Search Documents

By S. Usui

In a previous article1 the methyl stretching vibrations for a series of xanthates and amines were reported, and the frequency of the methyl stretching vibrations in a homologous series of the alkyl compounds were shown to decrease exponentially with chain length and approach a limiting value corresponding to that of saturated hydrocarbon beyond six or seven carbons. These observations were explained quantitatively by the theory of Goto and Takenaka2 who proposed an equation relating the frequency shifts to the inductive effect of polar groups. As a result, the alkyl groups in the shorter chain heteropolar compounds were interpreted as becoming somewhat polar, and a good correlation was observed between the CH3-stretching frequencies and such surface chemistry parameters as contact angle, surface tension lowering, solubility, and critical micelle concentration" The substitution of fluorine atoms, the most electronegative of all atoms, for the hydrogen atoms in alkyl groups was expected to reverse the direction of the inductive effect within a heteropolar molecule, and its effect on the C-F stretching frequency shifts and on some surface chemical properties became of interest. In a recent study the C-F stretching frequencies of a series of normal perfluorocarboxylic acids and a few 1,1' -dihydroperfluoro alcohols were determined as a function of chain length and the results were compared with the corresponding hydrocarbon analogs. Furthermore, the nature of the induced polarity in the hydrocarbon and fluorocarbon groups was investigated through surface potential measurements at the interfaces of air-aqueous solutions of normal butyl alcohol and of l,l'-dihydroperfluorobutyl alcohol and through differential capacity and electrocapillary measurements at the interfaces of mercury-aqueous solutions containing the above two alcohols. Experimental Normal perfluorocarboxylic acids and 1,1' -dihydroperfluoro alcohols were provided through the courtesy of the 3M Company, St. Paul, Minnesota. Normal butyl alcohol was purchased from Distillation Product Industries, Rochester, New York. A Perkin-Elmer Model 621 infrared spectrophotometer was used to investigate the spectra in the frequency region of 1200 to 1270 cm-l with frequency scale

Jan 1, 1971

By K. Takahashi

The methyl stretching vibrations for a series of normal and iso xanthates were determined using an infrared spectrophotometer, and the results were compared with the published information on the corresponding alcohols. The frequency shifts of methyl stretching vibrations may be attributed to the inductive effect of polar groups. The hydrogens in the shorter chain alkyl groups are somewhat polar and can be expected to interact with water molecules by hydrogen bonding. Contact angle, surface tension lowering, and solubility appear to be related to the induced polarity of the alkyl groups.

Jan 1, 1968

By J. Trow

Dowsing is really IESG which inductively locates electric gradients (dv/dx) on the flanks of SP anomalies. "Sensors" are in one?s head. The "meter" consists of one?s body, limbs, and two $.69 welding rods. The method was calibrated near Mamainse Point, Ontario, where IESG-negative chalcopyrite-bornite-chalcocite-native copper ores reveal mineral zoning related to the IESG-positive Keweenaw fault, down which oxidizing solutions moved. In Michigan, the IESG-positive Keweenaw fault suggests that oxygen-bearing solutions from the Jacobsville Sandstone moved downward to oxidize hydrothermal sulfur to produce native copper, and to supply sufficient water to satisfy Walter White.

Jan 1, 1992

By A. B. Stewart, I. J. Barker

Traditionally it has commonly been believed that the only problem with inductive reactance in a submerged-arc furnace is that it leads to difficulties with the electricity supply as a result of the Iow power factor. This paper sets out to show that inductive reactance can also give rise to the following problems in the metallurgical operation of a furnace: (i) dead and live phases (fairly well known in openarc furnaces), (ii) lack of sensitivity to electrode movement, (iii) interactions between electrodes. These problems increase with increasing inductive reactance relative to resistance, and thus they increase with furnace size. Each of these effects is discussed in detail, and suggestions are made for their alleviation.

Jan 1, 1980

By Edgar E. Vidal

The deposition of ceramic materials onto substrates is of special interest in the development of surface related technologies. Research interest has been placed on using thermal plasma as the deposition method, specifically inductively coupled plasmas. Many different modifications to the same basic principle of deposition have been performed through out the materials research community. Such a technique may have many advantages over more conventional techniques, such as high deposition rates, high surface area coverage, clean energy source, no contamination from electrodes and operation near atmospheric pressures. Materials deposited vary from simple oxide systems like TiO2 to more complex structures like ternary oxides and nitrides. This paper reviews recent developments relative to the inductively coupled plasma deposition of thin films.

