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By K. N. Han, Y. Guan

[The dissolution behavior of copper and gold from their pure state and from Au-Cu alloys in cyanide solutions has been investigated using a rotating disc. Oxygen was used as an oxidant. The effect of the alloy composition, stirring speed of the disc. [lixiviant] concentration, solution pH and temperature on the overall dissolution kinetics has been studied. An-Cu alloys of three compositions were used in this study. The atomic percent of gold in these alloys was 75, 50 and25, respectively. The dissolution behavior of these three alloys was compared, under the same chemical conditions, with that of pure gold and pure copper. In general, the dissolution of copper and old from alloys is controlled partially by surface chemical reaction and largely mass transfer.]

Jan 1, 1994

By Cheryl M. McInnes, Graham J. Sparrow, James T. Woodcock

Three composites, assaying about 3 g/t Au and 0.75% Cu, were investigated. Each contained oxide copper minerals, iron oxides, and silicates. One composite also contained copper and iron sulphides. Maximum gold extractions by thiourea leaching were obtained after copper removal by acid pre¬leaching at pH 1.5 and redox potentials of 400 mV (Pt versus SCE). Best thiourea leaching conditions were pH 1.5, redox potentials over 200 mV, and 0.4% thiourea. This gave 90% gold extraction in 2 h with thiourea consumptions of 25 kg/t. Lower potentials gave poorer extractions. Ferrous iron additions before leaching halved thiourea consumptions. Longer leach times and the presence of sulphide minerals sometimes resulted in reprecipitation of gold.

Jan 1, 1989

By J. W. Shuster

Test of trolley-diesel prime power is another step in the search to exploit the unused potential of electric wheel driven haulage trucks. The output of the present engine - a 700 horsepower diesel - is not adequate to exploit fully the 1200 horsepower potential of the two electric wheel drive motors. Power was supplied to a modified 100-ton haulage truck through a double wire trolley system. The vehicle was tested with various payloads on a 7% adverse grade haul road. More significant conclusions developed are: Power - Horsepower to propel the vehicle can he more than doubled to improve truck cycle time. Productivity - Trolley power up adverse grades can improve [producivity] rates from 18 to 36%, dependent upon haul road profile.

Jan 1, 1968

By W. S. Versluis, G. W. R. Kuzyk

Atomic Energy of Canada, Ltd. (AECL) is constructing an Underground Research Laboratory (URL), a major component of-the Canadian Nuclear Fuel Waste Management Program. In July 1988. AECL and the US Department of Energy commenced a cooperative research program that included extending the URL shaft by 190 m (623 ft) to the 443-m (1,453 ft) depth. The shaft extension, 4.6-m- diam (15-ft-diam), was excavated by full-face blasting using a burn cut. A Galloway stage accommodated the research activities and the sinking contractor's requirements. Blast designs incorporated controlled blasting techniques to minimize blast-induced damage on the shaft walls. The full-face method has been very effective, with 3.5-m (11.5-ft) rounds being advanced.

Jan 1, 1990

By Ted H. Eyde

The Bowie chabazite deposit has yielded the most mined tonnage of any natural zeolite deposit in the United States. Since 1962 the deposit has yielded about 12,000 tons of crude chabazite, with an estimated market value of S30 million when sold as an activated molecular -sieve product. Between 1,000 and 1,500 tons of high-purity crude lump chabazite is now produced annually by stripping and selectively mining the lower, massive, half-foot-thick, "high-grade" bed. All of the chabazite is still shipped out of State for grinding prior to extrusion and activation. Zeolite minerals were discovered at the Bowie deposit in 1875, when Oscar Lowe identified a hydrous silicate related to chabazite or stilbite from a tuff bed that cropped out in the San Simon Valley. It was not until 1959, however, that chabzite, erionite, and clinoptilolite were positively identified as the principal constituents of an altered vitric-tuff horizon that crops out in the area originally described by Lowe. Shortly after the rediscovery of zeolite minerals in the San Simon Valley, several of the major producers of synthetic zeolites acquired land positions covering the outcrops, including projected extensions, and began exploration drilling. By 1980 all of the known chabazite reserves had been acquired by five companies and two individuals. The more than 3,000 holes drilled to explore the deposit and the excellent exposures provided by the strip-mined areas indicate that the chabazite-bearing horizon (known as the marker tuff) is confined to a flat-lying lacustrine section known to the operators as the Green Lake Beds. The deposition of the parent airborne vitric ash and subsequent zeolitic alteration was controlled by many factors, including the lake-bottom topography, depth and cation content of the saline-alkaline lake water, and proximity to post-depositional erosion surfaces. Zeolitic alteration was complete when an extensive system of younger paleochannels deeply eroded the Green Lake Beds. This left only a few erosional remnants of the marker tuff and the lower "high-grade-bed" that constitute the present deposit. Both the channel gravels and the Green Lake Beds are overlain by a section of halite-bearing brown mud-stones, known as the Brown Lake Beds. The bowie chabazite deposit can be used as a model to guide the exploration and development of other zeolite deposits that formed in saline-alkaline lacustrine environments.

