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By Clarence Merritt

STAINLESS iron, as mild stainless steel is usually called, an alloy ranging from 11.50 to 15.00 per cent chromium with carbon under 0.12 per cent, has been considered to be not appreciably affected in respect to corrosion resistance by heat treatment. This metal, while one of the most widely used of the "straight" chromium stainless alloys, has failed in many applications because of insufficient information regarding heat treatment. These failures have been attributed to many possible causes from an inherent lack of resistance to corrosion and misapplication to mysterious electrolytic effects or comparatively minute non-metallic inclusions. Many uses for a steel with such excellent physical properties is are latent in this alloy have been lost on account of corrosion failures which could have been avoided by applying proper heat treatment. The alloy has not received the recognition or attention it should because of the fact that' the details of its metallurgical behavior were not thoroughly understood. Response to heat treatment of the steel is well known as regards tensile properties, 1,2 but its application has been for improvement in tensile characteristics or on account of machining considerations rather than for corrosion prevention. The potential user of this steel has not been clearly advised in papers, either technical or commercial, that have been written about it in the last 10 years or more, of particular features that are of prime importance in developing the excellent properties of this metal. The data to be presented in this paper are concerned mainly with the effect of heat treatment on the corrosion resistance, but a study has also been made of the concurrent microstructural changes and an explanation developed for the phenomena revealed, as well as a correlation to the other physical properties-hardness, tensile characteristics and impact strength. Stainless steel, largely used for cutlery purposes, an alloy of approximately 13.00 per cent Cr with 0.30 per cent C, must be hardened and the surface prepared by polishing or pickling for best resistance to staining and corrosion.3 Monypenny reports that a loss of hardness is

Jan 1, 1932

By E. Dalgaard

During linear friction welding of titanium alloy Ti-5A1-5V-5Mo-3Cr (Ti-5553), the weld zone exhibits beta (B) grain refinement and alpha (a) phase depletion that have the combined effect of deteriorating the mechanical performance of the weldment. In this work, linear friction welded Ti-5553 was subjected to pre- and post- weld heat treatments in order to determine the conditions under which a phase depletion could be mitigated in the weld zone and thermomechanically affected zone (TMAZ). The mechanical response of the welded samples to the heat treatments was determined by performing tensile testing at room temperature. While the pre-weld heat treatments had no significant effect, the post-weld heat treatments were instrumental in restoring the strength of the starting (heat-treated) material.

Jan 1, 2011

By S. K. Shaha, W. Kasprzak, D. L. Chen, J. Friedman, F. Czerwinski

The role of solutionizing conditions within the T6 heat treatment of the cast Al-Si-Cu-Mg alloy with micro-additions of Zr-Ti-V was assessed in terms of their influence on microstructure and mechanical properties. As a solution treatment, a single step process at 485 and 510oC and a two-step process at 510 and 525oC for varying time intervals from 0.5 to 9 h, were examined. In all cases, solution treatment was followed by isothermal aging at 150oC for 100 h. The microstructural analysis showed that the solution treatment changed the eutectic silicon morphology from needle-like, present after casting, to spherical shape in the T6 state and that the extent of changes was strongly influenced by temperature and time. The Cu- and Mg-rich phases completely dissolved during solution treatment while the Fe-containing phase, Al8Si6Mg3Fe, remained partially in the microstructure. The Ti, V and Zr containing phases, Al13Si2Ti3Zr and Al3Si26FeTiV10, present in as-cast state, were partially dissolved during solution treatment, reducing their size by 10 - 48%. The studied alloy reached the maximum ultimate tensile strength of 335 MPa and yield stress of 303 MPa for two-step solutionizing with a total time of 4.5 h. It is concluded that the two-step solution treatment resulted in higher tensile properties than the single-step process.

