Search Documents

By Kenneth N. McLeod, Donald W. McGlashan

In the use of free bubbles with precise temperature control and continuous pH measurement, the contact angle apparatus differs from all previous equipment. Experimental procedures differ sharply from the captive bubble method of introducing the gaseous phase in the three-phase system. When freed from the tube and captured by a solid surface, a bubble more closely conforms to the spherical ideal set up by the usual mathematical analysis of surface free energy or surface tensional relationships of the forces involved. The assembled equipment, Fig. 1, departs from the usual contact angle apparatus in providing: 1) water circulation for fixing temperature, 2) instruments to measure and record pH during testing, and 3) a system for producing and using free bubbles. The apparatus allows testing over a broad range of closely controlled conditions, and the use of free bubbles gives contact angles independent of operator manipulation, which was unavoidable in the older captive bubble method. A bubble released below the specimen rises through the liquid and contacts the mineral. If the mineral is gas-avid the bubble adheres, developing a finite contact angle.

Mar 1, 1956

By Jacob Grasmick, Bill Newns

Despite ongoing digitization and “hardware” technological advances, geotechnical uncertainty remains the most significant risk in underground and tunnel construction. And, whilst they are commonly held up as an example of the sophistication of the industry, the practice of drafting and using geotechnical baseline reports is subject to a wide range of influences, not all of which support good risk management. Uncertainties in predicting ground behavior, the gap between the pre-construction assumptions, and the systemic response to construction remains a significant technical and communication challenge. Accordingly, this paper presents a framework to quantify geotechnical uncertainty using geostatistics and translate these into practical tools for ground risk management throughout planning, procurement and construction. Adopting even some of the principles of this framework should provide improvements to contract risk management and should assist to minimize the potential for commercial losses.

Dec 1, 2022

By A. Mcdonald

"An X-Met Analyzer was purchased from Outokumpu in late 1983for use in the Hudson Bay Mining and Smelting smelter. Its first use was in the fuming plant to give zinc assays of each charge of slag tapped from the fuming furnaces. This quickly told the operators exactly when each charge had reached its economic tap-out point, and gave supervision a fool-proof method of identifying good operation. These and other factors led to major improvements in coal utilization in the fumers and to major increases in zinc oxide production. A second unit was later purchased for the reverberatory furnace to give silica and iron assays of the slag, and these were used to make adjustments in the feed composition to maintain the desired SiO2:Fe ratio in the slag. Since purchasing the units for the furnace, the oil consumption and copper content of the slag have dropped significantly. IntroductionSmelters have lagged far behind concentrators in process control by mean s of rapid product analysis. The on-stream X-ray analyzer was developed about seventeen years ago, and soon concentrators around the world were getting assays of the incoming ore, .concentrates and tailings every fifteen minutes, and using these to control reagent additions and other process variables. Almost always, the concentrate grade and recovery improved.In smelters, product streams are solids or molten materials, not the more easily handled slurries, and until seven years ago no inexpensive equipment was available to provide rapid analysis of this type of material. In approximately 1980, several companies developed instruments based on irradiating solid samples with low-intensity gamma rays from radio-isotope sources, and measuring the secondary X-rays emitted from different elements in the sample to provide an analysis of the elements desired.The smelter staff had a close look at what was needed and listed the following points as being critical:1. ability to provide Zn assays of a sample of slag within 15 minutes of taking it, in order to achieve optimum fuming times (zinc fuming , being a batch process, had the greatest potential benefit from rapid slag analysis);2. ability to give Cu and Fe assays on the slag, and on other smelter products, such as matte and converter slag;3. ability to give Si02 assays since the SiO2 content of the slag has a strong effect on fuming rate; and4. ability to stand up to an industrial atmosphere such as exists in the fuming plant."

