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By Jose F. Hevia

This study is part of a broader project on the hydrothermal conversion of copper concentrates to metallic copper by solid state reactions in which the copper remains localized in the solid phases. The kinetics of the solid/solid hydrothermal hydrogen reduction of tenorite (CuO) and cuprite (Cu,O) to metallic copper are presented. After an induction period, the process is governed initially by a nucleation step followed by rapid solid state reduction. Nucleation promoter agents decrease the induction period and control the particle morphology. Separate nucleation and reduction rate processes have been identified. Following nucleation, reduction follows a shrinking core process.

Jan 1, 1994

By J. Menashi, D. A. Douglas, A. S. Rappas

Aqueous solutions of Na2Cr04 are reduced with CO to produce hydrous Cr2O3 and NaHCO3/Na2CO3. CH3OH, HCOO- and HCHO in the presence of CO2 also reduce Cr(VI) and yield similar products. It is shown that the rate of Cr(VI) reduction can be represented by the expression -d [Cr(VI) ]/dt = k[Cr(VI)]0.5[R], where [R] is the aqueous phase concentration of CH3OH, HCOO- or CO. With these three reductants, the activation energies for the reduction processes are comparable and are of the order of 100 kJ/mol (43,000 Btu per lb mol). Rapid reduction rates are attained at temperatures in excess of 220°C (428°F). With these three reductants, a green acid-insoluble readily filterable hydrous Cr203, is formed. With HCHO, significant reduction of Cr(VI) occurs at about 80° to 100° C (176° to 212° F). The product is an acid-soluble violet modification of hydrous Cr203. Solutions of Na2CrO4 contaminated with Mo(VI) and W(VI) can be reduced to yield a Cr2O3 product with significantly reduced contaminant levels.

Jan 1, 1986

By I. A. Costa, Y. Fouquet, F. Barriga

"Lucky Strike and Menez Gwen are two hydrothermally active sites located along the border of the Azorean plateau, southwest of the Azores islands where the alteration processes affecting basaltic rocks are prominent (Costa et al., 2003). Here we report on a slabby brecciated rock, abundant at both Lucky Strike and Menez Gwen, composed mainly of basaltic fragments cemented by hydrothermal precipitates from warm fluid circulation system. Research reveals that hydrothermal alteration takes place mainly by replacement processes, in which silicification is dominant (Costa et al., 1997 and Costa, 2014).Petrographic observations, including scanning electron microscopy (SEM), microprobe analysis, and mass balance studies made on basaltic fragments within the breccia show that silicification is one of the main processes resulting from hydrothermal fluid circulation. This alteration process leads to complete replacement by silica, in extreme cases, forming an impermeable cap that may contribute to the formation of sub-seafloor sulphide deposits, including examples in the geological past."

Sep 1, 2014

By Chang Wei, Zhigan Deng, Jiqiang Liao, Minting Li, Hongsheng Xu, Yan Song, Cunxiong Li, Xingbin Li

"Abstract: Direct ?otation of oxidized zinc-lead ore is characterized by recovery of zinc and lead only around 55% and 50%, respectively. Mineralogical analysis shows that the sample used in the present study is a carbonate hosted zinc-lead ore, with a zinc and lead carbonate content that accounts for 80.14% and 75.63% of the total minerals, respectively. The carbonate hosted zinc-lead ore was hydrothermally sulfidized with elemental sufur and the experimental data indicated that under the conditions employed up to 75% zinc and 82% lead sulfidation extent were achieved. As a result of pre-sulfidation followed by flotation, the recoveries of zinc and lead into flotation concentrate were over 90%. A flotation concentrate was obtained with 52% Zn and 37% Pb from the materials which was treated by sulfidation.IntroductionSulfide ores are the primary source of zinc and lead, and they are becoming depleted; thus, metallurgical investigators are interested in using abundant oxidized zinc-lead ore reserves. The high-grade zinc-lead oxidized ore, which normally has a zinc content higher than 15%, can be disposed of by acid leaching and electrolysis. However, the low-grade ore, which has a zinc content lower than 10%, is difficult to smelt with pyrometallurgy and hydrometallurgy, and the processes are very complicated and expensive in terms of production flow and energy consumption. Therefore, making the low-grade oxidized zinc-lead ore more beneficial has become more important in recent years. Flotation is the most common process, and the primary method of recovering zinc and lead from sulfide or oxide minerals. It is well known that there is a difference between sulfurized and oxidized minerals regarding their separation by flotation. Flotation of zinc and lead oxidized minerals is extremely complex because of the similarities in the physicochemical and surface chemistry of the constituent minerals. There are no known direct-acting collectors capable of producing single metal concentrates [1-3]."

