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By J de Cuyper, G. Rinelli, A. M. Marabini, V. Alesse, W. Freyberger

Salicylaldehyde, a chelating agent for tin, has been found to function as a collector for the flotation of cassiterite. Infrared and nuclear magnetic resonance studies clearly show that salicylaldehyde can form a chelate compound in bulk and at the surface. Results are also given for the flotation of a tin ore with this reagent.

Jan 1, 1976

By Zhaohui Qiu, Yaguan Ji, Hong Zhong, Qingxia Liu, Yada Liu

"Water is a necessary process medium in mineral processing. For the operations where fresh water is not available, sea water could be used as an alternative processing medium to replace the fresh water if we would have built a solid understanding of the interfacial science and flotation chemistry of sulfide minerals in sea water. In this research, micro flotation of chalcopyrite and pyrite in deionized water and sea water were investigated. For chalcopyrite, the recovery starts to drop from pH 10 in deionized water and from pH 9 in sea water, and the flotation recovery close to 100% before it drops. We can found from the results that chalcopyrite flotation is depressed much at pH 11 in sea water when much white precipitate is found. For pyrite, the flotaion recovery changs a lot in deionized water with 1*10-5 M potasium amyl xanthate (PAX) as collector. It’s relatively high at pH 8~10 compared with that at pH<8 and pH>10. While in sea water, the trend is almost the same as that of chalcopyrite. Zeta potential measurements and chemical equilibrium calculation were used to find out that magnesium hydroxide species coats on the surfaces at high pH in sea water are the main reason for depressing the chalcopyrite and pyrite flotation. Through understanding the interfacial science and the solution chemistry of sea water and its impact on processing efficiency, this research will not only helps reduce the use of fresh water to minimize the disposal of spent water for environment protection, but also enhance the recovery of valuable minerals in froth flotation."

Jan 1, 2014

By R. A. Wharton, Z. Yang, R. W. Smith

The electrokinetic and flotation behavior of the green alga Chlorella vulgaris was studied in the absence and presence of Pb(II), Al(III) and flotation collectors. It was found that the presence of Al(III) is necessary for good flotation of the organism, whether or not Pb(II) is present, when dodecylammonium chloride or sodium dodecylsulfate is used as collector. Best flotation using dodecylamine is at about pH 8, and best flotation when using sodium dodecylsulfate is at about pH 4. It appears because of the small size of the organisms that the Al(III) is necessary for flocculation to enhance bubble-cell contact and C. vulgaris removal from water. When N-dodecyl-2-aminopropionic acid is used as collector, good flotation occurs at about pH 4 without the addition of Al(III).

Jan 1, 1992

By R. W. Smith

The electrokinetic and flotation behavior of the green alga Chlorella vulgaris was studied in the absence and presence of Pb(II), Al (III) and flotation collectors. It was found that the presence of Al (III) is necessary for good flotation of the organism whether or not Pb(II) is present when dodecylammonium chloride or sodium dodecylsulfate is used as collector. Best flotation using dodecylamine is at about pH 8 and best flotation when using sodium dodecylsulfate is at about pH 4. It appears because of the small size of the organisms that the Al (III) is necessary for flocculation to enhance bubble-cell contact and C. vulgaris removal from water. When N-dodecyl-2-aminoproprionic acid is used as collector good flotation occurs at about pH 4 without the addition of Al (III).

Jan 1, 1990

By W J. Bruckard

In Australia, ilmenite is produced from beach sand deposits. These deposits contain varying quantities of the valuable minerals zircon, rutile and ilmenite, along with a variety of other minerals. The valuable minerals are upgraded using combinations of gravity, magnetic and electrostatic processing techniques to yield high-grade products. One of the penalty elements present in ilmenite concentrates is chromium, present mostly as chrome spinels. This mineral is particularly difficult to separate from ilmenite, as the properties of the two minerals are very similar in relation to the traditional separation processes. While the deposits which have been treated in Australia in the past have had only low levels of chromium present, many of the newer deposits contain much higher levels of contamination and, thus, there is an increasing need to develop robust processes to separate chrome spinel from the ilmenite. Flotation, which is a unit process with the potential to solve this problem, has surprisingly received little attention for this application. The literature suggests the research effort to characterise the general flotation properties of chromite (chrome spinel with high chromium content) has been extensive and a substantial amount of data is available. However, the problem of separating a small amount of chrome spinel from a large amount of ilmenite requires a different approach to that from separating chromite from siliceous gangue, which has been the main commercial focus of chromite flotation in the past. Much of the work done has been fundamental in nature and the results obtained are fairly inconsistent, as is the testwork completed at batch and pilot plant scale. While these inconsistencies have been attributed to the variable composition of the mineral, there is little evidence supporting this premise. Just as chrome spinel and ilmenite have similar physical characteristics, the flotation response of both minerals is also similar. This paper reviews the literature relating to the flotation of chrome spinel and presents a considered approach to the development of a robust flotation method to separate chrome spinel from ilmenite.

