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By Felipe Beluche Lima, Caio Augusto Silva Santos

Brazil is the largest producer of crude steel in the Americas by BOF process and many challenges come along with the increasing market demand. In the BOF, a tubular wall hood structure has been showing premature failures related to the overlay welded tube technology placed in the hood wall. The main root causes were: thermal fatigue at 1800°C, hot spot formation, high heat-affected zone (HAZ) leading to susceptibility of stress cracking, carburizing corrosion and superficial wearing. Based on that, co-extruded tube technology (named composite tube by Sandvik) was the alternative chosen to enhance hood performance without compromising BOF process. In order to rises safety and productivity, composite tube has 100% metallurgical bond assuring stable expansion, high heat exchange efficiency, better corrosion resistance and less rough surface finishing. It was highly suggested to many others mills due to similar and already existing reported cases.

Oct 1, 2019

By T. Thuy Minh Nguyen, Sathish K. Lageshetty, Paul Bernazzani

The addition of nanoparticles to epoxy resins often results in changes in the physical properties of the material particularly when dealing with thin coatings. By characterizing the mechanism of interactions between nanoparticles and polymer chains the material could be tailored for specific applications or properties such as enhanced biodegradability. This study compared the characteristics of common DGEBA resin coated on a silicon substrate and embedded with nanoparticles of TiO2 and Fe2O3. Specifically, we investigated the rate of curing, and the thermal stability of these nanocomposites. Results show changes in the stability for compounds containing TiO2, while Fe2O3 significantly enhanced the curing rates of the nanocomposites while maintaining similar physical properties.

Mar 1, 2017

By Stryker Magnuson

While probe drills are not strictly necessary for all projects, the incorporation and use of probe drills and pre-grouting adds capability and insurance to boring operations. Water ingress and unstable ground can be resolved before becoming a problem and resulting in costly delays through the use of enhanced, 360-degree probe drilling setups. To do this, proper design of the array of drill ports in the shield, matched to the possible ground conditions, is critical. For ground with exceptional water and instabilities expected, additional probing locations are low-cost additions that can lower risk and increase efficiency. In this paper we will look at recent and ongoing projects including the Lower Meramec Tunnel and Jefferson Barracks Phase 2. We will detail the design of those probe drill arrangements, and our overall recommendations for probing/grouting systems that best suit challenging ground conditions and keep projects running smoothly.

Jun 13, 2023

By Detlef Ehlert

In view of the increasing level of cost pressure on the part of plant owners, optimized plant operation with top product quality and maintenance costs is indispensable. Unscheduled shutdowns with increased repair costs and production downtimes are significantly reduced by preventive maintenance and the stock-keeping of spare parts. To remain competitive in the steel market, it is important for plants owners to operate their plants with the highest possible degree of energy efficiency and at high availability in order to manufacture high-quality products. Plant Monitoring Systems make it possible to optimize the manner of production. An integrated overview of the overall process, under consideration of process stability, product quality, production costs and plant availability ensures a “transparent plant”.

Aug 16, 2017

By Qing Wang

Open pit mines require substantial capital investment at the beginning of the operation and replacement investment at later years. The objective of obtaining the highest possible return on investment in a mining project can only be achieved with an efficient long term production plan. This plan consists of optimally determining four principal elements: 1) the amount of ore and waste to be mined each year, 2) the specific blocks to be mined each year, 3) the optimum mine life, and 4) the ultimate pit limits, which delineate the total reserve to be mined. The existing methodologies only provide solutions to one or two elements, by assuming the others known. Furthermore, the cost of mining each block in the deposit is assumed to be known and independent of the production schedule. The four elements of production planning are interrelated and the cost of mining any block is a function of the production schedule. The ultimate goal of this study, ,whose first steps are' discussed in this paper, is to develop a solution methodology that can simultaneously optimize all four elements of the production planning problem in open pit mines without making a priori assumption on any of the four elements.

