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By E. V. Verhoef

The proposed EU directive on the restriction of the use of certain hazardous substances in electrical and electronic equipment promotes the substitution of lead in consumer electronics to reduce emissions from lead in the end of life phase. In this paper, the consequences of substituting lead in solders is assessed using the Eco-lndicator-99 method for the examples. The base metal production system is considered as an interconnected network modeled dynamically in Simulink 4 and Matlab 6 (Mathworks Inc 2000), where the recovery and production of metal components of the assessed product partially overlap. This approach requires global modeling of metal production processes and mass balances and resulting allocation choices. It also reveals the susceptibility of LeA scores to different choices in the modeling and data availability and uncertainty. Besides the comparison between lead-free and lead-containing solders, other side effects are revealed. Lead is carrier material for the recycling and production of many co-elements in the interconnected production and recovery system. Substitution may have adverse effects such as temporary shortages of other connected metals that are often not considered in normal LeA assessments, thus leading to erroneous results. The suggested approach provides directions for including these external effects and for further assessment of the environmental effects of substituting lead. This paper shows that in order to assess the environmental aspects of metallurgy, dynamic modeling of the total system is required based on the fundamental thermodynamics in each metallurgical reactor, the basis of this dynamic model. With this the true environmental impact of metallurgy can be explained. In the case of lead free solder, it is shown that the mining of substitutes has a very much larger impact.

Jan 1, 2003

By Moelans. N.

A method using an ex-situ electrochemical measurement device was developed to determine the oxygen potential of non-ferrous metallurgical slags. The electrochemical cell consists of the molten slag sample, an inert Ir electrode, a stabilized Zr02 solid electrolyte and a NilNiO reference electrode. Different slags from non-ferrous pyrometallurgical processes were analysed at I 100 and 1200 °C and pO2values between 10-3 and 10-12 bar were obtained. The measurements were evaluated with thermodynamic calculations and using processing considerations. It was found that the reproducibility and stability of the measurement was significantly improved by shielding the molten slag from the atmosphere by a thin layer of carbon, especially for slags with a low oxygen potential.

Jan 1, 2003

By I Taylor, M Nugus, C Gordon

Resource estimation and selective mining of structurally complex, high nugget orebodies presents a major challenge to the Mine Geologist. At the Golden Pig BIF-hosted gold deposit in Western Australia, an estimation method has been developed that replaces an assay-based resource estimate with one based on mineralisation intensity. Subjective coding of the mineralisation intensity has a more robust connection to local grade than drillhole assays. Indicator variograms of the five mineralisation codes are well structured with anisotropy directions similar to observed structural controls. The proportion of each mineralisation code is estimated and a weighted average of the average grade of each code calculated for a block. Initial validation has shown that the model is a good predictor of the mineralisation intensity, and the application of appropriate local average grade for each mineralisation code gives a reliable block grade estimate.

