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By N. Moony

The benefit of gravity separation in improving total gold recovery in grinding circuits has been outlined in a significant number of papers to date. However, the use of batch centrifugal concentrators (BCC) as an industry standard to extract gold has limited the potential for maximizing gravity recoveries -particularly in coarse gold deposits. This is a reflection of the high upgrade ratios obtained by BCC's which has an inverse relationship with recoveries. Survey work in Australia has indicated that installation of the InLine Pressure Jig as an alternative to the Bee will significantly increase recoveries of gold by gravity and, accordingly, increase total gold recoveries and lower operating costs.

Jan 1, 1998

"Mineral separation by exploiting the differences in mineral or metal specific gravities (sg) has been used since antiquity. In the modern era, this is most commonly seen in the recovery of gold by the use of centrifugal concentrators and the separation of coal (low sg) from waste rock (high sg) using heavy media cyclones and jigs. Other metals, notably oxides of tin and tungsten, are successfully recovered using some combination of jigs, spirals and shaking tables. However, many conventional gravity separation systems are limited to fairly coarse (>1 mm) to medium (>100 micron) particle separations due to the limitations of the gravitational separation forces in conventional equipment.Many of the high specific gravity minerals of interest are friable (e.g. cassiterite, wolframite, etc.) and excessive fines are generated in the grinding/comminution circuits which cannot be recovered with conventional equipment and may be lost directly to the tailings stream. Recent developments in centrifugal gravity separation equipment specifically designed for fine or ultra-fine particle separation and recovery have resulted in heavy mineral particle recoveries as fine as 10-20 microns. Ongoing research work has also identified the benefit of closed-circuit, multi-stage gravity recovery circuits using some combination of centrifugal concentrators and conventional equipment (tables, spirals, flotation, etc.) which can substantially increase overall plant recovery and final concentrate grade.This paper will provide details of the evolution of non-fluidized bed gravity concentrators for high sg mineral recoveries, correlate laboratory scale development work with plant results to confirm scale-up, and show how recent flowsheet developments have contributed to significantly improved plant performance.IntroductionGravity concentration is one of the oldest and most cost effective metal and/or mineral recovery systems, ranging from the classic hand panning of alluvial gold, through to the large scale production of a wide range of metals and minerals, including gold, silver, PGMs, black sands, coal and iron oxides. Conventional gravity recovery systems, comprised of some combination of sluices, spirals, jigs and shaking tables have limited application in fine particle (i.e. <100 microns) recovery, or where there are limited differences in particle specific gravities (sg), e.g. the separation of high sg, high value metal oxides (e.g. those of tin, tantalum or tungsten), from medium sg, lower value metal sulfides such as pyrite and pyrrhotite. These unit operations tend to have limited capacity, and while double and triple turn spirals and multi-deck tables have been developed, extensive floor space is often required in order to process the tonnages incorporated in the modern mineral processing plant."

Jan 1, 2017

By B. C. Paul, R. Q. Honaker, K. Ho

Recent research has shown that froth flotation is not effective at treating fine coals (-28 mesh) containing a large portion of middling particles. Due to their relatively large density differences, middling particles can be separated more efficiently using gravity-based processes. The ability of gravity separators to treat fine particles has been limited by the lack of particle inertia relative to the surface drag forces. However, particle inertia can be enhanced by the application of a centrifugal field. A commercial-scale centrifugal Falcon concentrator capable of treating a mass flow rate of greater than 1 tph continuously has been used to evaluate its feasibility for treating fine coal as an alternative to froth flotation. Tests conducted on a -28 mesh fine coal circuit feed have found the Falcon concentrator to be very effective at cleaning the 28 x 325 mesh size fraction. For an Illinois No. 5 coal sample, the ash content was reduced in the 100 x 325 mesh size fraction from about 18% to 8% while achieving a high combustible recovery value of nearly 97%. In addition, the total sulfur content was substantially decreased from 2.6% to 1.7%. The effects of the critical operating parameters on separation performance have been studied and their values optimized.