Jan 1, 1992

By Brady Butler

Many high capacity metal hydrides exhibit a high degree of stability in the hydrogenated state. This stability leads to a number of significant design problems with regard to the low temperature kinetics and thermodynamics of dehydrogenation. Nanometric metal hydride materials provide a promising route for increasing the reaction kinetics while altering the thermodynamic stability of the material. The use of nanometric metal hydride materials for hydrogen storage has largely been absent because of the difficulties associated with the synthesis of these materials. In this paper, research results on the synthesis of lithium based metal hydrides by vapor phase reactions are presented. The lithium based compounds that have been made in our lab include nanosized powders of metallic Li, Li₃N, LiNH₂ and LiH. The vapor phase process has also been used to custom engineer Li-based materials with other alloying elements or doping elements. The dependence of the characteristics of these materials on synthesis process parameters is studied. The effects of nanoscaled particle sizes on the kinetics of dehydrogenation and hydrogenation reactions are also explored.

Jan 1, 2006

By James A. Brierley, Rong Yu Wan

Bacterial pretreatment was evaluated as a process for enhancing gold recovery from a refractory ore from Newmont Cold's Cold Quarry deposit. This ore is refractory due to sulfide locking of the gold and preg-robbing carbon. The microbe Thiobacillus ferrooxidans effectively oxidized the sulfide component of the ore, but the preg-robbing carbon continued to be active. Thiourea was examined as an alternative to cyanide for extraction of the gold from the biooxidized ore. The thiourea, coupled with CIL, was effective for gold extraction resulting in up to 89% gold recovery for the sulfidic-carbonaceous refractory ore. The thiourea gold complex appears not to be bound by the preg- robbing carbon of the ore when in the presence of recovery carbon (CIL)

Jan 1, 1990

By P. A. Rusin

Many manganiferous silver deposits remain undeveloped because standard chemical extraction methods yield poor recoveries or are ' environmentally unacceptable. Biotreatment of such ore deposits in our laboratory resulted in manganese and silver recoveries of greater than 90%. Ore and sediment samples were collected from mining sites in Colorado and Arizona. Portions of samples were incubated in a semi-solid mineral salts medium amended with 20 mM glucose mid manganese dioxide (Mn medium). The cultures were incubated at 3(fC until manganese reduction was detected by a .color change fr:om .black to clear. Bacteria from these cultures were purified on Tryptic Soy Agar and individual isolates were retested for Mn reduction by an agar overlay method. Bacteria were identified according to Bergefs Manual ?of Systematic . Bacteriology. Most of the Mn-reducing bacteria are Bacillus species. Bacterial manganese reduction kinetic experiments were performed in 52 ml mineral salts broth supplemented with manganiferous silver ore instead of manganese dioiide. These cultures were incubated with agitation for 16 d. Aliquots were removed periodically and analyzed for solubilized manganese by atoniic absorption (AA). Cyanide (1,0 M) Vias added to the remaining ore-medium mixture for a 24 h bottle roll. The supernatant was analyzed for soluble silver by AA. Similar experiments were conducted on a larger scale using 15% pulp density. After bfotreatment of the ore, standard bottle rolls were performed. The pregnant solutions and the residues were analyzed for manganese and silver?using AA or fire assay as appropriate. In sterile. controls-which received no biotreatment, manganese and silver recoveries were 0.3% and 10% respectively; During biotreatment, total manganese solubilizatiori was as high as 99.8%. The reduced manganese could . be stripped from ?the growth medium using hydrometallurgical techniques. Silver recovery vaned from 70% to 92.5%. Microbial treatment of refractory mangairlferous ores can result in high recoveries of manganese and silver. Retention time varies depending upon the relative concentrations of manganese, silver, and other metals in the ore with only two days required in some cases, The biotreatment of ore is environmentally' acceptable while the use. of chemicals such as sulfur dioxide is less so.

