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Stringent environmental benchmarks imposed by governments and successful legal challenges in the country of origin have changed the risk profile for all mining companies over recent years. In developing countries, however, where high government standards may not always be in place, direct community action has often made worthless substantial investments in otherwise viable mining operations. Real limitations are therefore imposed from these risks on all areas of mining activity, wherever they may be. Thus, the bar has been raised for all companies developing or operating mines. This paper argues real financial and global industry reputation benefits accrue when all known environmental risks, where practical, are managed. In response, among major international mining companies, as the industry moves towards greater global consolidation, senior management teams have increasingly adopted corporate governance standards including æTriple Bottom LineÆ (shareholder/government/community) sustainability reporting. Sustainability reporting is encouraged by improved international stockholder and financial investor perceptions by contributing to lowered social, community and geopolitical risk which lowers the cost of access to funds as well as improving staff morale and productivity. New mines must not only be primarily financially viable but must operate throughout in a sustainable way. Case studies of some recent mining operations, who have not foreseen or proactively managed major environmental risks, demonstrate the dire financial and personal implications for managers, directors and shareholders from not identifying and managing these environmental risks. Merely having a corporate policy statement on environmental standards or high level Government approvals process for a mining activity does not preclude mining operations from the risk of direct action by local populations or future adverse legal implications from risks which were perhaps identified but not mitigated effectively. Methods and processes for the identification and active management of environmental risks in the global arena are discussed to add a practical element to sustainability, based on the authors recent strategy development processes with governments and major mining houses such as BHPBillition, Rio and Xstrata. Emphasis is placed on proactive, innovative yet practical solutions which, where possible, show positive contributions firstly to the financial bottom line but also the community at large.

Jan 1, 2003

The challenge of the sustainable development framework in mining today is to see that the minerals sector as a whole contributes to human welfare and well-being without reducing the potential for future generations to do the same. If the minerals sector around the world is to contribute positively to sustainable development, it needs to demonstrate continuous improvement of its social, economic, and environmental contribution, with new and innovative governance systems. Canada is an international leader in mining and related technology. Metals and minerals is Canada?s second-largest earner of foreign exchange. Canadians, along with the rest of the world, are increasingly concerned about the environmental impact of mining activities. The Canadian Mineral industry has acknowledged the importance of its environmental responsibility by taking a broad range of innovative actions in order to ensure a sustainable development of its resources. This paper analyzes how the concept of sustainable development can be related to mineral enterprises. It discusses a wide range of issues under three main areas: perspectives on sustainable development; processes for furthering sustainable development; and assessment methodologies and indicators. This paper also presents a proposed framework and a core set of key sustainable development indicators that could be useful in efforts to measure progress toward sustainable development in mining. The paper concludes with a case study of some key sustainable development indicators related to the Canadian oilsands mining.

Jan 1, 2003

By W Pytel

A special model of vertically loaded pillar behaviour is introduced to the general, multi-plate based, floor-pillar-roof system interaction analogue. This permitted analysing room-and-pillar mine systems in any geological conditions, including the effect of pillar elastic-plastic behaviour with strain softening. In the model, pillar instability is one of the important phenomenon, which may be expected to occur, and which the operator has to be prepared for. Thus the entire systemÆs safety is determined mainly by strong roof strata behaviour and therefore they have to be examined in actual stress-strain conditions utilising the appropriate strength theories. It was assumed that the so-called safety margin, representing the relation between load intensity and material strength, might serve as the basic indicator of possible roof instability development. Therefore, the safety margin may be estimated by comparing the actually computed components of stress-strain tensor with ultimate values characteristic for a given material determined in laboratory. In order to illustrate the effect of technological pillar size on roof strata stability, two different mining systems (methods of mining) in one of the æPolkowice-SieroszowiceÆ Mine districts was modelled using the finite element method formulated in three dimensions, assuming different materials within different rock mass strata, as well as a number of horizontal planes of discontinuity within the model.

