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By Tamas Kekesi

Anion exchange in HCl media is considered an efficient alternative to the combination of the conventional purification methods. Anion-exchange distribution functions have been determined for cobalt and the main impurity elements by the technique of batch equilibration. Results were confirmed by spectrophotometric investigations and elution tests. Based on the new and the available distribution functions, combined with the assessment of thermodynamic stability, a procedure of anion exchange separation has been devised to eliminate virtually all the impurities from the cobalt-chloride solution. Separation of copper has been enhanced by the introduction of a preliminary step under reduced conditions. The rest of the impurities are eliminated in a second anion-exchange step applying rinsing and elution stages under oxidized conditions. The optimum parameters of the procedure have been determined according to performance characteristics (purification ratios, yields and volume efficiencies) derived from the analysis of elution curves obtained with laboratory scale ion-exchange columns. Special computer programs have been developed to facilitate thermodynamic simulation, analytical correction and data processing.

Jan 1, 2003

By Adel Hanna

Earth pressure acting on piles driven in sand is playing a major role in estimating pile capacity. In literature, researchers entertained simplifying assumptions in estimating the earth pressure acting on the pile's shaft, ignoring the effects of pile installation and pile size. Empirical formulae were introduced based on laboratory or field test results, where major discrepancies can be found among these formulae. In this paper, the theory of cavity expansion and the finite element technique will be used to establish the effects of pile installation technique and pile's diameter on the earth pressure acting on the pile's shaft and accordingly on the values of the existing coefficient of passive earth pressure and overconsolidated ratio. It is of interest to note that pile driven technique and pile's diameter have significant increase on the earth pressure acting on the pile's shaft and accordingly on the overconsolidation ratio in case of loose or medium sands, while they may cause crushing and dilation in case of dense sand. Keywords: Single pile, Cavity expansion, Cohesionless soil, Driven piles, Numerical modelling, Finite element technique, Earth pressure.

Jan 1, 2003

By R. J. Pine, J. M. Rance, J. S. Coggan

ABSTRACT: The safe design of excavations created in a fractured rock mass is of paramount importance in rock engineering. Depending on the nature of the stress regime acting on an excavation, and the associated deformational behaviour of the rock mass surrounding the excavation, a number of potential failure mechanisms exist. These involve a combination of shear failure on existing joints, extension of critically oriented joints and propagation of new fractures through previously intact rock. Conventional numerical codes usually adopt either a continuum or discontinuum approach; this often results in significant over simplification and kinematic limitations particularly when modelling complex rock mass behaviour in the close vicinity of excavations. This paper describes the results from several case examples using a combined finite element-discrete element code, ELFEN that incorporates a crack propagation mode. Through the use of selected rock engineering examples, the authors demonstrate the potential of the code in the realistic simulation of complex rock failure both in underground and surface excavation applications. RÉSUMÉ: La conception sûre des excavations créées dans une masse de roche fracturée est d'importance primordiale dans la géotechnique. Selon la nature du régime d'effort autour d’une excavation, et le déformation associé de la masse de roche autour de l'excavation, il exsite un certain nombre de mécanismes potentiels d'échec. Ceux-ci comportent une combinaison d'échec de cisaillement sur les joints existants, la prolongation des joints d’orientation critique et la propagation de nouvelles ruptures dans la roche précédemment intacte. Les codes numériques conventionnels adoptent habituellement l’approche, soit d’un continuum, soit de discontinuum; ceci a souvent comme conséquence une sursimplification significative et les limitations cinématiques en particulier en modelant le comportement complexe de la masse de roche très proche des excavations. Cet article décrit les résultats de plusieurs exemples de cas en utilisant un code qui s’agit d’une combination d’élément discret et d'élément fini, ELFEN qui incorpore un mode de propagation de fissure. Par l'utilisation des exemples choisis géotechniques, les auteurs démontrent le potentiel du code dans la simulation réaliste de l'échec complexe de roche pour les applications aux excavations soit au fond soit à l’extérieure. ZUSAMMENFASSUNG: Das sichere Design der Aushöhlungen, die in einer zerbrochenen Felsenmasse verursacht werden, ist vom paramount Wert in der Felsentechnik. Abhängig von der Natur des Druckregimes, das auf einer Aushöhlung und dem dazugehörigen deformationalen Verhalten der Felsenmasse umgibt die Aushöhlung fungiert, bestehen eine Anzahl von möglichen Ausfalleinheiten. Diese beziehen eine Kombination des Scherausfalls auf vorhandenen Verbindungen, Verlängerung der kritisch orientierten Verbindungen und Ausbreitung der neuen Brüche durch vorher intakten Felsen. Herkömmliche numerische Codes nehmen normalerweise entweder ein kontinuum oder discontinuum Annäherung an; dieses ergibt häufig bedeutende Übervereinfachung und kinematische Beschränkungen, besonders wenn es kompliziertes Felsenmasseverhalten in der Nähe der Aushöhlungen modelliert. Dieses Papier beschreibt die Resultate von einigen Fallbeispielen mit einem kombinierten begrenzten Element - getrennten Elementcode, ELFEN, das einen Sprungausbreitungmodus enthält. Durch den Gebrauch von vorgewählten Felsentechnikbeispielen, demonstrieren die Autoren das Potential des Codes in der realistischen Simulation des komplizierten Felsenausfalls bei Anwendungen für beide Tagebaue und Untergrundsaushöhlungen.

