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By A. J. Schindler, F-P Sawyer, T. Logan, M. L. Shutey-McCann, R. M. Perry

"Test work on biooxidation pretreatment of low-grade refractory gold ores has been ongoing at Newmont Gold Company since 1988, including laboratory testing and pilot biooxidation heaps (360 to 23,000 tonne). Metallurgical results of the biooxidation process utilizing Thiobacillus ferrooxidans (T. ferrooxiddans) have culminated in the design, construction, and operation of a biooxidation demonstration facility. The facility has processed 708,000 tonnes of refractory ore, using a batched process with separate pads for biooxidation and ammonium thiosulfate gold extraction. Siliceous sulfidic refractory (SSR) and carbonaceous sulfidic refractory (CSR) ores are treated separately during biooxidation pretreatment unit operation. Following biooxidation, the ores are neutralization with lime and placed on oxide leach pads or stacked on the ammonium thiosulfate leach pad. Gold is leached with either cyanide for SSR ores or ammonium thiosulfate for preg-robbing CSR ores.This paper will only address the biooxidation pretreatment process of the SSR and CSR ores.AcknowledgmentsThe authors appreciate the cooperation and approval of Newmont Gold Company Carlin Operations management for its support and permission to publish this paper. The paper draws on efforts and assistance of the following people and several others which are to many to list who participated over the past five years in bringing this project to its fruition: Dr. James A. Brierley, Chief Microbiologist, Newmont Metallurgical Services; Dr. Rong-Yu Wan, Metallurgical Manager, Newmont Metallurgical Services."

Jan 1, 1997

By Alexander I. Raitchenko

"An electroconductive viscous liquid may flow in laminar or turbulent regime under Lorentz-force generated by the intercrossed electric current and magnetic field. When there is a starting flat layer between hard and free boundaries with surface tension the spatial Lorentz-force can create a specific stationary regime of flow: the plane free surface will transform into the wavy one, and the movement in the depth will be not laminar and not turbulent, but this regime will be characterized by organized forms with indications of ""rolling of long cylindrical drops"". Wave-length is determined by the viscosity, the density, the surface tension, the average thickness of layer, and Lorentz-force. ·The limit of wavy regime is determined by most long of wave which is directly proportional to the critical value of specific flow and inversely proportional to the kinetic viscosity. The proper critical value of Reynolds number is determined by the dimensionless combination containing surface tension, density, viscosity, and Lorentz-force. The mentioned dimensio.nless combination in our case is some criterion substituting the known Kapitsa number for case of the thin viscous liquid layers under gravity. Spreading of admixture by mechanism of wavy regime is more rapid than by common diffusion or by laminar flow. The suggested conception can be a contribution into the theoretical basis for elaboration of some specific liquid metals technologies."

Jan 1, 1999

TiO2 and Ti/TiO2 thin films were deposited on a quartz substrate by laser ablation of Ti02 and Ti targets using Nd:YAG pulsed laser. After sulfurization of the Ti02 film in H2S or CS2 gas at 1273 K for 1 hour, the surface atomic structure was changed. Furthermore, the Ti/TiO2 film was successfully prepared by the subsequent ablation of Ti and TiO2 targets. The morphology and structure of the films were characterized by XRD, XPS and AFM analyses.

Jan 1, 2003

By T. Nakamura

TiO2 and Ti/TiO2 thin films were deposited on a quartz substrate by laser ablation of TiO2 and Ti targets using Nd:YAG pulsed laser. After sulfurization of the TiO2 film in H2S or CS2 gas at 1273 K for I hour, the surface atomic structure was changed. Furthermore, the Tirri02 film was successfully prepared by the subsequent ablation of Ti and Ti02 targets. The morphology and structure of the films were characterized by XRD, XPS and AFM analyses.