Jan 1, 2003

By V. Korobko, M. Byantogtokh, N. Byambadorzh, V. Bysov

A three-stage operative planning of mining operations in ore opencasts is considered. The hierarchy of monthly-weekly, weekly-daily, daily-shift planning is offered. For the fastest elimination and deviations in problematic situations a level is analysed and weekly-daily or monthly-weekly operative plans are being constantly updated. Operative planning is formulated on information received of preparation and working of mining panels. The electronic maps of these panels are considered for automated operative planning. On the data of the registration of blasthole drillings on a panel, the position of blasthole entry, their depth and the number of a line are determined. The geologist specifies boundaries of ore grades by the bored silt. The qualitative characteristics of ores are determined by the chemical analysis of slime or magnetic logging of blastholes. The missing geologic information is obtained by interpolation on the data of detailed and operational explorations. During working of the mining panel the technologists mark the movement of shovels, associating this movement to blastholes. For this purpose technological attributes are used: when was the blasthole drilled, what drill-rig participated in drilling, what shovel was used and when was it worked? Around each blasthole the zone of its influence is built up. It represents a discrete, elementary volume of ore or waste. The discrete form of the data is most convenient, as it allows step-by-step methods to be employed of the scheduled tasks in many and various combinations. The account panel working technology avoids ‘combination’ explosions. The elementary blocks should be placed in a trajectory of shovel movement and the trajectory can not be arbitrary. It’s determined by the technological rules of extracting and loading of mine mass. In linking to blastholes, the trajectory of shovels is simulated by the sum of step-by-step moving from one elementary block to another. For this purpose a geometrical linkage of blastholes is used. At a railway haulage, or complete mining with truck haulage, the trajectory of movement is a shuttle along the front of operations in the panel. At a selective mining of ores the number of possible directions is limited to three: moving of a shovel by idle running along the front of operations in the panel, frontal pull all the way down of the panel, and withdrawal. The technologically acceptable trajectories of shovel movement are stored for the following estimation and selection of the best. The estimation is carried out on mathematical models with criteria on the method of the least squares of deviations based on preset parameters from the plan, uniform loading of shovels, and mixing of ore at unloading points. The equations of balance type and directive parameters of the plan, as well as technological restrictions of solid and of elementary blocks within the limits of a trajectory are the restrictions of the model. Depending on an industrial situation it is possible to choose one of the predetermined models. The presented technique is used for longitudinal shovel bench at the Erdenet ore-dressing company.

Jan 1, 2003

By Sabine Knott

The thermodynamic properties of four liquid ternary zinc alloys, Au-Sn-Zn, Ag-Sn-Zn, AI-Sn- Zn and Cu-In-Zn were measured with an electromotive force (emf) method at three or four cross-sections with an constant X:Sn or Cu-In ratio. At the Au-Sn-Zn and AI-Sn-Zn system calorimetric measurements were also carried out in order to compare the integral enthalpy of mixing from the direct measurements with the data of the emf measurements, which were derived by Gibbs-Duhem integration.

Jan 1, 2003

By E. M. Bloomfield, C. A. Jermy

Geotechnical tests were carried out within an area of the coastal sand dune cordon of northern KwaZulu-Natal which is currently being exploited through mining of heavy mineral sands. In situ and laboratory tests were carried out to assess the density, strength and stability of the dune sand material before and after mining. The most stable combination of sand (>63µm) and fines(<63µm) material was determined as well as the effects of compaction on the strength and permeability of the sand dune samples. In situ DCP and density tests showed that the sand dunes fall in density immediately after mining has taken place. However, settlement of the dunes occurs with time and the density increases within the top 2 metres, and particularly once the dunes become re-vegetated. Laboratory tests carried out showed that the dune sand with between 20% and 30% added fines had the highest shear strength and dry density, but the permeability was shown to decrease steadily with increasing fines up to 40% fines added. The addition of fines would result in steadily increasing water flow problems. Compaction of the dune sands was shown to significantly increase the density and the shear strength, but with a corresponding dramatic decrease in the permeability of the material. Slope stability analysis carried out on models of the dunes with increasing fines showed that the addition of fines increases the stability of the dune sands up to a peak of about 30% fines added, and compaction further increases the stability of the dune sands. Despite the benefits of compaction on the stability of the tailings dunes, the loss of permeability is thought to outweigh the benefits as well as the high costs involved. The stability of the tailings dunes greatly increases after re-vegetation. Compaction and densification of the tailings dunes may be necessary within the top 2 m interval if large-scale construction takes place on the sand dunes. Petrographic analysis was performed to understand the granular interactions of the sand and fines fractions, and the effect of the in situ weathering of the dune sands on the stability of the sand dunes. As the fines contents increase the gaps between the sand grains are filled, until a point where the percentage of fines begins to push the sand grains apart.