Jan 1, 1987

By D. F. Symonds

INTRODUCTION Dense medium processes have been used to separate coal and ores for over a hundred years. In fact Sir Henry Bessemer first patented a process in 1858. In recent years, their importance relative to other gravity dependent processes has increased. This is particularly true in the coal industry where over 60% of all preparation plants operating in 1984 in North America (1) contained either dense medium vessel or cyclone circuits. In addition, the stringent product quality demands of the consumer, together with increases in mining costs, dictate that the cleaning circuits be both predictable and efficient. Dense medium systems are the most predictable and efficient of all gravity- dependent processes. The majority of the text of this chapter will be concerned with dense medium applications as they relate to the coal industry. However, the techniques and calculation procedures can be applied, in general, to all non-coal minerals (such as diamonds, marginal iron and lead-zinc ores and gravel) which take advantage of a difference in specific gravity between the saleable product and the reject. The object in dense medium cleaning is to produce a liquid whose effective specific gravity is between that of the concentrate and the reject. In which case the lighter product will float to the surface and the heavier product will sink to the bottom. Unfortunately, this simple process becomes complicated by the following practical necessities: (a) collecting and removing the float and sink products from the medium without disturbing the free settling effects; (b) maintaining and controlling the specific gravity of the medium; (c) separating and reclaiming the medium once the products have left the separating vessel; and (d) separating finer sized particles which take longer to fall through the dense, and often viscous, medium. As a result of the last issue (item d) two main types of dense medium separators have evolved: dense medium vessels and dense medium cyclones. Dense medium vessels are essentially large baths through which the dense medium flows at a relatively slow velocity. The lighter products float to the surface and are carried out of the vessel by the medium flow. The heavier products sink to the bottom of the vessel and are physically transported out either by means of a conveyor (usually a chain conveyor) or a rotating, lifting arrangement (Figure 1). They generally

Jan 1, 1986

By Éder Domingos Oliveira, Carlos Antonio Morais, Ruberlan Gomes Silva

The objective of this work was to assess the influence of parameters such as residence time, solid content, and temperature in a process route towards purified rare earth liquor which could be adequate to produce marketable rare earth products. The steps of the process route proposed in this study comprised water leaching of a sulfated rare earth ore and removal of impurities through the purification of the rare earth sulfuric liquor, which is the product of the water leaching step. The sample used in the water leaching experiments was a sulfated rare earth ore produced by the reaction of a beneficiated rare earth ore with sulfuric acid followed by roasting at 700 °C for 2 h in a muffle furnace and cooling at 20 °C. The water leaching experiments showed that the best condition comprised a residence time of 30 min, temperature of 20 °C, and solid content of 10% w/w, resulting in a recovery of 71.3% of the rare earth elements (REE) and a lower impurity extraction, e.g., only 15.0% of Fe, representing the main impurity in the rare earth ore. Even when presenting low amounts of impurities, the rare earth sulfuric liquor still needed to be purified before it can be used in the production of marketable rare earth products. In the study, the rare earth sulfuric liquors were purified in two consecutive neutralization steps, first by dosing the limestone pulp to pH up to 3.5 and secondly by adding the lime pulp to raise the pH from 3.5 to 5.0. The application of two consecutive purification steps at 20 °C resulted in the highest overall REE recoveries (65.4%) throughout all the steps of the process, being 71.3% in the water leaching, 99.6% in the partial purification with limestone pulp, and 92.1% in the purification with lime pulp at 20 °C. Under this condition, there was a total elimination of Fe, P, and Th and a significant reduction in the Al, U, and sulfate concentrations in the purified rare earth liquor. The purified rare earth liquor attained through the experiment is expected to be amenable to be used in the production of marketable products due to the lower impurities/REO mass ratios.

