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By I. Iwasaki

Flotation characteristics of pyrrhotite by itself and in complex sulfide ores are reviewed with respect to the effects of oxidation, grinding media and other electroactive minerals.

Jan 1, 1988

By V. Lepetic, C. C. Harris

A systematic program of investigations covering all aspects of cell hydrodynamics,1-3 flotation kinetics,4,5 surface chemistry and their interactions has as a major objective the elucidation of the flotation micromechanism and the principles of cell design and scale-up.6 Purely from the scale-up point of view, a family of reactors should enable different throughputs of the same material to be similarly treated or, at least, to be treated in a manner which differs beween reactors in a predictable way. Thus, for the same material and residence time, the recovery and grade from differently sized cells of the same family should, ideally, be similar or, at least, be related to each other in a known way. It is well known, however, that different-sized cells do not always achieve similar results, and it is necessary to enquire into the reasons for these differences. For example, it may be that the relative dimensions of different-sized cells result in hydrodynamic conditions which preclude similarity; if so, different scaling may improve the situation. The major question concerns identifying the dynamic conditions and their associated geometric requirements which govern the flotation process, and the criteria which are necessary for their fulfillment. It is to answer such questions that the program referred to earlier was instituted. In connection with this program and in order to examine data concerning the physical features and operating conditions of existing flotation cells, the following survey was carried out. This work represents an approach which is complementary to experimental investigations, for it recognizes that the design of existing cells may embody several of the principles being sought. If data for enough cells, especially families of cells, are examined, some broad requirements common to all cells may emerge.

Jan 9, 1966

By Manlapig E. V

ABSTRACT- I Results are given for a series of tests in which a 300 mm pilot-scale Jameson cell has been used in copper recleaner flotation, and for the flotation of a lead rougher feed. the results indicate that the production rate of solids, at the same superficial air velocity Jg, is higher than in conventional columns. Thus in the copper recleaner application, the pulling rate reached 14 gm/cm2/min compared with between two and three for an operating column, while in the lead cleaner application the comparable figures were 12 - 14 gm/cm2/min for the Jameson cell vs 8 - 9 gm/cm2/min for a test column. A froth crowder was used to increase the air superficial velocity Jg in the Jameson cell in the copper recleaner, while holding the collection mechanism and pulp feed rates constant. The recovery increased from 50 per cent to over 90 per cent, suggesting that recovery is controlled mainly by the froth conditions, rather than the particle-bubble interactions in the Downcomer.

Jan 1, 1991

By G J JAMESON

The flotation cell has undergone a number of changes since the process was first introduced in Broken Hill in the early years of this century. The development of the mechanical flotation cell is reviewed, followed by a discussion of more recent developments such as the flotation column, the air-sparged hydrocyclone, the Wemco-Leeds cell, the Bahr and Deister columns and the Jameson cell.

Jan 1, 1992

By Anthony K. Anyimadu, Chris M. Rule

Froth flotation is the primary mineral processing separation step employed in the beneficiation of PGM ore bodies. Anglo Platinum operates a significant portion of the total installed flotation capacity in the PGM industry, which is installed at 20 operating plants across the Bushveld. PGM flotation has undergone a considerable evolution in both the capacity of flotation cells employed as well as in the circuit design configuration over the past thirty years. Certain of Anglo Platinum?s flotation circuits have been in operation for a relatively long period of time, (in some operations installed equipment dates from the 1960?s) and this allows comparative operating performance between various equipment types and circuits to be evaluated. This paper summarizes some aspects of this experience. Research trends in flotation are continuously monitored to incorporate appropriate findings into existing and future circuit designs. Continuous evaluation and monitoring of flotation performance is undertaken to identify opportunities for increasing flotation efficiencies. Mineralogical and fractional analyses of plant composites and survey samples are analysed to interrogate speciation and association data. This analysis has enabled a better understanding of priorities and opportunities for improved metallurgical performance. These opportunities are divided into three improvement areas: stability, liberation, and fines flotation. The paper discusses these, as well as the circuit design improvements required to take full advantage of the opportunities identified.

