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By F. -Z. Ji, G. A. Irons, M. Barati, K. Coley

The use of oxygen in electric arc furnace steelmaking is tied to the use of fossil fuels, and slag foaming. The current work examines the kinetics of carbon injection into EAF slags especially the saturation injection rate and available reaction area in the slag foam. Based on individual rate data and experimental gasification rates of carbon in the slags, the available reaction surface area in the gas bubbles was found to be around 1900¬4700 cm2.kg-slg-1 for carbon injection into EAF like slags at appropriate injection rates and steel making temperatures. The ratio of number of bubbles to number of particles is 1 to 17 and the weights of carbon per unit reaction area are 0.001-0.008 gC-cm-2. Using the relationship between active reaction area and x supplied in this study, the gasification rates of carbon in slags can be estimated with gas-slag interfacial reaction rates.

Jan 1, 2004

By W. D. Gould, A. Kapoor

Acid mine drainage (AMD) is characterized by low pH and high concentrations of sulfate and dissolved metals such as iron, manganese, aluminum, zinc, and copper. Chemical treatment of AMD achieves pH neutralization and toxic metal removal but also produces large quantities of bulky sludge that requires long-term storage facilities and monitoring. Chemical treatment of AMD achieves only partial removal of sulfate (SO4) and total dissolved solids. Sulfate reducing bacteria (SRB) have been used for the removal of sulfate from industrial process wastewaters. The biological sulfate reduction process generates sulfide and alkalinity. The sulfide produced in the biological sulfate reduction process is used to precipitate metals present in AMD as their respective sulfides and the alkalinity generated is used to neutralize the AMD. This review article will present an overview of biological sulfate reduction processes using SRB, bioreactor configurations, AMD treatment studies, and full-scale systems in operation for the treatment of acid mine drainage.

Jan 1, 2004

By S. J. Frank

The development of feedforward semi-empirical control models for furnaces and the evaluation of mass balances are based on plant data. The models can only be as good as the data and it is therefore required to know the inherent uncertainty associated with the plant data. This uncertainty stems mainly from the fact that the slag, alloy or dust, have a distributed nature that depends on the degree of mixedness. It is commonly accepted that melts from open bath furnaces are well-mixed, and submerged arc furnaces less so. The impact of this assumption is significant, as a reasonably homogeneous melt could be represented by one sample only. As so much of metallurgical control depends on the assay information of the alloy and slag melts from furnaces, it was decided to characterise the possible variation in melt chemistry and temperature. Sampling campaigns and continuous temperature measurement of the melts were performed for different alloy and slag taps at a major ferrochrome producer. Both a submerged arc furnace and open arc furnace are evaluated in this way, by way of comparison. The slags of both open arc and submerged arc furnaces were found to be of similar degrees of homogeneity, with much spatial variance in the reducible iron and chromium oxides. However, it was found that the alloy melts deriving from open arc furnaces were significantly less homogeneous than the alloy derived from submerged arc furnace alloy production. The compositional variance could be related to the furnace operating conditions and it affects both metallurgical accounting and process control. In all cases it was found that the variance in melt solute components are larger than can be ascribed to analysis instrument error. It will be shown how this predetermined variance in melt composition could be included in process modelling and control.

Jan 1, 2004

By C. Anim-Sackey, R. K. Amankwah

Some large-scale mining companies in Ghana have adopted proactive management strategies in dealing with small-scale (galamsey) miners who have encroached on their concessions. This has been mainly achieved by ceding portions of the concessions held by the companies to the Minerals Commission of Ghana for licensing to the small-scale miners. This development has created an amicable relationship between the mining companies concerned and the galamsey miners in their host community. Ghana’s small-scale gold and diamond industry The small-scale gold and diamond mining industry in Ghana has existed for many centuries as an informal sector. Since the regularization of the activities of small-scale mining in 1989, two types of small-scale miners have emerged — legal and illegal.

