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By Lauri Pajunen

DSA-anodes are widely used in metal electrowinning. In zinc electrowinning the electrolyte solution contains manganese ions, and the deposition of manganese dioxide happens on the anode. This manganese dioxide layer cannot be removed without losing the active coating of the DSA-anode. The same problem can be found with hybrid anodes. In hybrid anodes mixed metal oxide coated titanium mesh is attached to a lead base material. In this study, the effect of dissolved manganese on anode behaviour is studied with three different anodes. These anodes are lead anode with 0.6% silver, hybrid anode and DSA-mesh. Methods of study include polarization, galvanostatic and potential mapping experiments.

Jan 1, 2003

By G. J. Olson

This paper describes the microbiology basics underlying heap and tank biooxidation of metal sulfide ores and concentrates. The primary organisms are identified and described along with the reactions they catalyze and their growth requirements. Also described is the interaction between ore leaching bacteria and the leaching environment in terms of solution chemistry, temperature, and mineral precipitation. Specific factors and agents that stimulate or inhibit growth and activity of ore bioleaching will be identified. Some of these factors are organism-specific and others are generic for microorganisms that grow under acidic conditions. Current knowledge of the limits of bioleaching in terms of dissolved ions in leach solutions, pH, and temperature will be summarized.

Jan 1, 2003

By Grigori I. Voiloshnikov

"The long-term studies on development of the technology for precious metals recovery using activated carbons executed by Irkutsk Research Institute of Precious and Rare Metals and Diamonds (IRGIREDMET) were finished by successful introduction of ""Carbon-In-Pulp"" process in Russia (1984).The review of some studies, accompanied by development, testing, introduction and subsequent improvement of considered technology, carried out by IRGIREDMET is submitted in this paper.The basic regularities of gold and silver adsorption onto activated carbons from cyanide, thiourea, chloride and other solutions are investigated using various phisical-and-chemical methods ( X-ray photoelectron spectroscopy, Voltammetry, X-ray microanalysis etc.). Using voltammetry it was found that gold cyanide is adsorbed onto activated carbon without chemical changes and partial reduction of gold is possible only during drying of carbon samples before analysis. Metallic gold and silver may be dissolved in boiling cyanide solution at argon atmosphere when they are in contact with activated carbon surface. Gold adsorption mechanism for activated carbons has great differences from that for the ion exchange resins. So the most probable mechanism for gold adsorption from cyanide solution is adsorption of neutral molecules Me n+[Au(CN)2-]n.X-ray quantitative microanalysis technique was developed to investigate gold adsorption kinetics onto spherical activated carbon. Gold profiles in granules of activated carbon for various adsorption conditions were tested (carbon particle size, mixing efficiency, adsorption time etc.). Mathematical methods were used to determine gold diffusion coefficient within activated carbon granule.The properties of various types domestic and foreign activated carbons were tested and the demands to activated carbons suitable for gold extraction were determined. As a result foreign and Russian activated carbons AG-90, AG-95 were recommended for use at Russian gold plants. Domestic adsorbents are cheaper in comparison with foreign activated carbons. The methods to restore carbon adsorption activity including acid treatment and thermal reactivation were tested and implemented."

Jan 1, 2003

By J. Girard-Dwyer, J. Johnson, J. Whyatt

The choice of fragmentation method is one of the most fundamental aspects of mine design, and often has a major impact on the safety and economic viability of an operation. Almost exclusively, underground mining operations rely on either mechanical excavation or drill and blast techniques to extract rock. Each of these fragmentation methods has distinct advantages and disadvantages, and each is appropriate, and economic, for different mining conditions. However, the choice of fragmentation method can have a pronounced effect on the amount of damage created in the rock mass surrounding the opening. This paper reviews a number of case studies where both mechanical excavation and traditional drill and blast were used in underground mines. Ground support requirements in the mechanically excavated areas are compared to the support requirements in the blasted sections in order to demonstrate the potential safety and cost benefits of the various fragmentation methods.

