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By Jilai Xue, Jun Zhu, Germain Kouma Ndong, Qiaochu Liu, Luxing Feng

"High-temperature oxidation and corrosion behaviors of Ni-Fe-Cr alloy as inert anodes for aluminum electrolysis have been studied in oxygen and molten electrolyte. The oxidation and corrosion scales on the anodes tested were analyzed using XRD and SEM-EDS. The oxidation rate is found to increase with increasing temperature from 700 °C to 950 °C, which can be approximately described by an inverse power rate function. The oxidation scales at 750 °C, 920 °C and 950 °C contain Cr-rich phase along with FeCr204 and (Feo.6Cro4)203. The corrosion extent of Ni-Fe-Cr anodes in electrolyte is dominated by temperature, which can make the scales thickness double from 700 °C to 750 °C or from 920 °C to 950 °C. Cr and Fe in the scales on the anode in electrolysis corrode preferentially into the molten electrolyte, while the nickel oxides could better sustain the corrosive environment in electrolysis. The results can be useful for developing inert anode material for potential application in aluminum electrolysis.IntroductionThe development of an inert anode for aluminum electrolysis has been a long term goal for aluminum industry. The present process for primary aluminum production involves the reduction of alumina with carbon anodes, forming carbon dioxide:"

Jan 1, 2013

By H. Jehn

The high-temperature oxidation of Pt metals results' in the formation of volatile oxides. The evaporation of which considerably increases the metal losses in oxygen-containing atmospheres when compared with high-vacuum or inert-atomosphere conditions. The paper describes gravimetric investigations carried out to determine the metal losses of polycrystalline samples of Ru, together with earlier studies on Ir and Pt at oxygen pressures of 10-3 to 1000 mbar and temperatures > 1000 °C. A strong pressure and temperature dependence is noted. Preliminary results of the oxidation of Pd are reported, too (665 mbar 02, 1100-1300 °C). The oxidation mechanism is discussed and the oxidation rates of Ru, Pd, Ir and Pt are compared with those of the other Pt metals Rh and 0s and of refractory metals.

Jan 1, 1984

By Leszek Hoser

Polycrystalline oxide superconductors that have the perovskite structure, that are oxygen deficient, and that have compositions based. on the so-called. 1-2-3 (YBa2Cu3O7) compound, were investigated.. The materials exhibit a high critical transition to superconductivity at temperatures near 90oK. It was determined that maintaining the oxygen content within the correct range in connection with an appropriate amount of CU ions in the crystal lattice leads to high-critical temperature (Tc:) superconducting properties. High-Tc: superconductors with a critical temperature in the range of 100°K were developed. Further investigations, based. on the theoretical examinations of the origin of superconductivity, have been performed and are discussed..

Jan 1, 1989

By R. J. Zagrocki

Rekindled public concern about lead toxicity has intensified the awareness of lead-bearing materials in contact with the environment and the human population. Lead's common association with other metals makes the increasingly restrictive lead standards a primary concern for a large number of metal and metal-related industries. In commercial scale demonstration tests with lead-bearing wastes, the HRD Flame Reactor process has a demonstrated ability to separate and recover over 95% of the lead as a recyclable oxide, while rendering the remainder of the material as vitrified, non-leaching, and nonhazardous co-product. Recent Flame Reactor process tests and preliminary cost data for secondary lead soda slag are highlighted.

Jan 1, 1992

By Ruder, W. E.

CONSIDERABLE interest has been shown lately in various types of furnaces for the production of high, temperatures, both for laboratory purposes and for small industrial uses. Dr. J. A. Harker1 described certain modifications of the Arsem graphite resistance helix for high-temperature work at the National Physical Laboratory. Dr. Northrup ,also has developed two interesting forms of high-temperature furnaces. In 1911, Messrs. Winne and Dantsizen2 described two forms, of resistance furnaces using ductile molybdenum or tungsten as resistors. Since the discovery, by this laboratory, of methods for producing these metals in ductile form, their use as resistance elements in the research laboratory of the General Electric Co. has grown to such an extent that they are now almost indispensable. These furnaces are used here for alloy research, annealing, heat-treating, and practically all f the thermal processes requiring temperatures above 900° C. Various types of furnaces have been developed to meet the general needs of laboratory work, and it is the purpose of this paper briefly to describe some of these furnaces. A tubular furnace wound with a metallic resistor is the simplest type to construct, and almost every laboratory has made such furnaces. The only essential difference between a furnace wound with platinum or base metal and one wound with tungsten or molybdenum is that the coils of the latter must be heated in a neutral or reducing atmosphere. It has long been our custom here to build our resistance furnaces with a metallic casing from which the tube could be easily removed for rewinding. The heat-insulating material-usually calcined magnesia, alumina, silica, or silex, depending upon the nature of the resistor-is used in powdered form so that it can he readily removed and replaced. In order to adapt this method to tungsten or molybdenum windings, it