Jan 1, 2007

By Quilliam B, Richmond G

Aberfoyle Ltd. has utilised a variety of flotation technologies in the Hellyer concentrator in North-Western Tasmania. Hellyer ore, with its slow flotation rates and low rate differentials between values and gangue, requires the use of long residence times and low air consumption rates in the flotation circuit. The operation of the flotation circuit, with a nominal residence time of 7 hours, has necessitated the development of a control system to provide continuity through operator shift changes. Cell selections at Hellyer varied from the 54 m3 hybrid Dorf Oliver / Maxwell (DO/MX) cells, to smaller 32 m3 Maxwell cells, conventional Don-Oliver 300 (8.5 m3) and 600 (17 m3) trough cells, and a column cell. The advantages of the large cells included low specific power consumptions and a low capital cost. However, problems with mixing and the maintenance of consistent froth depth have been identified in the hybrid DO/MX cells. Short circuiting in the trough cells was apparent, causing a considerable reduction in metallurgical performance. The column cell performs to expectation, although the application is not ideal.

Jan 1, 1991

By Hinkley JT, Smitham JB, Nicol SK

Historical investigations of mineral flotation have highlighted the many factors which affect flotation. Some of these are related to the mineral, its degree of liberation (however defined), solution chemistry and flotation reagents. The complexity of the interactions between these factors often leads to uncertainty over whether the final grade/recovery results obtained in either laboratory or pilot scale tests are in fact the maximum recovery at a specific grade. The reason for this is that there has not previously been a general technique for establishing the floatability of an ore. This study describes the further development of the 'tree' flotation technique for minerals other than coal, and in particular its application to iron ores. Oxides have been chosen as a system of intermediate complexity between the simple coal system and sulphide minerals to illustrate the principles and develop the concepts. The 'tree' flotation procedure consists of the progressive flotation to completion of successive froth products, followed by reflotation to remove entrained material. It therefore represents an 'equilibrium' approach to floatability rather than a kinetic approach. By ordering the various products and tails in order of increasing grade, a cumulative curve of grade and recovery can be constructed against which an isolated batch or plant result on the same ore can be compared. In this investigation, a Jaspilitic iron ore was tested at various grind sizes to determine the 'best' flotation grade-recovery that could be obtained with a given set of reagent conditions. The separation characteristics of a process are best measured on a system which contains particles which behave as 'middlings' with respect to the process in question. For this reason a natural ore was chosen in preference to model systems in order to relate more readily to plant situations.

Jan 1, 1993

By Saeed Farrokhpay

It is known that the grinding condition has a major effect on the beneficiation characteristics of the minerals in subsequent processing, in particular, flotation. In the flotation process, particles surface and their condition can significantly influence collector adsorption and flotation performance. For example, particle shape and its surface roughness occurred during grinding may influence flotation characteristics of a specific ore. In fact, adsorption of different cationic and anionic species on mineral surfaces can be varied depending on the selected comminution procedure. The flotation performance of sulphide minerals can be detrimentally affected by the surface oxidation. The amount of surface oxidation may reduce the hydrophobicity of the mineral and makes adsorption of collectors less selective. Improved liberation may generally result in improved flotation recovery. However, this may result in finer grinding and slimes, and consequently, reduce the overall flotation recovery. This paper discusses the effect of wet and dry grinding on copper flotation of a complex Cu-Pb-Zn ore. Industrially, wet grinding is preferred due to its higher energy efficiency and owing to downstream processing requirements. In this study, series of flotation tests were conducted,and surface analysis (XPS and ToFSIMS) were performed after wet or dry grinding at two different P80 values. Mineralogical study was also conducted to investigate the liberation of valuable minerals after grinding. A higher copper flotation recovery was found for wet grinding. However, the copper recovery was increased by further grinding in both conditions (wet and dry). The results showed a higher collector adsorption on copper mineral surfaces after wet grinding. The surface analysis also revealed that the ore is slightly more oxidized after dry grinding probably due to higher temperature during dry grinding.