Jan 1, 2003

By Karl J. C. Harries

"4.1. INTRODUCTIONThis chapter, although divided into four parts, deals with only two principal topics. The first briefly describes and discusses some common types of property interests and considerations relating to them and the second deals with entering upon privately owned lands and obtaining the consent to do so.It should be noted that the terms “mining rights” and “mineral rights” are used interchangeably. As so used, they include the right to exploit the minerals and dispose of them for the benefit of the owner/lessee. This is relatively common in common law jurisdictions. In some jurisdictions, the two terms have distinct meanings, with “mining rights” referring to the right to work or exploit the minerals and “mineral rights” referring to the minerals themselves.Finally, it must be mentioned that the comments in the Introduction and §§ 4.2., 4.3. and 4.4. are based primarily upon Ontario law and Ontario’s mining and real property systems of registration. They have been included for illustrative purposes.4.2. LICENCES, CLAIMS, AND LEASESIn most jurisdictions, there are several basic types of interests that can be obtained from the state for mining purposes and that are of interest to the explorationist, as opposed to the operator. Different jurisdictions will have variations of these and possibly some extra ones that will address special purposes or local concerns. In virtually every jurisdiction, privately owned property rights are obtained through negotiation between owner and acquiror.Exploration or prospecting licence. This licence grants to the holder the right to prospect over a large tract of land and the exclusive right to acquire mining claims within that tract for the term of the licence. Such licences are usually negotiated documents requiring a minimum expenditure during the first year (often secured by a deposit or surety bond) and minimum annual expenditures thereafter to continue the licence in force up to its full term. The term will rarely exceed four years. The number of claims permitted to be staked will be limited in some way, possibly as to a maximum aggregate area or a maximum number of claims per annum. It is normal for the holder to have to drop part of the licensed area each year, so that the area shrinks annually, although exploration expenditure requirements will usually increase.These types of licences are usually used by governments to encourage exploration of otherwise unattractive or remote areas, such as the far northern parts of some of Canada’s provinces. They do not grant any real property interest in the area for which they are issued, and they will be subject to any claims or property rights that exist in the area. They are contracts with the state that grant certain exclusive rights in return for commitments to carry out work. They may or may not be specifically authorized by statute."

Jan 1, 2003

By Naoki Hiroyoshi, Hajime Miki, Tsuyoshi Hirajima, Masami Tsunekawa

"Acidic solutions for chalcopyrite leaching contain cupric, ferrous and ferric ions, and the oxidizing power of the solutions is indicated by a redox potential, determined by the concentration ratio of ferric to ferrous ions. This paper reviews our previous studies on the redox potential dependence of chalcopyrite leaching in sulfuric acid solutions. Leaching experiments indicated that copper extraction rate was accelerated by cupric and ferrous ions , and was higher at potentials below a critical value (critical potential) in the presence of these ions. This was in good agreement with the results of electrochemical measurements, i.e. in the anodic polarization curves for a chalcopyrite electrode, active-passive behavior was observed when cupric and ferrous ions co-exist, but the activation at low potential did not occur without these ions (Figure 1). The analysis of the AC impedance spectra for chalcopyrite electrode indicated that a high-resistance passive layer grows on the chalcopyrite surface without cupric and/or ferrous ions, and that coexistence of these ions causes a formation of another product layer and inhibits the passive layer growth at low potentials.These results are explained by a reaction model assuming the formation of intermediate Cu2S due to chalcopyrite reduction and the subsequent oxidation of the Cu2S. The critical potential corresponds to the redox potential of the Cu2S formation and the predicted values matched with the experimental results. Catalytic effect of silver ions on chalcopyrite leaching was also discussed based on experimental results and the above model."

Jan 1, 2003

By Donald R. Lamont

The paper outlines the reasons for and research behind the recent decision to adopt oxygen decompression in the UK. Currently used measures of decompression illness are critically appraised. The paper describes the main precautions to be taken on site to manage the fire risk from the use of oxygen underground. A summary of the initial results from the use of oxygen decompression in the UK is presented.

Jan 1, 2003

By I. E. Teymenson, N Fedunets

Mining-metallurgical complex is the base of any economics and influences directly on practically all branches of world economics. Therefore the task of estimation and selection of investment decisions in mining industry adequate to modern market conditions and the task of decreasing multidimensional alternatives selection uncertainty are very actual. An uncertainty of investment alternatives is explained by a number of reasons, main of which are a presence of several investors types, an unstable situation on the market and an absence of evident relations between appraisal criteria used. Maximum increasing of formalization and objectivity of information technologies applied for an estimation permits to reduce the uncertainty of investment variants estimation. A number of principled innovations, allowing to solve the task of decreasing of multidimensional alternatives selection uncertainty, are introduced into the information technology of estimating and selecting investment decisions in mining-metallurgical branch, developed by us. In the article the necessity of including a cognitive model into developed selection mechanism, which allows to take into consideration inter-influences of used critera, has been grounded. Besides, the forecasting model considering interconnected time rows has been applied for increasing the world conjuncture forecast quality. Further in the article main metrics types have been characterized and application of weighted Chebyshev’s metrics as the most compromised from all studied metrics for variants selecting has been proved, and also the developed procedure of directional search of effective compromise decisions has been described. Brief characteristic of designed instrumental means of multi-criteria variants estimation and selection finalizes the article. In conclusion expedience and efficiency of using the developed information technology for reduction of multidimensional alternatives selection uncertainty have been grounded.