Jan 1, 2004

By L C. Thompson

BioLix is the term for a new class of biologically-derived lixiviants for precious metals (gold and silver) recovery. BioLix can be used as an alternative to cyanide on virgin and spent ores. The BioLix process is based on inducing microbial enzymatic reactions that generate organo-lixiviant chemicals. The bioprocess involves a two-stage culture strategy. First, specialty microorganisms are cultured to generate a high biomass. Then, a food-grade quality amendment is introduced that forces the microorganisms to produce the organo-lixiviant. The second-stage culture is applied to the ore where the microbial/lixiviant system acts on mineral surfaces to extract precious metals. The process operates at ambient temperatures and near neutral pH. This paper will examine the BioLix process through an extensive laboratory development and demonstration project. Laboratory development consisted of identifying and isolating specialty microorganisms and inducing agents for the production of the organo-lixiviant solutions. A demonstration was performed on low-grade and high-grade oxidised ore from the Buffalo Valley mine in Nevada, USA. Results indicate that the BioLix process was comparable to cyanide in terms of gold recovery and operated at near neutral pH and ambient temperatures. Applications for the BioLix process will be discussed including spent-ore re-leaching, cyanide replacement for virgin ore, and in situ mining.

Jan 1, 2004

By A. J. Jager, D. P. Roberts

The stoping of platinum orebodies in the Bushveld has in the past been accomplished by using in-stope pillars to ensure stability of the workings. In the future, the use of continuous mining machines to mine the platinum orebodies is probable. It is not envisaged that such machines will cut in-stope pillars. This paper describes the alternative support systems that will replace the pillars and the stope geometries that will be required for this type of mining. The paper describes how the support resistance provided by in-stope pillars in current mining was determined and then evaluates support systems that can substitute for these pillars. Conceptual layouts based on existing breast mining layouts are presented. The layouts consist of panels of up to 100 m face length between rigid strike stabilizing pillars. A number of design charts are then proposed that allow for the design of appropriate support systems.

Jan 1, 2004

By I R. F MacCulloch, K Jones

Pintail Systems, Inc, a Colorado USA based company has developed and commercially applied bioremediation processes for biological detoxification of cyanide compounds in mine waste. Site-specific microorganisms are isolated from spent ore, tailings or process solutions and augmented in the laboratory for cyanide oxidation, denitrification and metal biomineralisation. Biological processes typically treat complex contaminants (cyanide compounds, soluble metals and nitrates) in a fraction of the time of conventional remediation processes. Cyanide is used in microbial metabolic processes as a carbon or a nitrogen source. Biological detoxification processes applied at the end of mine life can end long-term liability and perpetual monitoring and containment. Case studies from commercial application and demonstration programs for the US Environmental Protection Agency will be presented in this paper.

Jan 1, 2004

By B. Samanta

A quality characteristic analysed through construction of the Shewhart control chart is required to be normally distributed. In mining applications, this assumption is often violated as many quality characteristics follow skewed or lognormal distribution. In this paper, two methods were investigated using a heuristic approach for setting up the control limits for a skewed population. Based on these approaches a Mode chart, and a Weighted Variance (WV) control charts were constructed. The performance of the proposed methods was compared with the normal based Shewhart method through a case study conducted in a surface mine supplying iron ore to a steel plant. A simulation study was also conducted to evaluate the effectiveness of the proposed methods over the Shewhart method. The study revealed that the Shewhart control charts generated more out of control alarms compared with the Mode and Weighted Variance control charts for a skewed population of Fe%. The simulation results also revealed that for extremely high skewed population, the WV control chart and Mode control chart provided higher probability of coverage than the Shewhart method; although the detection rate (probability of detection) of out of control condition for these methods was slightly reduced compared with Shewhart method.

Jan 1, 2004

By T. Takahashi, K. Oyamada, Y. Miyata, T. Isoo

The carbonation reaction of steelmaking slag has been known for many years. However, the size of blocks manufactured from this by-product material has been limited due to the difficulty of achieving a uniform reaction throughout the block. Using newly developed conditions, large porous slag blocks (1.0 x 1.0 x 0.5 m) were produced by car¬bonation of steelmaking slag with the optimum amount of water and supplying CO2 deep into slag powder compacted in molds. The development of these blocks has great poten-tial to solve the problem of slag utilization, for example, by recycling slag in large car¬bonated blocks for artificial fish reefs and seaweed cultivation beds. This paper de¬scribes the carbonation reaction, the new process for producing large slag blocks, and the utilization of blocks in past and recent years.