Jan 1, 2003

By P. R. Taylor

Diamond films have been successfully formed in an inductively coupled plasma (ICP) chemical vapor deposition (CVD) system from several gas mixtures: CH,-H,, C2112-112, and C2112-112-02' Our previous thermodynamic study indicated that the substrate temperature could be lowered by the presence of oxygen species at moderate system pressures (0.3-0.5 atm) and that higher volumetric growth rates required a high temperature source and a moderate pressure system in CVD processing. The principal experimental results were consistent with the thermodynamic predictions. The deposited films were characterized by laser Raman spectroscopy, scanning electron microscopy, and X-ray diffraction. The films were well faceted and uniform, with the growth rates over 10 pm/hr on molybdenum substrates. The crystal size ranged between 1 and 2 microns for a two hour experiment. It was possible to decrease the substrate temperature to below 800 °C in this system.

Jan 1, 1995

By Robert J. Kuhne

The Iron Ore Company of Canada has successfully employed advanced process control (APC) to optimize the operation of their induration machines. A significant increase in machine throughput and a reduction in fired pellet quality giveaway were observed following the APC implementation on all six machines. This paper discusses the opportunity for process control optimization in induration, reviews the property estimation and multivariable control technologies, and describes how the IOCC control strategy captured this opportunity. APC performance data is presented. The dependence of APC performance on control room operator acceptance, process equipment and instrumentation is highlighted.

May 1, 2007

By M. Bhandari, D. Norval

The bulk of plain carbon steel is produced through conventional Basic Oxygen or Electric Arc Furnace routes where the development of the AC Ladle Furnace has made it possible to also produce alloy steels. Smaller Ladle Furnaces have limitations such as lower efficiency; high electrode consumption and diminutive yields rendering them uneconomical to operate and making the processing of low carbon steel grades difficult due to carbon pick up. The demand for special steels and alloys with strict specifications is increasing while commodity prices remain competitive. The production of special steels and alloys have specific process control requirements and the development of the induction melting furnace (IMF) has made it possible to produce smaller batches economically. Refining and alloying of the melt in the IMF further enhance the efficiency. The INDUREF furnace offers increased productivity and flexibility through increased thermal efficiency and can be utilised for holding molten metal for further processing such as granulating, atomising, nitriding, alloy additions and desulphurisation of Ferro-alloys and steels. The system utilises a specially engineered ladle which is placed in an induction-heating assembly comprised of a stationary water-cooled copper coil and lamination packs. The addition of equipment for vacuum degassing and decarburisation of steels and alloys is also feasible. Benefits are: ? No electrode consumption or carbon pick-up ? Lower installation, operation and maintenance cost. ? No line-flicker facilitates operation on a weak power grid. ? Good power factor and balanced load ? No skull formation and reduced refractory consumption ? Higher yield of Fe-alloys ? Automatic controlled stirring

Jan 1, 2004

By D. E. Gorse, R. G. Anderson

"Indusmin's history dates back to 1937 when they developed the Blue Mountain Nepheline Syenite deposit at Nephton, Ontario, and began supplying material for the glass, fiberglass, paint, ceramics and rubber industries.Since then, as a subsidiary of Falconbridge Nickel Mines, Indusmin has expanded the Nephton operation, diversified into the aggregate quarries for the construction industries, with operations at Acton and Halton, Ontario, established silica plants at St. Canut, Quebec and Midland, Ontario, to supply the glass, carbide, ceramics, cleanser and concrete products industries, and the purchase of a foundry, Fahramet Limited, Orillia, Ontario, supplying steel and alloy castings to the mining, construction cement and petrochemical industries.Indusmin also has a Technical Resource Centre and Head Office facilities in Toronto.As this paper deals with Indusmin's experience with dust abatement, and although dust control is a concern at the Nephton, St. Canut and Orillia plants, we will be confining this paper to the experience gained at the Badgeley Quarry and Midland plant of the Ontario Silica Operation."