Jan 1, 2003

By F. A. Camisani-Calzolari

South Africa has adopted its own code for public reporting of Mineral Resources and Mineral Reserves in 2000. The South African Code for Reporting of Mineral Resources and Mineral Reserves (SAMREC Code or Code) (SAIMM 2000) is presented here in its local and global context. The main aspects of the Code are listed and elaborated upon. The Code has been written with the participation of the major South African stakeholders in the field including Government institutions, the legal confraternity and the mining industry. The Code is modelled on, and is 90% compliant with, the Australasian Code for Reporting of Mineral Resources and Ore Reserves (JORC Code) (AusIMM 1999). The paper also elaborates on the duties and responsibilities of Competent Persons signing off resource and reserve reports and on the listing requirements of the Johannesburg Securities Exchange (JSE), formerly the Johannesburg Stock Exchange, which has officially adopted the Code. The listing requirements were updated in 2000 to incorporate the SAMREC Code and subsequently in 2002, effective 2003. The ongoing obligations of the JSE for the exploration and mining companies are being compiled and are expected to be effective from early 2004.

Jan 1, 2003

By Junhwan Lee

Pipe piles can be either closed- or open-ended piles. Pile load capacity for a closed-ended pile consists of the shaft and base resistances, while, for an open-ended pile, it consists of shaft, soil plug, and annulus resistances. In order to investigate the pile load capacity of both closed- and open-ended piles, two field pile load tests were performed. For the open-ended pile, the fully instrumented double-walled system was used to separately measure all the components of the pile load capacity. The soils at the test site were predominantly granular soils with relative densities varying from loose to dense with increasing depth. The incremental filling ratio (IFR), which affects significantly the load capacity of open-ended piles, was also measured during pile driving. The test results indicated that the total load capacity of the closed-ended pile was higher that that of the open-ended pile, mostly due to the difference in shaft capacity. The shaft and base load capacities of the open-ended pile were 44% and 20% lower than the corresponding values for the closed-ended pile.

Jan 1, 2003

By H. Yavuz

Physical modelling is one of the research tools in the understanding of the failure mechanisms and the deformations likely to be experienced by the strata during mining operations. Success of the physical models to predict the strata behaviour depends on satisfaction of the scaling requirements in modelling material used. This paper gives results from a laboratory work carried out into the factors influencing the strength and elastic properties of a physical model material to satisfy the scaling requirements determined from application of dimensional analysis to the pertinent variables affecting the deformation and failure of the underground structures. It was found that the conditions for preparing the material over its composition had a great influence on the final properties. The effect of different water quantities, sand size and mixing time upon the properties of modelling material was studied and water requirement for different proportions of sand/plaster to prepare the material was optimized. Various sand/plaster ratios of compositions were cured at three different levels of oven temperatures. Curing at low temperature produced material within the average modulus ratios ranging from 290 to 432, which are common to most rock types according to Deere?s rock classification, whilst curing at high temperature produced material within the low modulus ratios ranging from 64 to 140 depending on its composition. A combination of low and high temperature curing resulted with an increase in modulus ratio compared to high temperature curing. Curing the material at low temperature compared to other curing temperatures provided a satisfactory range of strength ratio. It has been shown that the relative amount of filler to plaster in the mix controls the frictional properties of the material and results with an increase in strength and modulus ratio of the material provided that suggested preparation and curing conditions were applied. Model material developed by curing at low temperature simulated modulus ranging from 241 to 343 and strength ratios ranging from 11.6 to14.8 of a coal mine rocks, satisfactorily.