Jan 1, 2003

By E. L. Frueh

AMAX Base Metals Research & Development, Inc. has developed a process for treating copper-nickel mattes to produce copper cathodes and a pure nickel sulfate solution. In this process, the input matte is preleached in a copper sulfate electrolyte bleed solution so as to dissolve nickel from the matte and cement copper from solution. The preleach leaves a substantially pure nickel sulfate solution. The residue from the preleach is roasted to less than about one percent sulfur. A portion of the calcine is leached with sulfuric acid to make a copper sulfate solution for input to the tank house. The residue from this leach and the remaining calcine are smelted to form a bimetallic (copper/nickel.) anode. The anodes are electrolytically refined and copper is preferentially deposited on the cathode while the nickel reports to the electrolyte, A bleed stream is taken from the electrolyte and used in the preleaching of the input matte. This process produces high purity metal streams while consuming less energy and smaller amounts of reagents as compared with other matte processes.

Jan 1, 1983

By Aline Maria dos Santos Teixeira, Francisco Manoel dos Santos Garrido, Joao Alves Sampaio, Marta Eloisa Medeiros

"Rocks for crops is a natural practice for soils fertilization which consists on adding rocks to the soil while water decomposes the rock, through chemical weathering, and gradually releases nutrients to the soil solution. This practice can be considered an alternative to the low production of potassium fertilizers in Brazil. In this context, the phonolite rock was characterized in order to evaluate its application as an alternative source of nutrients to the Brazilian agriculture. The phonolite studied is an igneous, volcanic rock with alkaline character that is chemically composed of a high grade of potassium due to the presence of feldspar minerals. In order to quantify the minerals present in the sample, characterization was carried out using several techniques such as X-ray diffraction, X-ray fluorescence and scanning electron microscopy.IntroductionBrazilian soils are generally acidic and nutrient poor due to the tropical climate in which high temperatures and intense rainfall favor a rapid decomposition of the rocks that from the soil. And as agriculture is one of the main bases of the country's economy, large amounts of fertilizer are used to make the soil productive.Although Brazil has large reserves of potassium, the demand for potash fertilizer is higher than the national supply, which makes the country dependent on fertilizer imports, especially in the form of potassium chloride. Thus, we must look for economic alternatives to traditional fertilizer [1].Stonemeal is a natural practice for soil fertilization that consists in adding basic or ultrabasic rocks to the soil so that water, through chemical weathering, decomposes the rock while it gradually releases nutrients."

Jan 1, 2011

By Versiane A. Leão

The hydrochloric leaching of chrysotile tailings and soapstone powders) is discussed. This two materials are magnesium compounds associated with carbonates and iron oxides. In this work the chemical and physical characterization of formers is presented and the thermodynamic analyses of leaching is carried out. Magnesium extraction is almost complete for chrysotile tailings while, for soapstone powders, one can be reached 60%. The behavior of iron and calcium impurities is discussed.

Jan 1, 1997

By C. Lupi

Zinc impure solutions as spent electrolytes, leach liquors coming from aqueous treatment of both minerals and solid waste, need to be purified before undergoing the treatment to obtain the final product. Solvent extraction is one of the most selective operations particularly when many metallic ions are present in solution. Zinc pure solutions are frequently obtained using DZEHPA as extractant. In this work an investigation on zinc extraction effectiveness of naftenic acid was carried out. After determining the best diluent and the optimal extractant concentration, the partition coefficient was determined as a function of temperature, equilibrium pH and zinc concentration. Finally same batch tests to determine the equilibrium curves at room temperature on exhausted electrolyte coming from zinc cell were carried out by using naftenic acid, D2EHPA and TBP. The pH giving, for each extractant, the best extraction yield was selected in order to compare the equilibrium curves. Experimental results show that all the examined extractants are very effective in zinc extraction if the process conditions are appropriately selected. In order to avoid an impure solution pre- treatment and to obtain the maximum ertraction yield the appropriate solvent can be chosen.