Jan 1, 2003

By P. Christmann

The operational paradigm of mining industries is shifting from ?optimal profit for the financial stakeholders? to a new concept compatible with sustainable development ethics: ?maximize economic and social returns at the local, national and global levels, while avoiding negative environmental impacts?. The number of stakeholders concerned by mining companies has grown significantly over the last few decades, and the role of local communities and civil society is now acknowledged by the mining companies adhering to the sustainable development ethics. ?Involve me? is becoming a key to maximize the returns the mining industry can provide to sustainable development. As the world?s major importer of many mineral commodities, several coming from developing countries facing severe short-term problems, the European Union (EU) is an important stakeholder and has a responsibility in supporting actions to strengthen corporate and public governance capacities. The purpose of this paper is to highlight the drivers leading to the development of sustainability indicators and to propose, within the 6th European Framework Programme for Research, Technological Development and Demonstration Activities (FP6), an European-level initiative to develop sustainability indicators adapted to the mining industry and its population with relevant data.

Jan 1, 2003

By J. S. Phipps, D. R. Skuse

"Aqueous slurries of fine particle size calcium carbonate are used in a diverse range of end-use products. In many cases, the end use performance is governed by the fineness of the particle size distribution. In turn, the maximum fineness of the particle size distribution is primarily determined by the efficiency of the dispersants used during the production process. Here we report the sodium polyacrylate mediated dispersion of calcite and kaolin. Firstly, we report a colloid chemical description of the dispersant behaviour and attribute the stabilisation to both steric and electrostatic mechanisms. Secondly, we describe how the understanding developed in the first part of the study can be utilised to produce more effective dispersant systems which allow the preparation of, added value, higher solids and finer particle size calcium carbonate slurry products.INTRODUCTIONConcentrated aqueous dispersions of fine, particulate kaolin and calcium carbonate are used extensively in the coating of paper. Currently more than 10 million tonnes of such dispersions are used annually in North America and Europe alone, and worldwide consumption is growing at around 3% per year.Generally, paper is coated to enhance its visual appearance. Firstly, coatings improve the optical properties of the blank sheet, i.e. its brightness (or whiteness), opacity and gloss. Secondly, they improve the physical properties of the sheet that will influence the quality of the final printed image, such as surface smoothness, porosity, and ink absorption. In order to achieve these aims economically, paper coatings must be applied at high speeds and with minimal drying costs.Kaolin and calcium carbonate pigments are the major components of most paper coating formulations. Particle size distributions are chosen to maximise the optical benefits that they confer, and to allow the production of formulations that can be easily pumped, handled and coated. Coating pigments are generally produced and transported as slurries, and so it is important to obtain dispersions with the highest possible solids content, both to minimise drying costs and the quantity of water transported. This paper examines the dispersant technology that is currently used in the industry and the mechanisms by which it functions, and illustrates ways in which this technology has developed and could be further improved in the future."

Jan 1, 2003

Cuspidine (3CaO?2SiO2?CaF2) is one of the most important compounds crystallized in mold flux films during casting in the continuous casting process of steel. The primary crystallization field of cuspidine has been experimentally developed in the CaO-SiOrCaF2-SiF4 system. The cuspidine-NaF binary and cuspidine-CaF2-NaF ternary systems have been also experimentally determined to study effects of addition of NaF on the primary field of cuspidine. In order to discuss its thermodynamic stability the standard Gibbs energy of formation of cuspidine has been determined by an electromotive force method using CaF2 as solid electrolyte and a transpiration method as follows: The chemical potential diagram and constituent activities for the CaO-Si02-CaF2 system have been evaluated based on the obtained thermodynamic data.