Jan 1, 2003

The AJ Parker Cooperative Research Centre for Hydrometallurgy is the focus of a world-class effort in providing technical solutions to the minerals industry. The 85 FTE staff are drawn from the CentreÆs five joint venture research partners comprising universities (Curtin, Murdoch and Qld) and government research agencies (CSIRO and WA Dept of Industry and Resources). There are also 12 industry partners, representing most of the leading mining companies in the world. Around 45 postgraduate students, mainly PhDs, make a significant contribution to the research effort. Total annual expenditure on R&D is around $17 million.Hydrometallurgy activities encompass both fundamental and applied research across the alumina, gold and base metal sectors. The Centre is now growing its client base into overseas markets, particularly North America, South Africa and Europe. Quality, strategic R&D by the Parker Centre is seen by the industry as an attractive investment. A recent survey of the industry revealed an estimated ten-fold return based on direct costs of research to the client. In addition, the Parker Centre has a strong commitment to education of postgraduate students wishing to enter the mining industry as well as providing specialist courses for those technical professionals already employed in the industry. The wide range of employment opportunities in the mining industry is reflected in the diversity of the disciplines amongst the CentreÆs research team, eg extractive metallurgy, chemistry, biotechnology, physics, engineering, molecular modelling, microscopy, geology and computational fluid dynamics. How does an atomic force microscope and molecular modelling improve our ability to control gypsum scaling or understand crystallisation of alumina in a Bayer plant? Can a biologist contribute to the problem of the slow leaching of copper from chalcopyrite? Why are computational fluid dynamics and lasers the basis of understanding how to make thickeners work more efficiently. Can you combine a PhD or Honours degree with industry experience? What is crud and why is nickel stressed? These are typical examples of the CentreÆs research activities and demonstrate the contributions of its multi-disciplinary teams which keep the Australian mining industry at the cutting edge of advanced global technology.

Jan 1, 2003

By D Newton

The Mt Morgan Minesite in Central Queensland has been subject to both underground and surface gold mining operations since the late-1800s. The site is largely unrehabilitated and poor quality surface run-off and subsurface leachate is contaminating the nearby Dee River. The site is dominated by a large open cut, which now stores contaminated surface and subsurface run-off. Three models were used to simulate the complex hydrologic processes occurring at the Mt Morgan Mine: a rainfall-run-off model, a groundwater model and a storage behavioural model. Study results showed that the open cut is filling with water and will soon spill large volumes of highly polluted water to the Dee River on a regular basis if no remedial action is taken. This will result in a three-fold increase in pollutant load to the Dee River. Based on a consideration of water quality and quantity it was concluded that the first priority for future minesite water management should be the prevention of spills from the open cut. Potential management options to achieve this objective included surface rehabilitation, catchment diversions, modification of the pump-back system and controlled releases to the Dee River during floods. However, assessing the relative effectiveness of these measures required a thorough understanding of the complex surface and subsurface hydrology of the site. The results of a 100 year simulation of hydrologic processes revealed that previously favoured management options would be ineffective in preventing spills to the river. On this basis, a continuous treat and release strategy was proposed as the only reliable method of preventing future spills. The results of this study demonstrate that good environmental management decisions must be based on an understanding of the relevant physical processes and consideration of cumulative effects over an appropriate time scale.

Jan 1, 2003

By Jana Dobrovska

Solidification and cooling of a continuously cast slab and simultaneous heating of a mould is a very complicated problem of transient heat and mass transfer. Nowadays, the solving of such a problem is impossible without numerical models of the temperature field not only of the slab itself, while it is being processed through the whole concasting machine (Caster), but of the mould as well. Two original numerical models have been developed and used in the investigation of a continuously cast steel slab. The first (one of two) 3D model of the temperature field of a concasting is capable of simulating the temperature field of a caster. Experimental research and data acquisition have to be conducted simultaneously with the numerical computation-not only to confront it with the actual numerical model, but also to make it more accurate throughout the process. After computation, it is possible to obtain the temperatures al each node of the network, and at each time of the process. The utilization of the numerical model of solidification and cooling of a concasting plays an indispensable role in practice. The potential change of technology-on the basis of computation-is constantly guided by the effort to optimize, i.e. to maximize the quality of the process. The user can therefore choose any appropriate longitudinal or cross-section of a slab and display or print the temperature field in a 3D or 20 graph whenever necessary. The second numerical model of dendritic segregation of elements assesses critical points of slabs from the viewpoint of their increased susceptibility to crack and fissure. In order to apply this model, it is necessary to analyze the heterogeneity of samples of the constituent elements (Mn, Si and others) and impurities (P, S and others) in characteristic places of the solidifying slab. The numerical model, based on measurement results obtained by an electron micro-probe, generates distribution curves showing the dendritic segregation of the analyzed element, together with the distribution coefficients of the elements between the liquid and solid states. The combination of both models enables the prediction of cracks and fissures in critical points of the continuously cast carbon-steel slab. Both models had been applied in the industrial investigation of a cast low-carbon-steel slab.