Jan 1, 2012

By Yang Hai-long, FAN Gang, LI Cun-xiong, WEI Chang, LI Min-ting, LI Xing-bin, DENG Zhi-gan

Hydrothermal sulfidation of pure cerussite with elemental sulfur has been reported in the present paper. The variables considered in the study were temperature, time, particle size and elemental sulfur fraction in the reacting mixture. Temperature was the most important factor at temperatures above 180 , PbS and PbSO4 were the only stable reaction products in the sulfidation of cerussite. The experimental data indicated that under the hydrothermal conditions with a particle size of -74+58 μm and sulfur fraction in reacting mixture of 15% at 200 °C for 120 min, and 92% of lead sulfidation rate was achieved.

Jan 1, 2016

By K. P. V. Lei

The U.S. Bureau of Mines investigated a hydrothermal sulfidation procedure to recover lead and silver from plumbojarosite. The plumbojarosite, generated during pressure-oxidative leaching of zinc concentrate in a commercial operation, contained, in percent, 25.4 pb, 18.8 Fe, 1.4 Zn, 29.5 SO,2-, 3.2 s?, 13.4 total sulfur, and 7.4 oz/ton Ag. The sulfidation was conducted in an autoclave and converted the plumbojarosite to amorphous iron oxide and liberated the lead and silver as sulfides. The best operating conditions were using 50 9 of plumbojarosite and 7 pct s? (2.04 9 S? added) in 500 mL of 2.0 mol/L NH3, 150? C, and 1 h. The sulfidation product contained, in percent, 37 Pb, 28 Fe, 6 S2-, 2 SO,2-, and 11.2 oz/st Ag. Ferric chloride leaching extracted 98 pct Pb and 97 pct Ag from the sulfidation product.

Jan 1, 1990

By Sophia Katsouri

Hydrothermal circulation that produces sulfide deposits in the marine environment can also produce sulfide deposits in lakes. The major differences in terms of process are (1) in lakes the hydrothermal fluid is meteoric water of low salinity whereas in the marine setting it is saline and (2) the rocks that are leached of metals to produce the deposits are continental crust in one case and oceanic crust in the other. We have examined sulfides that are presently forming in two lakes ? Lake Tanganyika in east Africa and Lake Oyunuma in Hokkaido, Japan. Tanganyika is the second largest lake in the world and the second deepest rift lake, after Lake Baikal in southeastern Siberia. Two hydrothermal fields are known in its northern basin at Pemba and Cape Banza (Tiercelin et al., 1993). At Pemba, CO2 and CH4-rich, low temperature (53-88°C) hydrothermal fluids are forming decimeter-tall chimneys at 2-46 m water depth. Our microscopic and x-ray diffraction study of samples from the Pemba site reveal marcasite and pyrite to be the most common sulfides. Minor minerals include barite, hematite, bornite and chalcopyrite. Quartz and feldspar are also identified and were probably incorporated from the surrounding lake sediments. At Cape Banza, aragonite chimneys, up to 70 cm high, are venting fluids at 66-103°C.

Jan 1, 2001

By Norihiro Murayarna

Hydrothermal synthesis of K type zeolite was carried out by using coal fly ash as a raw material and KOH as an alkali source. The change in various physical properties of the obtained zeolite, such as the kind of zeolite crystal, cation exchange capacity, surface structure of zeolite and particle size distribution were investigated through the overall reaction of zeolitization. The reaction mechanism of K type zeolite from coal fly ash was investigated from these results in this study