Jan 1, 2001

By H. Soto, G. Barbery

The effect of particle size on the flotation of coarse particles is analyzed. It is concluded that turbulence and the presence of the froth layer are detrimental to the recovery of coarse particles during conventional flotation. A counter-current column cell is proposed to avoid these two factors. In this column, a net upwards flow of water is prevalent, such that no froth is allowed to form on the top. Also, the levitation of heavy bubble-particle aggregates is helped by the ascending water current. Preliminary work at laboratory level with kilogram-size samples indicated that under similar conditions recoveries in the column were much higher than in conventional cells. Flotation results obtained with coarsely sized phosphate and quartz samples are presented. One interesting feature of this type of column is very fast flotation kinetics. Thus, a short column (only 55-cm collection zone) yielded, full recovery of floatable values.

Jan 1, 1992

By H. S. Soto

The exact reasons that explain the low recoveries of coarse particles in conventional flotation machines are not clear. Being a concern for only a couple of mineral industries comparatively very few studies have been devoted to the problem of coarse particle flotation. Coarse particles flotation is particularly important in potash and phosphate beneficiation. Potash concentrates with particles larger than 1-2 mm do not require additional compaction or recrystallization and receive a premium price. However, recovery of this size particle in conventional flotation cells is very low, and therefore, the coarse floation tailings have to be reground and refloated to produce, at a higher cost, a less desirable concentrate. In phosphate beneficiation deslimed coarse ore (nominally l4x35 or l6x35 mesh) is normally treated separatedly from the finer (35x150 mesh) ore. Concentration by conventional froth flotation alone yields very low recoveries, and therefore, additional processes such as agglomerate flotation in tables spirals and belt conveyors have to be used ( Moudgil and Barnett 1979). Fatty acids and fuel oil used in phosphate flotation have a moderate level of selectivity but considerable amounts of sand report to the froth product, thus concentrates have to be further upgraded by a double flotation process. Concentrates from the anionic circuit are scrubbed in an acidic media to desorb the collectors and then refloated in a cationic circuit to eliminate the fine silica (Lawver et.al. 1978). In this paper the reasons that explain the low recovery of coarse particles in conventional flotation are discussed. A flotation column modified according to the main conclusions of this discussion is tested with two coarse phosphate samples.

Jan 1, 1989

By Deepak Gupta, Brij M. Moudgil

Attempts were made to improve the recovery of coarse phosphate particles by adding selected frothers or precoated fine particles. A number of frothers for floating, specifically coarse coal and metallic minerals, were examined. Two of the frothers increased the flotation recovery of coarse phosphate by 3% on bench scale. Plant evaluation yielded improvements in overall phosphate recovery in the presence of these frothers. Addition of fine particles was also found to enhance coarse flotation under given conditions. Size, amount, and hydrophobicity of the fines added was determined to have a major influence on the coarse flotation efficiency. The grade of the product with and without frothers and particulate additives remained the same. Change in froth stability and viscosity are believed to be the primary reasons for enhanced recovery of coarse phosphate particles.

Jan 1, 1989

By W. C. Hirt

Deposits of ferromanganese crust containing cobalt and nickel occur on the seafloor in the Pacific Ocean near the Hawaiian Islands and Johnston Atoll. This paper describes developmental flotation metallurgy to separate crust from its associated substrate gangue. Important variables in ferromanganese crust flotation include reagent type, aeration rate, conditioning time and agitation intensity, pH, temperature, water type, and feed size distribution. Flotation in seawater of minus 600 ~m (-28 mesh) material assaying 6.2% Mn, 0.2% Co, and 0.13% Ni with diesel fuel-crude tall oil-sulfonate collectors produces concentrates assaying 15% Mn, 0.6% Co, and 0.3% Ni with recoveries of 89-95% while removing 62% of the feed weight.

