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By Wan-Kyu Choi, Arpad E. Torma

The electrochemical reactions involved in a zinc sulfide flotation concentrate leaching with sulfuric acid in presence and absence of Thiobacillus ferrooxidans, as well as with ferric chloride - hydrochloric acid containing media, have been investigated. The cyclic voltammetric measurements revealed that many intermediate electrochemical reactions are involved in the zinc sulfide leaching. Using chronoamperometric and chronopotentiometric techniques, it was found that the leaching process is controlled by solid - state diffusion. The activation energy of solid - state diffusion process was determined by the Price's approach to be 21.3 kJ. The leaching mechanism is discussed in terms of solid - state properties (energy bondings) of the high energy gap solid zinc sulfide semiconductor and energy density states of redox systems of acidic leach media. A generalized model for the mechanism of zinc sulfide oxidation is present.

Jan 1, 1990

By Kal V. S. Sastry

Modeling and simulation are two major tools available to a mineral process engineer for a consistent and systematic process analysis. The application of these tools to the analysis of specific mineral processing unit operations is well documented in the literature; nevertheless, they are used only to a limited extent in the industry. This is because the fundamental principles of modeling and simulation in the context of mineral processing context are not available. This paper represents the first in a series of papers planned to meet this need. General principles of process modeling and a unified mineral process model development methodology are presented. A simple example of model development using the flotation unit operation is given. A discussion of the practical significance, challenges and opportunities associated with mineral process modeling is included.

Jan 1, 1990

A linear programming model with integer sequencing variables is developed to schedule limestone production for a quarry in Central Japan. The model is used to optimize raw material production from the quarry supplying limestone to cement, quick lime and aggregate plants. Typically, the mining in the quarry takes place in four to six different areas each area having 3 or 4 mining increments. Each mining increment contains different quality of limestone. The limestone production from the quarry is transported to the plants byway of 3 ore passes. Each plant requires a given quantity of limestone per period meeting certain quality constraints. This paper will describe development of the scheduling optimization model and how it is used to schedule production by period within the quarry to meet the capacity and blending requirements of the plants.

Jan 1, 2003

By M. Leduc, M. Backens, M. E. Smith

An emerging technology for sustainable development in mineral development, tailings co-disposal™ is a means to dispose of conventional mill tailings within the void space of a waste rock dump. This method, while not applicable to all tailings systems, can offer a significant reduction in short-term and long-term environmental liability, land disturbance, closure costs, and negative public image. The concept is to dispose of the tailings simultaneously with the waste rock or leach ore, controlling the ratio of tailings to coarse material such that the resulting dump is stable both physically and chemically. The resulting co-disposal dump can be as safe as a conventional waste dump. In the case of alkaline tailings in a potentially acidic waste dump, the acid production can be buffered or slowed.

Jan 1, 2004

By Fathi Habashi

IT APPEARS that the phenomenon of ion exchange by which saline water was converted to sweet was known to Moses and Aristotle. However, the credit for the recognition of this process is generally attributed to Thompson (1850) and Way (1850), who reported that when a soil was treated with either ammonium sulfate or ammonium carbonate solution, most of the ammonia was adsorbed and calcium was released. It was later proved by Eichorn (1858) that the adsorption of ions from ground waters by clay constituents was a reversible process. The first attempts to utilize ion exchange phenomena was in the field of water softening around 1906, using natural and synthetic silicates. In 1935 Adams and Holmes in England observed that crushed phonograph records (phenol-formaldehyde and amine-formaldehyde resins) were capable of exchanging ions.

Jan 1, 1970

By John T. Crawford

Open pit limit analysis techniques of various types have been utilized for many years to design ultimate pit surfaces. In the last 15 years there have been many advances in the development of sophisticated computer methods to aid this process. The extensive capability of the computer has led to multiple alternative approaches to problem solving. Computerized open pit limit analysis methods can be applied to a broad scope of long-range and intermediate-range mine planning and design questions. A single computer run develops a pit design from a set of data. A set of nonsequential runs is used to evaluate changes in pit slopes, property restraints, and mineral model variables. Ore reserve economic sensitivity and intermediate-range mining plans can be developed using sequential computer runs. Present value methods are incorporated by using iterative sequential techniques. Multiple ore processes, dump leaching credits, and the trade-off between open pit and underground mining can also be handled. Many of the applications described are representative of current practice. The remainder are suggested extensions.