Jan 2, 1918

By M. E. Myers

An experimental program is being carried out to determine the thermodynamic characteristics of zinc solubilization in high-temperature iron and iron-carbon alloys. Two versions of an isopiestic technique are being used, with zinc at a lower temperature being equilibrated with pure iron foils or molten iron-carbon alloys at a higher one. The lower temperature sets the partial pressure of zinc vapor, and thus the activity relative to a given reference state. Initial results show Henrian behavior for dilute zinc solutions in austenite and a molten 4.6% C alloy, with unit-pressure solubilities in pure Fe that closely match the predictions of Wriedt.

Jan 1, 1992

By R. M. Wilhelm

HIGH-TEMPERATURE thermometry,, as treated in this paper, deals with the measurement of temperature in the range 100° to 550° C. The lower limit corresponds to the temperature of boiling water at normal atmospheric pressure, the upper limit is approximately the highest temperature to which mercury in a glass thermometer may be safely subjected.1 In this range., the domains of pyrometry and thermometry overlap somewhat, for high-temperature resistance thermometers and thermocouples generally classed as pyrometers are often used below 550° C. This paper will be confined to high-temperature mercurial thermometers, and indicating and recording thermometers of the vapor pressure, liquid or gas filled, and bimetallic or graphite-metal expansion types, a classification of which is as follows: CLASSIFICATION OF THERMOMETERS GENERAL CLASSIFICATION SUBDIVISIONS Mercury in glass Laboratory- Etched or engraved stems (mercurial) Enclosed scale (Einschlus) Industrial Vapor pressure Indicating and Pressure Liquid filled recording Gas filled Bimetallic Graphite-metal expansion

Jan 9, 1919

A. 0. ASHMAN, Palmerton, Pa. (written discussion?).-Owing to the conflict of the terms thermometry and pyrometry, in numerous cases the entire field of temperature measurements has been divided under these two headings. This confusion is probably clue to the fact that originally a pyrometer was understood to be an instrument for measuring temperatures above the range of a mercury thermometer. In modern practice, however, pyrometers are not only used to measure the temperature over the range of the thermometer, but also to a much

Jan 12, 1919

By M. Manrique, S. A. Pirzada, P. R. Taylor

A thermal plasma-assisted laminar flow reactor was used to evaluate the kinetics of converting alumina to sodium aluminate in flight. Free energy minimization calculations were used to determine experimental conditions. The experimental variables included alumina particle size, alumina/sodium nitrate molar ratio, temperature and residence time. A mathematical model for the conversion was developed and validated. Experimental and mathematical results are presented.

Jan 1, 1998

By J. E. Lawver

On the basis of both laboratory and pilot-scale tests, a newly developed high-tension electrostatic process is technically and economically feasible for the production of iron ore superconcentrates containing 0.02 to 0.20% silica at iron recoveries of 85 to 90%. The process can be used to recover both a superconcentrate and a pellet-grade concentrate, from a feed containing middlings, and the system is not unduly upset from changes in feed structure and composition. The adverse affect of excess quantities of material finer than 30 microns, i.e., above 10% in quantity can be avoided by a desliming step. Finally, because of the cost of drying, the best feed for the process appears to be dry-ground ores as well as spiral, flotation, or magnetic concentrates.

Jan 1, 1970

By George Schipper, Peter Gelten, Pepijn Adriaen, Hugo Uijtdebroeks

Tata Steel IJmuiden Hot Strip Mill 2 (HSM2, 5.5 Mtonnes/yr) is currently being upgraded, resulting in an increased rolling force and motor power capacity. With the current conventional work roll spray cooling, a deterioration in work roll & strip surface quality performance is expected as a result of the increased mill capacities. In order to improve strip surface quality, HSM2 decided to do a full-scale production trial with High Turbulence Roll Cooling (HTRC) at stand FM2. HTRC is a novel way of roll cooling using a high turbulent flow regime. HTRC is positioned very close to the roll surface and gap exit, which is beneficial for the roll surface quality. It is operated at a high flow rate but at a low pressure. HTRC not only significantly improves the roll surface quality, in addition, it makes high pressure pumps, needed for the conventional spray cooling, redundant, leading to substantial savings on electricity costs and thus CO2 emissions. HTRC is in trial operation since 7 August 2018. Results show no operational issues, an excellent roll surface quality and an increased cooling efficiency. In summer 2020 stands FM1-FM2-FM3-FM4 of HSM2 will be equipped with HTRC.