Jan 1, 1987

By J. L. Gaigher

A simple mineralogical regression model is described, which was devised in order to help the flotation plant cope with rapidly changing headgrades and feed mineralogy. Minerals in the feed were determined by means of quantitative X-ray diffraction and compared with plant performance parameters and flotation reagent consumption rates, using regression analysis. A mineralogical regression model for predicting recovery served to motivate flotation plant personnel and also set standards whereby flotation performance could be measured. The reagent consumption model indicated in which direction any or all of five flotation consumption rates should be altered. All practically measurable parameters, even those showing poor or no correlation, were included in the model, provision being made for the continuous update of a batch of data of 30 lines. Compared with the method of multiple linear regressions, the r2 is poorer at 0,41 (versus 0,50), but the mean standard error of estimate for both methods is identical at ± 6,6 units. The regression model is simpler than the method of multiple linear regressions, and although the accuracy of prediction is not high (41%), the mineralogical regression model proved to be successful in practice. Flotation efficiency, as measured by the mean ratio of head to tails grade, for the 9 month period after the mineralogical regression model was implemented on an hourly basis, improved from 2,8 to 3,2, which is equivalent to an improvement in average flotation recovery of 5% relative.

Jan 1, 1987

By J. -P. Nepper

It has been possible to largely contain converter aisle emissions of SO2 and fumes in the case of batch-wise operated Peirce Smith converters during normal blowing periods with the help of suitably designed primary hoods. Controlling the escape of off-gas during the periods of turning the converter in or out of the stack has been problematic in the past. Effective automated control systems have been developed for the purpose and successfully applied in smelter operations in Spain, Taiwan and Germany. This has led not only to an effective reduction of emissions in the converter environment but also to an improvement in the converter operation.

Jan 1, 1992

By J. -P. Nepper

It has been possible to largely contain converter aisle emissions of SO2 and fumes in the case of batch-wise operated Peirce Smith converters during normal blowing periods with the help of suitably designed primary hoods. Controlling the escape of off-gas during the periods of turning the converter in or out of the stack has been problematic in the past. Effective automated contro1 systems have been deve1oped for the purpose and successfully applied in smelter operations in Spain, Taiwan and Germany. This has led not only to an effective reduction of emissions in the converter environment but also to an improvement in the converter operation.

Jan 1, 1992

By R. D. Prengaman

Wrought lead-calcium-tin anodes developed by RSR Corporation have improved the performance compared with the other lead alloy anodes. These anodes have been in continuous service at various locations around the world for as long as fourteen years. Calcium provides mechanical strength to the anode to prevent the deformation while tin increases the mechanical strength, reduces the rate of corrosion, prevents the formation of non-conducting layers on the anode surface, and dramatically improves the conductivity of the anode. Tin is also instrumental in developing the unique rolled structure of the anode which leads to the reduced rates of corrosion, longer life, and improved oxygen evolution. Cobalt additions to the electrolyte further enhance the oxygen evolution and improve the anode life. Higher current densities and higher operating temperatures reduce the anode life. The unique patented method of attaching the rolled anode sheet to the bus bar substantially reduces the resistance of this important joint and offers the substantial savings in power over the life of anode.

Jan 1, 1999

By W Taylor, S Chen, R Haywood, M White, R West, J Ranasinghe

In March 2012 a combined BHP Billiton and Hatch team embarked on a program to improve the concentrate burner efficiency of BHP Billiton’s Olympic Dam copper flash smelting furnace. A multi-faceted approach including an analysis of the furnace using operational knowledge and first principles engineering led to the design and supply of a new central-lance (disperser). A new, patented, swirl method of introducing the copper concentrate into the furnace was developed to integrate with the existing concentrate burner. Plant trials in 2014 demonstrated an increase of nearly 10 percent in the oxygen efficiency of the furnace. The improved efficiency is expected to provide savings in operating costs and asset life extension of downstream gas and dust handling equipment.CITATION:White, M, Haywood, R, Taylor, W, Chen, S, Ranasinghe, J and West, R, 2015. Improved copper flash smelting at Olympic Dam, in Proceedings MetPlant 2015, pp 382–395 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 7, 2015

By Eugene Jak

Copper sulphide processing technologies face increasing pressures associated with decreasing concentrate grade leading to increasing thermal inefficiency and lower productivity. Impurity concentrations are on average increasing, creating potential environmental risk and additional treatment costs. In copper flash smelters dust, partially oxidised materials and fume formed from the condensation of volatile impurities, are routinely recycled to the feed. In the converting stage the heat balance is maintained by charging anode reverts and other inert materials. In both cases, the thermal energy available from sulphide oxidation is not fully utilised or optimised. The productivities of both smelter and converter stages can be potentially increased through the addition of a high copper, low iron, low impurity precipitated copper product. Calculations are carried out for fayalite smelter and calcium ferrite converter slags using an optimised FactSage thermodynamic database. The potential for significant increases in smelter and converter productivities using existing technologies are predicted.