Jan 1, 2003

By Deborah McCombe

-Canadian Regulators -Qualified Person -Professional Association -Resources & Reserves -Foreign Codes -Disclosure of Historical Resources -Issues in Application of Resources & Reserves -Industry Best Practices developed by CIM -Technical Report and Reserves and Resources -Summary

Jan 1, 2003

"The Companion Policy is guidance and not law. It sets out the views of the Canadian Securities Administrators (CSA) at to the manner in which the CSA interprets and applies certain provisions of NI 43-101 and Form 43101F1. The Companion Policy references the CIM Best Practice Guidelines for Mineral Exploration, and the Mineral Resources and Mineral Reserves, and that they should be followed by Qualified Persons.COMPANION POLICY 43-101CP TO NATIONAL INSTRUMENT 43-101 STANDARDS OF DISCLOSURE FOR MINERAL PROJECTS This companion policy sets out the views of the Canadian Securities Administrators (the “CSA”) as to the manner in which the CSA interprets and applies certain provisions of National Instrument 43-101 and Form 43-101F1 (the “Instrument”), and how the securities regulatory authorities or regulators (the “Securities Regulatory Authorities”) may exercise their discretion in respect of certain applications for exemption from provisions of the Instrument. PART 1 APPLICATION AND TERMINOLOGY 1.1 Supplements Other Requirements – The Instrument supplements other continuous disclosure requirements of securities legislation that apply to reporting issuers in all business sectors. 1.2 Evolving Industry Standards and Modifications to the Instrument- Mining industry practice and professional standards are evolving in Canada and internationally. The Securities Regulatory Authorities will monitor developments in these fields and will solicit and consider recommendations from their staff and external advisers as to whether modifications to the Instrument are appropriate. 1.3 Application of the Instrument -The definition of “disclosure” under the Instrument includes oral and written disclosure. The Instrument establishes standards for disclosure of scientific and technical information regarding mineral projects and requires that the disclosure be based on a technical report or other information prepared byor under the supervision of a qualified person. The Instrument does not apply to disclosure concerning petroleum, natural gas, bituminous sands or shales, groundwater, coal bed methane or other substances that do not fall within the meaning of the term “mineral project” in section 1.1 of the Instrument. 1.4 Mineral Resources and Mineral Reserves Definitions - The Instrument incorporates by reference the definitions and categories of mineral resources and mineral reserves as set out in the Canadian Institute of Mining, Metallurgy and Petroleum (the “CIM”) Definition Standards on Mineral Resources and Mineral Reserves (the “CIM Definition Standards”) adopted by the CIM Council on November 14, 2004, as amended. 1.5 Best Practices Guidelines for Mineral Resources and Mineral Reserves - A qualified person classifying a mineral deposit as a mineral resource or mineral reserve should follow the CIM Estimation of Mineral Resources and Mineral Reserves Best Practice Guidelines adopted by CIM on November 23, 2003, as amended. These guidelines are posted on www.cim.org."

Jan 1, 2003

By Markus A. Reuter, Antoinette van Schaik

"INTRODUCTIONGoods and products, such as passenger vehicles, are manufactured by using a wide spectrum of different raw materials to meet highest consumer requirements during use. Due to the time-varying composition and complexity of multi-component products such as cars, recycling is complicated. It involves a network of interconnected processes and material and energy flows. Improving the efficiency of the material cycle of the car to comply with the recycling targets as imposed by EU legislation, requires insight into all aspects influencing the closing of the material cycle (dynamics, technology, economy, legislation, etc.) and their mutual relation. In order to define the link between recycling end-of-life products, their changing composition and design a dynamic model was developed for the resource cycle of cars. The model integrates the optimisation of the material cycle with the dynamic behaviour of recycling systems."

Jan 1, 2003

My topic for today is the Crown Minerals of the future. New work initiatives are underway and the organisational structure is being overhauled. These are not insignificant changes and in this paper briefly summarises these proposals. These new work initiatives and changes to the organisational structure will have implications for the industry as a whole and also for the way individual clients interact with Crown Minerals.