Sep 1, 2012

By V. I. Purcell, R. E. Snow, S. C. Sun

FATTY acids have been used as standard collectors for floating the matrix1-8 but not the leached zone phosphate ores. After a series of investigations, Davenport9 and Tarbutton10 concluded that the Florida leached zone ores tested were unamenable to fatty acid flotation and must be upgraded by floating the siliceous gangue with Armac-T as collector. The cationic flotation was estimated11 to cost almost ten times as much as a fatty acid process that would ideally give the same flotation grades and recoveries of phosphates. Mineralization: Extensive deposits of leached zone aluminiferous phosphate occur in The ore sample used for this work was obtained from the Virginia-Carolina Chemical Corp., Clear Springs area, Florida. The ore is a potential source of uranium and aluminum as well as phosphorus. Since the uranium and the recoverable aluminum are contained in some of the phosphate minerals, an upgrading of phosphate results in a corresponding enrichment of both uranium and aluminum. The phosphate minerals in the ore are primarily pseudo- wavellite, millisite, and carbonate fluorapatite, with a minor amount of wavellite. Quartz and clay are the common gangue minerals, quartz being pre- dominant. Others present in small amounts are ilmenite, hydrated iron oxides, staurolite, monazite, and zircon.

Jan 1, 1957

By M. C. Fuerstenau

Flotation data indicate that sulfonate and dodecylamine adsorb physically on Mn02 at ambient temperature. Oleate also adsorbs physically if the zero-point-of-charge of the Mn02 is sufficiently high. Chemisorption of oleate apparently occurs between pH 8 and 9, and this phenomenon is enhanced considerably at elevated temperature.

Jan 1, 1966

By Young Hyun Paik, Hyung Sup Choi, Yeun Sik Kim

The basic studies on the surface properties and flotation characteristics of ilmenite were made by electrophoretic, adsorption, contact-angle and floatability measurements. The isoelectric point of ilmenite is found to be at pH 5.6. By combining the results of electrokinetic studies and adsorption measurements, a clearer picture of the ilmenite-solution interface was observed. These findings were correlated with the floatability of ilmenite obtained by Hallimond tube tests. The general flotation characteristics of ilmenite are compared with those obtained for magnetite and rutile. It is indicated that the above three minerals, namely, ilmenite, magnetite and rutile, have very similar surface properties and flotation characteristics. Therefore, it is difficult to make an effective separation of these minerals by flotation. However, it is found that sodium orthophosphate acts as a selective depressant for magnetite in anionic flotation. Therefore, close pH control of the pulp in the presence of the phosphate ion enhances the possibility for a successful separation of these minerals.

Jan 1, 1967

By M Brooks, M Nelson

A fundamental study was carried out on super pit sulphidic gold ore to establish the most influential flotation characteristics which were subsequently used in the development of an optimum flowsheet to achieve best economical recovery of gold. In developing the flowsheet, consideration was given to existing operational constraints in the treatment of the Super Pit ore. The fundamental study also included an innovative diagnostic investigation to establish the location and value of gold in the major mineral assembly of the super pit ore from a metallurgical rather than a mineralogical perspective. This study mapped a metallurgical fingerprint of the major types of super pit ore in relation to the location and association of gold.

Jan 1, 2000

By Strathmore R. B. Cooke, Iwao Iwasaki, C. S. Chang

PYRRHOTITE has long been considered a gangue mineral to be eliminated as tailing in the treatment of various sulphide ores. However, in recent years the world-wide lack of sulphur resources has called attention to this mineral as a potential source of both sulphur and iron. Its importance as an economic mineral, however, has not been particularly emphasized. For this reason very little is known about its response to flotation, except that it can be depressed easily in alkaline circuit, by long aeration,1,2 addition of oxidizing agents3 or by starch.4 The object of this work was to study the floatability of pyrrhotite. This includes the effect of oxidation by aeration, of copper activation, and of change in pH.

