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By S. K. Kawatra, S. K. Valluri, S. J. Root

Common carbon dioxide capturing reagents, such as amines and sodium hydroxide, are expensive, toxic, and energy intensive to regenerate. We have added frothers to a sodium carbonate solution in order to increase the surface area available for CO2 transport within the packed bed of a counter current scrubbing column. Addition of frothers has improved the performance of sodium carbonate scrubbing solutions to be on par with sodium hydroxide scrubbing solutions. This novel enhancement of a relatively inexpensive CO2 capture-regeneration cycle shows potential to allow plants to turn a profit by sequestering a waste product. These results are discussed in detail in the following manuscript. INTRODUCTION The combustion of fossil fuels converts chemical energy to thermal energy. CO2 is produced as a byproduct of the reaction. 80% of the world’s electricity is produced by using this thermal energy to power a generator, accounting for 40% of global carbon dioxide emissions. In an effort to stabilize the rising atmospheric CO2 levels, researchers are investigating the application of carbon capture and storage (CCS) systems in power plants. [1] Efforts to capture CO2 at some power plants have been successful, but the cost of installing and operating the required equipment is high. As such, very few power plants have CCS systems. If CO2 can be captured and processed into a product that can be sold at a profit, installing CCS systems in power plants will be a very attractive business decision. In order for the sale of captured CO2 to become a profitable venture, the cost of capturing the CO2 from a flue gas must be reduced. BACKGROUND The most common method for separating CO2 from a flue gas is by passing it through a counter-current packed bed scrubbing column. The flue gas enters the bottom of a column while a solution of a chemical with properties advantageous to the absorption of CO2 is pumped to the top. The fluids interact in a packed bed, where the CO2 is transported from the gas to the liquid. CO2 is an acid gas, so it is common for the scrubbing solution to be alkaline in nature in order to neutralize the carbonic acid that is formed when it is dissolves into water. The exhaust exits the top of the column free of carbon dioxide, which exits the column in the scrubbing solution, reacting or complexing with the absorbent. Figure 1 is a schematic drawing of a CO2 scrubbing column. It shows the molar flowrates and compositions of the gas and liquid at the bottom [1], the top [2], and an arbitrary height in the column [Z]. [2,15] L is the molar flowrate of liquid at any point in in the column. G is the molar flowrate of gas at any point in the column. Since the CO2 is transported from the gas to the liquid, L and G are variable with respect to height. To simplify calculations, the CO2 free molar flowrates Ls and Gs are often used. X is the fraction moles of aqueous CO2 per mole of CO2 free liquid. Y is the fraction moles of gaseous CO2 per mole of CO2 free gas. Figure 2 is a composition diagram of the scrubbing column depicted in figure 1.

Jan 1, 2019

By Ralph W. Barbaro

In many parts of the country, electric utilities use spot market coal to make up the difference between the amount of contract coal and the total amount burned. The utilities involved will normally have a structured contract for those companies supplying that spot coal. These contracts will often involve a pricing schedule with bonuses or penalties for coal above or below the specified coal quality goals. Normally, penalties will be assessed on the sulfur, ash, and other coal quality variables. This paper deals with some aspects of the pricing schedule of one of the eastern utilities that buys coal on the spot market. This utility has a number of plants that a supplier can attempt to supply through bidding procedures. The existence of the pricing schedule gives the supplier a number of different options. To the single-mine producer, options are available to send the coal to any demand site and to clean all, part, or none of the coal. In other words, he can ship to a number of different sites and can send different coal qualities to each site depending upon the level of preparation. In addition, the options to deliver blended coal to any given site will provide an additional level of complexity to the problem.

Jan 1, 1983

By Wescomb R. Jones

The United States is the world's largest producer of hydrofluoric acid (HF), with its 1971 output of 317,000 short tons representing about 40 percent of the estimated Free World production. U. S. production has increased over five fold in the past 20 years, with a growth rate of about 7 percent per year between 1960 and 1970. However, the growth rate to 1977 is expected to be less than 5 percent per year, due primarily to a reduced rate of growth in requirements by the aluminum industry and an expected increase in imports from Canada and Mexico. This discussion will include our analyses of the consumption pattern for HF in 1972 and the factors influencing the demand forecast for 1977.