Jan 1, 2015

By B. Egeberg

IN A previous paper1 the authors dealt with the physical properties of cold-rolled and heat-treated Britannia metal of the approximate composition Sn, 91 per cent., Sb, 7 per cent. and Cu, 2 per cent. It was found that cold rolling to more than 50 per cent. reduction produced a continuous softening of the metal when measured by the Brinell machine, whereas the Shore instrument indicated increased hardness; that the strength of the material followed the Brinell hardness and that the metal therefore became weaker the more it was cold-rolled; and further, it was found that hardness and strength could be largely restored to the cold-rolled metal by "baking" for about one hour at any temperature, between 200° and 450° F., the melting point. The higher the baking temperature, the more effective was the heat treatment as far as increased hardness was concerned. It seemed to be of little importance whether the metal was soaked or not at the baking temperature for a great length of time and the rate of cooling seemed to be immaterial. The present paper deals with the same alloy and more particularly with the resistance towards various forms of stress - tensile, bend and deep drawing. The metallography of Britannia metal has in part also been covered and an explanation attempted for the abnormal behavior of this alloy.

Jan 1, 1929

By G. Morin, S. Amira, F. Chiesa, B. Duchesne

"The effect of heat treatment on the stress corrosion cracking (SCC) resistance of A206 aluminum alloy was studied using the breaking load test according to ASTM G139 standard. This method uses the residual strength measurement from tensile test specimens previously stressed axially while exposed to the 3.5% NaCl alternate immersion test according to ASTM G44 standard. The residual strength after exposure is used as a measure of SCC degradation. The performed heat treatments were conventional natural aging T4 and artificial over-aging T7 tempers in addition to artificial aging T6 temper added for purpose of comparison. These tests showed that A206-T4 has a good resistance to SCC at pre-loads up to 100 MPa while A206-T7 was prone to SCC for pre-loads of 0 and 50 MPa, and showed total loss of ductility for pre-load of 100 MPa. Both A206-T4 and A206-T7 pre-loaded at 150 MPa showed poor resistance to SCC. A206-T6 showed the worst susceptibility to SCC as it lost all mechanical resistance at the end of the alternate exposure to 3.5% NaCl solution, even without any applied pre-load. Metallographic analyses showed that the resistance of A206 alloy to SCC is mainly affected by the transition from pitting to intergranular corrosion attack. The initiation and the propagation of intergranular corrosion attack might be assisted by high stress concentrations in the pits, particularly for pre-loads higher than 100 MPa. The transition from pitting to intergranular corrosion can also be promoted by hydrogen evolution from growing pits, which supports crack propagation by hydrogen embrittlement.INTRODUCTIONA206 aluminum-copper casting alloy offers ones of the best mechanical properties among the aluminum foundry alloys. This alloy belongs to the 206 alloy family developed in 1970s as an alternative to the highly resistant and ductile but more expensive Ag containing 201 alloy (Tiryakioglu, 2009). A206 showed also good low cycle fatigue strength (Sigworth, 2002). These properties made A206 alloy a strong candidate for some vehicles lightweighting applications. In spite of its interesting properties cited above, A206 alloy was rarely used in critical applications due to its tendency for hot tearing and stress corrosion cracking (SCC). Studies of A206 hot tearing behavior showed that this tendency can be reduced by improving castability and by grain refinement (Sigworth, 2002). The optimisation of the casting design can also prevent the tendency toward hot tearing. The SCC of aluminum-copper alloys arises from their susceptibility to localised corrosion, especially in chloride containing media. The localised corrosion in Al-Cu alloys is caused mainly by their heterogeneous microstructure, where the presence of many phases leads to the formation of micro-galvanic coupling with the matrix. However, most of the studies aimed at investigate the SCC of Al-Cu alloys concerned the wrought ones, especially the AA2024 alloy tempered in the T3 (or derivative) condition and few studies concerned the 206 and cast alloys in general (Alexopoulos, 2009 and 2016; Campestrini, 2000; Vogt, 1998; Talamantes-Silva, 2008; Zhang, 2003). Jean et al. (Jean, 2009) studied the effect of heat treatment on SCC behavior of B206 alloy using alternate immersion technique and grain boundary attack method and did not find direct correlation between the two methods. Another study showed that aging of 206 alloy may make a casting susceptible to SCC (Sigworth, 2002). However, these studies did not provide detailed information about the mechanisms of SCC of 206 alloy, as well as the effect of the stress intensity. The present work investigates the effect heat treatments and the stress intensity on the morphology of the corrosion attack and the SCC behavior A206 aluminum alloy. This study uses the breaking load test according to ASTM G139. This test utilizes direct tensile specimens and was developed to give a more quantitative measure of the SCC performance of resistant aluminum"

