that can be utilized by both aggregate operators and local government and to promote mine planning and resource identification as it relates to reclamation.

Jan 1, 2000

By P Tobar

The development plan (long-term plan) of El Teniente Mine, Codelco-Chile, includes 100 per cent primary ore, located at increasing depths, which may involve several difficulties related to the application of the current panel caving method, such as a high seismicity level, a coarse fragmentation and ore pass damage. Therefore, it is a strategic priority for the El Teniente mine, to design and to test alternative mining methods, at similar or lower costs to ensure an efficient and safe ore extraction. In this context, the Macrotrench method is developed, as a competitive alternative to the current method. The document describes the panel caving method, the experience achieved in the primary ore exploitation from the geomechanical point of view. It also describes the æmacrotrenchÆ method as an alternative to the current exploitation method. Finally, the comparative advantages of macrotrench in relation to panel caving are presented. The results obtained during the engineering stage include the following aspects:the mining design, the material handling, a geomechanical evaluation of the method, and a comparative analysis.

Jan 1, 2000

By Masami Taguchi

"It is found that lead monoxide, PbO, has an ionic conductivity, and the all solid-state electrochemical cell using this oxide as an electrolyte has attracted the attention of battery researchers. In this study, thin film PbO2/PbO/Pb solid cells were produced on glass substrates and their discharge properties were investigated. The acti.ve material for the positive electrode, PbO2, was obtained by reactive sputtering of a Pb target in oxygen plasma. The PbO electrolyte and the active material for the negative electrode, Pb, were vacuum evaporated from /3 -PbO powder and a Pb block, respectively. The open-circuit voltage of the cell agreed with the theoretical value based on the thermodynamic data, and the close-circuit voltage was improved by the addition of a univalent impurity such as sodium or potassium to the PbO electrolyte. The connection of the cells in series and in parallel produced a higher electromotive force and a larger capacity. Also, the charge-discharge cycling test revealed that the cell could be charged and function as a storage battery.IntroductionGenerally, the ionic conductivity of a solid-state electrolyte is lower than that of a liquid electrolyte near room temperature. This has been a serious obstacle to using such electrolytes in an electrochemical cell. However, some solid-state electrolytes, which can preferentially pass a specified ion and have high ionic conductivity, have been found. Lead monoxide, PbO, which is an oxygen ion conductor, is such an example (1)(2). If a solid-state electrolyte is adopted for use in an electrochemical cell the problem associated with a liquid electrolyte such as leakage can be alleviated. The cell structure also can be simplified, because the electrolyte plays the role of separator to prevent the active materials from mixing. Thus, physical vapor deposition technology may make it possible to develop a very thin film cell, which consists of only solid phases (3)(4). In this study, the thin film PbO2/PbO/Pb solid cell with a thickness· of only a few micrometers, in which all the constituents were systematically deposited on a glass substrate by reactive sputtering and vacuum evaporation, has been produced and the charge-discharge properties were investigated. An attempt was made to improve the discharge properties by doping impurities such as Na2CO3 and Sb2O3 into the PbO electrolyte. Moreover, the connection of the cells in series and in parallel to get a higher electromotive force and a larger capacity, and the charge-discharge cycling test to determine its use as a storage battery were carried out."

Jan 1, 2000

During the past decade geopolymer technology has emerged as a possible solution for the effective stabilisation and solidification of waste materials. Amorphous to semi-crystalline geopolymers form by the co-polymerisation of individual alumino and silicate species, which originate from the dissolution of silicon and aluminium containing source materials at a high pH in the presence of soluble alkali metal silicates. It has been shown previously that geopolymerisation can transform a wide range of waste alumino-silicate materials such as fly ash and blast furnace slag into building and mining products with excellent chemical and physical properties, including high compressive strength as well as fire and acid resistance. These chemical and physical properties suggest that geopolymeric matrices derived from waste materials are well suited for environmental and other applications such as the encapsulation of mine tails, the immobilisation of heavy metals and also the fabrication of structural products. The current challenge is to demonstrate that a wide variety of natural Al-Si minerals could serve as potential source materials for the synthesis of geopolymers. Moreover, it should be shown on a large commercial scale that it is possible to encapsulate waste materials into the geopolymeric structure without compromising the chemical and physical properties of the final product for the desired application.