Jan 1, 1973

By D. A. Robbins

The application of remote sensing for environmental measurements is already being utilized. Aircraft mounted imaging spectroscopy has been utilized to evaluate areas of historical mining operations as well as active mine sites. To the extent that remote sensing can provide more sensitive, cost effective, and timely monitoring potential, the technology is of interest to the industry. Questions remain about the application and validation of the data and the availability of the technology in the private sector. This presentation will discuss some of the potential uses, benefits, and concerns related to remote sensing and efforts to monitor the technology's development.

Jan 1, 1999

By Jan Jekielek

Increasing capacity of bulk material handling systems creates difficult problems for accurate in-line material weight measurements. At the same time increasing system complexity and growing user demands call for more measurements. Precision in-line weight measurements for bulk materials are usually accomplished by application of conveyor belt scales. Belt scale accuracies listed by scale vendors are applicable for ideal situations with suitable conveyor design, belt scale location and calibration means. This paper attempts to provide designers and users with simple means to evaluate belt scale accuracy for practical scale installations. Based on known mathematical models simplified formulas for measurement errors are derived and discussed. These formulas allow for simple determination of achievable accuracy for alternative scale installations on the conveyor, conveyor designs, etc.

Jan 1, 1979

By Charles J. Hass

INTRODUCTION Deformation measurements are some of the simplest and most useful measurements that can be made by the mining/rock mechanics engineer in assessing the sta¬bility of openings in rock. A number of tools and tech¬niques are presently available. This chapter will de¬scribe the most common instruments, their application, and present the equations needed for data reduction. MECHANICAL STRAIN GAGE Description of Instrument A mechanical strain gage of the Whittemore type shown in Fig. I is a useful instrument for measuring deformations of pillars, sidewalls, and roofs of under¬ground mines. Measurement gage lengths typically range from 51 to 254 mm (2 to 10 in.), and the dial indicator reads to 0.0025 mm (0.0001 in.). The instru¬ment measures the deformation between precision gage points which are anchored in the rock. The anchor points are typically grouted in small holes drilled 12.5 mm (1/2 in.) or so deep into the rock. Strain a is calculated from the measured deformation AL with the equation [ ] where L is gage length. A necessary accessory for the instrument is a master bar normally made from invar steel having a low co¬efficient of thermal expansion. This bar allows one to check the instrument for changes in the mechanical zero point and to correct for temperature effects on the measuring instrument. The instrument is available from Soiltest, Inc. for a cost of approximately $340; the cost of the master bar is approximately $55; and nonreusable brass inserts which are anchored in the rock are nominally priced at $0.27 each. All prices are for 1978. Applications Two classes of applications may be considered, one where only one measurement direction is involved and the second where three measurement directions are em¬ployed. Applications where only one measurement di¬rection is necessary include: monitoring crack or frac¬ture separation or shear movement with anchor points on opposite sides of the discontinuity; measurement of vertical strain in a pillar or sidewall; and measurement of steel support deformations with anchors in the steel members. The more general application involves a strain ro¬sette consisting of three measurement directions which for convenience are oriented 1.04 rad (60°) apart to form an equilateral triangle as shown in Fig. 2. Strains in the three measurement directions [ ]

Jan 1, 1982

By James Warren Andrews

The values of saturated water vapor pressure from steam tables have been found to be inaccurate for mine ventilation usage because the effect of air on the saturated water vapor was disregarded. Presented here are the newest and most accurate currently available tables from the National Bureau of Standards (NBS). Also included are: (1) a formula for correcting the saturated water vapor pressure for temperature and altitude. (2) a formula for computing unsaturated water vapor pressure, and (3) a formula for air density. Because Systeme International (SI) units are used in the formulas, conversions are given from U. S. conventional units to SI units. The intent of this paper is to show by means of six steps the accurate calculation of mine air density for use on modern computers.