Jan 1, 2003

By Winfried Rosenstock

The development of electronic initiation systems has partially reached or will reach in a short period of time full reliability for general use without limitations. Unfortunately those systems meet with a fully unprepared mining community and is confronted worldwide with blasting procedures which are not suitable to exploit the full range of the electronic option. This is for the time being only belonging to quarrying and general surface mining, for the use in underground operations the detonator is still not yet competitive, apart from special cases. It is not to be taken in doubts that the introduction for underground purposes will follow in a less shorter or longer period of time.

Jan 1, 2003

Several economic factors have caused the surface mining industry to require large-capacity shovels and trucks for efficient, high-production, low-cost operations. Some of those factors include technological advancements in equipment, commodity market depressions, increased labor and maintenance costs, contractural obligations and harsh operating conditions. The difficult operating conditions in surface mines, however, pose challenges to the use of high-capacity equipment. They include space limitations, weak over-burden, and weathered soils and rocks. So mining companies face major challenges in selecting appropriate shovels to meet the technical, operating, safety, environmental and economic requirements of their mines.

Jan 1, 2003

By Nobuaki Sato

The electrical conductivity, k, of pure and sodium doped sulfur melts was measured with and without ultrasonic waves at temperatures ranging from 140 to 340'C by the two probe method using an ultra high resistance meter. The k value of the pure sulfur melt with irradiation jumped at around 170°C by an order of 102 after which it mouutuniocally increased from 10-5 to10-4 A' 1 cm-1 with an increase of the temperature. The addition of the sodium metal to the sulfur melt was found to cause a larger jumping in the K value. The k value increased with the increase of Na proportion in the melt. For a 10mol% Na doped sulfur melt it was as high as max ~30 A 1cm -1 above 180 C under the irradiation of of ultrasconics.

Jan 1, 2003

By Hiroshi Sasaki, Herman D. Mendoza

"The surface-chemical property of nickel slag fiber was modified in aqueous media in order to act as an active and efficient collector of colloidal amorphous silica from geothermal effluent. Colloidal amorphous silica (0.05 µm) from geothermal wastewater causes operational and ecological problems. It clogs geothermal pipes and waterways, and when disposed to the environment poses hazardous effects on both the flora and fauna ecology. Because colloidal amorphous silica is extremely fine and remains in suspension in aqueous media, conventional solid/liquid processes to remove colloidal silica from its bulk liquid are rendered ineffective.A rapid separation technique is then developed to remove effectively amorphous colloidal silica from its bulk liquid by attaching the extremely fine particles of silica onto a nickel slag fiber coated with magnesium hydroxide, Mg(OH)2. The nickel slag fiber has the following characteristics: a high surface area and predominantly possesses negative charge in aqueous media with an iso-electric point at pH ~2.5. When soaked and saturated with Mg(OH)2 solution, the surface of the nickel slag fiber becomes coated with fine and compacted Mg(OH)2 precipitates. This modifies the surface- chemical property of nickel slag fiber transforming the negatively charged surface into a positively charged surface in aqueous media with an iso-electric point of around pH 11.8, which corresponds to the iso-electric point of Mg(OH)2. When geothermal effluent containing negatively charged colloidal amorphous silica particles (i.e.p. of silica is pH 2) is passed through a column-bed packed with surface-chemically modified nickel slag fibers under natural pH conditions, the colloidal amorphous silica particles are recovered by attachment onto the surface of the surface- modified nickel slag fiber. The recovery of colloidal amorphous silica by attachment is 97-99%, resulting in the production of a relatively clean and silica free output. Aluminum hydroxide, Al(OH)3, was also used to modify the surface –chemical property of the nickel slag fiber. In the same way, it also exhibited a positive response with the collection of colloidal amorphous silica from its bulk liquid, but yielding a lower recovery of 90%. This may be attributed to the lower surface potential and iso-electric point of pH 9.3 for Al(OH)3. The separation process was evaluated and analysed using existing potential energy theories. Figure 1 shows a micrograph of the surface of an unmodified and the Al(OH)3 –modified surface of nickel slag fiber."