Jan 1, 2003

A linear programming model with integer sequencing variables is developed to schedule limestone production for a quarry in Central Japan. The model is used to optimize raw material production from the quarry supplying limestone to cement, quick lime and aggregate plants. Typically, the mining in the quarry takes place in four to six different areas each area having 3 or 4 mining increments. Each mining increment contains different quality of limestone. The limestone production from the quarry is transported to the plants byway of 3 ore passes. Each plant requires a given quantity of limestone per period meeting certain quality constraints. This paper will describe development of the scheduling optimization model and how it is used to schedule production by period within the quarry to meet the capacity and blending requirements of the plants.

Jan 1, 2003

By Ho-Sang Sohn

The kinetic study on desulfurization of copper matte by gas bubbling was designed under the presumptions of lower FeO activity and of no slag formation, Copper matte with 59% Cu and 22.6% S in weight was oxidized at 1523K by bubbling of Ar + O2 gas through a submerged nozzle. The effects of oxygen partial pressure and flow rate of gas on the oxidation rate of matte were discussed. The desulfurization rate and the evolution rate of SO2 gas of copper matte were significantly influenced by the oxygen partial pressure, but the dependence on gas flow rate was rather complicated. The desulfurization rate and evolution rate of SO2 gas of copper matte were described by the mass transfer rate through the gas film around the rising gas bubbles. Thermodynamic correlation equations between the partial pressure of gaseous species and matte composition were incorporated to the kinetic calculation, The present model shows that the reaction path starts to transiently cross over an isobar line of PSO2 to asymptotically approach to the particular isobar line drawn in a matte composition plane of %S and %O.

Jan 1, 2003

By R. Zivojinovic, S. Vujic, T. Tanaskovic

The problem of determining the optimum exploitation life of machinery, namely the optimum time for machinery and equipment replacement, represents a complex and highly responsible engineering task. Taking into consideration the situation prevailing at coal pit mines in Yugoslavia, the tasks of this class are very complex and difficult. To make a decision on replacement of capital equipment and machinery, such as bucket wheel excavators within the mentioned systems, understands a management task of utmost responsibility. It requires high professional and analytical knowledge as well as the reliable arguments, based on multidisciplinary professional approach. In this paper, the authors present their views on the problem of establishing the optimum exploitation life of bucket wheel excavators, offering an algorithm, based on dynamic programming, as a solution. Keywords: Bucket wheel excavators, exploitation life of machinery, optimization, operations research, theory of replacement, dynamic programming

Jan 1, 2003

By Torn H. Okabe

A fundamental study was conducted with the purpose of establishing an environmentally sound recovery process for recycling of valuable metals, by combining scraps containing such metals. As an example, direct extraction and recovery of neodymium (Nd) in magnet scraps was investigated by utilizing liquid metal as an extraction medium. It was found that liquid magnesium (Mg) is a suitable extraction medium and can extract Nd from iron alloys with high efficiency at around 1100 K. The newly developed extraction apparatus for Nd is a mechanically simple and static device without moving parts, where the Mg extraction medium circulates due to differences in the temperature inside the reaction vessel. This developed device can simultaneously accomplish continuous extraction of metal Nd from scraps, re-extraction of Mg from Mg-Nd alloy and the eventual recovery of pure Mg. As a result, metal Nd with 98 % purity was directly recovered from magnet scraps under certain conditions. It was also shown that the extraction agent Mg could be reused. The results of this investigation show the possibility of establishing a new process for the direct extraction of Nd in pure metal form without oxidization.