Jan 2, 1954

By S. G. Dixit

Alunite (KAl3(SO4)2(OH)6] is one of the important nonbauxitic resources for aluminum in U.S.A. The major gangue material associated with a unite ore body is quartz. Experimental results indicate that oleic acid flotation of alunite is quite effective in upgrading the ore. The flotation chemistry of the alunite/oleate system has been investigated using various techniques such as: hallimond tube flotation response, measurement of adsorption density using I4C labeled oleated, electrokinetic measurements, infrared spectral studies, contact angle measurements and thermochemical measurements using an isothermal microcalorimeter. Alunite has been found to float readily with oleate in the pH range 4-10.5 and its flotation response is enhanced at higher temperatures. The PZC of alunite has been determined to be at pH 7.2 ± 0.15 which agrees with what would be predicted from solution chemistry and from the flotation response with physically adsorbed collectors. Infrared spectra show a specific peak in the range 1585-1600 cm-1 which has been attributed to the formation of an aluminum oleate surface species. Both adsorption density measurements and infrared spectra indicate that during adsorption multilayers are formed. The heat of adsorption of oleate on alunite has been found to be endothermic and of the order of 4-6 KJ/ mole.

Jan 1, 1980

By M. S. Celik, H. Du, J. D. Miller, F. Cheng, O. Ozdemir

"In this paper, recent progress with respect to the flotation chemistry of soluble salt minerals is reviewed, and some of the more relevant issues including the hydration states of ions, the interfacial phenomena of salt surfaces and the flotation behavior of selected soluble salts are discussed. Due to the high solubility, the flotation of most soluble salts has to be carried out in their saturated brines. Anecdotal evidence has suggested that the hydration states of the ions have significant influence on the physicochemical properties of the solutions, the surface charge and wetting characteristics of the minerals, the collector adsorption states and, further, the flotation behavior of the soluble salts. In this regard, reviewing past research findings, efforts are made to establish a correlation between the ion hydration states with the flotation behavior of the soluble salts. Further, advances in understanding the significance of colloid adsorption involved in the soluble salt flotation process are addressed, and future research efforts to understand the soluble salt flotation chemistry are suggested.IntroductionSoluble salt minerals are essential raw materials for the production of a variety of commodities, fertilizers, potassium hydroxide, soda ash, magnesium compounds and other chemicals. These soluble mineral resources can be processed using flotation technology and, currently, more than 80% percent of the world’s potash is produced by the selective flotation of KCl crystals (sylvite) from other salt crystals, predominately NaCl (halite) and other more complex salts (Searls, 1990). Despite the successful application of flotation technology in the potash industry, the mechanisms for collector adsorption on soluble salts have not yet been fully understood and, therefore, have been of considerable interest to flotation researchers for many decades."

Jan 1, 2015

By Mistra M, Hu JS, Wadsworth ME

The fluorite/oleate system has been studied extensively since the begin- nings of flotation research. The well-defined relatively simple crystal structure of fluorite and its ionic bonding make it a model system for study. Our understanding of fluorite/ oleate flotation chemistry continues to grow but as yet remains incomplete. Besides a review of our understanding of this system, recent findings are presented in this paper, and new research horizons are identified.

Jan 1, 1984

By N. R. Tipman, G. E. Agar, L. Paré

The flotation chemistry of the commercial INCO matte separation process was investigated. The slow cooling of Bessemer converter matte forms discrete phases of Cu2S and Ni3S2 and a Cu-Ni alloy. After magnetically removing the alloy, the Cu2S and Ni3S2 are separated by flotation at pH 12.4 (saturated lime) using diphenyl guanidine (DPG) as both collector and frother. DPG has been used exclusively in this flotation process because of its unusual selectivity for copper minerals. The surface product resulting from chemisorption of DPG onto theCu2S was identified as the double salt CU(DPG)2SO4.CU(DPG)2(OH)2. The adsorption followed Langmuir behaviour up to a monolayer coverage. In the absence of DPG, the rapid adsorption of oxygen by Cu2S in flotation pulps was observed. The surface product was identified as the insoluble basic copper sulfate CuS04.3Cu(0H)2 with the production of sulfate ion. In the presence of DPG, the oxidation reaction appears to be suppressed. The frothing properties of DPG and commercial frothers were compared. DPG is not a powerful frother. Batch flotation tests confirmed that DPG is a highly selective collector when compared to most sulfhydryl collectors.