Jan 1, 2003

By A-M Fleury

There has been much progress on the issue of acid drainage over the past 20 years; however, significant challenges remain. The International Network for Acid Prevention (INAP) is attempting to address them by globally coordinating acid drainage information sharing and research. INAP pursues three branches of activities: it links AD research, practice, and people; it organises, sponsors, and participates in regional workshops as a forum for technology transfer; and it instigates and funds key acid drainage research projects. Through these activities INAP is helping the industry deal with what is arguably its most serious legacy issue.

Jan 1, 2003

By Jung-Hoon Kang

Present study was stemmed from the survey associated with deep-sea mining in the KODOS area between Clarion Fracture Zone and Clipperton Fracture Zone located in the North Pacific Ocean. The study area, which is located in the southeastern part of North Pacific gyre, is oligotrophic waters with low nutrients and chl-a concentrations below 1µg/l (MOMAF, 1996). This area is also characterized by divergence at 8°N and convergence at 6°N, which moved northward or southward in the range of a few kilometers with seasonal and climate changes. If the waste materials related to deep-sea mining are intruded into the surface waters continuously, unexpected effects to water column ecosystem are anticipated negatively. In order to assess the impact on the planktonic ecosystem, natural variation need to be distinguished from anthropogenically induced variation in terms of the abundance and species composition of plankton. In this study, mesoscale variation of zooplankton community was reported in relation to the physical conditions in the northeastern Pacific during 1998 and 1999. Temperature and salinity were determined using a CTD from surface to 200m depth in July 3-20, 1998 and in June 22-July 1, 1999. Zooplankton samples were collected from two different depths (0-50m, 50-200m) by vertical towing using an opening-closing net (100cm diameter and 300 µm mesh size). The samplings were carried out at every one degree between 5° and 12°N (1998), between 5° and 11°N (1999) along the meridional lines of 131°30´ W. The net was lowered to the depth of interest from a stationary research vessel and towed upward to collect zooplankton at a speed of 25~30 m per minute. Zooplankton samples were transferred to 1-l sampling bottles and immediately fixed with neutralized formalin into the final concentration of 5%. Considering the characteristics of zooplankton such as diurnal vertical migration, all samplings were done during the nighttime. The volume filtered by the net was calculated from the readings of flow meter (Hydro-Bios Model 438-115). Zooplankton were identified to the genus level and enumerated under a microscope. The abundance of zooplankton at each station was expressed as the numbers/100 m3.

Jan 1, 2003

By S Pfaff, R Rajic

In the case when the number of independent variables is greater, a careful design for carrying out tests has to be made in order to obtain, with the smallest possible number of tests, as much as possible neutral information about the influence of independent variables on the dependent ones. Only on the basis of such design and its statistical analysis it is possible to come to right conclusions about the function of the whole system. The influence of pressure, temperature, humidity and granulation of the coal upon the resistance to pressure and the water absorption of the briquettes has been tested, with the aim to examine how each of the two dependent variables changes depending on the values assumed by any of the four independent variables and which of the mentioned independent variables significantly influences the dependent ones. The full factorial design with 16 experiments and the central composite design with 27 experiments have been applied. The influence of the independent variables upon the dependent ones has been examined by applying the analysis of variance. The influence values of individual factors and their interaction upon the dependent variables have been stated as well as coefficients of curvilinear equation.