Jan 1, 1980

By Dinesh Goyal

Industrial fly ash from (electro static precipitator) was mixed with soil at different levels on v/v basis for raising of pulpwood tree species. In field trials conducted on degraded soils increase in the plant growth of Eucalyptus tereticornis, Acacia auriculiformis and Casuarina equisetifolia by 10 %, was observed during the initial six months after plantation at 18-24% (v/v) fly ash concentration which was at par with chemical fertilizer treatment. Level of As, Se and Mo in flyash was 6.2, 3.6 and 4.0 ppm respectively. The radioactivity analyses 40K, soil and 28 fly ash showed that the activity levels of gamma emitting radionuclides K, Ra, Ac were within the permissible limits and mixing of fly ash with soil at tested concentration would have no deleterious effects. Available Co, Cr, Ni and Cd in rhizospheric soils were below detection limit. Fly ash at 10-20 % level (v/v) was also found to be a good potting mix material in forestry nurseries in terms of improving biomass production by 20 %, when tested in nursery seedlings of Eucalyptus tereticornis. Nursery addition of fly ash in soil decreased soil dehydrogenase activity and the soil bacterial population was negatively affected. These results indicate that use of fly ash in forestry sector involving nursery and plantations as a soil amendment agent upto 10-20 % v/v is a gainful utilisation of fly ash.

Jan 1, 2002

By Corby G. Anderson

In nature, mercury is quite commonly found in association with antimony ores. This can be as a separate mineral such as cinnabar or in direct association with the antimony ore. The most common antimony-mercury mineral is livingstonite that occurs in places such as Algeria, Mexico, USSR and China. In the Roznava deposit in eastern Slovakia, tetrahedrite ore containing mercury ore has historically been processed pyrometallurgically for its silver and copper values. As well, in Tajikistan, major antimony deposits there contain significant mercury ore concentrations within the stibnite ore body. The mercury contained in these materials poses both a processing and environmental challenge. This paper will outline the processing of these types materials by industrial alkaline sulfide hydrometallurgical methods. The economics relevant to this potential application at Roznava in Slovakia will be outlined.

Jan 1, 2003

By V. A. Kharchenko, V. M. Yeremeev

INITIAL PRECONDITIONS To solve tile problem of using the potential reserves of the different coal ranks efficiently (the coal reserves being many times superior in quantity to those of natural gas and oil) one must realise an integrated estimation of the coalfields' and coal deposits' reserves. The actuality of this problem increased especially in the recent years, when the Russian coal industry is being restructured. A structural reorgaisation of this industry, in order to in- crease its efficiency, covers a large spectrum of social and economic problems, comprising a withdrawal from mining the coal reserves that are unsafe from the standpoint of economy and labour protection. According to the information supplied by the 'Rossoogol' company, the Russian coal industry, accounting for abut a fifth of the world coal reserves, has a rather unsafe resource base, for about 5% of the reserves involved in mining do not correspond to the world practice conditions, regarding the coal grade, thickness, geological conditions, proneness to coal and gas outburst hazards. These concern first of all the Moscow, Kizelovsk and Donetsk coal basins, the Prokopievsk-Kiselevsk district of the Kuzbas basin and several other coalfields. Thus, the problem of efficient potential coal reserves' utilization calls for a paramount solution of two basic problems, namely: a) a comparative coalfields' and sections evaluation, and their ranging, in accordance with their industrial importance; b) choosing the 'active' reserves good to be efficiently mined under the present-day conditions. PRINCIPLES OF EVALUATION The investigations that had been carried out make it possible to formulate the following basic principles of the coalfields' reserves' estimation (or assessment). 1. The necessity, possibility and expediency of coal reserves' industrial exploitation are determined by a set of natural, technical, technological, practical, economic, environmental and social factors, thus calling for an integrated and gradual approach to problem solving. 2. One cannot consider the results of same reserves' estimation as being invariable because the former depend both upon constant (mainly natural) and market demands for different grades of coal (those of different power engineering and technological situations), capital investments, material and labour resources, economic (price-forming), technical, technological, environmental and other factors. 3. The rational size and sequence of the operating mines' and reserve sections' resources' involvement into mining depend upon the final aim of posing the problem, whose variants may be (the corresponding limitations being considered) providing for a maximum run-of-mine output (these essentially featuring the past stages of the industry's evolution); providing for a maximum efficiency, measured possibly by the specific or absolute indices of profits an expenses, labour productivity e. al. ; providing for a maximum extraction (maximum integrate utilization) of the known reserves. In this case an important park goes to the economic evaluation (or assessment) of useful application of the by-products being extracted (methane, mine water, rack) compared to the expenses necessary for their utilization. Regarding the steam coal (posing the problem any way it be possible), and extreme limit to the absolute non-efficiency of the coal reserves' exploitation may be posed, using the proportion of energy obtained from the possible amount of the coal to be extracted to the energy consumption necessary to extract, prepare, haul and consume this amount of coal. 4. The most reliable and efficient solutions providing for opening the reserves can be obtained for group of mines, rather than at the level of an individual mine section or an individual mine because it is only in the former case that the possibilities to re- distribute the expenses necessary to develop the good for mining and worse sections and seams can be realized to the greatest extent. Therefore the prospective approach to be considered is the one providing for an integrated organization and choice of the optimum combination of the variants of the ways to use the mines in operation and the free sections of the region in order to satisfy the growing up requirements for coal rather than the one providing for individual mine sections' resources' evaluation. 5. The future possibility and expediency of coal reserves' industrial exploitation will depend upon the prospects to implant at the mines in operation and reserve sections new engineering and technological elements and coal extraction technologies which may essentially change the actual idea concerning the coal reserves worth of being developed in an efficient way. For example, reserves not available to be exploited using conventional coal extraction technology may be regarded as potential resources for in situ gasification, e. g. the operating mines' reserves (non-commercial and non-mined commercial ones), balance and outside balance reserves of the free sections having proved not available to be mined using conventional coal-extraction technologies, as well as the non-extracted reserves of the abandoned and closed mines.