Jan 1, 2004

By J. H. Baek, S. Alexandrovskii, D. W. Lee, B. K. Kim

Nano-phase titanium carbide was synthesized by Mg-thermal reduction process using a novel route of Mg-thermal reduction. The processes are based on I) feeding of TiC14+CxC14 x = 1, 2 ) solution into liquid magnesium, 2) Mg-reduction of metal chlorides, 3) TiC formation by the reaction of released Ti and C atoms, and 4) vacuum separation of residual liquid phases of Mg and MgCl2. In this study, the process for titanium carbide production with composition close to stoichiometry and the minimum content of impurities was optimized with the various process parameters such as concentration of initial solution, its feeding rate and reaction temperature, as well as a kinetic study.

Jan 1, 2004

By J Liu

In situ coal gasification is a method of extracting a high proportion of the energy value from coal without the need for mining. In situ conversion of coal to combustible gases is achieved by drilling wells into the seam, injecting gasification agents and initiating combustion. The product gases are then extracted to surface using production wells. These gases are clean energy sources for power generation, heating or synthetic fuel production. In situ coal gasification is of particular interest with respect to its lower environmental impact, potential application to otherwise inaccessible energy resources (ie offshore, deep deposits or beneath protected lands) and low capital intensity. Practical application of this clean technology is restricted primarily by lack of satisfactory quantitative descriptions of the processes involved, in particular the hydromechanical processes.In this study, three characteristic physical zones of an in situ gasifier are identified as the rubble zone, combustion front and virgin coal zone. Coupled mechanical processes of coal consumption and overburden collapse are used to describe the permeability profile in the rubble zone. Additionally, the redistribution of overburden load associated with coal consumption is accounted for with the formulation of a stress (compressive) dependent permeability profile, which is applied to the virgin coal zone. The model was implemented into and solved by FEMLAB, an advanced computer simulation tool. The flow process, according to DarcyÆs Law, is subsequently described in terms of permeability dependent injectivity. Injectivity is an indicator of flow velocity, which has been identified as a crucial factor in determining the commercial value of product gases from in situ coal gasification. The stress alteration to coal permeability was found to have a dominating influence on the flow process. This finding implies that a greater understanding of the in situ coal burning induced deformation of surrounding rocks would be of significant value in assessing the economic viability of applying this clean technology to potential sites.

Jan 1, 2004

I report results of over 850 microprobe analyses of sulfides, sulfosalts and electrum from the Favona adularia-sericite epithermal deposit of the Waihi district in the southern Hauraki Goldfield of New Zealand. Pyrite and marcasite from altered wall rocks that enclose the veins are stoichiometric, with compositions of FeS2, and no significant trace elements. In contrast, pyrite in veins commonly contains appreciable As (up to 3.2 wt per cent), and locally contains several tenths of a percent of Cu, Zn, Co, Ag and Sb. Vein pyrite may contain up to 0.22 per cent Au, but Au contents do not show a positive correlation with As. Limited electrum data indicate that it ranges from Ag0.47 Au0.53 to Ag0.54Au0.41Cu0.01Zn0.04. Chalcopyrite is stoichiometric CuFeS2, and most galena is PbS, but some galena contains up to 4.4 wt per cent Se, which substitutes for S in its lattice. The galena is not argentiferous; the highest Ag content is 0.45 wt per cent Ag. Sphalerite averages 4 mol per cent FeS, but ranges up to 15 mol per cent. Tetrahedrites [(Cu,Ag)10(Zn,Fe)2(As,Sb)4S13] show variable substitution, but most are Cu- Zn- and Sb-rich. Veins also contain aguilarite (Ag4SeS), stromeyerite (CuAgS), naumannite (Ag2Se), and mckinstryite [(Ag,Cu)2S].

Jan 1, 2004

By J. Lux, B. Clermont

Magotteaux, with the co-operation of Anglo Platinum, has erected a fully instrumented pilot plant at Frank concentrator, which is being used to study the influence of a variety of grinding parameters. This paper will discuss only the influence of mill speed and pulp density on secondary stage grinding. A Ø0.82 x1 m open circuit mill was used with reclaimed Merensky tailings as feed. The conclusions apply to this pilot plant but further investigation needs to be done to verify whether the same trends will be applicable to a large industrial-scale mill.