By J. J. Taute, G. Chisakuta, P. Bwando, G. Mitshabu

"BASF Mining Solutions have developed a new generation of copper solvent-extraction reagents that offer significant benefits over the existing reagents available to the industry today. Initial laboratory studies and pilot-plant trials have shown that these new reagents offer the benefits of a dramatic increase in resistance to degradation and are nitration-proof. This paper details a recent pilot-plant campaign at a commercial solvent-extraction plant. The main focus was to evaluate the copper/iron selectivity, copper recovery and net transfer of the new reagent compared with the conventional oxime reagents. The new reagent displays similar copper recovery and net transfer capabilities from typical agitation leach solutions. The pilot-plant results show a step change improvement in copper/iron selectivity in comparison with the existing modified and non-modified hydroxyoxime reagents used on the commercial plant. INTRODUCTION Copper solvent extraction (SX) from an acidic aqueous solution is typically accomplished using a hydroxyoxime extractant (Jergensen, 1999; Kordosky, 2000; Szymanowski, 1993). There are three hydroxyoximes from which all standard formulations are derived: 5-nonyl salicylaldoxime (NSAO), 5-dodecyl salicylaldoxime (DSAO) and 2-hydroxy-5-nonyl acetophenone oxime (HNAO). In the case of NSAO, it is necessary to use equilibrium modifiers in order to increase the copper stripped from the extractant (Kordosky & Virnig, 2003). Blends of DSAO, NSAO and HNAO are used to cover a wide spectrum of conditions (Kordosky, 2008). Use of modified aldoximes and reagent blends over the last 30 years has influenced the way copper producers and equipment manufacturers have approached the operation of copper plants. Existing solvent-extraction reagents cater for typical pregnant leach solutions (PLS) of copper mining systems which do not have significant effects on the reagent. Table I illustrates the range of copper concentration, pH values, temperature and iron concentrations for different leaching operations. As conditions become increasingly aggressive (i.e., higher PLS temperatures in primary sulfide leach or high iron content), current reagents become less capable of functioning according to expectations. One example is the effect of high iron (Fe3+) concentration in PLS and operating SX to achieve high copper recoveries. The ferric is partially chemically extracted and is transferred to elctrowinning (EW) during the stripping stage. To avoid a build-up of iron in electrolyte, which negatively affects current efficiency, a bleed of electrolyte is required. This bleed leads to excessive consumption of reagents, such as cobalt added to the EW process, and thus increases operational cost."

Jan 1, 2015

By A. L. Grabovski

The potential of eccentric cone crushers for fine crushing has been improved by increasing the swing frequency of the moving cone, balancing the crusher, ensuring uniform feed via a rotating funnel with sideways discharge, introducing hyperbolic motion and employing the inertia crushing method, but further improvements to the specifications of existing cone crusher designs are limited by the rigidity of their kinematic coupling. A new design has been developed which combines two crushing modes, stone on liner and stone on stone, each with its own advantages. The main aims are to produce finer materials and to reduce liner weight. The benefits include an increase of more than 10% in the output of fine particles, improved protection of the liner against wear, as a result of filling of the cavities by material being crushed, and the use of almost 20% less material in casting of the liner. The chamber can be used in place of the usual liners of fine cone crushers

Jun 21, 1905

By Tullio Corsini

Scrap battery recovery process, developed by Engitec Impianti S.p.A., is improved transforming batches operations in continuous. Benefits expected: constant and better quality of the products; easier and more reliable control of the operating parameters, reduction of manpower requirements. Paste will content less sulfate, particularly in soluble form. Sodium sulphate is obtained with higher and constant purity.

Jan 1, 1993

By Miller M. J, Bauer J. C

The continuous copper drossing process operated at Port Pine since 1962 has had limited copper removal capacity as determined by a maximum tolerable Cu/S ratio in feed and the level of sulphur in blast furnace bullion. Recent process development has been to overcome these limitations to meet increased copper throughput requirements. A sulphur addition system was developed and installed in August 1987. The system has capacity to increase sulphur input by over 150%, meeting the increased copper capacity requirement and also allowing independence from the upstream process for sulphur supply. Developments in process understanding have been applied within the limitations of the existing furnace design with a 10% increase in the maximum tolerable Cu/S ratio.