Jan 1, 1995

By S. Orr

Flow in heaps and dumps is a two-phase flow phenomenon, though for many applications it could be simplified as unsaturated flow. Unlike saturated flow (typical of ground water flow), where permeability is independent of other hydraulic parameters, unsaturated flow permeability depends on the degree of saturation and/or on capillary pressure. Several recent field studies suggest that flows in heaps and dumps tend to concentrate in preferred pathways, bypassing much of the ore. Different preferential flow phenomena are triggered, promoted and influenced by different heap structures, by pretreatment, by the composition of the leach solution and by application rates and schedules. The structure of heaps and dumps is determined and affected by every stage of their construction -from blasting to crushing to conveying and stacking of the material. History of heap construction and operation combined with monitoring, mapping and certain field tests can reveal patterns of flow and transport in a given heap and can shed light on the physical mechanisms behind it. Such insight can provide a first cut on heap leaching enhancement by either eliminating or bypassing physical barriers to flow and leaching. Based on the understanding of the heap structure, advanced flow and transport models can be constructed and further enhance the insight. This insight is essential for understanding cause and effect and can provide a basis for decision making. Further, based on the physically-based models, an intelligent control agent, such as MRDS1, can learn and build a self-learning representation (or a model) of the complex heap leaching system, followed by dynamic optimization and planning of heap leaching and heap rinsing.

Jan 1, 2003

By V. Vesselinov, S. Orr

"Enhanced heap leaching - Part 1: Insights" (Orr, 2002), different flow and transport phenomena that could significantly reduce leaching recovery were investigated. The combination of such understanding with advanced flow and transport modeling establishes the link between cause and effect, thereby, directing operators to optimal design and construction of new heaps. Modeling of flow and transport in heaps could also point to a unique change in application method or rate that would maximize leaching enhancement of an existing heap under existing situation and leaching history. The use of such a model is cost effective in that it can simulate multiple scenarios of alternative leaching enhancement methods. By simulating a large number of irrigation scenarios, such a model can point to the optimal and/or the most promising alternatives for a particular heap. The authors&apos; simulations concentrate on the effects of changes in application rates and heap design on changes in flow paths and enhanced leaching recovery. Based on such simulations, an intelligent control agent, such as Multiple Resolution Decision-Support System (MRDS) (Meystel and Albus, 2002), could build a new representation of the complex heap-leaching system. And, by learning from historical data and current information, it could provide optimal management of heap leaching and heap decommissioning.

Jan 1, 2003

By D. Doepker

The dissolution of metals from various metal/ non-metal mine tailings has been studied through column leach tests at US Bureau of Mines laboratories. Metal mobilization in unsaturated columns was consistently greater than metal dissolution in water-saturated columns. Leachate pH was also frequently lower when a leachant was passed through columns but showed a mixed residence-time dependence. On the other hand, metal and sulfate ion concentrations in the leachate increased with dry-cycle residence time. Results suggest that acid formation through atmospheric oxidation of pyrite may compete with non-acid-forming oxidation of other metal sulfides. The two processes lead to decreased pH and increased metal mobilization, respectively. Leach tests using sodium lauryl sulfate indicated that microbial activity was not a factor in these studies.

Jan 1, 1991

By H. -S. Yoon, C. -J. Kim, K. W. Chung

"With the final goal of ultrasonic application to ion exchange in a resin-in-pulp (RIP) system, the feasibility of an indirect ultrasonic application with a submersed ultrasonic probe was investigated first for the enhancement of ion exchange in the following resin-in-solution (RIS) system: Lewatit MonoPlus MP 600XL in an artificial solution with 106 ppm uranium. Ultrasonic radiation enhanced the ion exchange efficiency without mechanical degradation of resin. For 3.6 g/L of resin, the enhancement was 79 percent after 10 min of ion exchange and it gradually decreased to 11 percent at 60 min. In addition, a preliminary test of the mechanical stability of the resin in the RIP system showed little mechanical fracture of the resin due to ultrasound, which indicates that indirect ultrasonic application by a submersed ultrasonic probe is applicable for RIP systems. IntroductionIn uranium ore processing, the ion exchange process has been used on a commercial scale for preconcentration and purification (Gonzalez-Luque and Streat, 1984). The ion exchange process is divided into two processes: (1) a resin-in-column process with the uranium-bearing solutions passed through columns containing resins and (2) a resin-in-pulp (RIP) process with the leached ore pulp exposed to resins. The latter does not require the separation process of leach liquor and ore solids, which reduces process costs. This process, which has been developed commercially since 1955, has a certain drawback. The adsorption rate and efficiency in the RIP process are relatively low, so numerous contacts between resins and leached ore pulp are needed, which adds to the cost (Merritt, 1971). It is necessary to study methods to reduce process costs.Ultrasound can intensify mass transfer, increase the rate of chemical reactions, and change reaction pathways (Thompson and Doraiswamy, 1999; Luque de Castro and Priego-Capotem, 2007; Adewuyi, 2001; Luque-Garcia and Luque de Castro, 2003). It has great potential in chemistry and is especially considered to be a promising method for enhancing mass-transfer-limited processes, such as ion exchange. Enterzari and Tahmasbi (2009) reported the effect of ultrasound on water softening by ion exchange. Band et al. (1997) proposed a modulated ultrasound application to water desalination with ion-exchange hollow fibers. These reports revealed that ion exchange kinetics could be enhanced by the application of ultrasound. As for hydrometallurgy, Feng and Aldrich (2000) reported that the elution of an ion exchange resin was enhanced by the use of ultrasonication."