Jan 1, 2003

By Kazuyuki Kikuta

MMAJ, a govemmental organization in Japan, has carried out a 4 year project for the development of the decontamination and metals recovering technology for the fly ashes from municipal waste incineration. Heavy metals (zinc, lead and copper) are recovered as raw materials for the non-ferrous metals production, without formation of any waste materials to be disposed. More than 500 thousands tonnes a year of fly ashes generation from the municipal waste incineration has been one of the main social issues in Japan, because most of them need to be disposed to the registered areas after decontamination, and occupy 5% of the municipal wastes disposed. The segregation, flotation and chemical process are applied to the treatment of the primary fly ash from municipal waste incineration, and MF (Mitsui-type blast furnace) Process after the chlorine removal to the secondary fly ash. The main results of experiments are -About 90% of heavy metals, zinc, lead and copper, can be recovered from the primary and the secondary fly ashes to the products for the non-ferrous metals production. -Both of the leaching residue from the primary fly ash treatment and the slag from the secondary fly ash treatment can be used as a raw material for the cement production, meaning that the decontamination technology for the ashes without the landfill has been established. -Dioxins in the primary ash can be decomposed satisfactorily, and the dioxins content in the segregation furnace gas is less than O.lng-TEQ/Nm3 without any gas cleaning system

Jan 1, 2003

By R. Romano

Some topics, which difficult the effective use of RMR for dam foundations, are reviewed and a new geomechanics classification system, DMR (Dam Mass Rating), is proposed -as an adaptation of RMR- giving guidelines for several practical aspects in dam engineering and appraisal of dam foundation. On revise quelques problems qui ont fait difficile l’application du RMR pour les fondations des barrages. On propose un nouveau classification système, DMR (Dam Mass Rating)-comme un désarroi du RMR-qui donne recommendations pour quelques problèmes pratiques dans le projet et construction des barrages, et de ses fondations. Es werden einige die praxisgerechte Nutzung des RMR (Rock mass Rating) erschwerende Themen betrachtet und ein neues Geomechanisches Einteilungssystem, das DMR (Dam Mass Rating), eine Anpassung des RMR, vorgeschlagen. Daraus resultieren neue Richtlinien für verschiedene praktische Aspekte beim Dammbau und bei der Beurteilung von Dammunterbauten

Jan 1, 2003

By V. A. Luganav

The behavior of arsenopyrite under heating has been studied by many scientists. It has been already established that under heating at more than 650°c and without air access the arsenopyrite dissociates with the formation of one atom arsenic. Under vacuum the dissociation process begins at 5500C with the formation of elemental arsenic. The residue of dissociation process contains pyrrhotite and throilite. In the presence of pyrite, arsenopyrite dissociates under lower temperature and with a higher velocity than without it. The industrial realization of fool scale processing of arsenic bearing raw materials is possible only by the use of standard equipment and oxygen containing blast. In this view the paper presents the results of the study on the effect of oxygen in the gaseous phase and its addition into the charge of pyrite in the process of arsenopyrite decomposition. Thermodynamic analyses showed that under thermal processing of arsenopyrite in the presence of pyrite and limited quantities of oxygen in the gaseous phase the formation of arsenic sulfides is possible according to the following reactions:

Jan 1, 2003

By R. Hope, C. van Heerden

In any process or organization inefficiencies are costly. In times of abundance this reality often does not receive much attention. During such times the focus is rather on increasing capacity to increase production. However, there is a growing awareness in the world of tougher economic, social as well as environmental conditions, and enterprises find themselves facing greater demands for accountability towards shareholders, the environment and the public, as well as growing competition for market share and limited global resources. This reality is no different in ensuring a sustainable mineral sands operation. In order to achieve this, any operation needs to be stripped of all process as well as operational inefficiencies. In this context it has become essential for any Mineral Separation Plant (MSP) to have the necessary process monitoring and control systems in place to continually monitor and optimize the production of on-spec products and maximize operational efficiency and consistency. The MSP Grade Control Solution developed by Crusader Systems and running on top of the CSense platform contributes towards these goals by improving the consistent production of on-grade product. This allows the process to operate closer to the maximum allowable product grade constraint, which in turn maximizes production.