Jan 1, 1991

By P. Rusin

Many oxide silver and molybdenum deposits remain undeveloped because chemical extraction yields poor recoveries or is environ-mentally unacceptable. Bio-reductive leaching of such ore samples at MBX resulted in high recoveries of silver and molybdenum. When baseline 3-day cyanide bottle roll tests were conducted on manganiferous oxide silver ore, 13.7% of the silver was extracted. In contrast, 86% of the silver was microbially solubilized into the organic growth medium by bio-reduction with 99.8% dissolution of manganese. A follow-up cyanide bottle roll test yielded an additional 8.5% silver recovery for a total recovery of 94.5%. Baseline 3-day acid bottle roll tests of the iron oxide molybdenum ore yielded 1.8% moly. However, bio-reduction solubilized 93.3% of the moly into the growth medium. An additional 0.3% moly was recovered during the follow-up acid bottle roll test. Microbial treatment of refractory oxide ores with bio-reductive bacteria resulted in higher recoveries of silver and molybdenum than conventional chemical leaching. The bioleaching process occurred at a near-neutral pH at ambient temperatures. The bacterial solubilization of silver and moly was achieved without the use of cyanide or sulfuric acid.

Jan 1, 1992

By Mingchun Lu, Zhe Wang, Mingming Cao, Xiangdong Xing, Shan Ren, Jianliang Zhang, Zhengjian Liu

"The effect of reduction temperature on the vanadium titano-magnetite carbon composite pellets was investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM), and the discussion has put emphasis upon the enhanced reduction mechanism of additives containing CaF2 and NaF in this paper. The results showed that the reduction temperature of 1350°C was needed for the generation, mergence and growing up of metallic iron as well as monomer dissociation between metallic iron particles and slag phase in the vanadium titano-magnetite metallization pellets. The iron compound was completely reduced into metal iron, and Fe2Ti04 was mainly transformed into metal iron, (Fe,Mg)Ti205 and FeTi03 at 1350°C. The maximum metallization ratio was only 88.5% at 13500 for 30 min without any additive. However, with the addition of 3.0% CaF2 or NaF, the metallization degree of pellets could reach up to 94.8% and 92.5%, respectively.IntroductionVanadium titano-magnetite which is mainly distributed in the area of Panxi, Chengde and Maanshan in China is a kind of complex iron ore which contains various valuable metal elements such as iron, vanadium, titanium, etc. Among the above areas, Panzhihua (Sichuan Province in China) area possesses the largest deposits of vanadium titano-magnetite and the future reserves are more than 100x108t, and the reserves of Ti existing as Ti02 reach to 8.7x108t which occupy over 91% of the whole nation and ranked No.1 in the world[1]. Lots of researches on the comprehensive utilization of vanadium titano-magnetite have been conducted in the world. And many technological processes have been applied successfully in industrial production. Among these processes, the process of rotary kiln-electric furnace is employed to recover iron and vanadium in South-Africa, while the process of blast furnace-rotary furnace is widely used in Russia and China. Besides, many researchers have made efforts on employing new direct reduction process to realize the effective comprehensive utilization of vanadium titano-magnetite[2-4]. However, the direct reduction process is only researched in laboratory and it has not been used in industry."

Jan 1, 2013

By Adolfo Pillihuaman Zambrano

Fe-Cr-C production is a very high electrical energy consuming process. Decrease up to 10% of this electrical energy is expected when self-reducing agglomerates are used. This research aims to understand how the synergetic effects are when stronger reductant, like Fe-Si, is substituted for coke in self reducing pellets. Brazilian chromites containing 41.2%Cr2O3 were mixed with petroleum coke and agglomerated with cement as the binder. Small amounts of 1%, 2% and 4% of Fe-75%Si were substituted for the equivalent petroleum coke, and pure silica plus hydrated lime were added for adjusting the slag composition. The mixture was pelletized, dried and submitted at 1773K up to complete the reactions. The results showed that the reduction reactions were 1.4 and 2 times faster with 1% and 2%Fe-Si addition, respectively, than with no addition. The microscopic analysis showed that it was formed a liquid phase, but the pellet did not collapse what indicates that the coalescence of the metallic phase depends on the dissolution of the pre-reduced particles of the chromites into slag.