Jan 1, 1998

By Minge Zhao, Yuandong Pei, Zhixing Zhao, Zejun Ma, Lili Ban

"Confocal scanning laser microscope (CSLM) has been applied to carry out the in-situ observation of melting and solidifying characteristics during iron ore sintering process, accompanied with TG-DSC test. It can be found that apparent Liquid phase forming temperature(LFT) and ending solidifying temperature(EST) is about 1190? and 1160?, respectively. Forming liquid phase during sintering process goes through four courses, these are shrinking, expanding, shrinking and expanding coexisting and expanding totally. For Yandi fine, the corresponding temperature of these four courses is about 1120-1160?, 1190-1196?, 1218-1220? and 1233-1270?, respectively. Although CAJ fine has more difficulty in forming initial liquid phase, but when liquid phase expands, it may have better fluidity and easier for liquid phase formation. Adding enough CaO, CAJ fine takes on high fluidity like Yandi fine, because liquid phase during sintering process is formed mainly by reaction between CaO and Fe2O3.IntroductionConfocal scanning laser microscope (CSLM for short) has been applied to carry out the in-situ observation of metallurgical phenomena, especially in steelmaking process. Recently, many researches on ironmaking process were conducted with CLSM. While for high temperature properties during sintering process, there are limited reports on in situ observation1-2). In this paper, melting and solidifying characteristics of iron ore were observed with CLSM under simulated sintering temperature, and high temperature properties of iron ore during sintering process was clarified based on the in situ observation results and TG-DSC research."

Jan 1, 2012

By Z. Y. Xie

The visualization techniques were employed for the analysis of computer simulation studies of dislocation core structure in ordered alloys. Atomistic computer simulation was used for the study of the local configuration of the material in the vicinity of the dislocation. Stresses were applied in the simulation in order to study the necessary stress level for the dislocation to move and onset plastic deformation of the material. The results were analyzed in terms of the strain tensor as a function of the position (x, y) in the material with the dislocation located at (0, 0). Various visualization packages are used to plot the invariants of this strain tensor and to visualize the changes that the dislocation core undergoes under stresses until it finally moves.

Jan 1, 1993

By Dietmar Eifler, Benjamin Jost, Marcus Klein

This paper focuses on the ductile cast iron EN-GJS-600 which is often used for components of combustion engines. Under service conditions, those components are mechanically loaded at different temperatures. Therefore, this investigation targets at the fatigue behavior of EN-GJS-600 at ambient and elevated temperatures. Light and scanning electron microscopic investigations were done to characterize the sphericity of the graphite as well as the ferrite, pearlite and graphite fraction. At elevated temperatures, the consideration of dynamic strain ageing effects is of major importance. In total strain increase, temperature increase and constant total strain amplitude tests, the plastic strain amplitude, the stress amplitude, the change in temperature and the change in electrical resistance were measured. The measured values depend on plastic deformation processes in the bulk of the specimens and at the interfaces between matrix and graphite. The fatigue behavior of EN-GJS-600 is dominated by cyclic hardening processes. The physically based fatigue life calculation “PHYBALSIT” (SIT = strain increase test) was developed for total strain controlled fatigue tests. Only one temperature increase test is necessary to determine the temperature interval of pronounced dynamic strain ageing effects

Jan 1, 2015

By Peter R. Whiteley

"This paper discusses gaseous, solid and liquid injection technologies employed in the aluminium industry. The reasons for injection systems are presented, together with a description of the processes used. This includes a review of injection in crucibles, furnaces, launders, and into special purpose metal treatment boxes. The paper covers both the primary and secondary aluminium industries. IntroductionMany injection technologies are used in the aluminium industry and are in a rapid state of development. This paper provides a review of these systems and presents some thoughts on the possible future application of injection to further improve productivity and reduce losses associated with current applications.The Needs for InjectionThere are many issues facing the process metallurgist in the aluminium industry which call for the application of injection technologies now and in the future. In order to categorise these issues the industry may be broken into primary and secondary aluminium, although some of the concerns occur in both areas.The forementioned issues are variously concerned with improving metal quality, improving productivity, and reducing process problems.The use of injection techniques will be discussed under the heading of solid, gaseous and liquid injections, and the objectives and benefits of each covered briefly."