Jan 1, 1979

By Z. F. Wang, W. K. Choi, A. E. Torma

The present study has investigated the bioleachability of low-grade and high-grade pyritic gold ores and the extraction of gold from the leach residues of bioleaching with thiourea solutions. Final gold extractions as high as 96% were obtained from the high-grade ore and above 93% from the low-grade ore. The gold extraction was found to follow the extent of pyrite biooxidation. Using a cyclic voltammetric technique and carbon-paste-FeS2 electrode it was found that the semiconductor pyrite oxidation involves many intermediate electrochemical reactions. Furthermore, the oxidation is solid-state diffusion controlled as suggested by chronoamperometric and chronopotentiometric measurements.Using Sand's approach, the activation energy of solid-state diffusion biooxidation of pyrite was determined to be AEa=22.4 kJ. A generalized model for the mechanisms of pyrite oxidation has been presented.

Jan 1, 1990

Open pit optimization and mine design depend upon a realistic estimate of the grade-tonnage dis¬tribution. The estimate should reflect what can be reasonably recovered and processed. The McCoy/Cove operation in central Nevada is a gold and silver mine. Recoverable reserve estimations of gold and silver were made using indicator kriging and the indirect log normal variance correction to construct the grade- tonnage distribution. Optimal pits were generated using this distribution, and the results were compared to the pits generated by ordinary kriging and indicator kriging block mean methods. The results indicate that the proposed method for multimetal recoverable reserve estimation shows an improvement in terms of predicting the recoverable tons and grades. The optimal pits generated from the recoverable resource model are larger than those generated by the ordinary kriging and indicator kriging block mean methods. This model maximizes the overall recovery of the mineral resource.

Jan 1, 1999

By Eugene V. Cilento, George B. Georgellis

The hypothesis that freshly-sheared quartz makes it more reactive in lung tissue than aged quartz was tested by its ability to stimulate superoxide anion (02-) release from single adherent pulmonary alveolar macrophages (PAM). Fresh quartz was prepared by grinding for 30 min and then used within 2 hr, while stale quartz was from the same stock but aged 15 days prior to use. Also, dipalmitoyl lecithin (DPL), the major constituent of lung surfactant coating the alveoli surfaces, was coated onto the particles. Release of 02- was measured after 40 and 180 min of direct contact with quartz dust (225 µg/ml). Fresh quartz was more reactive than aged quartz, as indicated by the 78 and 63% increase after 40 and 180 min, respectively. A time delay and suppression of 02- release was observed in the ability of the DPL- coated fresh or stale dust to stimulate PAM. These results supported the hypothesis that the natural process of surfactant coating of inhaled particles in the alveoli may play a role in their phagocytic removal by PAM.

Jan 1, 1991

By Winfield G. Wright, Greg P. Meeker, Philip L. Verplanck, Douglas B. Yager, Dana J. Bove, M. Alisa Mast

A really extensive acid sulfate-altered and mineralized rock in the southeast Red Mountains area is noted for its association with naturally occurring and mine-related acidic and metal-rich waters. Integrated geologic and aqueous geochemical studies demonstrate that the degree of metal mobilization and acid production in natural waters correlates well with the type of hydrothermally altered rock and structural features in which these water interact. Quartz-sericite-pyrite, quartz-alunite, and argillic alteration assemblages are associated with some of the most naturally acidic, high-metal waters in the study area; calcite-bearing propylitic rocks are related to the most pristine waters and buffer sulfate-rich, acidic waters produced by pyrite oxidation. Trace metals in natural waters are mostly derived from enargite, zinc-rich tetrahedrite and sphalerite. Pyrite oxidation contributes very little with respect to base-metals in these natural waters.