Jan 1, 2004

By Philemon Desrochers, Ken Qian Liu

Following the success of the West Ore Zone distress mass blast in 2001 at Brunswick Mine, a similar approach was taken to distress the North Regional Pillar (NRP) which contained over 3 million tonnes of high grade ore. The NRP is located on the 1000 m Level with very poor hanging-wall (H/W) rock mass qualities. After an extensive geotechnical review, the distress slot is located close to the foot-wall (F/W) of the NRP in order to have the competent ore as H/W. The longitudinal area to distress covers 115 m along the strike and 85 m high from 1000 1-sub to 850 Sill. Prior to the final mass blast, 3 voids were created to allow rock swelling: the North void, the South void and the trench just below the mass blast. After over one year of preparation, the mass blast of 202,000 tonnes was successfully initiated on February 7, 2003 with 1561 electronic detonators and 210,000 kg of emulsion explosives. The blast achieved its objective of distressing the NRP as indicated the mine-wide micro-seismic monitoring system. This paper describes different stages of the project from void preparation to the mass blast itself, as well as some detailed aspects such as muck-pile prediction for mucking sequence with the help of DMC_Blast simulation code and electronic detonators.

Jan 1, 2004

By R. Khanna, M. Dubikova

A variety of carbonaceous reducing materials are being used for the production of ferroalloys. Reductant materials include not just carbons such as coke, coal, char but also bio-carbons in form of charcoal produced from different types of wood. This paper discusses critical properties and reactions of carbonaceous materials and their significance in dictating reductant performance. Main considerations include among others, gasification of reductant, dissolution of carbon into molten metal, and direct reduction of slag by solid carbon. These are discussed in relation to material properties such as structural order, mineral matter content, composition, physical characteristics etc. A brief review of both conventional and novel approaches towards characterisation of carbonaceous materials has been included. Due to complexity and heterogeneity of carbonaceous reducing materials and a wide range of process requirements, the selection of the most appropriate reducing agent will depend on a number of considerations such as the availability of raw material and associated costs, product and process requirements and environmental aspects of waste gas emissions.

Jan 1, 2004

By D. J. Wesolowski, D. A. Palmer, P. Bénézeth, S. Hilic

The equilibrium solubilities of gibbsite, Al(OH)3, and boehmite, A1OOH, have been extensively studied in our laboratory from 30 to 90°C, and 100 to 300°C, respectively, to ionic strengths of 5 mol.kg-1 (NaC1) over a wide range of pH. The resulting solubility constants have been treated with consistent empirical models that incorporate appropriate experimental data taken from the literature. These studies were initiated in part to understand and quantify scale formation in geothermal fields as a result of fluid re-injection from electric power generating plants. Most of the experimental results were obtained through application of a unique potentiometric method that allows for rapid, precise measurement of the in situ pH and allows the approach to equilibrium to be monitored from under- and super-saturation. The experimental program was extended to deal with more basic solutions (e.g., five molal NaOH), in which the dissolution of boehmite was measured for application to the refining of bauxite by the Bayer process. More recent results in strong caustic solutions at temperatures below 90°C were obtained to investigate the dissolution of aluminum-containing sludge from holding tanks at the Savannah River waste reprocessing site. In this case the solubility enhancing effects (kinetic and equilibrium) of triethanolamine were also established and quantified. Finally, potentiometric solubility experiments were conducted (50°C in 0.l mol-kg-1, NaCl) on aluminum alloy sheets to identify mainly the nature of the aluminum oxide/hydroxide surface layer formed under these conditions.

Jan 1, 2004

By Edwin de Jesús Deveaux

After 32 years of operations beneficiating lateritic nickel ore in a fully integrated pyrometallurgical complex, Falconbridge Dominicana (FALCONDO), situated at Bonao and La Vega Provinces, Dominican Republic, has become profitable with one of the lowest nickel grade content processing plants in the world, and literally without any by-product (granulated slag, will be utilized in the future as a post-processing subproduct). To December 2002, mineral reserves were 64.1 million tonnes containing laterite grading as low as 1.15 % Ni when full dilution is applied. At a cut-off grade of 1.20% Ni, the reserves will provide 15-20 years of production. The mineralized thickness over the seven active deposits averages 6 m. Development of very selective and unique mining practices, together with improvements in the process plant, are key to achieving the production goal (30 kt Ni/yr) and to meet the quality standards for the ferronickel produced. Keywords: Laterites, grade control, mining methods, environment