Jan 1, 1976

By J de Cuyper, N. R. Tipman, G. E. Agar, L. Laré, W. Freyberger

The flotation chemistry of the commercial INCO matte separation process was investigated. The slow cooling of Bessemer converter matte forms discrete phases of Cu2S and Ni3S2 and a Cu-Ni alloy. After magnetically removing the alloy, the Cu2S and Ni3S2 are separated by flotation at pH 12.4 (saturated lime) using diphenyl guanidine (DPG) as both collector and frother. DPG has been used exclusively in this flotation process because of its unusual selectivity for copper minerals. The surface product resulting from chemisorption of DPG onto the Cu2S was identified as the double salt Cu(DPG)2SO4,.CU(DPG)2(OH)2. The adsorption followed Langmuir behaviour up to a monolayer coverage. In the absence of DPG, the rapid adsorption of oxygen by Cu2S in flotation pulps was observed. The surface product was identified as the insoluble basic copper sulfate CuSO4.3Cu(OH)2 with the production of sulfate ion. In the presence of DPG, the oxidation reaction appears to be suppressed. The frothing properties of DPG and commercial frothers were compared. DPG is not a powerful frother. Batch flotation tests confirmed that DPG is a highly selective collector when compared to most sulfhydryl collectors.

Jan 1, 1976

By P Wigley

New methods of analysing and modelling flotation circuits have been developed as part of the AMIRA P9 mineral processing research project. A study using these techniques was conducted on the Olympic Dam copper flotation circuit to provide the following outcomes: an estimate of the flotation cell hydrodynamic properties and froth performance characteristics, and identification of potential areas for improvement; an estimate of the feed floatability parameters for basic model development; and identification of potential flotation circuit improvement opportunities. A flotation circuit model of the Olympic Dam copper concentrator was developed using the data collected from mass balanced site surveys, along with hydrodynamic data, froth performance data and numerous laboratory batch flotation tests. The simulator that has been developed from the model has the ability to estimate the influence of selected changes (such as circuit changes) on flotation circuit performance. Several stream destination simulations were conducted to provide guidance for further testwork and possible circuit improvements. The results from these simulations are presented.

Jan 1, 2003

By Dan Alexander, Ivan Crnkovic, Sarah Schwarz

"Several plant studies have been conducted at the Zinifex Century Mine over the past 5 years. For each of the plant studies, surveys of the zinc primary circuit were conducted, characterisation measurements for each operating cell taken, and the floatability components of the ore mapped to develop a model of the circuit. The floatability components and machine parameters were then used to simulate changes in circuit configuration and operating conditions, enabling further potential improvements in circuit performance to be identified.This paper reviews the current flotation practice at the mine, as well as various circuit changes and developments implemented by site. The application of the methodology and the evolution of the standard procedure are also discussed.INTRODUCTIONBase metals were first discovered in the Lawn Hill region of Queensland’s North West in 1869 and the first mining lease in this area was pegged in 1887 over what is now known as the Silver King vein deposit. The area encompassing these veins, which includes the Century deposit, was proclaimed the Burketown Mining Field in 1899. Exploration titles were granted to CRA in 1987, precisely 100 years after the initial discovery at Silver King, hence the name ‘Century’.Century was commissioned by Pasminco in late 1999, with the mine becoming fully operational on 1 March 2000 and the official opening taking place in April. Pasminco had bought the Century and Dugald River deposits from CRA in 1997 for A$345 million, and invested some A$710 million in bringing Century into production. Today, Century is the world’s second-largest zinc mine in terms of its output, having reached full capacity in 2003.The Zinifex Century Limited (“ZCL”) lead-zinc-silver deposit is located approximately 250 kms north-north west of Mt Isa in north-western Queensland. The deposit is a large flat-lying ore body covering an area of some 1.2 by 1.4 km, the 45 m-thick stratabound sulphide orebody is hosted within an 850 m-thick sequence of Proterozoic siltstone, shales and sandstone, amenable to open-cut mining methods. The mine has ramped up to full production delivering five and a half million tonnes of ore per annum, yielding approximately 900,000 tonnes of zinc concentrate and 90,000 tonnes of lead concentrate. Mine life is expected to be about 8 years"

Jan 1, 2008