Jan 1, 2015

Digitally enhanced Landsat MSS images are being used&apos;in delineating the structural and tectonic features in the Arabian Shield as part of a project funded by King Abdulaziz City for Science and Technology (KACST) of Saudi Arabia. The delineated features together with statistical modeling and structural analysis are to assist in an improved understanding of the evolution and mineralization of the Arabian Shield. Specific emphasis is to be given to relating the extracted linear features to the location of known mineral occurrences and areas of potential geologic hazards. A number of textural (spatial) and spectral enhancement techniques have been applied, to the MSS data covering selected areas, in selecting the most optimal enhancement product for visually delineating the structural geologic .features.

Jan 1, 1988

By O. G. Olvera

"Refractory sulfidic ores consist of materials in which gold occurs finely disseminated within metallic sulfides or forming solid solutions, with pyrite and arsenopyrite being the two sulfides most commonly associated with gold. Typical cyanide operations show poor performance and require oxidative pretreatments to increase gold recovery. Pretreatment alternatives include roasting, pre-aeration, acidic and alkaline high pressure oxidation, and bacterial oxidation. The presence of arsenic, however, introduces a serious disadvantage to the use of roasting and bacterial leaching, while high pressure oxidation involves high capital costs. This work focuses on evaluating the effect of the addition of a carbon resin as a sulfur collector on the oxidation of different arsenopyrite concentrates under atmospheric tank leaching (ATL) conditions. The addition of the resin improved the oxidation of sulfides and favored the formation of elemental sulfur over the generation of sulfate. The use of AF5 in ATL resulted in higher gold recoveries under standard cyanide carbon-in-leach and thiosulfate leaching.INTRODUCTION Refractory sulfidic ores consist of materials in which gold occurs finely disseminated within metallic sulfides or forming solid solutions, with pyrite and arsenopyrite being the two sulfides most commonly associated with gold. Gold is not readily accessible to solutions in these types of ores and typical cyanide operations show poor performance, thus making the use of oxidative pretreatments a requirement to increase gold recovery. Pretreatment alternatives include roasting, pre-aeration, acidic and alkaline high pressure oxidation, and bacterial oxidation. The presence of arsenic, however, introduces a serious disadvantage to the use of roasting and bacterial leaching, while high pressure oxidation involves high capital costs. The use of carbonaceous materials to enhance the dissolution of sulfides is not novel, and leaching additives such as coal, activated carbon and carbon powder have been considered for the improvement of bioleaching, atmospheric leaching, and pressure oxidation leaching processes. However, this type of technology has been focused mainly on the recovery of copper from copper concentrates containing chalcopyrite with less attention paid to other sulfides."