Jan 1, 2003

By E. Kozeschnik

A new model is presented for the simulation of the evolution of precipitates in a multi-component multi-particle multi-phase environment The mathematical formulation as well as the physical background of the model are briefly introduced and its capabilities are discussed on the example of a precipitation sequence in a complex steel. Keywords: Modeling, precipitation kinetics, nucleation, growth, coarsening

Jan 1, 2003

By Martin Herenknecht, Michael Knabe, Ulrich Rehm

In Switzerland at present, the longest railway tunnels in the world, the Gotthard(57 km) and the Loetschberg base tunnel (34km) are under construction. For thischallenge six high-tech HERRENKNECHT Hard Rock Tunnel Boring Machines (TBM)are applied, which have to excavate approx. 80 km at the Gotthard and 20 km at the Loetschberg Tunnels. The machines being used are of a single Gripper-TBM type, which are equipped with the latest rock support techniques, in order to optimize the quality of the working conditions for the personnel which have direct impact on the quality of the tunnels. The different requirements of the projects based on different speci?cations within the tender documents led to completely different TBM concepts which will be reviewed in detail in this paper.

Jan 1, 2003

By Leon Lorenzen, Charlene Gokhale

"In excess of 24 x 106 tons (Eskom, 1997) of coal-derived fly ash is produced annually in South Africa for the production of electric power. A large quantity of this ash is disposed of as a solid waste in landfills, thus posing a serious environmental problem. Due to the shortage of landfill sites, new ways of utilising fly ash are needed. Recently several authors have shown that various combustion fly ashes can be converted into zeolites to obtain industrial products with applicability in environmental management. Geopolymerisation has emerged during the last few years as a possible solution to some waste stabilisation and solidification problems. henolic compounds have been shown to be toxic to soil microorganisms at the parts-per-million level. Indeed several of the organic compounds classified by the U.S. Environmental Protection Agency as priority pollutants, are phenols. Immobilisation of phenols by adsorption on zeolites and encapsulation in a geopolymer appears to be a promising solution to this problem.This paper reports a technique for the production of a low-silica sodium zeolitic material from fly ash (zeolite NaP1), and its application for the stabilisation of phenols by adsorption and subsequent encapsulation in a geopolymer matrix. A commercial zeolite, clinoptilolite was also utilised as an adsorbent. Due to their uniform pore sizes and large surface areas, zeolitic materials are suitable for ion exchange and adsorption of certain organic substances. Adsorption data show that the commercial zeolite, clinoptilolite was an effective adsorbent for organics. Adsorption data showed that between 51.2 ppm and 74.3 ppm of chlorophenol or between 15.4 ppm and 32.5 ppm of phenol could be adsorbed. Physical encapsulation of the coated zeolite loaded with organic within a geopolymeric matrix increased the compressive strength of the matrix from 28.80 kN to 40.79 kN. Leaching data for the various geopolymer matrices with encapsulated and loaded zeolites show no organics being leached from the system at a detection level of 2ppm. According to the SABS these would have been acceptable organic concentrations within a waste water stream."

Jan 1, 2003

By Norihiko Fukatsu

In order to use effectively the previously reported new sensing system for hydrogen and oxygen potentials in molten copper, the criteria of the potentials for getting sound castings have been determined in the laboratory experiment. The copper melt equilibrated with a given hydrogen and an oxygen potential was rapidly quenched in the crucible. The relations between the holding potentials and the gas porosity in the solidified sample were investigated by measuring the density of the sample and microscopic observations. It was found that the defects of the gas porosity became the maximum at the potentials where the dissolved amount of hydrogen and oxygen was in the mole ratio 2:1. The samples having the density more than 99% of the theoretieal value were obtained in the higher oxygen and lower hydrogen potential region or in the lower oxygen and higher hydrogen potential region. The criteria thus determined were examined by comparing with the measured potentials in the practical casting machine. In tough-pitch copper casting, the problem due to gas porosity was found to be serious when the hydrogen potential increased. In the. oxygen-free copper casting, the evolution of hydrogen was found not avoided. The gas porosity in the casting, however, was found eliminated when the oxygen potential was kept at a low value.