Jan 1, 2008

By J J. L du Plessis, A Spaeth

The objective of this paper is to demonstrate the efficiency of machine-mounted active explosion suppression systems (AESS). Their proven effectiveness against methane explosions is highlighted, as well as their additional potential when used as an early warning system should frictional sparks occur during the coal-cutting operation at the coalface.Methane and coal dust explosions remain one of the primary and unpredictable risks in underground coal mining. Although technologies such as proactive ventilation, methane monitoring and wet-head cutting systems are widely used as preventative measures, there are no fail-safe controls able to reduce the risk to zero. None of these controls is designed to be able to counter the negligence associated with human error or to deal with rapidly changing face conditions which could lead to flammable gas ignitions. Machine-mounted AESS have been installed on various continuous miners as an additional control to further reduce the risk of ignitions and to act as a safety shield when all the other precautions taken have failed. This was the primary motive for the development of AESS. As an additional feature, the ExploSpot® AESS is being enhanced to identify frictional ignition sources at the coalface that reach a predefined monitoring level. This functionality may serve as a further effective preventative measure.As part of ensuring coalmine operational safety, the detection of frictional ignitions can play a huge role in creating heightened awareness of potentially dangerous situations. By being able to process the frictional spark burning pattern, the AESS could support the decision-making process regarding whether to continue the coal-cutting operation, whether there is a need for maintenance or whether the operation should be stopped completely due to the increased risk of a flammable gas ignition and an ensuing explosion.CITATION:Spaeth, A and du Plessis, J J L, 2015. Enhanced risk reduction using early warning technologies embedded in active explosion suppression systems, in Proceedings The Australian Mine Ventilation Conference, pp 315–322 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By S. Behl

A major limitation in developing successful selective, flocculation schemes is the difficulty encountered in adsorbing the polymeric flocculant only on the desired substrate. In this paper, a correlation between selectivity of flocculant adsorption and separation efficiency is outlined, and a potential technique to achieve selective adsorption of flocculants is discussed.

Jan 1, 1994

By S. Behl

A major limitation in developing successful selective flocculation schemes is the difficulty encountered in adsorbing the polymeric flocculant only on the desired substrate. In this paper a correlation between selectivity of flocculant adsorption and separation efficiency is outlined and a potential technique to achieve selective adsorption of flocculants is discussed.

Jan 1, 1992

By S. Behl

In the selective flocculation process, polymers with specific functional groups can yield highly selective adsorption and, therefore, high separation efficiency. Selectivity in polymer adsorption may also be attained by specific additives that inhibit the adsorption of the flocculant on some solid surfaces but not on others. Generally, these additives have a different chemical nature than the flocculant. In this study, the lower molecular weight fraction of the flocculant was successfully evaluated as a site blocking agent, leading to higher separation efficiency than obtained otherwise.

Jan 1, 1993

By A. Welty, T. Garn, K. Lyon, B. Jakovljevic, R. S. Herbst, M. Greenhalgh, Cytec Solvay Group

"Industrial rare earth separation processes utilize PC88A, a phosphonic acid ligand, for solvent extraction separations. The separation factors of the individual rare earths, the equipment requirements, and chemical usage for these flowsheets are well characterized. Alternative ligands such as Cyanex® 572 and the associated flowsheets are being investigated at the pilot scale level to determine if significant enhancements to the current separation processes can be realized. These enhancements could be defined as higher separation factors, reduced stage requirements, or reduced chemical consumption. Any of these enhancements can significantly affect the costs associated with these challenging separation proccesses.A mid/heavy rare earth element (REE) separations flowsheet was developed and tested for each ligand in a 30 stage mixer-settler circuit to compare the separation performance of PC88A and Cyanex® 572. The ligand-metal complex strength of Cyanex® 572 provides efficient extraction of REE while significantly reducing the strip acid requirements. Reductions in chemical consumption have a significant impact on process economics for REE separations. Partitioning results summarized Table 1 indicate that Cyanex® 572 offers the same separation performance as PC88A while reducing acid consumption by 30% in the strip section for the mid/heavy REE separation."