Jan 1, 2016

By M. M. Kim

As-electrogalvanized coatings of pure Zn, Zn-11% Fe, and Zn-18% Fe coatings were characterized in terms of initial crystal structure and surface morphology. Samples were then subjected to heat treatments simulating the paint bake cycle of automobile manufacturers. Surface morphology changes were correlated with the process variables, and crystallo.graphic changes were interpreted by mapping heat treatment routes on the Fe-Zn phase diagram. The morphology of pure zinc electrogalvanized coatings with heat treatment from platelets to smeared platelets. The zn-11% Fe coating changes with heat treatment from tetrahedral nodules to a mixture of round and tetrahedral nodules, with the Zn-:18% Fe coating always having round nodules. Regarding crystal structure, a critical transformation time can be defined at any selected temperature, below which the crystal structure does not change. This temperature is related to iron content.

Jan 1, 1990

By Haofeng Xie, Lijun Peng, Xujun Mi, Xue Feng, Xiangqian Yin, Zhen Yang, Guojie Huang

The Cu/Al composite wires have been widely used in cable industry. Especially in the development of aerospace, the light weight character of wires is particularly important. The wires are fabricated by a drawing process and heat treatment. Mechanical and electrical properties are measured and analyzed. The bending behavior is studied by scanning electron microscope. INTRODUCTION Cu/Al composite is a typical bimetallic composite that has been used in plenty of fields such as automobile and aerospace. The composite has the advantages of excellent conductivity as well as low weight, which cannot be obtained from single copper or aluminum. Industrial products of Cu/Al composite include Cu/Al composite joints (Uscinowicz, R., 2013), Cu/Al bimetallic sheets (Li, X. et al., 2011), Cu/Al flat bar (Wu, Y. & Liu, X. & Xie, J., 2014) and CCA wires (Ahmed N., 1978). CCA wires refer to the composite wires that copper layer concentrically coated on the surface of aluminum core conductor, implementing solid combination of two metals on the interface and forming an integral. At present, the aircraft cable generally use copper or copper alloy conductor, which makes the wire in the aircraft occupy a considerable proportion due to the large density of copper. Therefore, the use of Cu/Al composite wires instead of copper wires for weight loss, is of great significance to the development of aerospace technology industry. Heat treatment is an indispensable procedure to improve plasticity during cold working process, which is of great importance to preparation of wires (Wang, Q. et al., 2008). During the heat treatment, the Intermetallic Compounds (IMCs) are inevitable formed at the contact area of Cu/Al due to the occurrence of diffusion (Lee, S. et al., 2012). According to the results of former researchers, kinds of IMCs were discovered. Antoine Gueydan (2014) identified the formation of three IMCs (Al2Cu, AlCu, and Al4Cu9) at the interface between copper and aluminum after thermal aging. IMCs have a significant effect to the properties of Cu/Al wires. Bending performance is a vital property for the actual application of wires. The brittle IMCs may create a stress concentration that can cause crack initiation during bending process. This work focus on the mechanical properties of Cu/Al composite wires after heat treatment. The effect of various annealing condition on mechanical and electrical properties are studied, in order to find the appropriate annealing conditions, which produce optimal combination properties of Cu/Al clad composite wires. Bending fracture of composite wires is discussed by morphology observation.

Jan 1, 2019

By H. Jung

The microstructures and grain sizes of nanocrystalline Co and Co-1.1 wt % P alloys were characterized by X-ray diffraction. The corrosion properties of as-deposited and annealed Co-l.l wt % P alloys and pure nanocrystalline Co were studied in a deaerated 0.1M H2SO4 solution using electrochemical measurements and XPS surface analysis. Potentiodynamic polarization testing and impedance measurements revealed that an addition of P to pure nanocrystalline Co improved the anodic-corrosion resistance, however, this enhanced corrosion resistance was compromised by the heat treatment process at 350 and 800°C. The corroded surface of annealed nanocrystalline Co-1.1 wt % P at 350°C exhibited a more porous P-enriched layer compared with the as-deposited case. A sample annealed at 800°C corroded uniformly showing second-phase precipitates. The enhanced corrosion resistance of as-deposited nanocrystalline Co-1.1 wt % P was attributed to the elemental P on the surface that acted to hinder the anodic dissolution kinetics of surface Co following an initial selective dissolution of Co. However, at a higher anodic overpotential region, the superior corrosion resistance of Co-l.l wt% P alloys did not last because of the formation of a non-protective surface film consisting of mainly hypophosphite and phosphate as well as elemental P.