Jan 1, 1990

By M. S. Celik

The principal impurities in some feldspar ores are titanium and iron which impart color and in turn degrade the quality of the ore. The mineralogical investigations indicate that titanium element originates from mainly rutile with small amounts of sphene. Conventionally, fatty acids and particularly sodium oleate are extensively used in the flotation of colored minerals from feldspar ores with reasonable success. In this study, new reagents, oleoyl sarcosine and hydroxamate have been used to float colored impurities before and after magnetic separation. Oleoyl sarcosine is found to exhibit better results compared to fatty acids and hydroxamate. The mechanism of the action is elaborated on the basis of experimental data.

Jan 1, 1999

By O. I. Rychkova, M. N. Sycheva, E. V. Poryadochnova, G. V. Sedelnikova

Deposits of copper-porphyry type occupy a leading position in the mineral resource base of the world copper industry. They are characterized by large and gigantic scales, often complex composition, their development is carried out in an open way. The raw material base of the Russian copper industry is mainly sulfide copper-Nickel and copper-pyrite ores. Exploration of copper-porphyry deposits and the creation of long-term large mining facilities on their basis is one of the most promising and priority tasks for the Russian industry. This task is especially acute for the copper enterprises of the Urals in connection with the depletion of copper - pyrite ore reserves. In recent years, Russia has carried out a large complex of studies on the composition and technology of processing of copper-porphyry ores of different subtypes. In this work the complex poor copper-molybdenum-gold ore of one of the deposits is investigated. The chemical and mineral composition of the ore containing 0.49% copper, 0.020% molybdenum, 0.39 g/t gold, 5.85 g/t silver was determined. The forms of finding metals and their distribution by size classes are established. The dependence of extraction of metals into concentrates of collective-selective flotation on the size of ore grinding, pH of the medium, reagent consumption is shown. Under optimal flotation conditions, copper concentrate with 18.6% copper content and 92.32% extraction and molybdenum concentrate with 21.5% molybdenum content and 73.4% extraction were obtained. With a high concentration of molybdenum in selective flotation products, it is possible to conclude about the expected molybdenum concentrate with a content of 45% and a recovery of 70%. The associated extraction of gold and silver into copper concentrate is 76.8 % and 73.4%. Keywords: Collective-selective flotation, copper, molybdenum, porphyry ore, grinding, pH, reagents

Jan 1, 2020

Flotation of Composite Synthetic Particles

Sep 13, 2010

By V. M. Lepetic

Large tonnages of copper and molybdenum sulfide ore are treated by flotation. Substantial savings could be realized, particularly in high-capacity concentrators, by use of a simplified flotation technique involving lower reagent consumption. Chalcopyrite and molybdenite from some deposits can be floated by use of only a frother as a single flotation reagent; acceptable concentrate grade and recovery can be obtained. Separation of molybdenite from copper sulfides may become simpler and less costly. The genesis of the ore and the ions present in the flotation pulp liquid phase appear to be the major success-determining factors.

Jan 1, 1972

By Li Changgen, A. Bahr

The adaptability of pneumatic flotation cells for the flotation of sulfide ore and the conditions for sulfide ore flotation in pneumatic cells were investigated. The advantages of pneumatic flotation cells over mechanical flotation cells, as well as flotation columns, for the flotation of sulfide ore were demonstrated. Test results indicated that the Cu grade and recovery for concentrates obtained when using the pneumatic flotation cell were 1 % to 2% and 4%, respectively, higher than those obtained when using the mechanical flotation machine.

Jan 1, 1993

By R. W., Ludt

THE use of froth flotation for the separation of minerals has become one of the most important of ore dressing processes. Its particular adaptability to the enrichment of low grade ores has made the process an important factor in the national economy. The methods have been extended to the recovery of a great number of minerals. Among the few minerals which have resisted efforts toward industrial flotation is chrysocolla, a hydrated partly colloidal copper silicate. Chrysocolla, being a product of natural oxidation, has been found to occur in small quantities with many ores which are recovered by flotation methods. In present practice, these small quantities of copper silicate pass off with the tailings and are lost. The advantages to be gained by a satisfactory process for the recovery of chrysocolla is apparent. Any application of principles which points a way toward the satisfactory industrial flotation process for copper silicate would be of advantage. This paper presents an attack on this problem.