Jan 1, 1989

By R. M. Von Storch

Most coal mining areas of the Western United States are characterized either by thick beds, steep pitches or heavy cover. Individually, each of these may present inherent safety hazards that influence miring. When all are met at one location, the combined effect is to make the safe operation of the mining property a challenge to management. These combined, conditions are met in most coal mines in southeastern Utah including those of the United States Steel Corporation. This coal bed measures up to 16 feet in thickness, the pitch is as much as 25% and mining is under a cover approaching 2, 000 feet. The Sunnyside coal bed is found in the Book Cliff Mountains, a great escarpment extending from west of Castle Gate, Utah, some 180 miles to Grand Junction, Colorado. West of Green River, Utah, the Book Cliffs swing sharply to the north because of the domelike uplift of the San Rafael Swell to the southwest..It is in this northerly extension of the Book Cliffs that the Sunnyside coal in the Blackhawk Formation of the Mesa Verde Group, Upper Cretaceous Age is found. The strata are transected by numerous faults with from a few inches to as much as a hundred feet of displacement. All of these faults have had some effect on the mining operation, either in roof control or, in the case of major faulting, the pattern of mine development.

Jan 1, 1967

By A. Pinches, R. Winby, P. J. van Staden, M. K. Rhodes, P. C. Miller

This paper is a progress report on the commercialization of using bioleaching for base-metal concentrates. The paper focuses on bioleach processes for recovering copper from chalcopyrite and nickel/cobalt from pentlandite/pyrrhotite. Data is discussed from pilot-plant trials in which an overall recovery >95% was obtained for the bioleaching of copper from chalcopyrite. The pilot plant was operated in closed circuit with solvent extraction and electrowinning circuits for final metal recovery. For the bioleaching of nickel and cobalt from pentlandite/pyrrhotite, an overall recovery of 97% was achieved. Precipitation routines were used to produce a final nickel/cobalt product. The pilot plants were capable of treating a few kilograms of concentrate per day. Prominent features in the design of a 1-t/day (1.1-stpd) copper-bioleach demonstration plant for the treatment of chalcopyrite concentrate are discussed. The plant, which is now under design, will be constructed and operated based on the results obtained from the laboratory pilot-plant campaigns. Issues of scale-up for the demonstration plant, together with integration into upstream and downstream processing, are also addressed. Independently derived capital and operating costs are presented for a possible commercial plant. These cost studies indicate the principle economic issues in considering the application of bioleaching to the extraction of base metals. The benefits of bioleaching complex concentrates that are not amenable to physical beneficiation and economic treatment by conventional smelting are highlighted. Issues, such as the environmental aspects, that illustrate the benefits of bioleach technology are given.

Jan 1, 2000

By W. A. Cincilla, Z. T. Bieniawski, E. Unal

Although coal mine tunnels such as the main haulageways or roadways are the lifelines of coal mines, little attention has been paid to them in terms of pre-construction planning and design. This paper presents the results of research aimed at improving design methods for coal mine tunnels. Studies of the current practice and design needs in the United States were performed for coal mine development entries. A design approach evolved for coal mine tunnels is presented. It is based on field investigations and laboratory model studies aimed at integrating into reinforcement guidelines for coal tunnels. An up-to-date bibliography on coal mine tunnels is provided.

Jan 1, 1981

By Claude Froger

The compared advantages of digital and analogue computers for solving ventilation problems have for many years been a matter of discussion among the specialists whose respective arguments have prevailed in turn depending on the progress of technology. In the French coal mines however none of these two techniques has superseded the other so far. In France, between 1956 and 1962 only the digital computer and from 1962 to 1967 only the analogue computer was used. Since then they are both used concurrently and complementarily. Depending on the problems dealt with, the most advantageous method is chosen in each case. In the case of ventilation planning for projected workings, it is possible to test variant forms of the development plans and many parameters can be varied. In such a case the flexibility of the analogue computer is a great help. Wrong lines taken will be rapidly abandoned and little by little solutions will be found. By examining the results of a test, new ideas will generally come into the mind and they can be tested right away. Such an investigation is always-carried out in conjunction with the engineers of the mine concerned. In complex networks it often leads to solu¬tions which could not have been devised from the start. The same work could be done by using a numerical method and the digital computers operating in the different coal mine districts, but for the same tests, the time required would be much longer and the participants would not be encouraged to use their imagination so intensively. Or the other hand for calculations of ventilation networks in ventilation surveying, use is made of the digital computer which gives the possibility of storing the data corresponding to the different mines concerned. The questions to be solved concern problems for which the ventilation network is essentially known, and in which only a small number of parameters can be varied. The few possible alternatives to be calculated can therefore be handled by the digital computer in spite of the relative lack of flexibility of the method. To sum up our ventilation studies are conducted in France as follows: - For ventilation studies and modifications due to projected workings use is made of the ana¬logue computer. For a given mine the updating of such ventilation studies is carried out every 3 or 5 years according to the progression of the workings. - For ventilation surveying while normal working operations are in progress, use is made of the digital computer.