Jan 1, 2000

Profiled here are the eight RMCMI 2000 Scholarship Award winners. Six of the eight attended the 96'' Regular Meeting and convention at the Sheraton Tamarron Resort in Durango, Colorado in late Tune. Each spoke during the Scholarship Awards Monday luncheon and shared their goals with attendees. In addition to receiving a 52,000 tuition credit, thanks to the Patrons of the Institute annual funding of scholarships, each received recognition at the luncheon with a brass plaque signifying this honor. The winners arc guests of the Institute Sunday through Tuesday noon and have an outstanding opportunity to meet many in the coat industry who could be potential employers. The state vice presidents host the winners and pay for their travel and hotel expenses. This is a continuing scholarship and may be renewed for tuition credit again in the senior year it the winner is a full time student and is recommended by the dean of the college or university. A resident from each of the eight member RMCMI states is selected by the Scholarship committee from Board approved institutions. Criteria for these annual awards is that the recipient (1) is a full time sophomore student who will use the tuition credit the junior year. (2) Be both a U. S. citizen and a legal resident of the member state. (3) Maintain good academic standing, be pursuing a degree in a mining related field and have an expressed interest in western coal as a possible career path. Contributions to this worthwhile project are tax deductible to each individual RMCMI member or his company. Through donations of $100 or more to the Patrons of the Institute, each Patron receives a plaque and a year bar for each additional year contributions arc made. There may be directed to RMCMI Patrons, 3000 Youngfield Street, #324, Lakewood, CO 50215. [ ]ARIZONA WINNER David L. Vatterrodt University of Arizona The son of Charlene and Larry Vatterrodt, David graduated from Marana High School, Tucson, Arizona where he attained a 3.6 GPA. In his second year at the University of Arizona he has a 3.4 GPA and is pursuing a Bachelor of Science in Mining Engineering. He is a member of SME and enjoys playing tennis and riding his motorcycle. He is the recipient of a $1,000 Tradition of Excellence scholarship. David volunteers every Saturday morning during the academic year at the U of A. San Xavier Mining Laboratory. His tasks there include work area inspections, jack-leg drilling, scaling, roof bolting, operating an LHD and overshot mocker, track laying and other general maintenance. COLORADO WINNER [ ]Jonathan B. Casten Colorado School of Mine. Graduating with high honors and a 3.99 GPA from Windsor High School, Colorado, Jon is well prepared for the rigors of academia. In high school he was on the Dean's list, Salutorian of the Senior Class, member of National Honor Society, Colorado Boys State delegate and lettered in varsity golf.At Mines, Jon belongs to SME and Work Study and maintains a 3.75 GPA. He enjoys golf, hiking and weight lifting. His parents are Katherine and Fred Casten of indsor. Jon has chosen Mining Engineering as a career as he plans to improve the nation's efficiency of extracting natural resources.

Jan 1, 2000

By Kostas Fytas, Pierre Bousquet, Bill Evanelou

Acid mine drainage (AMD) is a serious environmental problem that preoccupies the Canadian Mining Industry. Considerable amounts of money are spent every year in an effort to prevent or reduce the acid mine drainage phenomenon. AMD occurs when sulphide minerals (ex. pyrite) contained in rock are exposed to air and water and subsequently oxidise to produce low pH water. This acid effluent has the potential to mobilise any heavy metals contained in the rock. Coating the sulphide minerals with silicates is a new promising technology to reduce AMD. Pynte is treated with a solution containing H2O2, sodium silicate and a buffering agent. H2O2 oxidises a small part of pyrite producing ferric iron (Fe3+) ions. These ions subsequently react with the silicate ions to produce ferric hydroxide-silica that precipitates on the pyrite surface producing a passive coating. This silicate coating can protect the grains of pyrite from oxidation. This paper presents a series of experiments that confirm that silicate coating can considerably reduce AMD.