Jan 1, 2003

By Stefan Mutz, Thomas Pretz, Jörg Julius, Frank Hilbk-Kortenbruck, Aachen, Hartmut Harbeck

"The annual global production of primary aluminium was about 22 million tons in the year 2000. This represents the second largest production rate in the world market after steel. Experts are predicting that the global demand for aluminium will rise in the near future.In contrast to other metals such as copper, the recycling of aluminium is considered relatively difficult. There are two main alloying groups, namely cast and wrought. In the case of aluminium it is important that the constituents within the scrap aluminium to be smelted are clearly identified. Within the secondary remelting process alloying does take place, but a removal of unwanted metal constituents is problematic. Therefore mixed aluminium scrap (not genuine in-house collected material) can only be used to produce cast aluminium. Thus, in other words a down-cycling of wrought (extrusions and rolled) products occurs. However, in spite of these difficulties there is an increasing trend to produce aluminium from secondary scrap (approx. 35% in Germany). Similar trends have been identified in the USA and other industrialised countries. This development is mainly caused by the high energy consumption for the production of aluminium from bauxite. Producing aluminium from scrap is saving about 95 % of the energy in comparison to the processing of primary raw materials.An improvement in sorting technology is necessary to separate wrought and cast alloys of aluminium as the absolute amount of recovery from old scrap is higher than the demand for cast.This contribution presents some alternative methods, utilizing automatic picking technologies, which will be used to separate secondary aluminium in the future. During the recent years, some major progresses have been made in automatic picking technologies for different applications in the processing of primary and secondary materials.For the sorting of aluminium scrap a special additional sensor will be necessary. The best detection will ultimately be based on online elemental analysis of single particles. First investigations in the field of laser based systems for these applications have already been performed several years ago. One of the laser based techniques is the laserinduced breakdown spectrometry (LIBS)."

Jan 1, 2003

By M. J. Blattman

Upon completion of an underground mine design, the planning engineer is faced with a surprisingly complex problem, “What development and mining sequence should be implemented so as to maximize the return on investment?” The problem relates to the scheduling of development headings to access stope production areas in such a way that the most money is made as quickly as possible for as long as possible. The total dollar value of the stopes, the average grade, the total tonnage, nor even the profit margin do not accurately give an indication of the “proper” mining sequence on their own. This paper will outline a method being developed by the author that can create a sequence of events that maximizes the net present value (NPV) of a given development and production design using information already being generated during the design process.

Jan 1, 2003

By P. Wittke-Gatterman

ABSTRACT: A three dimensional constitutive law for swelling rock is presented. It can be applied to the osmotic swelling of mudstone as well as to the swelling of rocks containing anhydrite. It describes the development of time-dependent strains and stresses due to swelling considering elastic and viskoplastic behaviour. Furthermore an anisotropic swelling behaviour can be considered. This constitutive model was implemented within a numerical computation program according to the finite element method and calibrated on the basis of the results of measurements in the investigation drift of the Freudenstein tunnel which is completely located in the unleached Gypsum Keuper. A parameter combination could be found which results in a good agreement between numerical solutions and results of measurements. Therewith an analysis procedure which enables the design of tunnels in swelling rock is available. ZUSAMMENFASSUNG: Im vorliegenden Beitrag wird ein dreidimensionales Quellgesetz vorgestellt, das nach derzeitigem Kenntnisstand sowohl auf das osmotische Quellen von Tonsteinen als auch auf das Quellen anhydrithaltiger Ton- beziehungsweise Schluffsteine anwendbar ist. Das Stoffgesetz wurde in ein Finite-Elemente-Programm implementiert und anhand von Meßergebnissen des im unausgelaugten Gipskeuper liegenden Untersuchungsstollens des Freudensteintunnels kalibriert. Es ist gelungen, eine Kennwertkombination zu finden, mit der alle Meßergebnisse gut beschrieben werden können. Damit steht ein Bemessungsverfahren für Tunnel in quellfähigem Gebirge zur Verfügung. RÉSUMÉ: Dans l&apos;article présent un loi de gonflement à trois dimensions est présenté, qui peut être appliqué aussi bien au gonflement osmotique de l&apos;argile compactée q&apos;au gonflement de l&apos;argile compactée ou du limon compacté contenant de l&apos;anhydrite. Le loi de comportement était implémenté dans un programme numérique d&apos;éléments finis et calibré avec des résultats de mesures de la galerie de recherche du tunnel de Freudenstein, situé dans le Keuper de gypse non lessivé. On est réussi à trouver une combinaison de paramètres avec laquelle tous les résultats de mesures peuvent être bien décrits. Par ce moyen, une méthode de dimensionnement existe pour des tunnels dans de la roche capable de gonfler.