Jan 1, 1989

By J. L. Nebreda, Z. Fan, J. B. Patel

"A380 alloy has been widely employed to produce thin-wall components via high pressure die casting (HPDC). During HPDC processing, there is a significant problem of property variation even with the very stable and precision automated casting procedure. The enlarged variation lowers the component performance and affects the steady and uniform property distribution along the whole component. In this study, high shear melt conditioning technology was developed and applied to the melt prior to pouring into the shot sleeve. Experimental results show that with application of intensive melt shearing, the variation of elongation was decreased from 21.8to 13.9%, and yield strength variation was reduced from5.5to 3.6%. The improved property variation is attributed to enhanced nucleation both in shot sleeve and the die-cavity, and to the improved distribution of porosity and secondary phases as a benefit of high shear induced grain refinement. With application of high shear, large number of the Spinel phase (MgAl2O4) particles with double size distribution in average diameter of 80and 300nm were formed. Due to the good orientation relationship and small misfit between alpha Al and MgAl2O4, the particles act as the effective nuclei in shot sleeve and die cavity, respectively.INTRODUCTIONA380 alloy had been widely used for produce automotive components by cold chamber high pressure die casting(HPDC) processing, due to its relative good mechanical properties and cast ability performance, and more important most of A380 ingots were produced by recycled Al alloys. Therefore, to promote utility of A380 will contribute to reducing emission of CO2and to the lightweight of automotive industry as well. When cold chamber HPDC was employed to produce the components, the mechanical properties of A380 alloy always have a distribution range (named variation herein), or in other words the properties were not stable. The reason was ascribed to the typical solidification characteristics occurred in HPDC processing. During HPDC processing, there are three steps of melt movement. The first step is that the melt was poured into shot sleeve at temperature of about 680°C, in which shot sleeve was preheated by few shots of melt filling, or by heater. During step one, the first solidification of melt was happened in shot sleeve and about 20% solid made of coarse a-Al grains was formed(Li, Xiong, & Guo, 2016).Such kind of grains will retain in the final products and deteriorate the properties variation. The second step is that the melt was forced moving forward slowly by plunger at about 0.2–0.3m/s until the liquid melt front to the inner gate of mold. The third step is that the melt moved very fast to complete the filling of die cavity and refilling the solidification shrinkage by fast movement of plunger about 2–3m/s. The second solidification was occurred in die cavity and fine a-Al grains will be formed by high cooling rate at about 500–1000°C/s. From the solidification point of view, the grain size was dominated by nucleation and growth. When HPDC was employed to produce components, the melt quality becomes the priority factor to control the solidification process as the other casting parameters were kept at the same."

Jan 1, 2018

By Z. T. Bieniawski

This paper presents the results of a survey of room and pillar dimensions and design practice in U.S. coal mines aimed at improving the design procedures in room and pillar mining. A review is given of the current pillar strength formulas and suggestions are made for better utilization of research results in engineering practice.

Jan 1, 1981

By Z. T. Bieniawski

The efficient and safe design of room-and-pillar coal mines still remains as one of the pressing problems facing the mining industry in the United States. Present day design is a trial-and-error approach based mostly on experience. Although much research has been directed to stability of mine roofs and coal pillars, no generally-accepted design method has been formulated. This paper reports on a three-year research effort directed to an improved design of room-and-pillar coal mining in the U.S.A. Essentially the study consisted of three aspects: (i) determination of stable roof spans; (ii) determination of the strength of coal pillars; and (iii) determination of safety factors for room-and-pillar coal mining in the United States. Furthermore, three novel approaches were utilized during this research: i) the "petite sismique" technique was assessed for possible determination of coal pillar deformability ii) the "Geomechanics Classification" was extended for determination of safe roof spans in room-and-pillar coal mining. iii) a national survey of the current design practice and mining dimensions was performed with the aim of assessing factors of safety for room-and-pillar coal mining The outcome of this work, which is summarized in this paper, is a design code for room-and-pillar mining in the United States.