Jan 1, 2002

By Hideki Yamamoto, Norihiro Murayama, Junji Shibata

"Hydrothermal syntheses of zeolite from coal fly ash were carried out by using various alkali sources. NaOH, Na2CO3, KOH, K2CO3 and their mixture were applied for an alkali source of zeolite synthesis. The various physical properties of the reaction product, such as the kind of zeolite crystal, cation exchange property, surface texture and so on, was investigated through the zeolitization reaction from fly ash. The mechanism of zeolitization reaction was considered from these results.Zeolite P(NaP), hydroxysodalite(HS) and chabazite(K-CHA) are synthesized as zeolite species, when fly ash hydrothermally reacts in various alkali solutions at 393K. The crystal structure of the products obtained in NaOH solutions for 3h changes from NaP to HS with increasing NaOH concentration. K-CHA formation in KOH solutions needs 10h of reaction time, which is longer than that of NaP or HS.Dissolution, condensation and crystallization steps exist in the zeolitization reaction from fly ash, and the particle surface of products remarkably changes in each step. The fly ash is spherical particles and the surface is smooth(Fig.1(a)). The dissolution of fly ash occurs in the heating process until 393K, and the particle surface changes like unevenness(Fig.1(b)). In case of NaP, the condensation of aluminosilicate ions takes place at 373-393K, and the amorphous aluminosilicate is deposit on the unreacted fly ash(Fig.1(c)). The crystallization of NaP already begins to occur at 393K and the surface is covered with fine zeolite crystals for 24h(Fig.1(d))."

Jan 1, 2003

By Guo Jun

In this study, BaTiO3 ultrafine particles surface-modified with stearic acid were synthesized by the hydrothermal method in a system of BaCl2-TiCl4-NaOH. The effects of NaOH/TiCl4 molar ratio, Ba/Ti ratio and time on structure and morphology of BaTiO3 ultrafine particles were investigated experimentally. The formation mechanism of different crystalline BaTiO3 particles was discussed, and it is considered that in a hydrothermal system, the main factors determining BaTiO3 crystalline are H+ replacement of Ba2+ causing H+ deficiency and anatase growth units involving in crystal growth, which clogs the axial channel for Ba2+ transference. By means of increasing the alkalinity of system and barium content, H+ deficiency and involvement of anatase growth units in crystal growth could be effectively controlled. The results show that when molar ratio of NaOH to TiCl4 is 9 and ratio of Ba to Ti 1.5, and time 8 hours, high purity tetragonal BaTiO3 ultrafine particles with a narrow grain-size distribution and nonpolar surface are obtained at 240oC. The particles have excellent flowability, which is ascribed that the surface polarity of barium titanium powder modified with stearic acid is changed and the interaction between the particles is weakened.

Jan 1, 2006

By I. Douni

The aim of this study is to synthesize hydrated compounds of calcium silicate (tobermorite) using as siliceous source perlite milling process wastes, containing more than 70% of SiO2. Calcium silicate hydrates are mainly used for construction of lightweight building materials, plasters, tiles and filters. The effect of temperature, time and particle size of perlite on the quality and composition of the solid product was studied. The solid products were characterized by X-ray Diffractometry, Differential Thermal Analysis and the amount of Acid Insoluble Residue. The synthesis of tobermorite was per-formed by the hydrothermal treatment of perlite waste with a saturated calcium hydroxide solution at a molar ratio CaO/SiO2 of 1, liquid to solid ratio 10 mL/g and 1% w.t. NaOH addition. Three experimental sets were performed. In the first series of experiments the synthesis temperature was kept constant at 205°C while the synthesis time varied from 0.5 h to 24 h. In the second experimental series the synthesis time was kept constant at 2 h while the temperature varied between 150°C and 245°C. In the third experimental set the temperature was 205°C and the reaction time was 2 hours and two perlite waste size fractions were used, a coarse (d50=18 µm) and a fine grained one (d50=8 µm). Reaction products consisted of semicrystalline calcium silicate hydrate (I) and crystalline Al-substituted tobermorite or a mixture of both. An isomorphic Si4+ ions substitution with Al3+ ions in the hydrated calcium silicate lattice was detected by thermal analysis. The experimental results show that good quality crystalline Al-tobermorite can be produced after 6 hours of autoclaving at 205°C or after 2 hours of hydro-thermal treatment at 225°C. Generally, the in-crease of synthesis temperature or time favors the crystallization of calcium silicate phases and enriches them in aluminum. The use of fine grain size perlite is more efficient for the hydrothermal synthesis of calcium silicate hydrates.