Jan 1, 2005

By I. K. Chopde, M. M. Dhobe, C. L. Gogte

"The quality of machined surface is becoming more and more important to satisfy the increasing demand of component performance and its reliability. While machining any component, it is necessary to satisfy the surface integrity requirements. Heat treatment plays an important role in improving the characteristics of the material.This work investigates the effect of heat treatment on the surface characteristics of AISI D2 tool steel after Wire-Electro Discharge Machining (W-EDM). The test specimens were prepared by hardening and tempering and then machined with Wire-Electro Discharge Machining process. Optical and scanning electron microscopy, surface roughness and micro hardness tests were conducted to study the surface characteristics of the machined surface. After characterization based on microstructures and test results, it is observed that the recast layer droplets are of smaller size with reduced white layer thickness resulting in higher hardness and lower surface roughness.IntroductionWith the development of mechanical industry, the requirement of alloy materials having high hardness, toughness and impact resistance is increasing. At the same time the quality of machined surface is becoming more and more important to satisfy the increasing demands of component performance and reliability. When machining any component, it is necessary to satisfy the surface integrity requirements. Surface integrity has two important parts. The first is surface texture, which governs mainly surface roughness. The second is surface metallurgy, which concerns to the nature of surface layer produced in machining [2]."

Jan 1, 2012

By Onder Guney, Erdem Demirkesenm

"In this study, the crystallization behavior and thermal expansion coefficient of a lithium disilicate (LS2) based glass-ceramic derived from SiO2-Li02-AhO3-K2O-ZrO2 system was investigated by using x-ray diffraction (XRD), high temperature x-ray diffraction (HTXRD), differential thermal analysis (DTA) and dilatometer techniques. Analytical reagent grade chemicals were chosen as raw materials for preparing glass batches. Nucleation and crystal growth heat treatments were planned according to DTA results. The amounts of the amorphous and crystalline phases developed during the heat treatments were determined by quantitative XRD. XRD results of crystallized samples showed simultaneous formation of lithium silicate (LS) and quartz in the early stage of the crystallization followed by formation of lithium disilicate (LS2) at higher temperatures. The thermal expansion coefficients of glassceramics were also measured depending on the applied heat treatments.IntroductionSignificant developments occurred in all ceramic materials provide the fabrication of high quality dental implants [1]. Glass ceramic based dental restorations like dental inlays, crowns, bridges and veneers are becoming increasingly popular with their reliable and durable performance [2,3]. In addition to their advanced functional properties, glass ceramic implants especially lithium disilicate glass ceramics also face the esthetics expectations of patients and dentists and in this way they are starting to take the place of metal based restorations today [1,3,4,5]. Lithium disilicate glass-ceramics derived from multicomponent glass systems have some superior mechanical and optical properties comparable to natural teeth [ 6]. In restorative dentistry, mechanical characteristics of biomaterials play very crucial role in order to resist the masticatory forces occurred during biting and chewing [7] According to three point bending test results of Roland, flexural strength of the lithium disilicate glass-ceramics were 400±40 MPa and their fracture toughness (K1c) are approximately 3,3 MPa m112 [2,6]. In addition to high mechanical strength, aesthetic appearance is another important prerequisite as material for dental restorative applications. Translucency and light transmission of the LS2 glass ceramics mimic enamel. Moreover, opacity of the material can also be adjusted depending on the restoration types [2,6, 7]. These superior properties of the LS2 glass ceramics are directly related with chemical composition of the base glasses and controlled crystallization heat treatments [ 4, 7]. The aim of the present work is to determine the effect of heat treatment schedules on the crystallization behavior and thermal expansion of the LS2 glass-ceramics."