Jan 1, 2017

By A. Miura, R. Winarko, D. B. Dreisinger

Chalcopyrite leaching in acidic ferric sulfate media at ambient temperature exhibits slow kinetics and poor leaching efficiency, which is typically attributed to surface passivation. Recently, the presence of small amounts of iodide in the leaching media has been reported to significantly accelerate chalcopyrite dissolution. To further explore the behavior of chalcopyrite leaching in the presence of iodide, it is essential to determine the factors that control the leaching kinetics. In this study, we investigated the effect of initial solution potential, iodide concentration, particle size, and temperature on the kinetics of copper extraction from chalcopyrite. The key in the experimental setup was to minimize iodide loss by iodine evaporation and precipitation as cuprous iodide. The former was achieved by performing the leaching tests in fully sealed leaching systems. The latter was achieved by maintaining the solution potential higher than 420 mV (versus Ag/AgCl electrode), where formation of CuI precipitate is possible. The experimental results show that higher solution potential and higher iodide concentration had a pronounced positive effect on the rate of chalcopyrite dissolution. There was no effect associated with particle size, which might be due to the narrow size range tested. The positive effect of increasing temperature only manifested itself when the solution potential was sufficiently high. INTRODUCTION The main challenge of chalcopyrite leaching using ferric ions as the oxidant at ambient temperature is the slow kinetics and poor extraction. The reason for this leaching behavior has been attributed to passivation resulting from formation of insoluble passivating layers on chalcopyrite surfaces, which could be metal-deficient sulfides, elemental sulfur, polysulfides, and iron precipitates (Klauber, 2008). To overcome passivation, technologies using higher temperature and pressure have been developed to leach chalcopyrite concentrates, such as the CESL process (Mayhew, McCoy, Mean, & Woeller, 2013), FLSmidth Rapid Oxidative Leach (ROL) process (Mulligan et al., 2017), Galvanox (Dixon, Mayne, & Baxter, 2008), Albion process (Hourn, Turner, & Hourn, 2012), HydroCopper (Hyvärinen & Hämäläinen, 2005), TPOX (Dreisinger, 2006), and AAC/UBC process (Dreisinger, Dempsey, Steyl, Sole, & Gnoinski, 2003). Even though they are effective in accelerating copper leaching kinetics, those technologies typically have higher capital and operating costs associated with production of concentrates and application of autoclaves. This makes them unsuitable for treating low grade primary copper sulfide ores.

Jan 1, 2019

By Jose Hector Figueroa P.

Mexicana de Cananea, S.A de C.V. is a major copper producer mining a large deposit of the disseminated porphyry type considered one of the largest copper resources of the world with 2.7 billion tons of 0.60% copper for the mill plus 4.1 billion tons of averaging 0.26% copper for leaching. Mining of low grade sulfide leach ore, has been an important part of the overall production of the open pit mine which started in 1944. Before this time all the mining in Cananea was by underground methods. The leaching process in Cananea began on the 1920&apos;s with in situ operations in the underground mine and small dumps up to the 1950&apos;s. Large scale leaching operations began in 1960 and the copper solutions produced were treated in precipitation plants until 1,980 when the first SX/EW Plant was put in operation in Cananea. Leaching action is essentially ferric-bacterial, with no fiesh acid added to the leaching solutions. Traditionally, 5540% copper extraction is recovered fiom ROM, 70- 120 meter high leach dumps in 80 months of leaching. Cananea has successfully improved copper recoveries by implementing several actions that include: 1. Stripping of old dumps. 2. Leaching of old dumps through slotted casing. 3. Crushing conveying leach ore to minus 8 inch and stacking it in 30 meter lifts. As result of these actions, copper recovery has been increased&apos; to about 70% of total copper with actions 1 and 2 and up to 85% in half the time by crushing-conveying the leach ore, based on the same solubility index of the run-of-mine ore. This paper describes the above actions that were implemented to enhance the leaching recoveries from. sulfide leach dumps and the economics of such actions.