Jan 1, 2003

By R. Hurman Eric

The dew-point technique of activity measurements take advantage of the volatility of a component in solution. The pressure of the volatile component over a sample is determined from observations of the temperature at which condensation of the vapor occurs. The method is applicable best when the vapor pressure of the components would differ by about two to three orders of magnitude. Experimentally, this is a closed system involving the use of evacuated and sealed transparent quartz sample probes. Furthermore reliable vapor pressure data of the volatile component is essential along with a specialized high temperature furnace capable of giving reproducible results. In this context, the vertical Dew-Point Furnace (DPF) was designed and built after elaborate trails until enough proficiency was gained for reprodueible results. Over the years the DPF was modified and improved. The DPF developed was versatile and could easily be used for activity measurements in the isopiestic mode (another method of measuring activities of a volatile component in a solution). The necessary ancillary systems; namely evacuation-flushing-evacuation followed by sealing of quartz sample probes under vacuum were also perfected over the years. As and when necessary the dew-point technique was supplemented by classical equilibration-quenching method employed on the sealed quartz sample probes to reveal necessary phase equilibrium information. The following were studied utilizing the above technique: (i) Activities in CuzS-PbS and FeS-PbS binaries and CU2S-FeS- PbS ternary at 1200°C; (ii) Activities in CuzS-SnS and FeS-SnS binaries and Cu2S-FeS-SnS ternary at 1200°C; (iii) Phase equilibria and thennodynamic in Cu-Pb-S, Fe-Pb-S, Fe-Sn-S, Cu-Sn-S and Ag-Sn-S systems. Most recently the following systems have been tackled: (i) Phase equilibria and thennodynamics in the Ag-Pb-S and Sn-Pb-S systems; and (ii) Activities in Ag2S-FeS-CuzS-PbS quaternary at 1200°C.

Jan 1, 2003

By S. J. Thomas, P. A. Lilly, J. A. L. Napier

An industry research project has been established to examine the issue of rock mass failure in large open pit slopes. The approach began with numerically modelling failure at the laboratory scale with a displacement discontinuity program. The interim results from the program suggest the output failure mode is dependent upon the input parameter cohesion weakening. Es wurde ein Forschungsproject mit unterstützung von Bergbauindustrie bearbeitet. Die Zielsetzung der vorliegenden Arbeit war die Analysierung des Böschungsgefähr im größen Festgesteinstagebauen. Das Verfahren besteht aus der numerischer Modelierung mit Ansatz einen sonderen Rechnerprogram. Die erste Ergebnis zeigt, daß die Aufgabe am Angabendaten (cohesion) abhängig sein wird. Un project de recherche industriel fût conduit avec le but d’examiner les éboulements de roche dans les mines a ciel ouvert. La premiere étape a été de modelliser numériquement les éboulements dans un laboratoire en utilisant un programme de déplacement discontinu. Les resultants préliminaires du programme indiquent que la prédiction des ébouliements est directement reliée à la magnitude de la cohesion.

Jan 1, 2003

By David Ziegler

A formal blast plan is sometimes required for projects involving rock excavation. A written blast plan submitted with a bid proposal can also be an important sales tool. A blast plan will cover the basic elements of shot design: hole diameter, spacing, burden, loading, and so forth. Some suggestions are discussed here for additional items or topics to address, including: safety issues, ground control, traffic & site control, public relations, pre-blast inspections, seismic monitoring.

Jan 1, 2003

By E. Yan

Electrostatic separation has been a mainstay of minerals sands flowsheets for over 50 years. Recent electrostatic developments have shown better conductor/non-conductor separation than technology previously available. Results to date show significantly increased separation efficiency over prior-art high-tension roll electrostatic separator (HTR). These improvements allow greater simplification of MSP circuits by minimizing re-circulating loads. The distinct features of the eForce include: 1) A provision that minimizes the affects of particle size to improve separator performance, 2) an enhancement of the design and arrangement of the static electrode providing a greater attraction force for separating fine conductive particles, and 3) inner roll and outer plate electrode configuration to improve separation efficiency and throughput capacity. Key Words: eForce, Electrostatic, Ion bombardment, HTR, Separation Efficiency, Electrostatic Classifier

Jan 1, 2003

By George J. Tamara

The urban environment presents special challenges for the design and construction of earth retention systems. Complications arising from difficult subsurface conditions are compounded by the presence of urban infrastructure and existing and prior construction. The proximity of adjacent structures as well as intense prior use can cause special concerns including the potential for archeological artifacts or contaminated ground or ground water. Utilities and structures may be particularly vulnerable to the effects of ground movement, dewatering and vibrations. Difficulty of access, congestion and limited work areas may severely restrict means and methods of construction. Dewatering may be limited or prohibited because of concerns for disposal of clean or contaminated water, depletion of aquifers, drawing of contaminants to the site or dewatering induced settlements.