Jan 1, 2003

By Ulrich Langosch

In the 1990s the German mining industry introduced a new generation of shield supports. The new design of support has a maximum load capacity of 10,000 kN, making these units as strong as the shields used in Australia and in the USA. DMT took more than 3,100 underground observations in order to verify the roof fall frequency by statistical analysis. The results of this work have led to practical recommendations for roof control and the required shield support system on longwall faces. The underground observations have been correlated to Rock Mass Classification, to stress calculations and to the angle between the direction of the fissures and the direction of longwall mining_ The analysis work yielded the following two sets of results: 1. There is a critical distance between the canopy tip and the coal face (Tip to Face TF,n,). The TF,n, is predictable and relates to: the thickness of the first roof layer and its uniaxial compressive strength. The face support should have a TF that is less than the TFcrtt in every underground longwall situation. Exceeding the TF crit call immediately result in a roof fall. 2. Using the obtained regression equation DMT is able to calculate the probability of the roof fall frequency (FF), which describes the roof fall sensitivity. When TFcr;, is exceeded the predicted roof fall FF relates to: the measured support resistance (MSR) of the shield support the calculated vertical stress (p?) the fissure-direction index (DI = angle between main fissure direction and direction of mining) and the distance by which TFcrit is exceeded (ATF). Armed with these results DMT is now able to predict the critical distance between the tip of the canopy and the coal face (TFcrit), as well as the roof fall frequency, for all shield designs. By applying the new calculation method it is now possible to compare alternative longwall layouts and different shield support types under pre-set geological conditions. Mining engineers on site are therefore in a position to make the necessary roof control preparations required to run the longwall operation to maximum efficiency. The results provide a useful basis for making practical recommendations and for selecting the most effective design of shield support. The paper uses practical examples to demonstrate the R&D results and present the various methods now available for calculation and prediction in longwall roof control.

Jan 1, 2003

By Fred N. Kissell

This handbook describes effective methods for the control of mineral dusts in mines and tunnels. It assumes the reader is familiar with mining. The first chapter deals solely with dust control methods, regardless of the application. It is a brief tutorial on mining dust control and will be of help to the reader whose dust control problem does not conveniently fit any of the mining equipment niches described in later chapters. The subsequent chapters describe dust control methods for different kinds of mines and mining equipment. This includes underground coal and hard-rock mines, as well as surface mines, stone mines, and hard-rock tunnels. Because dust sampling has so many pitfalls, a chapter on methods used to sample dust is included. For those occasions when there is no practical engineering control, a chapter on respirators is also included. Except for those listed as ?future possibilities? in the longwall chapter, the dust control methods described are practical and cost-effective for most mine operators. If controlling dust were a simple matter, dust problems in tunnels and mines would have been eradicated years ago. Unfortunately, most underground dust control methods yield only 25% to 50% reductions in respirable-sized dust. Often, 25% to 50% reductions are not enough to achieve compliance with dust standards. Thus, mine operators must use several methods simultaneously, usually without knowing for sure how well any individual method is working. In fact, given a 25% error in dust sampling and day-to-day variations in dust generation of 50% or more, certainty about which control methods are most effective can be wanting. Nevertheless, over the years, some consensus has emerged on the best dust control practices. This handbook summarizes those practices.

Jan 1, 2003

By A. A. EI-Geassy

High-grade iron ore fines rejected from the DRI plants (>96%Fe2O3) were isothermally reduced in 30-60%CO/H2 gas mixtures at 973-1273K. The freshly reduced reaction products were then subsequently carburised in either Hz/CO or H2/CO/S mixtures at 823-1 073K for 30-120 min. The thermogarvimetric technique was used to follow up both of reduction and carburisation reactions as a function of time. The carburised samples were characterized by X-ray and Mossbauer techniques. Chemical and carbon analyses were also applied. The influence of temperature and gas composition on the reduction behavior was investigated. The calculated values of apparent activation energy, application of gas-solid mathematical formulations were correlated with the microstructures to predict the reduetion mechanism. The influenee of carburization time, temperature, CO contents in H2/CO or H2/CO/S were investigated. A conversion extent of Fe to Fe3C was taken as a measurable index for the efficiency of carburization rcaction under the different experimental conditions.

Jan 1, 2003