Jan 1, 2004

By C. Beckermann

"A diffuse interface model is derived for the direct simulation of two-phase flows with surface tension, density differences between the phases, and phase change. The derivation starts from the balance equations for a sharp interface and uses a formal averaging procedure on an atomic scale to obtain diffuse interface versions of the equations. Two approaches are considered: (i) the two phases have different velocities inside the interface and separate conservation equations are solved for each phase, and (ii) the two phases have the same velocity inside the diffuse interfuce and mixture conservation equations are solved. Based on a superposition of microscopic (atomic-scale) and macroscopic interface morphologies, an expression for the interfacial momentum source term is introduced that models surface tension effects and accounts for immiscibility between the phases.IntroductionDiffuse interface methods have been a popular tool in the direct simulation of two-phase flows [I]. In diffuse interface approaches, the interface between the two phases is characterized by a rapid but smooth transition in the properties, such as density and viscosity. Usually, a phase function ? is introduced to represent this transition, and the evolution of ? in the domain is computed from a separate equation or recipe. A unique set of conservation equations (e.g., mass and momentum) is solved on the entire domain, irrespective of the phase present, by accounting for the transition in the properties and introducing terms that account for interfacial sources. The continuum surface force (CSF) model of Brackbill et al. [2], which accounts for surface tension, is an example of the latter. The volume-of-fluid (VOF), level set, and phase-field methods are all examples of diffuse interface approaches. The major advantage of diffuse interface methods is that explicit tracking of the interface and the application of traditional sharp interface conditions are avoided. A disadvantage can arise from the artificial smearing of what is in reality an interface of atomic-scale width; however, techniques have been developed to overcome this problem."

Jan 1, 2004

By B Roberts

The Department of Industry and Resources (DoIR) is responsible for several sets of legislation, which, among other things, regulate the storage, handling and transport of dangerous goods as well as every aspect of the life cycle of explosives in order to prevent explosions, fires and spillages. The legislation with particular relevance to explosives includes: The Explosives and Dangerous Goods Act 1961; the act deals with the storage, manufacture, sale, import, authorisation and use of explosives. It is primarily framed for use of explosives and fireworks in the general community but also has relevance for storage on mine sites. The Dangerous Goods (Transport) Act 1998; this act regulates the transport of explosives on public roads, but not on mine sites. The Mines Safety and Inspection Act 1994 (MSI Act); this act and supporting regulations deal with the full spectrum of occupational health and safety in the mining industry. There is a substantial section in the regulations dealing with the use of explosives at a mine site.DoIR has identified the need for security upgrades of the Government Explosives Reserves, the need to tighten security measures at mine sites, the need for improved security checking for licensed shotfirers and the need to restrict the availability of explosives to authorised people who have had appropriate security checks. It is also clear that we need restrictions on the sale and use of ammonium nitrate (AN). A number of additional security measures are being proposed and all proposals are being refined by ongoing industry consultations. These will be adopted into new explosives regulations in association with the new Dangerous Goods Safety Act 2002 (DGS Act). Government finalised the act in June 2004. The act remains dormant until new explosives and dangerous goods regulations have been prepared. When the DGS Act and a suite of regulations are proclaimed as a package, sometime between December 2004 and April 2005, the old legislation consisting of the current two acts, will be automatically repealed. It is also proposed that all explosive regulation, including those under the MSI Act will be consolidated in one place under the DGS Act for user friendliness.

Jan 1, 2004

By John Jordan, Tesarik, Steven J. Knoll, Theodore J. Williams, David K. Denton, Douglas F. Scott

Highly stressed rock in stopes continues to be a primary safety risk for miners in underground mines because this condition can result in failures of ground that lead to both injuries and death. Personnel from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health studied two methods for identifying stress in rock. A seismic tomographic survey, finite-difference analysis, laboratory measurements of compression wave (ultrasonic) velocities in rock cores, and site geology were integrated to evaluate the use of seismic tomography for identifying induced pressures in an underground pillar at the Edgar Mine, Idaho Springs, CO. Electromagnetic (EM) emissions were also investigated in the Galena Mine, a deep underground mine in Idaho, in an effort to determine if these emissions could be used as indicators of impending catastrophic ground failure. Results of this research indicated that (1) seismic tomography appears to be a useful tool for determining relative stress in underground pillars, while (2) EM emissions do not appear to be significant precursors of impending catastrophic ground failure.

Jan 1, 2004