Jan 1, 1999

By G. Deschênes

In the last 4 years, the high price of silver attracted more interest for improving its extraction. Metallic silver and silver minerals require a high concentration of cyanide and show slow leaching rates and poor extraction. This investigation determined the effects of dissolved oxygen, lead nitrate and a pretreatment on silver leaching from slurry containing quartz mixed with metallic silver and high purity acanthite. Stephanite, pyrargyrite and polybasite were also used in the study. The silver minerals were characterized by chemical assay, X-ray diffraction analysis (XRD), image analysis (MP-SEM-IPS) and electron microprobe analysis (EMPA). Increased dissolved oxygen of the slurry produced the fastest silver leaching kinetics. The leaching of silver from high purity acanthite was determined under various conditions and compared to a new process called ?CANMET Enhanced Leaching Process (CELP). For a slurry containing acanthite, a 23% improvement (from 76% to 99%) in silver extraction was obtained with the CELP. In presence of pyrargyrite and polybasite, silver extraction increased from 75% to 90% and 86% to 99% respectively using the CELP. No improvement was obtained for the slurry with stephanite (99% extraction in 72 hours). However, the sliver leaching rate was much faster with the CELP. XPS analysis of individual silver mineral particles showed that CELP leached surfaces were considerably more oxidized relative to the conventional cyanidation leached surfaces. Leaching of two gold/silver ores indicated that the efficiency of the CELP increased with the refractoriness of the sample. Gold extractions were comparable for the two technologies while silver extraction improved up to 5% (70g/t) for the CELP. The final leach solutions contained lower concentrations of copper, which consequently reduces the effluent treatment costs.

Jan 1, 2014

By M. Misra

Improved liberation and flotation of kerogen from eastern oil shale were accomplished with high-temperature grinding and a1 so with the addition of fuel oil during the grinding stage. Liberation measurements indicated that possible coalescence and aggregation phenomenon of kerogen particles during grinding may reflect this behavior. Additionally, ultrasonic treatment of the rougher concentrate prior to cleaning improved the quality of separation.

Jan 1, 1984

High Pressure Grinding Rolls (HPGR) are said to be a good option in new grinding circuits. Due to their low energy consumption compared to other grinding systems such as SAG milling, there is a strong incentive to check their behaviour for certain ore types. With rising energy prices the operation will become even more beneficial in future. As published in the past, the HPGR is claimed to increase the liberation of the valuable mineral component within an ore. An investigation at the research centre of Polysius was conducted to substantiate the liberation behaviour in finish grinding operations. A pilot scale HPGR test unit (POLYCOM MAGRO) with a roll diameter of 950 mm and processing capacity of 80 t/h was used. Grinding tests were completed with a screen and a two stage drying air separation process (SEPOL). Analysis included standard screen analysis, fractional XRF and modern MLA technology. A technique was developed to oppose the amount of produced slimes (resuming bad flotation) against the positive effect of producing high mass fraction at flotation-easy sizes. The paper shows how effective the use of a dry grinding separation could be in terms of production of mass of liberated metal.

Jan 1, 2012

By R. Erpelding

High Pressure Grinding Rolls (HPGR) are said to be a good option in new grinding circuits. Due to their low energy consumption compared to other grinding systems such as SAG milling, there is a strong incentive to check their behaviour for certain ore types. With rising energy prices the operation will become even more beneficial in future. As published in the past, the HPGR is claimed to increase the liberation of the valuable mineral component within an ore. An investigation at the research centre of Polysius was conducted to substantiate the liberation behaviour in finish grinding operations. A pilot scale HPGR test unit (POLYCOM MAGRO) with a roll diameter of 950 mm and processing capacity of 80 t/h was used. Grinding tests were completed with a screen and a two stage drying air separation process (SEPOL). Analysis included standard screen analysis, fractional XRF and modern MLA technology. A technique was developed to oppose the amount of produced slimes (resuming bad flotation) against the positive effect of producing high mass fraction at flotation-easy sizes. The paper shows how effective the use of a dry grinding separation could be in terms of production of mass of liberated metal.

Jan 1, 2012

By R. Mohan Srivastava

In any operating mine, especially in precious metals operations, immediate improvements in profitability m readily achievable through more effective grade control. Just as the oil industry has come to recognize that enhanced oil recovery (EOR) in existing oil fields yields a higher return on investment than exploring for new oil, so too must the mining industry recognize the benefits of enhanced metal recovery (EMR). Current grade control practices are generally dismal. The very word "control" suggests a willingness to make the best of a bad situation -- as in "damage control" or "disease control" -- and a failure to perceive the opportunities for improved profit. While damage and disease can merely be controlled, success and improved profit can be engineered. This paper presents one approach to enhanced metal recovery. It shows how existing methods can be used to address the issue of ore/waste discrimination. The following sections outline the problem, describe the current state of the practice of grade control, propose an alternative approach and. illustrate the application of the proposed alternative to actual blasthole data from an operating gold mine.

