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By Donald S. Cameron

By dispersing gold in high surface area form supported on metal oxides, its inert character can be transformed to make economical, effective catalysts. Gold has already been demonstrated in a number of fuel cell applications such as gas phase catalysts, electro-catalysts, and electrical connectors. In this paper, the various types of fuel cell systems are reviewed, and several opportunities for gold identified. Low temperature fuel cells, including alkaline and solid polymer electrolyte types rely on high surface area platinum group metal catalysts which are highly susceptible to poisoning by low concentrations of carbon monoxide in the fuel supply. Hydrogen is frequently obtained by steam reforming hydrocarbons, followed by the water gas shift (WGS) reaction. A promising initial use for supported gold catalysts is in catalysing this WGS reaction. Research has shown that gold supported on iron oxide (Au/a-Fe2O3 ) WGS catalysts are more active than the current commercial copper oxide / zinc oxide catalysts, and effective at temperatures as low as 120oC. Products from reformer/ water gas shift reactors can be further purified by removing traces of carbon monoxide. If a small proportion of oxygen is introduced into the fuel gas stream, carbon monoxide can be preferentially oxidized to carbon dioxide even in the presence of hydrogen. Gold nanoparticle catalysts on iron oxide support (Au/a-Fe2O3 ) have exhibited higher activity than commercially available platinum on alumina (Pt/?- Al2O3 ) preferential oxidation catalysts. The low temperature of this reaction may make it feasible to incorporate these catalysts within the fuel cell itself. Proton exchange fuel cells provide several possible applications for catalytically active gold and its alloys. Carbon supported platinum group metals would benefit greatly from improved electrical conductivity if gold replaced some or all of the carbon support material. As electrode current densities are raised, electrical resistance constitutes an increasing proportion of voltage losses within the fuel cell. Dramatic reductions in cell stack voltage losses have already been demonstrated by reducing inter-cell contact resistance using gold plating. The low temperature oxidation properties of gold catalysts have been investigated in controlling gaseous emissions from direct methanol fuel cells, and gold also provides essential catalysis in building direct borohydride oxidation fuel cells. The prospect of a range of other applications for gold in fuel cells to contribute useful improvements in corrosion resistance and conductivity is assessed. Globally, fuel cells have been developed for a wide range of applications including stationary generators, cars and buses, industrial vehicles and small portable power supplies, each of which represents a substantial market. Hence there are likely to be many and varied opportunities for gold catalysts to contribute to the performance and economics of the systems being commercialized.

Oct 1, 2003

By Masakazu Daté

Moisture effect has been studied for the CO oxidation over Au/TiO2, Au/Al2O3 and Au/SiO2, in the range of H2O concentration over four orders of magnitude. It has been found that the catalytic activity is generally enhanced by moisture in the reactant gas. The enhancement is as large as two orders of magnitude. Response to the moisture concentration, however, depends on the support oxide, indicating different contributions of the support to the reaction steps. The moisture effect is reversible and the activity is mainly determined by the amount of moisture absorbed by the catalyst. The apparent activation energies are not significantly influenced by moisture for Au/TiO2 and Au/Al2O3. On the contrary, non-uniform conversion curves versus temperature observed for Au/SiO2 are drastically changed, which indicates that the reaction over Au/SiO2 does not take place at low temperatures without moisture. The moisture effect may be probably attributed to the decomposition of carbonate species accumulated during the reaction, while the ?OH group might directly participate in the reaction pathways as a promoter.