Jan 1, 2003

By Stacy Loizeaux

The Beirut Hilton Hotel, which was built in 1975, but never occupied, was imploded on Sunday, July 14, 2002 by Controlled Demolition, Inc. (CDI) of Phoenix, Maryland and their client, Optimal Engineering Consulting & Contracting, SARL, (OECC) of Antelias, Lebanon to make room for a new hotel. Twenty-seven years ago, just days before the grand opening, the Hilton Hotel became the site of fighting in Lebanon’s Civil War. Christian and Muslim militiamen fought room to room for control of the building and other nearby hotels. The Hilton, two other major hotels and other high-rise buildings were ravaged by the fighting. The building was one of the three major hotels badly damaged, but not rebuilt, in Lebanon. Located in the City Center, the Hilton stood out in a major redevelopment area which, in recent years, had erased the scars of the 15 year long Civil Wa r.

Jan 1, 2003

By I. E. A. Aghachi

During static strain-aging of low carbon steel, when the material is pre-strained, the dislocation density increases. If totally or partially unloaded and aged for a prescribed time, interstitial solute atoms diffuse under the influence of the dislocation stress fields, thus tending to lock dislocations causing an increase in yield stress. If held for long periods at certain aging temperature, a decrease in yield stress (over-aging) is observed following the initial increase. This behaviour has been variously attributed to either recovery of cold worked dislocation structure and/or formation and coarsening of carbide precipitates. The present work demonstrates that, using a "process control" model for the competing processes of hardening and softening, dislocation recovery is responsible for over-aging of mild steel specimens under conditions tested during this investigation. Keywords: Strain-aging, Precipitation, Recovery

Jan 1, 2003

By A. Foscolos

Land reclamation and rehabilitation of depleted coal mines in the wider area of Ptolemais-Amynteon is practiced by the Division of Mines of the Public Power Corporation of Greece in order to conform to the concept of environmentally sustainable economic development of its operations. Detailed chemical and mineralogical studies were performed on reclaimed soils and their crops in order to evaluate the results of land reclamation and rehabilitation while similar studies were undertaken in adjacent, regularly cultivated, soils. Results indicate that trace element concentrations as well as concentrations of elements of environmental concern to be higher in regularly cultivated soils than the reclaimed ones. However, the concentration of the elements in wheat grains harvested from both, regular and reclaimed, group of soils is the same. The reason for this behavior is the very low water solubility, of the elements in the soils, due to their high pH values and the nature of their occurrence. As a result, wheat crops produced from reclaimed-rehabilitated soils developed on depleted lignite mines in the wider area of Ptolemais-Amynteon do not pose any health problem on either humans or animals when consumed.

Jan 1, 2003

By Gretel Parker

In situ Raman spectroscopic investigations of copper iron sulfides in leach solutions have been undertaken. Coupling potentiodynamic techniques to Raman spectroscopy produces a powerful tool for studying mineral surface response to changing conditions, while ESEM and high-vacuum techniques provide complementary ex-situ information on surface structure and composition. Oxidative acid leaching of chalcopyrite at ambient temperature yielded a product with S-S bonds that were shifted from those seen with covellite, with little evidence of elemental sulfur formation. Leaching of chalcopyrite led to non-homogeneous product distribution. Raman spectroscopy was able to identify the products formed on the mineral surfacein situ while leaching was occurring. Raman mapping and imaging demonstrated a surface distribution of the products which can be related to composition and structure changes of the mineral surface. The surface formed on chalcopyrite after anodic oxidation at 0.570 V vs. Ag/AgCl in 0.1 mol dm-3 HCl undergoes laser-induced transformation.

Jan 1, 2003