Jan 1, 1996

By Nagahiro Saito, Takahiro Ishizaki, Daisuke Yata, Akio Fuwa

"Ternary compound-semiconductor, CuInTe2, film was deposited cathodically under potentiostatic conditions on titanium substrate from aqueous solution containing CuCl2, InCl3, TeO and HCI in this study.The deposition parameters such as electrolytic solution composition, potential and temperature were optimized· for electrodeposition of CulnTe2. Structural characterization of the: deposited film was also carried out using XRD and SEM. Electrodeposited films Were prepared and analyzed for their chemical composition using ICP. The ICP analyses showed that the stoichiometry of the films could be controlled by (1) the deposition potential and/or by (2) the electrolytic bath composition.1. IntroductionThe ternary chalcopyrite type compound semiconductors exhibit such electrical, chemical and optical properties that make them promising for photovoltaic devices (Kazmerski and Wagner 1985)(1). Many researches have been devoted to the characterization of these materials for over one and a half decades. High efficiency solar cells based on p-CulnSe2/n-CdS have been reported (Mickelson and Chen 1983)(2).The electrodeposited fil ns of semiconductors have more advantage than other physical and chemical deposition techniques; it is relatively easy and economic technique and the semiconducting properties such as band-gap variation, concentration of dopant stoichiometric composition and so on can be controlled with some accuracy. The electrodepositions of the ternary CuInS2, CulnSe2 have been reported by many workers (Hodes and Cahen 1986, Bhattachaya 1983, Singh et al 1986, Lokhande and can be prepared as both p-type and n-type. Therefore, its potential for application in optical and photovoltaic devices is one of the great interests. Bhattacharaya and Rajeshwar (1986)(9) reported the electrodeposition of CuInTe2 from an acidic bath· on indium tin oxide (ITO) and Mo substrate. Triethanolamine (TEA) was used as a complexing agent for indium. The electrodeposited CuInTe2 films were non-stoichiometric in composition under all their experimental conditions by electron-probe micro analysis (EPMA) and Auger depth profile analysis. In this paper, we report our results on the behavior .of Cu-In-Te electrodeposition from ·acidic baths; the preparation of CulnTe2 and the effect of bath composition on electrodeposited films obtained."

Jan 1, 2000

By JiaPeng Xu, Brian Lo, Uday B. Pal, Yihong Jiang, Soumendra N. Basu

"The Solid-Oxide Oxygen-Ion-Conducting Membrane (SOM) electrolysis process has been successfully tested on a laboratory scale, producing silicon directly from silica in a cost-effective and environmentally friendly way. A yttria-stabilized zirconia (YSZ) tube, closed at one end was employed to separate the molten salt containing dissolved silica from a liquid metal anode placed inside the YSZ tube. When the applied electric potential between the liquid tin cathode in the molten salt and the anode exceeds the dissociation potential of silica, oxygen ions are pumped out of the molten salt through the YSZ membrane and oxidized at the anode while the silicon cations in the flux are reduced to silicon at the liquid tin cathode. The presence of high-purity silicon crystals on the surface of liquid tin cathode was confirmed by scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDS). Silicon crystals were extracted from tin cathode by chemical etching.IntroductionPhotovoltaics (PV) generate electrical power by using solar cells, and dramatically reduce the emissions of greenhouse gases (GHG). Through 2006 to 2011, it grew the fastest of all renewable technologies with operating capacity increasing an average of 58% annually [l]. However, the cost of manufacturing solar-grade silicon (SoG-Si) for high-efficiency solar energy production represents a major barrier to achieving the industrial goal for solar power of $1/Wp (watt at peak exposure) which would enable widespread grid parity. The current contract price of silicon to PV manufacturers is $50-$60/kg, with the spot market in 2007-2008 showing prices as high as $300/kg [2]. This makes the development of low cost and environmentally friendly manufacturing of high purity silicon very important."