Oct 1, 2003

By Candido Bariáin

A new vapochromic material of formula [Au2Ag2(C6F5)4(bipy)2]n (bipy = 2,2´ bipyridine) has been developed and used for the detection of some volatile organic compounds as acetone either in vapour or in water solution. The material is presented in the form of powders which colour changes with acetone vapours turning from bright yellow in the absence of vapour to white in the presence of vapour. By using the sol-gel technique, the powder ? dispersed in tetraethyl orthosilicate- was easily deposited on optical fibres. In order to study experimentally the behaviour of this material for construction practical optical fibre sensors, a sol-gel material doped with the vapochromic material is deposited onto an extreme of a monomode fibre connected to a coupler. The behaviour of the material was studied for different wavelengths and concentrations of acetone vapours and acetone/water solutions. Changes up to 4dB in the reflected optical power were detected. Optical fibre sensors have many advantages over conventional ones, such as electromagnetic interference immunity, passivity behaviour, possibility of using multiplexation techniques, low weigh and little size, etc. Actually, there is an increasing interest in developing optical fibre sensor for vapour detection in the chemical industry and in fact many sensor had been developed [1]. Some are based on the deposition of a sol-gel-based material either over the core of an optical fibre [1] or onto the thinner zone of a biconically tapered optical fibre [2]. Others are based on Fabry-Perot interferometers [3]. Also there are sensors based on the reflection of the light on films, on the fluorescence of dye-doped polymer cladding in fibre, on colorimetric reagents in the core of a silica fibre or on surface plasmon [4]. The possible materials for the construction of such sensor should be colorimetric reagents able to change the colour or refractive index in the presence of same organic vapours. There are not many metallic complexes with these properties, although same interesting examples have been reported in the chemistry of palladium and platinum as [Pt(p-R-C6H4NC)4][Pd(CN)4] described by Nagel [5] and Mann [6], which reported the construction of some LEDs. We recently reported the preparation of a novel vapochromic material (Fig 1) [7] which can be used for the construction of optical fibre tapered environmental sensors [8,9] of vapour organic compounds (VOC´s). Also we reported other nickel and palladium derivatives which present this type of behaviour [10]

Oct 1, 2003

By Michele L. Kimble

A fast-flow reactor mass spectrometer has been utilized to investigate the reactions of gas-phase gold cluster anions with CO and oxygen. Addition of CO to Aun - produces species of the form Au(CO)m -, where m = 2-5. However, CO does not bind to Au2 - or Au3 -. With oxygen addition in the cluster source, gold oxide species with both molecular and atomized oxygen are produced. The addition of carbon monoxide to these preoxidized gold cluster anions reveals that select species with 1, 2, and 3 gold atoms participate in the oxidation reaction to produce CO2. Bimolecular rate constants for the reactions between these species and CO are also discussed.

Oct 1, 2003

By S. Ivanova

The results presented in this paper show that the gold solution dilution is a key parameter to control the dispersion of gold on ?-Al2O3 the selected support. The variation of concentration leads to changes in pH which modify the nature of gold complexes from HAuCl4 formed in the solution. These complexes are presented. Some of them (AuCl3(OH)- and AuCl2(OH)2 -) react with the surface of alumina and give interesting interaction. AuCl2(OH)2 complex has been considered as an ideal complex because of the strong anchorage of a bidentate species on the alumina. This complex is formed mainly in a solution of gold with a concentration of 10-4 M giving a pH of 3.5-4.5. The nature of the anchorage and the amount of chlorine, has an influence upon the formation of Au-Cl bridges which modify the dispersion of the gold on alumina of the final catalyst as shown by TEM.

Oct 1, 2003

By John A. Rumball, Martin R. Houchin

Data from autogenous and semi-autogenous tests in a 1.67m diameter mill have been analysed in terms of a new model for rock abrasion. This model defines specific rate as the rate of production of fines (material less than 13mm) per unit mass of rock, where the term “rock” is applied to all ore pieces of ore coarser than the grate size. In most cases, an allowance for preliminary rounding and cleavage was made. A method has been developed to analyse steady-state data, using piecewise fitting to the cumulative size distributions. The model was compared to the well-established models, which are based on the population balance method. The specific rate increased for all rock sizes as the volume of 100mm balls in the mill was increased. Tests using a coarser feed and smaller balls provided further evidence that once rocks are rounded, abrasion is due to localised surface damage, caused by impacts, rather than rotational shear. An allowance for rapid rounding of jagged rocks, followed by less rapid abrasion of rounded pebbles was also tested, but the analysis was not conclusive. The average specific rate is a useful measure of the capacity of a primary mill. The effect of power intensity (kW/t of ore) was also investigated as a means of extrapolating the pilot-plant data to large production mills.

Sep 29, 2003

By Jerry Vila Valenzuela

"Ante la incertidumbre de las bajas en los precios en los metales, las empresas mineras buscaron herramientas que ayuden a controlar y cumplir con los objetivos a alcanzar. En esta perspectiva, la mina Chungar ha creado unaherramienta de control denominada ZINC CASH COST DIARIO, cuya función informa sobre el resultado económico de las operaciones del día anterior, las acumulaciones del mes y la proyección a fin de mes, permitiendo a la unidad reaccionar rápidamente a los cambios imprevistos de los precios. En este sentido, el presente trabajo describe describe el procedimiento, secuencia, toma de datos, el procesamiento, emisión de reportes y análisis del mismo y así transmitir y compartir las experiencias logradas con el uso de esta herramienta. "

Jul 31, 2003

By Manuel Retamozo

El presente texto señala cómo el ejercicio físico adecuado y la dietética mejoran la producción y disminuyen el absentismo laboral en la empresa minera BHP Billiton Tintaya S.A a través de un política de prevención de salud. Entre los objetivos principales está determinar la frecuencia con que realizan ejercicio físico adecuado los trabajadores del área de mina, señalar si existieron cambios en las costumbres alimenticias de los trabajadores del área de mina después de la educación alimentaria, delimitar si existe asociación entre el aumento de la producción en el área de mina con la práctica del ejercicio físico adecuado y la dietética, así como entre la disminución del absentismo laboral en el área de mina con tales prácticas.