Jan 1, 2000

By JoAnn Silverstein, Eric A. Marchand

Competition between Thiobacillus ferrooxidans and non-iron-oxidizing heterotrophic bacteria was induced by the addition of glucose to a co-culture of T. ferrooxidans and A. acidophilum in an oxygen-limited environment. Iron oxidation was inhibited as dissolved oxygen was used preferentially for glucose metabolism. Furthermore, as the water became anoxic, glucose was consumed along with the oxidized iron species (Fe3+) during iron respiration resulting in a pH increase from 2.0 to 4.0. Results suggest that biologically mediated acidification of drainage water can be reversed by dispersion of an easy to degrade, soluble, and inexpensive carbon source such as glucose into the subsurface.

Jan 1, 2000

By R. J. Wesely

Non-ferrous smelters traditionally have a hot gas handling system. In these systems, the dust is captured as a dry material which is often recycled to the process. Some smelters use wet gas cleaning methods with the recovery of the dust as a wet sludge. Although this sludge can be recycled to the process, in some cases it is preferable to dispose of the sludge. This paper will discuss the disposal methods available and specifically will deal with one type of sludge which has a high arsenic and high lead content. Problems with this sludge were investigated and methods were tested with the aim of stabilizing the sludge so that it passes the EPA TCLP test. Results of the laboratory tests are given.

Jan 1, 2000

The concept of Extreme Gravity is the latest in a series of innovations that has seen a re-introduction of gravity recovery systems into the milling operations of most gold mines. Traditionally, most gold milling circuits are designed around flotation and cyanidation requirements, with the gravity circuit being fit in where possible. Extreme Gravity takes the novel approach of optimising the circuit, in order to maximise recovery by gravity. In some cases gravity systems can achieve high enough recoveries to eliminate the need for chemical systems such as cyanidation or flotation. There are many advantages of such a system including low capital cost, reduced permitting, improved cash flows and much reduced environmental issues. There are a number of plants currently in operation which utilise this new methodology. The Muzhievo project has been an example of a recent turn key success achieving recoveries from 85 - 90 per cent. The details of this project are examined as a case study.

Jan 1, 2000

By A. C. Cascalheira, L. M. Abrantes, M. Savic

This paper reports our results on the application of a novel process for the spontaneous and sustained reduction and recovery of elemental silver and gold on an electroactive polymer surface. This work incorporates the metal recovery from photographic films (silver) and goldsmith residues (gold), by direct contact of metal containing solutions with polymer. The performance on such process of electrochemically and chemically prepared polyaniline (P ANI) is evaluated. SEM coupled with EDX and XRD analyses confirmed the presence of metallic silver and gold deposited onto polymeric material.

Jan 1, 2000

By R. L. Grayson

Conventional mine safety wisdom states that "the most efficient mines are also the safest." Since the 1980s, small mines (and contractors) have been targeted as the most dangerous because of their fatality records. However, statistical analysis of West Virginia safety and production data from 1993 indicated that, when considering the correlation between accident severity and tons mined per employee-hour worked, the most efficient mines were, with the exception of very small mines, not the safest operations. This paper presents the results of an extended analysis of West Virginia mine safety using 1993 and 1996 data and concludes with the method used to suggest current priorities for focusing interventions.

Jan 1, 2000

A general review of grinding mill steel liner evolutions/developments in recent times. The driving force behind these developments has been the mill operators desire to minimise the nett cost of their operation. These developments have resulted from a team approach between supplier, operators and reline crews. The move towards larger diameter high aspect mills, faster mill speeds, pebble ports and the use of large diameter grinding media has affected the traditional liner designs, which is placing higher demands on the supplier to meet these new working parameters and expectations. Operators are also taking closer ownership in the liners being supplied, as demonstrated by the development of their own mill liner specifications. This paper outlines some of liner developments and changes undergone at various milling operations around Australia and overseas (such as Cadia Hill, Kidston, Ok Tedi Mining, PT Freeport, etc) and where to in the future?