Jan 1, 2016

By R. O. Ifill

Alternating current electrocoagulation (AC/EC) may be an alternative to chemical coagulation in the thickening of tailings in the mineral, coal and petroleum industries. In the current study, ground silica (d50 as received, 20 µm) served as the model tailings solid with characteristically poor settling behavior. Its natural initial settling rate was 1.6 x 10-3 cm/min. This paper discusses the indirect application of AC/EC via aluminum electrodes to the enhancement of the settling behavior of the silica. ?Indirect AC/EC? means that the silica was coagulated upon dispersion in water that had been treated by AC/EC. The effect of AC/EC retention time on settling behavior is examined and the water chemistry is analyzed. Test results show that the initial settling rate of silica was enhanced by a factor of 4,000 at its maximum of 6.4 cm/min, under the conditions employed. Settling enhancement was achieved upon contact between the AC/EC-treated water and the silica, and the enhanced initial settling rate was dictated by the floc size. The aluminum dosage increased with AC/EC retention time, reaching a maximum concentration that was equivalent to 13.1% of that predicted by Faraday?s law. Complex aluminum ions are considered to have adsorbed onto the silica surface and an adsorption mass ratio of 0.3 mg Al/g silica was the most effective in enhancing settling behavior. Owing to pH change or slow kinetics, aluminum hydroxide precipitation did not lower the ion product ([Al3+][OH-]3) below the KSP of 6.3 x 10-32.

Jan 1, 2011

By R. S. Boorman, L. J. Surges

"Ore reserves at Brunswick Mining and Smelting totalled 101(106) tonnes grading 97 grams tonne-1 silver at the end of 1981. Silver is recovered as a byproduct in the copper, lead and bulk concentrates and is lost to the zinc concentrate and plant tailings. Recovery of silver for the year 1981 was 58,5%. The loss of potential revenue is in excess of Cdn $50(106) year-1 at current silver prices and milling rates.Silver is known to occur in solid solution in galena and as tetrshedrite. Evidence indicating the identity and significance of a third silverbearing mineral assemblage is reviewed and the distribution of silver losses is detailed. Characteristics of each the carrier which may be responsible for observed distribution, including size, surface quality, liberation and composition are considered, and the third carrier is shown to have possible implications for improved silver recovery by other Canadian producers as well as by Brunswick Mining.Silver tetrahedrite tailings distributed tailings and losses occur as coarse, free and as very fine unliberated galena in losses of the third carrier are between the zinc concentrate and are concentrated in the finest size fractions. Process alternatives for enhanced silver recovery by physical and chemical means are reviewed."

Jan 1, 1983

By R. Reifsnyder, J. LaRosa Thompson

Slurry or slimes dispersion is a critical factor controlling the efficiency of sulfide mineral comminution and concentration operations. The PQ Corporation has conducted innovative sodium silicate-based studies to determine the effects of enhanced dispersion on whole ore grinding and flotation behaviors and on downstream separation and cleaning steps. The work has advanced the understanding of the role of pulp rheology on the optimization of commercial grinding, agitation leaching, and flotation operations. This paper reviews the role of sodium silicate as a selective wetting agent and surface charge modifier in sulfide mineral systems, and discusses the results of silicate experiments conducted on various ores of copper and molybdenum, gold, platinum-palladium, and copper zinc, all of which contain clay minerals or highly floatable gangue constituents.

Jan 1, 2002

By Klaus Pronold

Once installed rolling mills can look forward to a long life. Around 40% of the 140 conventional hot strip mills presently in operation were built between 1960 and 1970. 17 of the 29 CSP®-plants were commissioned before the year 2000 and have automation platforms that are obsolete and/or have outdated rolling technology. Keeping pace with the market requirements is an ongoing challenge for producers of flat steel. It is a real balancing act keeping production facilities performing at necessary levels, safeguarding the investment and keeping outage periods to a minimum. To overcome these demanding factors and strike the right balance allowing for the production of higher grade steel that meets the current market price the installation of mechanical equipment as well as automation platforms and process technology must meet the latest technology standards. Being discussed in this paper are the different motives for modernizations along with their impact on project handling and commissioning philosophies. Experience gained during recent modernization projects in the field of flat steel rolling relating to Steckel / plate mills or current CSP® modernizations will be shared and demonstrate that each modernization has its own individual solution. Specific strategies are explained to help optimize production, increase plant agility and maximize the return on investment.

Aug 17, 2017