Jan 1, 2006

By J. Shibata, N. Murayama, H. Yamamoto

As one of effective usages of wastes discharged in the non-ferrous metal industry, the syntheses of AlPO4-5 and hydrotalcite were carried out using aluminium dross as a raw material. AlPO4-5 is an aluminium phosphate condensate with properties of zeolitic materials and large pore size. Hydrotalcite is an inorganic anion exchanger and has a layered structure of complex hydroxide. They were synthesized in an autoclave at high temperature and pressure. Various physical properties such as crystal structure, surface texture, and specific surface area were measured. AlPO4-5 can be synthesized from aluminium dross under hydrothermal conditions at 180°C-200°C, and 3h. At the same time, AlPO4-34 and non-porous AlPO4 were also formed as by-products. The crystals of AlPO4-5 have a hexagonal structure. Lt is desirable to heat the reaction product at around 550 °C to remove tri-ethyl amine. The specific surface areas of the reaction product before and after heat treatment at 550°C were 17.9m2/g and 358m2/g, respectively. Hydrotalcite can be obtained by a co-precipitation method from the aluminium dross and waste MgCl2 solution discharged in the aluminium regeneration process. Small amounts of SiO2, Al2O3, and Fe2O3 remain in the reaction product as an impurity component. The interlayer distance of the obtained reaction product is about 0.3 nm. Hydrotalcite changes to Mg-Al oxide during calcination at 500 °C for 3h, and then hydrotalcite is formed again by a rehydration operation. The physical properties of the reaction products obtained from the wastes were very similar to those from fresh reagents.

Jan 1, 2004

By Nicholas C. Lias

Quartz crystals are the raw material from which are made the crystal units utilized in filters and oscillators so vital to the performance of all long distance communications systems. These devices act as the heart of equipment that permits a single telephone cable to carry hundreds of conversations simultaneously. Quartz crystals are of value in communications because of this piezoelectric nature, that is when an electric signal is applied to the quartz, there is a resulting mechanical motion and conversely, a mechanical stress results in an electrical output signal. A plate cut from a quartz crystal will oscillate at some specific frequency, which is determined by the physical dimension of the plate. During the early stages of telephony, all quartz plates were cut from natural quartz, which was imported mainly from Brazil. Since the source of this important raw material was based upon a foreign supply which is located at a great distance from the user and could be vulnerable in time of a national emergent, it became necessary to maintain a large inventory of this strategic material. Also due to the considerable cost of natural crystals of a size and quality suitable for Bell System use, an investigation was made by Bell Laboratories into the possibility of developing a substitute material. The effort was successful and led to a joint development program between Bell Laboratories and Western Electric. This program brought about the design of manufacturing facilities capable of producing large quantities of cultured quartz at Western's Merrimack Valley Works, No. Andover, Massachusetts.

Jan 1, 1973

By P Grieve, J L. Mauk

The Central Maratoto Valley in the Coromandel Peninsula contains a sequence of veins in pervasively altered dacite + andesites of the Waipupu Formation. We recognise at least eight different vein types: (1) pyrite stringers, (2) quartz + carbonate veins, (3) crystalline quartz veins, (4) carbonate veins, (5) chlorite + carbonate veins, (6) siderite veinlets, (7) siderite + carbonate veins and (8) carbonate + pyrite veins. The overall temporal trend of the veins is from early pyrite to quartz and then to late carbonate veins. Carbonate veins and pyrite stringers both form planar and irregular veins, whereas some carbonate veins have diffuse contacts with the wall rock. Gold and base metal sulphides are associated with some of the quartz + carbonate veins. Textures within the veins reflect open space filling and multi-phase reopening. A partial record of hydrothermal activity has been preserved by vein crosscutting relationships, hydrothermal alteration minerals and fluid inclusions. Hydrothermal alteration minerals display zonation from south to north. The alteration increases from unaltered to weak propylitic alteration of andesite in the south (MVRCDC1), to sericitic alteration of andesite and dacite in the north (MVRCDC3). The alteration assemblage is dominantly sericitic, with no adularia present, drawing parallels to the Thames region where there is no adularia.