Jan 1, 1996

By G. M. Hutt

Introduction The major development of industrial minerals in Manitoba has been in building materials. 'The building-stone industry is developed far beyond the needs of the Province, and the well known Tyndall limestone is marketed over a wide area throughout the other provinces to Canada. Similarly, gypsum and gypsum products are produced in excess of local requirements and are exported to adjacent provinces. The crushed-stone, sand and gravel, limestone, and lime industries are sufficiently developed to supply the needs of the Province and, notably in the case of lime and lime-stone, there is a surplus for export to the adjacent provinces and to the United States. The manufacture of common brick is well established, but for face-brick and other clay products the Province is dependent largely on importations. Production of silica-sand will increase as Canadian markets become available through recognition of the utility value of the Black Island sand as foundry-sand and for other purposes. There is some possibility of the export of feldspar, of lithium ore and concentrates, and perhaps of salt. A considerable part of the Province has not been seriously prospected for industrial minerals and it may be expected that, as time goes on, other deposits of non-metallic minerals will be discovered and opened up, especially as the prairie provinces become more industrialized. At the present time, there is some activity in the southern part of the Province based on gas and oil indications. Whatever may be the outcome of this work, it should yield valuable information concerning the geological structure of the area.

Jan 1, 1934

By Dale Zacherl, Andreas Buhr, Rainer Kockegey-Lorenz

"The microporous calcium hexaluminate insulating material SLA-92 has been introduced as an alternative to refractory ceramic fiber and other insulating refractory materials. Key properties associated with this product include: high chemical purity, long term high temperature stability up to 1500 °C, low thermal conductivity up to 1500 °C, and high thermal shock resistance. The properties of the new material and various applications in the steel and ceramic industries have been reported in previous papers. The current paper summarizes the industrial application experiences with innovative refractories based on SLA- 92 and discusses potential new applications in various manufacturing as well as energyrelated industries.IntroductionSLA-92 was introduced to the refractories industry in 1998 by van Garsel, et al. [1] as a new insulating raw material for high temperature applications, followed by investigations [2] of long term temperature stability for this new lightweight aggregate up to 1500°C.SLA-92 was developed as an innovative alternative to commonly used refractory ceramic fibers. It has unique properties regarding chemical purity and mineral composition and is a microporous, silica-free calcium hexaluminate (CA6 – mineral name: hibonite)."

Jan 1, 2010

By Duane A. Houkom

Down time in the Oil Refining and Petro Chemical Industry is extremely expensive. Each day of non-production may easily cost several million dollars. Explosives have been accepted by this industry to solve many of its problems. Explosives offer a solution which is faster, more economical and most important, safer than many of their methods. Our specialties for these industries include: Refractory removal, industrial cleaning, metal cutting and concrete removal. This report does not include information on concrete removal.

Jan 1, 1982

By China University of Mining & Technology, Yuemin Zhao, Bo Zhang, Liang Dong, Zhenfu Luo, Chenlong Duan