Jan 1, 1980

By Janusz Szywacz, Bozena Bojko, Stanislaw Wasilewski

Two groups of computer programs are described in the paper. First one is the OWEN system containing software modules designed for air flow distribution analysis and prediction within the whole ventilation network of a mine. The second group is a set of programs commonly used in a routine design work connected with chosing the optimal ventilation schemes and equipment for individual areas of a mine (headings. longwall districts etc). All the programs are designed for running on the IBM PC/XT, IBM PC/AT and compatible computer systems.

Jan 1, 1989

By Miroslav Cervenka

The Coal, characterized by coal quality parameters as for example, ash content (Ad), moisture (Wrt), heat content (Qr1), sulphur content (Sd) and other parameters is still in many countries the basic source of energy. Energy is life, especially in modern society, where the demand for ecologically clean energy is very high; and therefore, there is great importance in effective coal utilization Direct utilization - burning of coal for energy generation, is still one of the most effective methods. In most cases, it is one of the cheapest energy transformation methods in spite of the fact that this energy transformation is connected with the deterioration of our surroundings. Deterioration can be substantially reduced if the burning of coal at power stations, heat power stations and other coal consumers is optimized. That means the burning is done in steam boilers, the technical state of which is very good; the coal has minimimum .variations with respect to the projected values; and the burning process is controlled and checked not only from a regulation point-of-view but also from an ecological point-of-view. The instrumentation capable of measuring the characteristic coal quality parameters in real time exists and it forms the basic assumption for the work our research team has made. The proper application of this instrumentation is able to provide information for burning process optimalization. It is the main topic of this paper, which is the compilation of the information on our work -made during the last five years. The whole information is based on practical experience and applied systems in Czechoslovakia in the mines and power engineering industry. See [Cervenka, 1989]

Jan 1, 1992

By Nathaniel Arbiter, Brij M. Moudgil

Separating oil shale from waste material or into high- and low-grade fractions can have a major economic influence on the surface retorting process. Different shale rock components vary significantly in physical and surface chemical properties, such as specific gravity, color, and water wettability. Various techniques that use the differences in one or more of these properties have been proposed to preconcentrate oil shale before retorting. This article discusses some proposed techniques, such as gravity separation, sorting, and froth flotation. Retorting oil shale is the most common method for recovering oil from the rock. This process is accomplished either underground (in situ) or above ground (ex-situ or surface retorting). Both techniques have serious limitations, such as low recoveries in the underground method and the ability to process rich shales only in the above ground retorting method. Also, environmental problems are associated with both techniques. Some of these limitations could be overcome if feed to the retorts is of consistent grade. This could be achieved by selecting appropriate sites for in situ retorting and selective mining for surface oil shale retorting. Both of these, however, would have a serious economic impact on shale oil recovery. Obviously, little control can be exercised over preparing feed material in the in situ retorting process, but beneficiation of oil shale could definitely be advantageous in surface retorting, and should have positive influence on the overall economics of recovering oil from the shales. For example, preconcentration of mined shale could result not only in reduced costs for materials handling, but also in waste disposal costs, since waste characteristics before and after the retorting process are significantly different. Upgrading the oil shale might also allow substitution of alternate technology for retorting as well as extend the process to recover oil from marginal deposits. Also, the separated material may become a potential source for recovering other values from shale deposits. Overall, the incentives for preconcentration are to reduce costs and improve thermal efficiency of the recovery process. Oil Shale Properties Important to Preconcentration Oil shale is a carbonaceous rock assaying 5-30% organic material (kerogen) and 70-95% ash-forming minerals. Kerogen is soft, nonbrit¬tle or semi-brittle material, and generally forms a matrix between irregularly distributed mineral grains. Inorganic mineral mat¬ter-quartz, feldspar, dolomite, kaolinite, dawsonite, and nahco-