Jul 31, 2003

By Ron H. Derammelaere

"The paper point out of the copper slurry pipelines in South America, providing key statistics, such as throughput, diameter, length, etc. In addition, it will present technical aspects of pipeline design that are unique tomountainous terrain, specifically: choke stations for the control of slack flow, batch hydraulics, automation and training.The pipelines listed in this paper operate successfully at availabilities in excess of 98%. Breaks and plugs can occur due to operator error, but are extremely rare. A review of cross-country slurry pipeline operations worldwide over the last 30 years shows that such a major event occurs, on average, once every five years. Under such a worstcase condition, the downtime rarely exceeds five days. Some pipelines have already been in operation over 30 years, the life span being a function of how well corrosion is kept in check."

Jul 31, 2003

By Marc Leduc

Since co-disposal technology promises to replace conventional tailings disposal methods at sites with high strip ratios or plentiful old dumps. While the mine waste needs to be relatively strong and low in fine material, and chemical compatibility must be assured, when these parameters are satisfied there are no other significant hurdles to its implementation. In this sense, the paper describe the resulting benefits range from substantial reduction in capital and operating costs to reduction or essential elimination of the short- and long-term liabilities associated with tailings dams are impoundments.Since tailings dam failures are arguably the greatest environmental liability and public relations problem in the industry, reducing the quantity of tailings managed behind dams is a worthy goal.

Jul 31, 2003

By Jorge Tovar Pacheco

El presente trabajo describe los resultados del estudio de ingeniería básica y de detalle para el abandono de los depósitos de Excélsior y Quiulacocha desarrollado por la empresa CESEL S. A, cuyo objetivo principal fue el diseño de las obras de cierre que garanticen la estabilidad hidrológica y geoquímica de los depósitos. En ese sentido, las obras de cierre diseñadas para que en un futuro los efluentes de agua ácida se reduzcan al mínimo y que su tratamiento sea en lo posible pasivo, son las siguientes: el encapsulamiento del depósito Excélsior mediante la impermeabilización del tope con geomembrana y de sus taludes con arcilla, la derivación de aguas subterráneas limpias en Champamarca a través de una pantalla impermeable para interceptar el agua subterránea del manantial Excélsior y descargarla al canal lateral de la margen izquierda y el drenaje superficial para descargar las escorrentías hacia los canales laterales. Asimismo, a fin de interceptar las aguas subterráneas que descienden desde el Club de Golf, y descargan en el lado Sur del depósito Excélsior, se implementará una pantalla mediante inyecciones de concreto.

Jul 31, 2003

By Samuel Canchaya Moya

Si bien en las últimas décadas se aplicó el estudio de la geoestadística en la minería, el uso de la técnica no ha logrado una mayor difusión. En ese sentido, el presente texto señala la aplicación de los paquetes de software en la minería a través de los módulos de geoestadística. En este punto, la optimización del muestreo, se convierte en un problema tanto en la etapa de exploración como de producción. Por ello, es necesario conocer y comprender los conceptos y métodos geoestadísticos que se apliquen a la medida de muestreo de la veta, ver distancia y ubicación de taladros, costos de campaña de exploración, entre otras medidas, etc.

Jul 31, 2003

By Oswaldo Ortiz Sánchez

El presente trabajo describe la alternativa de uso del mortero de resina en la fijación de pernos de anclaje de las excavaciones mineras, consolidación y disipación de vibraciones en los cimientos de plataformas para la instalación de molinos, winches, tolvas, etc. Esta opción surge en respuesta al problema de reforzamiento con pernos de anclaje en ambientes con aguas corrosivas o en proceso de deformación acelerada en las excavaciones mineras, así como ante obstáculos de subsidencia de cimentación en plataformas, donde se encuentran instalados equipos de gran tonelaje, y que producen fuertes vibraciones durante su funcionamiento.