Jan 1, 2003

By Paul Downing

Anyone in business today knows how difficult and time consuming it is to keep abreast of new and revised federal regulations. Those in the explosives industry know that such a task can be next to impossible as the regulatory environment faced by those in the hazardous materials community continues to undergo a major overhaul following the events of September 11th, 2001. This paper will attempt to clarify today’s regulatory picture by identifying some of the regulatory “hotspots” and “pitfalls” that affect individuals and companies involved in the sale, transportation, distribution and use of explosives.

Jan 1, 2003

By Heinrich Hutchison, Thomas von Moltke, Roelof F. Sandenbergh, Katarina P. Cerovic

Although the cyanidation process for gold leaching has been applied for more than a hundred years, some aspects of it, such as the passivation of the gold and the depassivating action of heavy metals, are still not well understood. In this work the anodic behaviour and surface composition of gold in alkaline aqueous cyanide with lead additions were investigated using polarization experiments and XPS. It was found that lead in the solution activated the gold at low concentrations, somewhat more positive than the reversible potential for gold, but that the activity again decreased at higher concentrations of lead. The potential range for the activation of the gold coincides with that where underpotential deposition of lead occurs, i.e. –200 to –600 mV(SCE), as indicated by the surface composition of the gold, shown in figure 1. Note that the concentration of lead on the surface of the gold only increased with time in the bulk plating potential range for lead, where gold is not activated by the presence of lead. It is also shown that up to 20 mg/L of lead added to the solution will activate the gold, provided that bulk plating of the lead is avoided. It is also important to avoid reducing conditions during leaching, where bulk plating of lead may occur, if the gold is to be activated by lead to achieve a high leaching rate, as the bulk plated lead screens the surface rather than activating it.

Jan 1, 2003

By M. Ghiani, P. Massacci, A. Manni, R. Peretti, Center for Mining and Mineralurgical Studies, S. Serranti

"The research study has been devoted to point out the better way to process a colemanite concentrate characterised by a high content of two kind of As sulphides (realgar and orpiment) finely disseminated in the matrix of the boron mineral.Scanning Electron Microscopy analyses have been carried out to determine all the mineralogical constituents and to evaluate their distribution, frequency and mutual relationships.There is a not neglectable part of realgar highly disseminated into the colemanite crystals.The orpiment recurs in small acicular crystals of 20÷30 µm in length and 5 µm in width, very difficult to liberate from the colemanite mineral particles.The colemanite concentrate, in fact, has been addressed to a chemical plant which products were boric acid and gypsum, the contaminated by As. It was unacceptable for further applications and very dangerous if rejected in the environment.Grinding tests under dry and wet conditions have been carried out in order to evaluate the liberation modality of the As sulphide minerals from the colemanite.Some difficulties have been overtaken in order to obtain a selective liberation of the As sulphides from the colemanite even if a certain decreasing in As grade in the higher size classes has been registered.All the comminution products have been analysed by SEM monitoring the liberation degree of the mineralogical constituents.Flotation tests have been carried out after different comminution flow sheet adopting different modulating conditions in order to evaluate the influence of the following parameters:• collector concentration versus contaminants concentration (As minerals) in the froths;• kind and quantity of the frothing agent to maximise the mineral recovery in the froths;• kind and quantity of the modulating agents to maximise the selectivity of the process;• conditioning modalities in order to obtain a suitable dispersion of fines and to avoid segregation of Asbearingparticles together with colemanite ones;• solid/liquid ratio of the pulp to minimise the water flow into the plant."

Jan 1, 2003

By Ragnhild Aune

In fire refining of copper, the affinities of various impurity elements on dissolved oxygen is of great significance. Further, in the design of oxygen probes in liquid copper, the influence of solute interactions on the activity of oxygen need to be considered in order to evaluate the oxygen concentration in molten copper. The present paper presents a series of measurements of the activities of oxygen in liquid Cu-M-o alloys (where M stands for Mn, Zn, As, Se or Te) carned out by the present group employing the solid electrolyte galvanic cell technique. Extreme care was taken to control the oxygen potentials in the inert gas atmosphere, and to keep the oxygen levels very low in the molten metal. The oxygen content was determined by analysis of the samples taken out from the melt. The results obtained showed that Mn has a strong negative influence on the activity coefficient of oxygen in liquid copper. A similar, but less prominent effect was observed in the case of Zn. Arsenic had no influence on the activity of oxygen in Cu (liq.). Se and Te had slight negative effect on oxygen activities in copper at XQ >10-5, while at lower oxygen levels the interaction coefficients were found to be positive. The results obtained were compared with empirical models for the calculation of interaction coefficients available in literature.