Jan 1, 2000

The extraction of world-class mineral deposits using massive underground mining techniques is not an entirely new theme to world mining companies and experts. Previous MassMin conferences have helped to gather and disseminate the valuable experience and knowledge so important for the proliferation of safe and efficient mining of large underground deposits. With the passing years since the first MassMin conference in Denver in 1981, a number of factors have contributed to an increase in massive underground mining around the world, including environmental pressures, gradual exhaustion of shallower deposits and the enabling effects of improving technology in disciplines related to underground mining. Massive underground mining is heading deeper, embracing challenges which include working with elevated temperatures, increasing in situ and mining induced stress levels and longer ore transport routes. Improvements in mineral processing technology will tend to lead operators to contemplate the extraction of lower grade orebodies in the event that the ore can be efficiently transported to the surface and hence the plant. No doubt this tendency, and its associated challenges is encouraging a rich growth in innovative engineering in such fields as mine planning and materials handling as well as geomechanical issues such as support design and the simulation of extraction sequence effects on stress re-distribution. MassMin 2000, we are sure, will showcase a wide variety of new contributions in thought and actions in these fields. There is a definite place for academic institutions and mining related suppliers in the process of developing new technologies and practices in support of present and future endeavour in this field. Dyno Nobel has its own part to play, certainly as an enthusiastic and proud major sponsor of MassMin 2000, but also by means of identifying common cause between our Vision and Values and the needs, present and future, of the underground massive mining industry. The critical success factors, which Dyno Nobel pursues are:health, safety and environment, customer relationships and market development, cost optimisation (while maintaining quality), technology and innovation, organisational development, and leveraging capabilities globally. Through the present paper we would like to share some of these values and offer some practical insights as to how their realisation will contribute to the achievement of MassMin goals and needs.

Jan 1, 2000

By Chris Harnan

This paper describes the geology of three European cities and outlines how the geology has lead to the development of specific foundation construction techniques. Comparative tables of techniques commonly employed are given in Section 5. It can be seen that despite the presence of the 'single market', techniques still have wide diversity despite some similarities in geotechnical conditions.

Jan 1, 2000

By Thomas L. Vandergrift

Multiple-scam mining is becoming more common in the United States, especially in the East, where primary reserves arc being depleted, forcing mining companies to develop secondary seams, Although mine engineers and planners are aware of the basic effects of seam interaction and generally follow guidelines for columnizing entries and avoiding load abutments, mine design earn greatly benefit bum more quantitative estimates of scam interaction effects. This paper presents case studies from two eastern mines subject to seam interaction effects where pre-mining stresses were quantified: the Mingo Logan Coal Company's Mountaineer Alma A Mine, and Peabody Group's Lightfoot No. 2 Mine. In each of these mines. mining is being carried out within 60 to 90 ft of overlying longwall and pillar panels under maximum cover of about 1,100 ft As part of overall mine planning and design efforts al these mines. NSA Engineering performed numerical modeling analyses using the non-linear boundary-element code MULSIM/NL Input parameters were calibrated by modeling areas where ground conditions resulting from seam interaction were well documented. By incorporating actual cover loading based on topography and seam dip, and the integrity of remnant, gate road, arid harrier pillars in the overlying mines, the pre-mining vertical stress in the underlying scants was estimated based on the pre-mining stress, plans for mains, gate road, bleeder, and pillar panels were developed. Although mining experience in these areas has beers somewhat limited to date, she designs developed as a result of these analyses have so far proven successful.

Jan 1, 2000

By L. Alan Weakly

Coal mines and power plants utilize different methods to control dust for the safety of their workers and to protect their installations. The methods that they use are limited by the Environmental Protection Agency or the states in which they operate. Now there is a new technology for controlling dust at conveyor transfers! The Passive Enclosure Dust Control System utilizes several proven technologies to mitigate fugitive dust. This new system has been proven to be four times more effective than standard enclosures utilizing bag house collection and is considerably less expensive to install and operate.

Jan 1, 2000

Over 45 of the Best Qualified Technical Specialists, Consultants, Engineers, Scientists, Explosive Supplies, Educators and Mine Operators in the World!

Jan 1, 2000