Jan 1, 2011

By Matthew S. Hall

Gold/iron oxide catalysts have been prepared and their catalytic performance evaluated for low temperature CO oxidation. The method and temperature used to dry the sample has a significant effect on their catalytic activity. Analysis by TEM revealed the catalysts contained Au particles, although catalysts with high and low activity did not always differ in their microstructure as evidenced by TEM. Catalysts were characterised using XPS and the difference between the Au(4d) and C(1s) binding energies measured; in general the greater the difference, the higher the catalytic activity of the material.

Oct 1, 2003

By Kazutami Imai

Effects of heavy metal ions on the growth and the activities of iron and sulfur oxidation of Thiobacillus ferrooxidans were investigated. Mercuric, silver, and stannous ions inhibited both of the growth and the iron- oxidizing enzyme system of the bacterium. On the other hand, uranyl ion inhibited the growth, but it gave almost no effect on the iron-oxidizing enzyme system. The inhibitory effect of uranyl sulfate on the growth of the bacterium is intensified on lowering the cultivating ' temperature from 28 ºC to 7 ºC. In the concentration of 10-3M, cadmium and copper ions inhibited colloidal sulfur-oxidizing activity of the cells 69 and 52 %, respectively, though they did not inhibit the iron-oxidizing activity at all in the concentration. On the contrary, stannous chloride did not givr any effect on the sulfur-oxidizing activity of the cells, though it inhibited the iron-oxidizing activity 55 % in the concentration of 10-3M. Several differences were observed among the cytochrome systems of cell-free extracts of the cells grown on iron and on sulfur.

Jan 1, 1976

By N. Champigny

The geostatistical estimation of the reserves of an ore deposit is highly dependent on the quality and stability of the variograms of the sample grades. Gold deposits commonly show a skewed grade distribution. The few high grades at the tail end of the distribution produce unstable variograms that are difficult to model. If these grades are cut to a lower grade value or removed, more stable variograms are obtained. However, outlier grades may make a deposit economically viable, and their cutting or removal should be treated with caution. To reduce (but not to eliminate) the effect of high grades, a transformation of the raw data can be performed. Most commonly used transformations are: logarithm, gaussian anamorphosis, rank and indicator. Variograms of the transformed grades are resistant to high grades and present a clear structure. The weak point of data transformation appears when grades are estimated by kriging; the estimates are very sensitive to slight variations in the parameters of the back-transformation. More robust variogram estimation procedures can also be used, but often these procedures are not suitable for skewed grade distributions as they are based on an assumption of a contaminated normal distribution. The Porgera gold deposit in Papua New Guinea has a highly skewed grade distribution, with grades ranging from 0.01 to 3500 g/t and a coefficient of variation greater than 5. For the geostatistical estimation of the high grade zone of the deposit, the influence of the high grades was quantified by calculating and comparing the following variograms: raw grades, raw grades with the highest grades removed and transformed grades. The study confirmed that there is no general method for handling high grades in a geostatistical reserve study. Several methods should be tried to quantify the influence of high grades.

Jan 1, 1991

By K. Hanna

This manuscript describes an extensive ground control study at the Inland Steel No. 2 Mine near McLeansboro, IL, conducted by the U.S. Department of the Interior's Bureau of Mines (USEM) in cooperation with Inland Steel Coal Co. The mine experiences severe ground control problem primarily due to high horizontal stress, particularly at entry intersections. Mine experience has shown that reorienting mine entries, modifying the bolting pattern, and altering the mining sequence are effective in reducing the severity of roof falls and out-of-seam dilution. However, the frequency of roof falls has not been significantly reduced. This research project was designed to provide a thorough explanation of the intersection failure mechanism through combined analyses of company in-mine experience and Bureau field measurements. Stresses and deformations were monitored in a four-way intersection during all stages of development and were related to site observations and theoretical analyses. The results of the combined analyses indicate that high horizontal stress is the predominant factor contributing to intersection roof falls in the Inland Steel No. 2 Mine. The horizontal stress induces shear zones to form along the outby 1 ribs, causing the immediate roof layer to detach 1 and behave as a cantilever beam oriented diagonally across the intersection and parallel to i the maximum horizontal principal stress. As the shear zone progresses upward, roof layers successively detach and fail, forming a dome-type roof fall.