Oct 1, 2019

By F Shi, W Huang, D Seaman, K Runge

High Voltage Pulse (HVP) technology is a novel process that could potentially be the step-change needed in ore processability in the mining industry. The propensity of high voltage pulses towards mineral-enriched ore particles during treatment makes this technology selective and has the potential to enable ore pre-concentration by size separation. In this study, the potential for pre-concentration of a low grade copper-gold ore sample subjected to HVP pretreatment is investigated and compared to that achievable after mechanical breakage in JKMRC’s rotary breakage tester (JKRBT). The data show that a better pre-concentration result can be achieved after HVP processing than conventional breakage. The gold pre-concentration potential is much better than that observed for copper. 4D HVP pre-concentration characteristic curves were produced to assess the metallurgical performance possible as a function of energy input. The case study shows that when targeting a nominal metal recovery of 90 per cent for gold, the HVP pre-concentration technique can split the low grade ore (0.9 ppm gold and 0.28 per cent copper in the feed size 26.5-37.5 mm) into two components – a low grade oversize material (0.3 ppm gold and 0.15 per cent copper) and a high grade undersize material (1.0 ppm gold and 0.3 per cent copper). The mass split to the low grade is 23 per cent. Under this mass split scenario, gold recovery to screen undersize is 90 per cent and copper recovery is 85 per cent. The HVP treatment of this feed size requires a specific energy (spark) of 2.8 kWh/t.There is further research that would be required before industrial uptake of the HVP pre-concentration technology would be possible. This paper also outlines the research challenges that need to be overcome.CITATION:Huang, W, Shi, F, Antonio, C, Runge, K and Seaman, D, 2018. High-voltage pulse pre-concentration study using a low-grade copper-gold ore, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 327–338 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By G. Stenning

The paper outlines the need for high-volume ventilation in a uranium mining operation based on the design to meet environmental requirements for dust, radiation and diesel equipment. Mining methods in a highly mechanized operation, a key factor in design, are discussed. The construction and installation of major intake and exhaust fans are described briefly, together with the development of the mine airways and distribution system. Controls in the form of doors and bulkheads are important considerations in planning. Finally, the need to lower ventilation requirements in response to increasing power costs will result in future improvements.

Jan 1, 1979

By Charles Pretorius, Henk Ludik

Navachab Mine experiences difficulties with pit wall stability in certain areas of the mine. The main reason for the instability is the fact that the geology comprises many joints and faults. Blasting, without impacting negatively on the stability of the pit walls, poses a major challenge.

Jan 1, 2006

By André de Jager, Henk Ludik

Navachab Mine experiences difficulties with pit wall stability in certain areas of the mine. The main reason for the instability is the fact that the geology comprises many joints and faults. Blasting, without impacting negatively on the stability of the pit walls, poses a major challenge. The mine has installed a technologically advanced seismic monitoring system with monitoring sensors positioned at various locations and depths throughout the pit. The electronic data recording system records all relevant information on a continuous basis with early warning signals in cases of potential danger. From the information recorded by this micro-seismic system it was established that the energy release into the high-wall is predominantly influenced by the mining rate, water content and mining tempo and to a lesser extent by the blasting operations. To limit the negative effects of blast vibrations, the use of Electronic Delay Detonators (EDDs) was introduced. The optimal delays were determined through signature trace analysis. The vibrations obtained during blasts initiated by means of electronic delay detonators were monitored and compared to those traditionally obtained when standard pyrotechnic delay detonators had been used. The measured vibration data indicated an improvement of 25% to 100% drop in vibration amplitude compared. The accuracy and programmability of EDDs presented huge potential for blast optimization in terms of limiting the vibrations without compromising fragmentation. The whole project was conducted over a twelve week period with some 4000 EDDs. The average size of a blast was in the order of 350 holes using about 40kg explosives per hole, which equates to 14,000 kg explosives over 12 different blasts. The paper deals in detail with the blast optimization process with regard to: - determining the rock response time; - establishing the signature traces; - analyzing the wave interference patterns; - predicting the direction of constructive and destructive wave interferences; - optimizing of the inter-hole and inter-row delay periods; - measuring the ground vibrations. The results obtained during electronic blasting are compared to those obtained during pyrotechnic blasting. Comparisons are being made with regard to the following: - ground vibration measurements; - pit wall stability measurements; - blast safety.