"In China, approximately 65% of coal reserves are in the west region, where water shortage is a serious problem: high-efficiency dry coal beneficiation technology is desired. Using magnetic powder and fine coal as heavy medium, and using air as the fluidizing agent, a novel air dense medium fluidized bed separator is proposed for coal preparation. Coal can be efficiently separated according to density in the fluidized bed, where bed density is steady. The separator is highly reliable, the circulation quantity of heavy medium is low, and the gas distributor cannot be easily easily. The world’s first industrial modularized dry coal preparation plant was built by China University of Mining and Technology. Dry coal beneficiation technology was first used to produce low-ash coal. Results of industrial production show that the ash content of clean coal is 3.46%, the probable error E value is 0.055 g/cm3, and the organic efficiency is over 90%. The advantages of the modularized dry coal beneficiation system are the high separation accuracy, the simple process flow, the low operation cost, low energy consumption, and so on. This technology provides a new effective method for coal separation in acid region and coal tending to sliming.INTRODUCTIONCoal is the most important primary energy source in China, where coal output reached 3.68 billion tons in 2013 and represents approximately 68% of the primary energy consumption. Coal has made a great contribution to the development of the Chinese national economy, but it also brings serious environmental pollution. However, approximately 65% of coal reserves are in the arid west region in China where water shortages present a challenge for wet coal preparation technology. In addition, the abundant lignite resource, because it is easy to mud in the water, should not be treated with the wet separation method. Therefore, it is critical to develop highly efficient dry coal preparation technology to meet the demand in arid areas. Further, water resource shortages are a global problem, thus the development of efficient dry coal preparation technology in has potential application in other water-short countries like South Africa, Brazil, India and Turkey."

Jan 1, 2016

By Marko Oosthuizen, Charl P. Botha, Lidia Auret, Annelette Malan, Marthie de Leeuw

Flotation performance is affected by upstream disturbances (e.g., mineralogy, water quality, flow rate) and controlled variables (e.g., pulp level and air addition). Process disruptions can lead to undesired conditions, such as pulp overflowing flotation cells (with insignificant/absent froth, and thus no valuable mineral concentration). Early detection and appropriate intervention of pulping events improves concentrator performance. An approach to real time flotation pulping event detection by means of convolutional neural networks is presented, including a case study of the industrial application of this technology on three flotation banks.

Feb 22, 2026

By T. C. Rao, Vanangamudi. M., J. P. Barnwal

Experiments were carried out on 76 mm laboratory heavy medium cyclone treating -2.0 t 0.5 mm coal and on two 600 mm industrial heavy medium cyclones treating coal in the size range -13.0 t 0.5 mm. The variables studied were spigot diameter and feed medium gravity. The generalised distribution curve for the separation of coal in these heavy medium cyclones has been defined by the equation [ ] The specific gravity of separation SG has been found to increase linearly with increase in feed medium, gravity (SGf). The relationship for SG of industrial cyclone is given as 50 SG = -6.801 t 6.463 SGf t 0.0327 Spig 50 -0.02625 SGf. Spig. Further, the probable error for the separation has been found to be linearly related to (SG50 - SGf ) according to the equation [ ] The model equations developed have been used to select appropriate levels of operating conditions to achieve an increase in the yield by about 2 to 4% without affecting the quality of the product.

Jan 1, 1990

By Yuhe Tang

High Gradient Magnetic Separator with Horizontal Magnetic Line is a new type High Gradient Magnetic Separator product. It has many specific advantages, such as water-air joint discharging technique, double pulses pulp dispersion technique, multi-magnetic gradient for collecting matrix with different diameter rods, better discharging rate with the especial matrix dispose, high separating accuracy and wide applicability. In this paper, the author makes a description of High Gradient Magnetic Separator with Horizontal Magnetic Line, and puts its emphasis on analyzing industrial production data using high gradient magnetic separator with Horizontal Magnetic Line to separate weakly magnetic minerals. It is found that as the rougher for weakly magnetic minerals separation, High Gradient Magnetic Separator with Horizontal Magnetic Line has more stable metallurgical performance and cheaper running costs than other types of High Gradient Magnetic Separator when the properties of the ore change greatly and there is in the case of embedded fine particle size distribution. Keywords: high gradient magnetic separator, self cleaning technology, horizontal magnetic line, water air discharging technique

Sep 1, 2012

Natural gas was introduced to the Melbourne reticulation system in April 1969 and since that date sales to industrial consumers in the Gas & Fuel Corporation of Victoria area of supply, have increased by over 50% This increase has occurred despite the fact that the areas in which the new fuel is available have been dependent on the progress of the conversion operation from manufactured gas. The half way mark for conversion was reached in May 1970. The reason for the adoption of natural gas by industrial users is usually the result of objective financial analysis leading to the conclusion that the new fuel will give the lowest overall production cost. Many factors are involved in such an analysis of which the price of the fuel is only one. Amongst other important elements in the cost calculation are:- -ò òò -(1) The effect of fuel on product quality (2) Maintenance and handling costs for alternative fuel. In addition to economic gains for the individual user, the use of natural gas should benefit the whole community through its effect on such things as, air pollution and overseas balance of payments.

Jan 1, 1970