Jan 1, 1983

By C. E. Silverblatt

The advent of larger quantities of -1/4 inch coal in the raw feed to the preparation plant and the necessity of recovering this material has made the problem of meeting product moisture specifications more difficult. For a number of years thermal dryers have been used advantageously as a means of reducing fine coal moisture content where the over-all economics would justify such an installation. However, these units are not without their drawbacks because of high capital and operating costs, safety hazards and possible degradation of the product, and thus an alternative method of moisture reduction is highly desirable. After the various mechanical variables associated with filtration have been optimized, an examination of theory shows that surface tension and liquid viscosity are the only two remaining variables which might be altered to reduce moisture content.

Jan 1, 1964

By P. Mpofu

In this work, the modification of interfacial chemistry of colloidally stable kaolinite clay dispersion has been carried out to improve its flocculation performance and dewatering behaviour. Synergistic action between dispersion pH, hydrolyzable metal ion and high molecular weight polymeric flocculant structure type (anionic polyacrylamide-acrylate copolymer (PAM) and non-ionic polyethylene oxide (PEO)) was found to play a pivotal role in inter-particle bridging, the enhancement of the settling rate and extent of consolidation of the pulps. Flocculation with PEO led to higher settlings rates in acidic than alkaline pH, whilst for PAM, the maximum dewatering rate was achieved in the neutral pH range 6 - 7.5. Upon shear, the PEO flocculated pulps showed dramatic improvement in consolidation to 40 wt%, the extent of which was greater at lower than high pH values. For PAM-based pulps were however, not shear-responsive, lower sediment solid contents of 15 - 23 wt% was observed between pH 3 and 11. Hydrolysable metal ions, Mn(II) and Ca(II), used respectively at pH 7.5 and 10.5 in conjunction with PAM and PEO, significantly enhanced the settling rates and consolidation of the pulps. The findings exemplify the strong links existing between pH-mediated particle surface chemistry. polymer structure-conformation, inter-particle bridging and dewaterability of kaolinite dispersions.

Jan 1, 2004

By Carl-Oscar Nilsson, Åke B. Nilsson

"The embankment dam at Storfinnforsen is 23 m high and was completed in 1954. The dam has an impervious zone with timber sheet piles and a support fill of glacial till. The pore water pressure in the downstream shoulder has during recent years increased due to deterioration in the sealing function of the timber sheet piling. There is a concern that the high pore water pressure in the glacial till will cause internal erosion initiating at a thin coarse transition layer between the glacial till and the rock fill along the downstream toe. As a remedial action in order to improvement of the leakage resistance a supporting berm of coarse rockfill against the downstream slope of the dam was constructed in year 2013. In addition a new impervious seal in the centre of the dam e.g. a diaphragm wall was considered. However, after further studies and a trial stretch of 40 drains each 20 m long and diameter 0.3 m an alternative with vertical drilled drains in the downstream support was selected. A contract has now started up to drill in a similar way to treat the full length of the dam with drains. The work is in the planning to be completed in 2016.Dam ConstructionStorfinnforsen Embankment Dam was put into operation in 1954. The dam is 330 m long and maximum height is approximately 23 m. The dam is constructed with a central core zone and supporting zones of earth and rockfill on the upstream and downstream sides giving an almost symmetrical cross-section about the dam axis, see Fig. 1. The upstream slope is 2H:1V down to el. 270 and 2.5H:1V below. On the downstream side the slope is 1.75H:1V down to +269 and 2H:1V below. The core zone consists of a timber sheet pile wall with a Zone 5 of glacial till, approximately 2 m wide, adjacent to the wall on the upstream side."

Jan 1, 2016

By Liz Diaz, Tacio Ferreira

Capstone Copper’s Pinto Valley Mine faced challenges in recovering rock and ore on final walls because of geotechnical constraints that require restrictions on methods for loading blastholes adjacent to the pit boundaries to preserve wall stability. The operation had been using the same drill and blast designs for years. With changing geology, such as harder rock, as mining progressed, material was being left unmined in final walls because of poor breakage. The amount of unrecovered, unprocessed ore was estimated at approximately 380,000 tons a year generated from an average of 60 final wall blasts performed annually. The engineering team from Capstone and Dyno Nobel engaged to minimize the amount of material left on the final pit walls. This paper presents how we collected data, reviewed design standards, and found opportunities to improve ore recovery from pit final walls without increasing drilling and blasting costs. The results collected from implementing the new design on two benches showed the potential for extra revenue of approximately $3.6 million generated annually from reducing final wall unrecoverable underbreak by nearly 71% on the mine’s highwalls.

Feb 1, 2025