Jan 1, 2006

By Philip Morse

THE Australian lead-smelting plants began to use charges carrying high zinc percentages somewhat earlier than was common with American plants. When lead smelting first started in Australia the immense deposits of oxidized lead at Broken Hill were available but later these oxidized ores became exhausted and were replaced by sulfides. This was before the days of flotation and these sulfides when concentrated carried about 1 per cent. of zinc to 6 per cent. of lead. The works of the Sulphide Corpn. at Cockle Creek was perhaps the pioneer in high-zinc slags but the Port Pirie plant of the Proprietary Co. was a close and very able second and has continued the work to the present time. The Cockle Creek lead furnaces remained in operation until shortly after the war when most of the Broken Hill companies combined and took over the Port Pirie plant to treat their concentrates. As it was the practice both at Cockle Creek and Port Pirie to carry 20 per cent. or more of lead on the charge, it was found that under these conditions of large amounts of zinc in the charge, good roasting was absolutely necessary and matte production was unwise. The Huntington-Heberlein system of roasting was introduced and later the Dwight & Lloyd process. In this way, by roasting the sulfide portions of the charge as thoroughly as possible and making no matte, a method of smelting was developed where the slag over long periods carried as high as 20 per cent. ZnO without serious furnace troubles, and slags carrying even up to 33 per cent. ZnO have been reported. The zinc slags were not very different in appearance from the ordinary slags produced in American practice except that they gave off more smoke and fume on tapping. The slag usually ran hot and freely, coming from the tap in a full stream. Normally there was little crust on the sides' of the furnace and the tuyeres gave no trouble though they were always rather dark.

Jan 1, 1929

By Bruce Vandenberg, R F. Chiappetta

"The High Speed 2D Analysis program allows the user to bring in data from several different sources. Of course, keyboard entry is included as a source. Other data is inputted through the serial port (X-2321 of the PC. Two types of data are transferred via the serial port. The first is the tablet digitizer data. The three types supported presently are the GTCO, tablet digitizers. and the Calcomp 2500 and 9100 series To transfer digitized data turn on the selected digitizer and place the cursor on the tablet. Enter the High Speed pmg.ram and select from the Input Program menu the Digitize Inputs(20) option and follow the instructions. TO exit the session, either a keyboard entry or a cursor button is pressed. The second type of serial port input Is from the collectors of the listed survey systems. Typically a file transfer program will be used to send the data from the collector to the PC. This topic will not be addressed at this time."

Jan 1, 1989

By Robert Charles Alfred

Evolution is continuing in the field of rock drilling, Campbell Limestone Company is experimenting in the higher air pressure phase of drilling, It has been determined that there is a definite relationship between Air Pressure, Penetration Rate, Bit & Tool Wear and Life, In our drilling we have determined that &e higher air pressure gives a better penetration rate with less bit wear per foot. Drilling with 180 to 200 PSI air pressure, instead of 100 PSI for air and/or churn drills, has decreased our primary costs by approximately one half.

Jan 1, 1963

By M. A. Hararah, T. Neesse, M. G. Farghaly, G. Proellss, P. Kaniut, W. Rubarth

ABSTRACT: This paper presents two new options for hydrocyclone control. Volume split control using a control valve in the overflow is applied for the stabilization of separation results at changing feed conditions. Controlled water injection to the conical part of the cyclone leads to the reduction of fine particles in the underflow. Hydrocyclone monitoring in both cases is performed by optical sensors that indicate the spray angle of the underflow. Applications in mineral processing for desliming, classification in closed-circuit grinding, and dewatering are demonstrated.

Jan 1, 2011

By Leith Sharp

I was confronted with a profound dilemma as an undergraduate engineering student at the University of New South Wales in Australia in 1992. I had been taught that our planetary life-support systems were in a state of alarming decline by an institution that operated as if what the faculty was teaching was irrelevant. Lights were left on in empty overcooled classrooms, recycling bins were nonexistent, lawns were maintained using pesticides and herbicides, diesel trucks spewed fumes as they passed on their way to drop off chlorine-bleached virgin paper. This disconnect was very alarming to me. While it was obvious that universities should play a leading role in teaching and researching sustainability issues, I wondered how it could be possible to make widespread institutional changes to meet the demands of environmental sustainability when it was not even being done in the very university sector where these ideas were being promulgated. If universities would not change, then who can and who will, I wondered? To a growing number of people, the idea of teaching sustainability without demonstrating it is highly problematic. It is also widely believed that the ability of the higher education sector to reform its own practices is an important indicator of humankind?s ability to address the global environmental imperative across all sectors of society. These sentiments have helped fuel what is now referred to as the campus sustainability movement, a movement dedicated to transforming our campuses into living laboratories for the demonstration and practice of environmental sustainability.

Jan 1, 2010