Jan 1, 1949

By Subrata Roy

The slag produced in metallurgical smelting processes contains considerable amount of valuable metals. The present work focuses on recovery of copper value by froth flotation from the copper smelter slag. The slag samples are subjected to detailed characterization including automated quantitative mineralogy using Mineral Liberation Analyzer (MLA). The MLA results indicate that a part of copper is present in sulphide form in fayalite (iron-silicate) matrix and very poorly liberated. SEM-EDX analyses also reveal that a certain part of the copper is present within the fayalite (Fe-Ca-Si) matrix, perhaps either as lattice impurity or very fine grain. The copper smelter slag is ground in wet mode in a ball mill, to particle size distribution suitable for flotation. Subsequently, the slurry undergoes froth-flotation in lab-scale Denver-type flotation cell. Various combinations of sodium iso-propyl xanthate (SIPX) and alkyl hydroxamate collectors are used along with pine oil as frother. A multiple collector dosage is required for effective flotation of non-sulphide copper phases associated fayalite and alkyl hydroxamate is identified as one of the effective collector for non-sulphide minerals. The copper recovery can be enhanced by 7-10% with a combination of collectors as compared to conventional sulphide flotation using only xanthate type collectors. However, the grade decreases to some extent. Keywords: flotation, copper slag, hydroxamate collector

Sep 1, 2012

By Wang SS, Frattaroll DR

In the development of novel sulfide collectors, especially for the low-lime and acid circuits, flotation of chalcopyrite, chalcocite, covellite and pyrite was studied with both new and commercially available S- containing collectors. The natural float- ability of sulfides, water quality, and redox potentials - all of which were considered im- portant in assessing collector strength and selectivity - were also investigated. Chalcopyrite exhibited the highest natural floatability. The response to most collectors, however, was chalcocite > covellite > chalcopyrite > pyrite. Water quality had a very significant effect on both natural and collector-aided floatability. De- ionized water and tap water had a flotation suppression effect compared with doubly- distilled water. Flotation results with single minerals are correlated with those for copper and pyrite from natural ores. Several novel collectors have now been developed for sulfide flotation in acid, neutral or mildly alkaline circuits. The results for four of these collectors, which have shown promise in commercial applications, are discussed in this paper.

Jan 1, 1986

By Chris Cox, David Green

Outokumpu has developed the HG or High Grade flotation cell over the past decade. This machine gives upgrading and selectivity performance superior to conventional mechanical cells while maintaining their simplicity, ease of operation and recovery characteristics. The HG design is available in a tank cell configuration which provides a number of benefits in plant design and operation. This paper will describe the HG Tank Cell and the "Virtual Column" concept. Results are given from the operation of the HG Tank Cells at Lac Minerals - Est Malartic in Quebec, Canada. Further discussion of applications for gold recovery is also provided.

Jan 1, 1993

By W. J. McKenna

THE International Smelting Co. concentrator at Tooele, Utah, first operated on a custom basis for the treatment of lead-zinc-iron ores on Nov.&apos; 1, 1924, with a capacity of 500 tons per day. On May 1, 1925, the capacity was increased to 1000 tons per day by the addition of another 500-ton section. The concentrator has since operated on the two-section basis, each treating 500 tons per day entirely by flotation. LABORATORY AND TEST MILL In connection with the concentrator, a well-equipped laboratory and small continuous testing plant are maintained. The flotation equipment in the test plant is of both the Callow and Mineral Separations Sub-"A" types, so that actual concentrator conditions may be duplicated as closely as possible. PURCHASING OF ORE A new shipper usually sends to the plant a 25 to 50-lb. sample, representative of the ore to be shipped. Batch flotation tests are made on this sample to determine its amenability to the concentrator treatment flowsheet and reagent combinations. The results of these tests, which are accurately correlated with those obtained at the concentrator, both as to grades of products and recoveries, determine the actual value of the ore as submitted in the ore purchasing department&apos;s treatment schedule. Hearty cooperation has existed at all times between the ore purchasing and operating departments in the selection of ores as concentrator feed. ORE TREATED The basic tonnages for mixtures on the two sections come from the Park City and Bingham mining districts. The Park City tonnages are received by rail and consist of crude ores and gravity mill products. Those from the Bingham district are received by rail and aerial tramway,

Jan 1, 1928

By R. G. Weavind

ONE of the most important fields of investigation at the Diamond Research Laboratory in Johannesburg is concerned with improvements in metallurgical practices for the diamond mining companies, with particular reference to increased recoveries of the smaller industrial stones. Considerable work has been done on the possible application of flotation processes to the diamond industry.

Jan 7, 1951