By F. M. Doyle, Jiang Tao, Xu Shi, Chen Jin, E. Peters

Tafel curve technique and leaching tests have been applied to study the kinetics of gold leaching with thiosulfate. Results show that cupric ions and ammonia play the part of catalysts in the leaching of gold with thiosulfate. The activation energy of gold dissolution is calculated as 27.99 KJ/mol in the absence of both cupric ions and ammonia. However, the energy is reduced to 15.54 KJ/mol in a solution of 0.01 mol/L Cu (NH3)2 4* and 0. 5moVL total ammonia. The reaction order of Cu (NH,) g is one in the range of 0.001~0.1mol/L. These results support the electrochemical-catalytic mechanism pro- posed by the authors and explains the behavior of cupric ion and ammonia (Jiang Tao, et al., 1993)

Jan 1, 1993

By R. W. Hughes, R. Koopmans

This paper investigates the effect of varying stress levels on the determination of deformation moduli and examines the sensitivity of the borehole dilatometer in measuring rock mass scale features and its ability to represent rock mass characteristics. Cubical blocks of sandstone, limestone and granite were tested in the laboratory under triaxial stress conditions. Field programs were conducted in both granite and sandstone rock masses surrounding underground openings. The dilatometer's zone of influence was determined by conducting tests within an instrumented concrete cylinder and by performing a finite element analysis. Laboratory and field results suggest that the deformation modulus of a rock mass can be substantially affected by the stress field and that the borehole dilatometer is sensitive enough to profile deformation moduli as dictated by the in situ rock mass characteristics.

Jan 1, 1986

By S. D. F. Rocha

The influence of surfactants on the crystallization of calcium sulfate was investigated in both hatch and continuous systems. The investigation was per formed at the following conditions. 343 °K, 28% P205 and with a sulfate level of 2.0%. At concentrations of 5 and 200 µgig, respectively, dodecylbenzene sulfonic acid (DBSH) and sodium diisooctil sulosuccinate (SSNa) promoted both an increase in the size and a reduction in the length/width (L/W) ratio of the calcium sulfate hydrates produced in the hatch and continuous crystallizers. Unique effects were observed in the batch system at higher DBSH concentrations. At 10 µg/g, the precipitation of hemihydrate crystals with a distinct morphology and texture occurred under conditions where dihydrate precipitation was expected. Above 50 µg/g, the precipitation of calcium sulfate hydrates was completely inhibited.

Jan 1, 1996

By C. K. Blair, V. J. Hucka, E. P. Kimball

In central Utah, a coal mining operation is taking place under an 0.5-m (20-in.) pressurized natural gas pipeline. The room-and-pillar method with pillar extraction is being used to extract the coal from the seams. The pillars beneath the pipeline will not be extracted; however, there is a possibility that some subsidence may occur due to pillar failure. To assess possible damages on the pipeline, an attempt has been made to predict subsidence in the area where pillars may collapse. The resultant values of subsidence strain and slope have been used to determine the magnitude of strain, stress, and shear induced in the pipeline. Also, a network of survey points has been installed along the pipeline to detect ground move¬ment that would indicate excessive subsidence.

Jan 1, 1987

By Robert A. Bauer

Two basic types of subsidence occur in Illinois: pit and sag / trough. Pits develop over mines less than 165 feet deep and where relatively incompetent strata are found over the mines. Sag subsidence is found over mines as shallow as 75 feet and more generally over mines of greater depths. The percentage of subsidence and angles of draw associated with sag subsidence appear to be controlled by the rock properties at each specific site. The percentage of subsidence and angles of draw are smaller where the sites are not affected by geologic structures. An investigation to determine if a time factor based on the time interval from the date of mining to the subsidence events has shown that simple correlations with time, percent extraction, average pillar stresses, and pillar dimensions is not evident in Illinois.

Jan 1, 1982

By G. A. Eltringham

Mining and extraction methods in the copper industry use basic technologies developed over a period of almost 150 years. Paradigm shifts in the industry have been rare, yet human involvement in the activities has changed dramatically. Clearly defined extraction paths have become more blurred as economic considerations broke down the barriers that had encouraged specialization. What had been a labor-intensive industry unfettered by environmental restrictions was forced to change. Better productivity and "cleaner" operations resulted in much higher capital costs on a plant basis. Many of the changes were truly innovative in the same spirit as in the mining revolution of the first decade of the twentieth century. What role will innovation play in the next 20 years as lower-grade, mixed-metal orebodies are exploited in more remote locations?