Jan 1, 2000

By H. Tutu

The legacy of gold mining operations continues to affect water quality in the Witwatersrand Basin in South Africa. The acid mine drainage (AMD) emanating from the tailings dumps liberates heavy metals from the ore minerals. The objective of this study was to characterise the geochemical processes that are important in understanding chemical evolution of polluted water in the study area. Analytical results for water samples collected in the catchment of the study area generally showed elevated concentrations of heavy metals in the vicinity of tailings dumps and mining operations and a decrease in the distal. Dams and wetlands, despite their proximity to the tailings dumps, recorded low concentrations of heavy metals and other pollutants. The characterisation of AMD was summarised in a conceptual model in which plots of redox potential versus pH and electrical conductivity versus pH were identified as the most important sub-models that captured the gross physical-chemical characteristics of polluted water and its interaction with the environment.

Jan 1, 2006

By M. W. Rutland, E. Manev, R. J. Pugh

Data collected from several different fundamental surface chemical techniques were compared to study the interfacial interactions in the dodecylaminelmica flotation system. In the present study, the method used was the microinterferometric free foam film technique of Scheludko (1967) in which the stability, thickness and interfacial potentials at the air/dodecylamine solution interface were determined. These results were compared to previously published data, obtained from surface force measurements (Rutland et al. 1992), in which the interaction and hydrophobic adhesion (pull-off force) between molecularly smooth mica sheets in the amine solution had been reported. Also equilibrium contact angle measurements were used for comparison. The data was collected over a range of pH values and related to the batch flotation response of mica in dodecylamine solution. It was found that maximum flotation occurred at pH 8, but this did not correlate with the minimum in double layer interaction potential. However, it appeared to correspond with a tightly packed collector monolayer giving maximum hydrophobicity to the mica surface. Finally, from the extended DLVO theory, it was shown that heterocoagulation between the bubble and the mica could only occur, providing there was a very long range hydrophobic interaction force to counterbalance the repulsive van der Waals and electrostatic forces.

Jan 1, 1995

By G. Belardi, G. Marruzzo, P. Plescia

This paper presents the results of grinding tests performed on magnetite from Kiruna (Sweden) and on chromite from Skoumtza (Macedonia. Greece). Stresses were measured by XRD, which determined the variations in the characteristic structural spacings of the minerals both before and after, grinding in a HSM/250 Herzog laboratory ring mill. Anal Isis of the magnetite and c hromite crystallinstallin was performed hi measuring the broadening of the strongest diffraction peak (311). .Also, structural analysis on chromite was carried out using the Mikheev model. Ultrafine-grinding tests on the magnetite and chomite demonstrated that this type of treatment can induce profound variations m the surface-stress state. These included plastic variations of the cell followed by "chemical" stress with oxidation front the stricture to form hydroxide or carbonate, films. This can have a great influence on the mineral reactivity to flotation reagents

Jan 1, 1996

By Ke Yang

In Chinese coal mines, extraction of deep, highly gassy soft coal seams sandwiched between soft floor and soft roof in complicated geology is commonly encountered. How to safely and efficiently excavate such seams is a very significant and important problem. It has been a focused research area in recent years. By combining the characteristics of fully mechanized longwall mining methods such as large cutting height and mining along the dip, an integrated method and technologies for the Zhangji Coal Mine were developed. This technology includes the design of a complicated geological exploration system, optimization of mining method and working face parameters, control of rock pressure and high levels of gas, reliability model of the production system, and selection and compatibility of equipment. Engineering practice shows that the integrated technology was successful in mining these complicated seams. This study not only enriches the mining method, but also improves the coal mining practice, especially ensuring both safety and productivity under complicated geological conditions.

Jan 1, 2009

By J. W. III Leonard, T. E. Wilson

In addition to coalbed thickness and basic coal quality data, coal drill cores can produce design data for coal beneficiation processes. To generate design data, a coal drill core should be reduced from its original cylindrical form to a particle size distribution and composition that represents (with the possible exception of top size) a raw coal process stream. Reducing a coal core with a crushing machine rarely accomplishes this representation. This investigation employs drop-shatter impact breakage followed by dry batch tumbling in a steel cylinder rotated about its transverse axis to characterize the core in terms of first-order and zeroth-order break- age rate constants, which are indices of the propensity of the coal to degrade during handling. To reduce composition variables and conserve difficult-to-obtain coal cores, the initial drop-shatter and dry-tumbling tests were done with synthetic cores. Then, cores from three coal beds, Illinois No. 6, Upper Freeport and Pocahontas No. 5, were tested. Comparison of a crushed drill core and a drill core prepared by drop-shatter and tumbling indicated that the size distribution and size fraction composition of the drop-shattered/tumbled core more closely resembled the plant feed.