Jan 9, 1982

By N. A. Sareyed-Dim

Nickel ores may be classified into two major categories : sulphide ores, and oxidized lateritic ores, these latter containing nearly 80% of the known reserves of the metal (1). Two types of lateritic ores are recognized; ores high in iron but low in magnesia and silica are known as "limonitic", while ores low in iron but containing high percentages of magnesia and silica are called "silicate" (see Table I). Sulphide ores can be beneficiated readily by conventional ore dressing techniques and the technology for nickel recovery from such ores has been well tested in a number of commercial processes (1-4). Unfortunately, no economically viable process for the concentration of nickel from low-grade deposits has yet been developed, and so only the high grade ores are able to be worked profitably. Silicate ores have been treated pyrometallurgically for the production of ferronickel (2) (3) (5); limonitic ores have been processed hydrometallurgically to produce nickel metal (2) (3) (6) (7).

Jan 1, 1975

By J. Cooper, M. W. Staub

Environmental management systems (EMSs) have been in use for more than a decade. US mining companies are only just beginning to adopt EMSs. This lag is primarily due to lack of market forces and lack of evidence that EMSs add value over standard compliance programs. Several recent studies concluded EMSs improve environmental performance and reduce costs. State and federal regulatory agencies are using EMSs as an innovative tool to streamline the regulatory process and achieve continual environmental improvements. The climate is right for the mining industry to adopt an EMS model that improves environmental performance and takes advantage of new regulatory programs.

Jan 1, 2004

By G. Schubert, H. Hoberg

A large number of diverse size reduction machines is currently available for the comminution of waste materials. Equipment selection is determined by the nature of the material to be treated and by its behavior under external mechanical stressing. Accordingly, wastes can be divided into those with elastictbrittle and those with ductile/viscous behavior. The scientific understanding of the comminution of wastes is lagging strongly as compared to that of the grain-shaped mineral raw materials. Only in a few unique cases have the fundamentals of the comminution of ductile or viscous materials been presented. The paper centers on a characterization and systematic analysis of the types of stress fundamental to comminution. On the basis of this discussion an overview is presented of the currently available technologies for the comminution of wastes, with attention centering on those machines designed for materials with ductile or viscous behavior.