Jan 1, 1999

By Crawford J

The paper asks the question 'Why Limit the HYDROTRANSPORT of material to the confines of your washplant'.A brief historical review of widely accepted slurry transport operation establishes that we are not talking about new technology - simply applying proven experience to an innovative continuous system.The paper reviews a simple potential application and compares capital and operating costs with conventional trucking.No attempt has been made to develop a complete mine plan and the comparison has been limited to material transport costs.

Jan 1, 1992

By S. K. Dimitrov

?Ellatzite Med? is one of the biggest mining companies in Bulgaria, processing about 12,000,000 t of ore per year. Waste materials left after extraction of copper concentrate are deposited in tailings dam ?Benkovski 2?. The hydraulic structure is built according to the downstream method, through hydrocyclonization where the downstream batter and the body of the wall are formed by the separated coarse sand particles of the separated tailings. In connection with the prolonged concession of Ellatzite Med and the enlarged capacity of Benkovski 2, the tailings dam has expanded on to the surrounding terrain. To guarantee a normal hydrocyclonization and build up of a tailings wall during waste deposition from the ore mill, the technological scheme of the hydraulic transport system of Benkovski 2 has been changed.

Aug 1, 2013

By L. Xia, B. Hart, K. Douglas1, S. C. Chelgani

Development work to optimize a flotation flowsheet for rare earth element (REE) recovery is underway. The original approach used alkyl phosphates and phosphoric acid ester as collectors to concentrate REE minerals. To improve REE recovery, hydroxamates as alternative collectors were investigated. In this paper, micro flotation of REE minerals using salicylic, benzoyl and naphthoyl hydroxamates is reported. Unlike phosphonic collectors, slime removal does not show a significant effect on REE recovery when using hydroxamates as collectors. Among the three hydoxamates, the grade of La, Ce, and Nd for concentrates produced by salicylic hydroxamate is the highest. The recovery response with naphthoyl hydroxamate is similar to that of salicylic hydroxamate; good grades for La, Ce, and Nd, less effective for Nb, Y, and Zr. The data indicated an affinity by salicylic and naphthoyl hydroxamtes for LREE over the HREE minerals. In comparison, benzoyl hydroxamate indicated an affinity for Nb, Y, and Zr. Temperature effects on REE recovery were also studied. The grade and recovery of REEs generated by flotation using a mix of salicylic and benzoyl hydroxamates at room temperature was almost identical or even better relative to the recovery using naphthoyl hydroxamates at elevated temperature.

Jan 1, 2014

By J. L. Yordan, T. Hilderbrand, R-H Yoon

High brightness clays are produced from Georgia kaolin by flotation. Fatty acids are used commonly as collectors for anatase, which represents the major colored impurity in the crude. This process requires activation of the minerals with divalent cations such as Ca2+, in which case proper control of the activation step is crucial to the success of the flotation process. In the present work, laboratory tests have been conducted using alkyl hydroxamates as the collector for anatase. A major advantage of using hydroxamate is that this new collector requires no activator. The laboratory tests show also that the hydroxamate collectors produce consistently better products with higher yields from a variety of kaolin clays.

Jan 1, 1994

By Don McCarthy

Modern mining has been dominated by the drill-and-blast method for more than a century. There have been steady improvements in drilling technology, explosive products, methods of initiation and integration of the two techniques but the essential cyclical nature of drill-and-blast rock excavation naturally limits continuous improvements in cost and productivity. Dynamite and safety fuses, compressed-airdriven tools, and most of the crushing and grinding machinery in use today were all developed before 1900. Moreover, virtually every mechanized mining system used today was in use by the late 1950’s.

Jan 1, 1998

By R. Quintero

The HYL Direct Reduction Process was the first in the world to operate successfully at industrial scale. The results were so innovative and attractive that other steelmaking companies acquired licenses for the HYL Process. Now in its 40th year of commercial operation, the HYL process has evolved into a modem, highly efficient and economical technology -HYL III. The technology offers high productivity, minimum energy and water consumption, electricity co-generation, raw material flexibility, premium quality DRI/HBI, and is highly versatile for meeting the specific needs of each user. A historical review as well as recent developments and future plans are presented in this paper.

Jan 1, 1998