Jan 1, 1986

By Hematian J

A high horizontal stress field has significant effect on the stability of underground roadways and influences the design of a support system in this environment. The high horizontal stresses at E1lalong Colliery, NSW, Australia provided the environment for this study. Samples of coal measures 'rock were collected and tested to determine their mechanical properties. The lithology, stress state, geometry and conditions prevailing in particular areas of the mine were obtained from geotechnical reports available at the mine and by field observation. The results of a series of finite element models constructed and tested under various conditions provided a basis for comparison with field observations. Analysis of the results indicated sufficient correspondence to provide a basis for the proposed design of an optimum support system. It is not suggested that finite analysis provides 'exact answers', but it does show the relative importance and interaction of various parameters.

Jan 1, 1995

By T Higuchi, T Yamamoto, K Takehara

Iron ore fines are used as raw materials for sintered ore for blast furnaces in the world. Since the production and quality of sintered ore have a great influence on the stable operation of a blast furnace, many technologies were developed for controlling the heat profile in the sintering machine, which largely affect the sintered ore properties. In particular, the influence of oxygen in the suction gas, which plays an important role in combustion, was investigated over the years. It is known that increasing the oxygen ratio by about 30 per cent not only significantly improves the combustion rate, but it also increases the strength and yield of sintered ore. However, the details of the mechanism for improving these qualities are unknown. In this study, we investigated the influence of oxygen enrichment at higher ratios (O2: 21–40 per cent) and tried to understand the sintering behaviour enhanced by oxygen. The effect of oxygen enrichment on sintered ore quality and the heat profile were evaluated by sintering tests using a quartz glass pot. From the results, sintered ore yield had a maximum value for O2 = 30 per cent, but strength was increased for O2 = 40 per cent. From heat pattern analysis, it is clear that the high temperature holding time also reached a maximum at O2 = 30 per cent. Furthermore, we found that with increased oxygen ratio, the combustion speed (flame front speed) was increased, but the area of combustion was enlarged. It is considered that there could be a maximum oxygen ratio value for the yield from the balance of these positive and negative effects on high temperature holding time. To clarify the reason for strength improvement, thermodynamic calculations were performed and it was found that melting behaviour could be improved by changing the oxygen ratio.

Sep 18, 2023

By Sharad Mathur

The purpose of this paper is to present the benefits of high reactivity meta kaolin (HRM) in high performance cement-based systems. HRM, unlike other pozzolans, is manufactured from selected naturally occurring kaolin ore and carefully processed under stringent conditions to result in a consistent product with highly pozzolanic properties. HRM is an ultrafine pozzolan that enhances the mechanical properties (workability and strength) and chemical stability (durability) of Portland cement concrete and cement-based products. HRM is unique with respect to its white color which makes it an ideal choice for architectural applications where visual and aesthetic concerns are critical.

Jan 1, 2003

By P. Raghavan1

Reverse froth flotation experiments were carried out in the laboratory using two different types of kaolins for the separation and removal of coloring titanoferrous impurities from cryo-filtered clay after subjecting to high shear pre-treatment. This high shear pre-treatment consists of high shear agitation of a high solids clay slurry with the dispersant (high shear dispersion, HSD) followed by high shear agitation with the collector (high shear conditioning, HSC). After this pretreatment, the slurry is diluted and reverse flotation is carried out. One sample is from, Gujarat, India (Mamuara clay, ?MC?) while the 2nd sample is from Amberg, Germany (AKW clay, ?AC?). While MC consisted of 89% particles below 2µm and analyzed 1.06% of TiO2 and 0.29% Fe2O3 and measured a brightness of 83.4 %ISO, the corresponding values for AC are 67% below 2µm, 0.3% of TiO2? 0.49% Fe2O3 and 83.4 %ISO. The flotation performance is found to be greatly influenced by the conditions of high shear treatment. Important variables are HSD intensity (rpm), HSD time, HSC intensity (rpm), HSC time, HSD/HSC time ratio, ?HSD+HSC? total time etc. Higher shear intensities favor both the impurity liberation and collection. For both clays, it could be shown that impurity removal increases as total pretreatment time (?HSD +HSC? total time) increases up to a certain limit. For MC, the HSD time was only half or less than that of HSC time, while for AC, HSD time is at least twice (or more) than HSC time which is just an opposite manifestation. This is believed to be due to the striking differences between these two clays. Most importantly, the shear frequency is found more influential than the shear rate for the overall flotation performance for both clays. Interestingly, at high shear frequencies, i.e., when a stirrer with more number of teeth on the rotor is used, the ?HSD+HSC? total time is greatly reduced. Again, increased shear frequency helps to reduce flotation time and significantly improves flotation performance. At optimum conditions, product titania reduced to 0.35% for MC whereas the same reduced to 0.13% for AC. The product of flotation of MC measured 85%ISO brightness while that of AC measured84.6%ISO thus enhancing the value of the final product. It could also be established that the high shear pre-treatment shows better flotation performance than that due to collector dosage. Keywords: high shear dispersion, high shear conditioning, titanoferrous impurities, shear rate, shear frequency, brightness, clay recovery, Mamuara clay, AKW clay