Jan 1, 1998

By G. D. Ritson

Gold surveys were sent to 21 gold operations around the world. Eleven different surveys were sent, each targeting a dif­ferent unit operation used commonly in gold processing. On a monthly basis the individual reports were returned to the opera­tions. Empirical data collected during the surveys has con­tributed to more effective engineering design. Graphical rela­tionships established have been used by the operations to "benchmark" performance against the industry and identify areas of possible improvement. This paper presents some of the findings related to the fol­lowing four surveys that investigated parameters specifically relating to carbon processing. Rescan Gold Survey GO 1 - Carbon Management practices Rescan Gold Survey 003 - Carbon Stripping Rescan Gold Survey 006 - Carbon Loading Isotherms Rescan Gold Survey 007 - Screening A final report documenting all the surveys will be compiled

Jan 1, 1998

By Steven Schurman

Acid Rock Drainage (ARD) is one of the most serious and persistent pollution problems facing today's mining industry. ARD is formed when pyrite (FeS) is exposed to natural weathering conditions. Pyrite weathering, formally the oxidation and hydrolysis of pyrite, leads to the generation of soluble, hydrous iron sulfa-salts and the production of acid in the form of H+. The resulting effluent is water that is characterized by high levels of iron (and any other metal contained in the rock undergoing weathering) as well as high concentrations of sulfate and a low pH (acid). Rocky Mountain Remediation Services, L.L.C., has developed a patents pending Envirobond'™ product, Envirobond™ ARD, to treat acid rock drainage. Treating pyrite with Envirobond™ ARD inhibits the oxidation and hydrolysis of pyrite thus curtailing the pyrite oxidation cycle.

Jan 1, 1999

By C. H. L. Bastos

A physical and chemical characterization study was carried out on 483 kaolin samples from 2.9 km2area at the Para Pigmentos mine along the Capim river, northern Brazil. The samples obtained from cores, drilled with regular spacing of 100 m, were evaluated using grit percentage, particle size distribution (psd), brightness, leachability, magnetic response and viscosity. These parameters were correlated with each process step in the plant and also the physical and chemical properties of the ore and finished product. Cluster analysis was performed and four main groups of kaolin were identified. These were then related to their performance at the various process steps and the quality of the initial product. These groups are well defined by plotting grit X “psd” and TiO2x “psd” in scatter plots.

Jan 1, 2004

By Fathi Habashi

THE MOST important arsenic minerals are shown in Table 6-1. The recovery of arsenic from arsenic sulfides is treated in Chapter Four. Arsenical ores may be either leached directly, or first smelted to volatilize as much arsenic and sulfur as possible, and the resulting product, called speiss, is then leached. A speiss is mainly a complex mixture of metal arsenides, but its [Table 6-1. Arsenic minerals. Arsenides Niccolite NiS Smaltite CoAs2 Skutterudite CoAs3 Sulfarsenides Cobaltite CoAsS Enargite CuaAsS4 Arsenopyrite FeAsS Arsenic sulfides Realgar As4S4 Orpiment As2S3] composition varies widely, depending on the type of ore treated. A speiss usually contains 15-35% arsenic. Methods of leaching are describedd in the following paragraphs.

Jan 1, 1970

By Krystyna Raszka, Jerzy Iskra

The paper presents results of spectrophotometric investigations concerning the adsorption of sodium oleate on silicon carbide in the presence of the cations of multivalent metals, applying the ATR IR technique with computer-aidedprocessing of the spectrum. The analysis of these spectra indicates the occurance of distinct OH and COOH bands in the pH range in which the hydroxy complexes of metals of the type MeOH+ and MeOH++ reach in the respective cases the highest concentration in the solution. The correlation of these results with those of flotation, measurements of the zeta potential confirms the proposed mechanism of activation of the flotation of silicon carbide, applying sodium oleate as a collector, the collection taking place over the adsorption of hydroxy complexes of the type MeOH+ and MeOH++

Jan 1, 1995

By J. Partyka

Fumes produced during blasting operations in underground mines are defined in this paper by an equivalent contaminant source. The primary goal is to establish a method which would allow all those parameters not measured directly to be determined reliably from field data. The parameters to be identified are the diffusion coefficient , and the position and size of an equivalent source. The diffusion-value is computed from the peak concentrations taken by two monitors located in the drift. The first monitor is placed close to where blasting pollutants join the main stream, while a second monitors is moved downstream a some distance from the first point. The position and size of the dust source and the total amount of dust produced during blasting are determined from the data recorded by only one monitor.

Jan 1, 1991

By Leonard Harris

The 1980s marked a boom in gold mining and exploration in the United States particularly in the state of Nevada which lifted this country to second place in the world, after South Africa, in gold production. With this boom came many positive aspects such as increased employment, increased investment, increased payment of federal and local taxes, higher purchases of goods and services and higher expenditures on social and economic uplift programs. With the arrival of Minera Yanacocha in Peru in 1992, the gold mining boom shifted to this country which has lifted Peru to first place in Latin America in 1996 and ninth place in the world in gold production. As in the case of the United States in the 1980s, similar positive impacts are being felt throughout Peru in the 1990s.

Jan 1, 1998