Jan 1, 1998

By William D. Meakins

INTRODUCTION Today, auxiliary fans, or boosters as they are sometimes called, are commonly used underground to provide ventilation for safe working conditions for personnel. Fans are installed in many ways and for many purposes; however, their use falls into three main categories depending upon the application. Auxiliary Face Ventilation For Coal Mines Usually the application of auxiliary fans underground in coal mines presents problems not normally encountered in other types of mining. Two of the major problems deal with liberation of methane at the coal face and the production of coal dust in the mining process. For these conditions it is necessary to use permissible (explosion-proof) type of equipment. As a result, these fans are discussed in a category by themselves. Auxiliary Fans For Tunnel and Drift Ventilation Tunnels and drifts present unique ventilation requirements. For instance, tunnels and drifts can be developed for considerable distances into virgin territory. Since they are generally dead-ended, the only way to obtain ventilation at the face is to use ventilation pipe to establish one leg of a ventilation circuit. The ventilation of tunnels and drifts therefore falls into another natural category. Other Uses of Auxiliary Fans For Mining Purposes Fans can be applied to mining applications in many ways other than those discussed under the other two categories. For example, many times auxiliary fans can do a much more practical job of proper air control and distribution that can be achieved with any other mechanical means; therefore, these other uses are discussed as a special category. AUXILIARY FACE VENTILATION FOR COAL MINES After 1936, federal and state coal mining laws prohibited the use of auxiliary underground fans in coal mines since such equipment had been widely misused. In certain cases, recirculation of face air had been allowed to occur thereby creating a serious potential explosive hazard by the possible buildup of excessive methane concentrations. By the late 1950s, mining machines with rapid face penetration were commonly being used in coal seams which liberated higher quantities of methane than in earlier years. As a consequence, in the late 1950s and early 1960s, the use of auxiliary face fans was again allowed under strict experimental conditions because conventional methods of face ventilation control without fans were becoming inadequate. Today, auxiliary face fans are widely used under strict federal and state control. Such auxiliary ventilation does not reduce the need for the amount of primary air from the main mine fans; however, it does help to distribute primary air more efficiently at the face. The present trend is toward an exhaust system of ventilation utilizing 406- to 610-mm (16- to 24-in.) diam tubing extending from the face to an outby auxiliary fan. Since the tubing is normally applied with negative pressure, spiral wire reinforced tubing has been replaced largely with metal and, more commonly, fiberglass tub¬ing. Additional auxiliary blower units are often used at the mouth of the room being developed, or installed on the miner or loader near the face, depending upon the amount of gas liberation present. Often one (or more) of the fan units is equipped with an integrally mounted hopper and feeder which automatically adds a continuously metered amount of rock dust to the exhaust air. The combination unit tends to make the mixture of discharge particles noncombustible and reduces to some extent the need for additional rock dusting of return airways. In this part of the chapter, typical auxiliary ventilation systems are described including curves and photograph of typical/applicable equipment. Reference will be made to "blowers" and "ex¬hausters." Both are fans and are basically the same units. They take on their name through the manner in which they are used. A blower usually has an inlet bell on the inlet side to help to obtain good air flow into the blades. An exhauster often has a discharge cone added to reduce the discharge loss. Any basic fan unit can be used either as a blower or an exhauster. Description of Auxiliary Ventilation Systems Several auxiliary ventilation systems and modifications of basic systems have evolved over recent years. Some of these systems are described and illustrated. System No. 1, an exhaust system for faces with comparatively low gas liberation, is shown in Fig. 1. Here

Jan 1, 1982

By Frederick W. DeVries, J. Brent Hiskey

Cyanide has been recognized for about a century as the most effective reagent for processing gold ores. Cyanide leaching has been adapted to various metallurgical settings and continues to be improved. However, in recent years attention has been directed to alternative lixiviants for treating refractory ores and concentrates, and to the development of less environmentally controversial substitutes for cyanide. This paper reviews some of the reagents considered as alternatives to cyanide and focuses on environmental implications for using these newer reagents.

Jan 1, 1992

By Alfred L. Anderson

Thorite and rare earth deposits in the Lemhi Pass area of southeastern Lemhi County, Idaho, are contained along complex shear and fracture zones and in reopened gold-quartz veins and copper lodes in quartzitic and phyllitic rocks of the Pre-cambrian belt series. Some of the shear and fracture zones are several tons of feet across and comprise broad zones of irregularly mineralized rock. These lodes contain a notable concentration of thorium and rare earth elements along with considerable amounts of barium, .potassium, calcium, iron, aluminum, phosphorus, sulfur, and silicon. The principal minerals are thorite, locally allanite, monazite, xenotime (?), apatite, specular hematite, barite, potash feldspar, occasionally calcite and quartz. Exept for some of 'the specular hematite, barite, reddish feldspar, calcite and quartz, the minerals are not distinguishable without the microscope. The thorite and locally allanite were deposited first, then the monazite and other phosphates, which were in turn followed successively by barite, potash, feldspar, calcite, and quartz. In exceptional cases, deposition of thorite and specular hematite was repeated after the feldspar. Some of the deposits contain several percent thoria, but the average os generally under one percent. The rare earth content is comparable with that of the thoria. The deposits appear to be of hydrothermal origin and are probably related genetically to late Cretaceous or early Tertiary igneous activity, manifested locally by a few dioritie and lamprophyric dikes.

Jan 1, 1959