Jan 1, 1992

By Billy W. Parks

This paper reports on the first 2 years in operation of a special-purpose coal handling rig which provides blending, temperature reduction, and continuous, automatic mechanical sampling as part of midstream barge to ship coal transfers. Briefly reviewing some of the characteristics of coal handling peculiar to midstream transfers, the paper discusses how the most beneficial aspects of midstreaming were enhanced through the design of this blending and sampling rig.

Jan 1, 1986

By A. Martin

Detailed porewater profiles of arsenic and other interstitial metabolites were used to assess the relationship between trophic status, sediment redox chemistry and arsenic mobility in a historic tailings repository. The results demonstrate that in eutrophied systems which exhibit greater sediment oxygen demand, the depth of the Fe(III) redoxcline, and hence depth of arsenic release, may lie in close proximity to the sediment-water interface. As a result, arsenic scavenging mechanisms are significantly reduced, resulting in a greater flux of arsenic to the water column. Such considerations have important implications for the management of pit lakes, tailings ponds and contaminated lakes which may consider: 1) the discharge of sewage to the water body during operations; and/or 2) post-closure fertilization as a remediation strategy.

Jan 1, 2002

By R. I. Iacobescu, Y. W. Chiang, A. Van Audenaerde, R. M. Santos, T. Van Gerven, P. Knops

In this work, we explore a novel mineral processing approach using carbon dioxide to promote mineral alterations that lead to improved extractability of nickel from olivine ((Mg,Fe)2SiO4). The precept is that by altering the morphology and the mineralogy of the ore via mineral carbonation, the comminution requirements and the acid consumption during hydrometallurgical processing can be reduced. Furthermore, carbonation pre-treatment can lead to mineral liberation and concentration of metals in physically separable phases. In a first processing step, olivine is fully carbonated at high CO2 partial pressures (35 bar) and optimal temperature (200 °C) with the addition of pH buffering agents. This leads to a powdery product containing high carbonate content. The main products of the carbonation reaction include amorphous colloidal silica, chromium-rich metallic particles, and iron-substituted magnesite ((Mg1- x,Fex)CO3). Carbonated olivine was subsequently leached using an array of inorganic and organic acids to test their leaching efficiency. Compared to leaching from untreated olivine, the percentage of nickel extracted from carbonated olivine by acid leaching was significantly increased. It is anticipated that the mineral carbonation pre-treatment approach may also be applicable to other ultrabasic and lateritic ores.

Jan 1, 2014

By Ralph Harris, Xia Qi, Frank Komsic

"Gold cyanidation kinetics which are often limited in commercial operations by the rate of oxygen dissolution from gas bubbles into the slurry, are discussed. Emerging technologies for improving the rate of oxygen dissolution are compared and the gas efficiency, energy use and operating performance of inverted cones and a device based on a jet diffuser are examined. The effect of solids loading is also reviewed and a relationship between operating parameters and the kilograms oxygen dissolved per kilowatt-hour is presented.Inverted cones are shown to create slurry settling problems at high gas flow rates and surface tension lowering agents are shown not to greatly improve the overall rates of oxygen dissolution.The novel jet diffuser technology operates at a range of gas to liquid ratios that improves its energy use over conventional technology and the performance of a number of designs are discussed.Gas efficiencies as high as 35% were observed with the novel diffusers at 40 cm diffuser immersion and are expected to increase at greater immersions. Energy use of 1.8 kg 02 I kWh were estimated for prototype full size diffusers operating at 100 cm immersion. Energy use of 3.S kg 02 /kWh is conservatively expected at 600 cm immersion.IntroductionGold ExtractionGold that can not be recovered by gravity separation can be recovered by either the Merrill-Crow process or the newer carbon in pulp (CIP) or carbon in leach (CIL) processes 1. Reductions in operating costs and improvements in gold recovery are central mill operating strategies. The present paper examines the potential for improvement that can be achieved in the gold cyanidation step of gold recovery. This paper introduces a number of emerging technologies and provides a basis for comparison of the performance. It shows that the basis for comparison of a particular technology depends on the type of gold extraction circuit employed and the type of reactants employed."

Jan 1, 1996