Sep 1, 2012

By E. Contestabile, B von Roser

Schedule IV containers in Canada and IME- containers in the United States have made possible the transport of mixed loads. That is, using these containers for detonators, one can simultaneously transport detonators and explosives on the same vehicle. As a result of a recent accident, the Canadian Chief Inspector of Explosives asked for a review of the appropriateness of the Schedule IV container in its present use. The Canadian Authority asked for a re-assessment of the adequacy of the Schedule IV container in preventing propagation of a reaction from the detonators in the container to the remainder of the explosives on the truck, and its ability to contain fragments generated by the detonators. A series of tests was performed to determine the initiation threshold temperature for non-electric detonators and the failure threshold temperature for the shock tube to establish some guidelines for preventing communication from one case of detonators to another within the transport container at elevated temperature. Tests fell into the following categories: inter-case sympathetic detonation, detonator thermal auto-initiation, shock tube thermal sensitivity, and intra-case sympathetic detonation. The results indicate that temperature is a critical factor, which determines to what extent, if any, communication occurs.

Jan 1, 2002

By Francis S. Kendorski

High-extraction mining of coal and other stratified minerals has a predictable effect on the surface and subsurface. Impacts on ground waters in overlying strata and on surface waters, that are associated with overlying sequential zones of collapse, fracturing, aquiclude, constrained strata, and surface disturbances can be anticipated. Since first quantified around 1979 in Bureau of Mines sponsored contract research work and others (and often adopted by state regulators), with zone extents based upon multiples of mined seam height of 24 to over 60 for the fractured zone, much new data have become available. In examining the sources of data and the methods and intents of the researchers of over 65 case histories, it became apparent that the strata behaviors were being confused with overlapping vertical extents reported for the fractured zones and aquiclude zones depending on whether the researcher was interested in water intrusion into the mine or in water loss from surface or ground waters. These more recent data, and critical examination of existing data, have led to the realization that the former "Aquiclude Zone" defined for its ability to prevent or minimize the intrusion of ground or surface waters into mines has another important character in increasing storage of surface and shallow ground waters in response to mining with no permanent loss of waters. This zone is here named the "Dilated Zone." The existence of the dilated zone explains the ratios of up to 60 times the mined thickness. Surface and ground waters can drain into this zone, but seldom into the mine, and can eventually be recovered through closing of dilations by mine subsidence progression away from the area, or filling of the additional void space created, or both. A revised model has been developed which accommodates the available data, by modifying the zones as follows: ? collapse and disaggregation extending 6 to 10 times the mined thickness above the panel ? continuous fracturing extending approximately 24 times the mined thickness above the panel, allowing temporary drainage of intersected surface and ground waters ? development of a zone of dilated, increased storativity, and leaky strata with little enhanced vertical permeability from 24 to 60 times the mined thickness above the panel above the continuous fracturing zone, and below the constrained or surface effects zones, whose thickness or existence is dictated by the zones above and below ? maintenance of a constrained but leaky zone above the dilated zone and below the surface effects zone, whose thickness or existence is dictated by the zones above and below ? limited surface fracturing in areas of extension extending up to 50 ft or so beneath the ground surface

Jan 1, 1993