Jul 31, 2003

By Henry John Luna Córdova

El presente trabajo describe el proceso de gestión de calidad en la administración de los derechos mineros a través de la automatización de procesos desarrollados por el Instituto Nacional de Concesiones y Catastro Minero (INACC) organismo público descentralizado del Sector Energía y Minas que administra el Procedimiento Ordinario Minero para el otorgamiento de Concesiones Mineras, el Catastro Minero Nacional y la distribución del Derecho de Vigencia a escala nacional. Entre otras funciones de dicha institución está la creación de una serie de base de datos numérica, que le han permitido optimizar dichos procesos en calidad. Así como en el aspecto de la administración del Derecho de Vigencia y Penalidad, se creó el software para automatizar sus procesos y efectuar el cobro respectivo en las entidades del sistema financiero nacionall. Finalmente en el aspecto catastral, se generalizó el uso de coordenadas UTM (PSAD56) para identificar los derechos mineros, asimismo, se crearon los parámetros de transformación de coordenadas WGS84 a UTM.

Jul 31, 2003

By Roque Pereyra

Uno de los aspectos más importantes en el reinicio de las operaciones en Tintaya radica en el acarreo, dado que representa la estructura de costos del área de costos del área operacional minero. En este sentido, el objetivo del presente trabajo es determinar el neumático adecuado para los camiones Komatsu 830E, en base a los criterios de alto rendimiento y bajo costo. Para ello, se necesitó el apoyo de las áreas de Operaciones, Mantenimiento, Planeamiento Mina y Logística, así como de los proveedores de neumáticos, así como se realizó un benchmarking con otras operaciones mineras, de forma que se pueda establecer los criterios clave para una selección óptima de los neumáticos en la operación minera.

Jul 31, 2003

By Williams Morales Céspedes

Uno de los problemas que surgen durante el proceso de chancado reside en el porcentaje de humedad en los minerales. La presencia de arcillas en forma de bolones causa menor productividad puesto que atora las chancadoras y, por consiguiente, se debe reducir el tonelaje de tratamiento. En ese sentido, el presente trabajo señala el proceso de aglomeración como alternativa de mejora química y física del mineral, de forma que se utilice fajas de mayor resistencia a la abrasión. Para ello, se realizan pruebas con adición al cemento en menor cantidad, para en un futuro dosificar con menor cantidad de cemento sin afectar los actuales parámetros de lixiviación. Así, el cemento, aparte de servir como aglomerante, es un regulador del pH, que actualmentese envía al Pad con promedio de 11 pH.

Jul 31, 2003

By William R. Adamson

"The paper point out how mechanistic blast outcome models can be employed to explore the likely extent of achievable benefits associated with application of different explosive products, of quantifiably known characteristics.maximizing the advantages of the use of this modeling approach requires the use of field based measurements as model inputs, as has been done in this particular study. Inevitably, enhanced confidence in the routine application of the approach will be obtained through the collection, analysis and interpretation of field performance verification data such as fragmentation size distribution data. "

Jul 31, 2003

By George Shou

"The paper point out about economics of thickened tailings transportation. In this sense, the optimal concentration is determined based on the balance between the incremental costs of thickening and transportation and theincremental environmental benefits. A detailed feasibility study is essential for financial success of a tailings project. Hydraulics modeling is the key to estimate the transportation cost curve. "

Jul 31, 2003

By David Ramírez

"Dentro del proceso de optimizar la fragmentación del mineral por voladura, el principal objetivo es determinar el impacto que tendría la incrementación de las partículas medias y finas sobre la extracción de cobre en elmineral ROM, (Run of Mine), que actualmente constituye una de las fuentes de producción por lixiviación en la Sociedad Minera Cerro Verde. En ese sentido, el presente trabajo describe la cantidad de cobre que aporta el mineral ROM a través de su optimización en el proceso, así como el impacto económico que tendría a futuro. Para ello, se utilizan los resultados de las pruebas para los módulos experimentales 12 y 13 desarrolladas entre 1998 y 2000, y la validación preliminar del sistema de análisis granulométrico por fotos (Split Desktop) desarrollado en julio del 2002 para así otorgar validez a los resultados fotográficos de granulometría reportados para las diferentes pruebas de voladura. "

Jul 31, 2003

By Efrén Peña Pino

El presente texto señala la aplicación del sistema SAP en la minería subterránea de Minsur. Este sistema operativo maneja las propiedades y procesos de la Sociedad Minsur, el cual cuenta con tres Centros, dos de los cuales son operativos (San Rafael y Pisco) al margen de la central de administración (Lima) y permite la planificación de todos los recursos de la empresa de manera integral, evitando imprevistos y una mejora de decisiones.

Jul 31, 2003