Jan 1, 2003

By M. Karmis

Promoting a strong safety culture requires that the significance of unsafe acts be emphasized. This can be achieved vividly by accurate recreation of unsafe actions in the workplace, demonstrating explicitly how they resulted in a fatality or significant injury. Visual reconstructions of incidents can be realized today on personal computers. The approach described in this paper uses readily available PC software and hardware and results in output that can be presented to the intended audience using a variety of delivery methods. An actual incident involving a surface mining operation is reconstructed using Virtual Reality techniques. Use of the visualization approach to accident reconstruction as a training tool is discussed.

Jan 1, 2003

By Vincent Tirolo

Two separate secant pile cofferdams were constructed as part of an extensive rehabilitation and modernization of the New York City Transit's Lexington Avenue/Third Avenue IND Station at 53rd Street in Manhattan. Major high rise structures and outpatient hospital facilities bordered the site. The roadway is an important east-west corridor in mid-Manhattan. In order to perform the construction of new escalator and elevator shafts over 250 linear feet of secant wall was installed to the top of rock or to the existing subway roof. Much of the secant wall was constructed from below a temporary roadway decking system using a low headroom rig. The roadway decking system was supported on shallow spread footings. The secant piles were drilled using crawler mounted hydraulic rotary drill rigs. The secant wall provided a watertight, rigid cofferdam that minimized settlement and other disruptions to existing structures and utilities. During later stages of the project the secant wall also supported the roadway decking system.

Jan 1, 2003

By Karl J. C. Harries

"6.1. INTRODUCTIONThis chapter comments on some of the more common types of agreements related to property examination and acquisition, other than the farm-in/joint venture agreement or common undertaking, which is dealt with in the next two chapters. Many of the comments made in Part IV of Chapter 4 apply equally to any such agreement. In addition, many of the comments in Chapter 8 and the examples in Volume II are most certainly relevant to many other types of agreement.6.2. RIGHTS OF FIRST REFUSAL1A right of first refusal is a right that obligates an owner to offer his property, or an interest therein, to the holder of the first right if the owner intends to sell or otherwise dispose of it. It may be triggered either by the owner wishing to offer his property for sale or by receipt of a bona fide offer to purchase his interest from an “outside” third party. The mechanics and procedures to implement a first right should be set out clearly in the agreement, and their basics are the same, whether the first right is a stand-alone document or is part of an acquisition agreement.2Rights of first refusal are common in agreements to permit some control over the disposition of an interest and there they can be a valuable provision. However, some explorationists feel that they are also a good stand-alone agreement to have while a property is being evaluated to decide whether or not it is worth optioning. The reasoning is that such an arrangement will tie up the property to allow a quick look and, if the property looks interesting, the balance of the term of the first right will give an ample exclusive period of time to negotiate with the owner and settle an acquisition agreement. In addition, the explorationist is protected by the first right if the owner decides to negotiate a deal with another party."

Jan 1, 2003

By D. Hatfield, G. de Jager

"The rapid developments in computer vision and computational resources are creating new possibilities for the use of machine vision systems for industrial control. A number of commercial image analysis systems exist, and research into improved measurements of froth performance is ongoing. An integral part of the implementation of these systems is the validation of the relationship between image analysis measurements and flotation cell performance. This paper discusses the factors affecting concentrate flow and presents the results obtained from one such system with respect to its ability to estimate the flow of concentrate from a flotation cell.The relationship between froth flow speed and the rate of recovery of concentrate from a flotation cell was investigated on two industrial operations, both processing PGM (Platinum Group Metal) bearing ores. Results are presented that show a relationship between froth flow speed and concentrate yield."

Jan 1, 2003