Jan 1, 2013

The oxidation of ferrous ions by oxygen in sulphate solutions is a very slow process, but it tills long been known that the addition of sulphur dioxide increases the rate of reaction very significantly. The kinetics and mechanism of the process were investigated in the laboratory and the results confirmed the advantage of adding small amounts of sulphur dioxide to the oxygen stream for the removal of iron from solutions. The effect of various parameters on the overall rate of iron oxidation and precipitation was studied. In particular, temperature, acidity and composition of the gas mixture were considered and the optimum conditions for the precipitation of goethite were determined.

Jan 1, 1991

By Juergen Antrekowitsch, Stephan R. Steinacker

The main aim of the electric furnace treatment in the primary copper industry is the reduction of valuable metals such as zinc, lead or copper itself. On the one hand legal restrictions for the further use of the treated slag are constantly getting stricter while on the other every type of loss in the oxidic phase leads to economic disadvantages. In order to fully understand and to improve the process, kinetics during the reduction play an essential role. In the first part, this paper highlights the theoretical background of the reduction process, while the following chapters present experimental aspects and results from laboratory scale trials at the Montanuniversitaet Leoben. In addition, the comparison between the chemical reaction and the diffusion model plays a continuously important role. By investigating the reducibility of electric furnace slag, process adaptions and ameliorations are developed.

Jan 1, 2016

By Chuang Y-Y

A summary is made on the thermodynamic analysis for two of the four ternary systems of the quaternary Cu-Fe-Ni-S. The analysis is being extended to ternary Cu-Fe-S and then to the quaternary. An analysis is already made for the metal ternary but is not reported here. Experiment is being carried out to measure the liquidus surface. of Fe-Ni-S equilbrium with the fcc solid solutions of (Fe, Ni). The presentation at the Symposium will include all the results obtained at the time of presentation.

Jan 1, 1983

By S. A. Platias

Large amounts of dunile tailings can be recycled for olivine produdion from the existing beneficiation adivity of chromite ore in northern Greece. This olivine production aims at the preparation of a material suitable for the substitution of the environmental hazardous quartz sand in the foundries of Europe In smelting of chromite ore the losses that occur ore usually of the order of 6-8% Cr that report in the slag. Most of this is in the form of oxides that cannot be recovered, but usually 30-35% is in the form of FeCr alloy that can be recovered by gravity methods. About 90% of the produced slag is sold for road construdion after crushing to a desired grain size. Finally, recycling of chromites sludges from the ferrochrome produdion plant, through the preparation of pellets, improved the total chromite yield by 2%.

Jan 1, 1996

By Zongshu Zou, Qiang Li, Mingming Li, Mingxia Feng

The impingement onto the surface of bath by top-blown jets is a significant process characteristic in BOF and EAF steelmaking process. The cavity is one of the most important outcomes of the interaction and plays an important role on reaction kinetics and reactors performance. But to date, the understanding to cavity is still so limited. In present study, a water model for a BOF converter is established and the dimension of cavity profile is investigated. The effects of lance height, gas flow rate, nozzle inclination angle and the amounts of slag are discussed. The results show that penetration depth increases with the increase of gas flow rate and the amount of slag, and the decrease of lance height and nozzle inclination angle. Furthermore, a theoretical model of cavity dimension is proposed for multiply jets impinging liquid bath on the basis of energy balance at the stagnation point of cavity.

Jan 1, 2015

By Saskia Duyvesteyn

Ion flotation is a technique applicable to the removal of metal ions from dilute solutions, using ionic surfactants.- While there are a number of physical and chemical parameters that influence the ion flotation process, this paper focuses on two of the important chemical ones, namely frother concentration and ionic strength. The effect of several frothers, including ethanol, iso-propanol and MIBC at concentrations ranging from 0% to 0.4%, was studied for the model Cd-dodecylsulfate and Cu-dodecylsulfate systems. The ionic strength, as well as the effect of monovalent and multivalent counter ions, was also studied in the range of 1@3 - 1 M, at constant pH. The results are discussed in terms of applicability to a range of effluents from minerals and materials processing operations.

Jan 1, 1994