Jan 1, 2003

By A. D. Davis, C. J. Webb

Brohm Mining Co.'s Gilt Edge Mine in the northern Black Hills was a surface heap-leach operation that was active from the 1980s until 1999. Financing problems and acid drainage concerns at the mine were reported in the late 1990s. In February 1999 the Governor of South Dakota announced plans to request the US Environmental Protection Agency to help clean up acidic water at the mine and reclaim the site. In July 1999 the parent company of Brohm, Dakota Mining, filed for bankruptcy in Canada. Because of the bankruptcy and environmental problems, the State of South Dakota intervened and began water treatment. The mine was declared a Superfund site in 2000. Hydrologic issues include the potential for acidic drainage from the site. The mine is at the headwaters of Strawberry Creek, which drains into Bear Butte Creek. About four miles downstream, Bear Butte Creek loses its discharge to swallow holes in the karstic Madison Limestone aquifer, a regionally extensive and valuable groundwater reservoir. Other concerns at the site include treatment of acidic water in mine pits and a waste rock dump.

Jan 1, 2003

Slake durability of rocks is an important property of rock-mass and rock-materials in geotechnical practice. The slake durability of rocks is closely related to their mechanical properties. In this paper, mechanical properties and slake durability tests for weak and clay-bearing rocks from Beypazari Trona Bed in Ankara, were performed in order to assess the slake durability and mechanical properties (especially rock strength) of these rocks as well as to understand the relationship between mechanical properties and slake durability. In performing this relationship, statistical based correlation has been applied.

Jan 1, 2003

Simulator technology has advanced to the point where the cost of mining equipment simulators is beginning to make commercial sense. Simulator-based evaluation allows operators or potential employees to be assessed in a pseudo-real environment under surface and underground mining conditions. Simulator training also allows operators to be exposed to emergency and advanced situations such as brake or steering failure or a tireblowout. ThoroughTec, of South Africa, provides simulator equipment to the mining industry. The company’s various packages of simulator products provide an unbiased evaluation score that removes human error from the assessment process. This same evaluation score is also presented at the end of normal training or refresher training sessions. In this way, the simulator helps eliminate bad habits and improve efficiencies.

Jan 1, 2003

By A. I. A. Salama

The CANMET Western Research Centre (CWRC) has developed a hydrocyclone model simulation of dewatering and fine particle separation circuits. The simulation is based on an existing empirical model. Utilizing a cyclone manufacturer’s published data, some modifications have been developed and integrated into the model. Feed stream characteristics, cyclone mechanical dimensions, and operating conditions are used in the CWRC modelling simulation. The computer results are presented in 3D graphs and corresponding 2D maps showing the cyclone mass recovery, percent solids by mass in underflow and overflow, and cut size as functions of the cyclone apex diameter and cyclone throughput (i.e., inlet pressure or pressure drop). Results of the computer simulation have been used in the economic feasibility and design of several dewatering circuits in oil sand plants.

Jan 1, 2003

By Osvaldo A. Bascur, J. Pat Kennedy

"The profitability of mining and metallurgical operations continues to lag behind that of other industries despite the technical advances that have occurred in recent years. A primary reason for poor performing in this economic sector is the lack of integration of mining and metallurgical information. The mine cut-off grade can be optimized if mining and metallurgical engineers have the data to optimize milling for the type of ore in hand.Integration of mine transactions, stockpile inventories, process flows and assays is the key to determining the economics for each blast strategy in a mining site. Real-time information from manufacturing assets greatly affects the profitability and flexibility of a company, but gross errors from faulty sensors, inaccurate instrument calibration, or incorrect process models may corrupt actionable information. New software tools can model the process, sift through available data to identify and eliminate gross errors, and use statistical data reconciliation to create materially balanced and consistent readings. The reconciled data is unified for use by both monitoring and decision making processes.Creating a real-time information environment where upgrade and change are allowed is becoming an accepted methodology to accelerate and simplify the integration of applications such as production monitoring, equipment performance management and yield and inventory management.This paper describes the data integration requirements in a mine, concentrator and port for unification of the redundant data. The capture of the mining events, stock pile management and the metallurgical information is the base requirements for a dynamic environment to reduce the overwhelming amount of information to unified set of information. Part of any decision support program should entail these results to continuously improve the measurement system to address the costs in mine and milling the ore."

Jan 1, 2003