Jan 1, 2000

By Michael DiMatteo, Michael D. Gardner, Eric F. Perry, John K. Felbinger, Robert S. Evans

A hydrologically isolated surface coal mine was reclaimed using acid material handling, alkaline addition and ground-water management techniques. Eight pit floor drains were installed during reclamation to intercept ground-water flow in the mine backfill and minimize water table buildup. All drains began flowing within six months of installation. Water quality and ground-water discharge have been monitored for four years after mine closure. A thin water table aquifer about five to seven feet thick has developed in minespoil about 20 to 40 feet thick. Ground-water flow direction is largely controlled by geologic structure and the drains. Median ground- water discharge is about 0.43 gallons per acre per minute, and varies an order of magnitude between wet and dry seasons. About 19 % of precipitation enters the aquifer as recharge. Seven of the eight drains typically discharge net alkaline water. Alkalinity is produced continuously and concentrations are highest during dry periods. Conversely, sulfate and acidity concentrations increase during wet periods as slugs of accumulated acid products are leached. Overall water quality is controlled principally by minespoil geochemistry and added alkaline material. The drains have successfully directed ground-water to a planned discharge area. Without the drains, a ground-water mound was expected to form against a buried highwall and discharge over a large area.

Jan 1, 2000

By Christian Jeger

After recalling the principles underlying fire-damp flow in coal and the essential part played by permeability (Darcy's law) in the intensity of flow, a few theoretical and experimental results showing the possible causes and range of variation of coal seam permeability are presented. The study of firedamp flow into gate roads and of residual gas concentrations in coals as a function of the gate road distance, shows that, in French mines, coal seams in a virgin zone have a very low permeability, but they become permeable when destressed by mine workings, in particular overlying workings. This is the case not only in the fractured zone round a mine excavation in which the gas is released, but also beyond the limit of the zone degassed by the excavation. In the floor of flat seams, upward boreholes can be used for predegassing seams that have been relaxed but not degassed, as the result of an overlying coal face. In this respect we shall describe the predrainage experiment carried out in the Marienau district of the Lorraine coalfield. Predrainage can contribute considerably to the reduction of methane emission in the ventilation of newly opened longwall faces. But to be efficient and useful predrainage should meet certain conditions.

Jan 1, 1980

By Scott G. Britton

Traditionally, water removal has taken a backseat to many other coal mining functions. However, it is a vital part of the total mine support system. In many US coal mines, more tons of water are removed each year than tons of coal. An excellent discussion of general drainage characteristics can be found in Chapter 8 of Elements of Practical Coal Mining, published by SME-AIME. This chapter is organized into three major sections. These are: designing effective drainage systems; constructing the main mine pumping station (static system); and constructing a portable pumping station (dynamic system). Each topic presents a separate discussion of the elements a construction foreman or engineer should consider for effective installation and operation of the mine drainage system. In addition, a list of pumping equipment manufacturers is available to interested persons and follows these sections.

Jan 1, 1983

By T. P. Lim, J. A. Cherry, A. J. Vivyurka, R. D. Blair

The first phase of an investigation of the chemical composition of subsurface water and the hydrochemical processes in and near the abandoned Nordic tailings at Elliot Lake, Ontario, was conducted in 1979. The Nordic area, which covers 85 hectares with an average thickness of 10 m and overlies deposits of permeable glaciofluvial sand, contains 15 million tonnes of tailings with 4-7% pyrite. Nests of standpipe piezometers installed at three locations on the tailings indicate that seepage through the tailings is predominantly downward. The water table in the tailings slopes from the north side of the tailings dam, where it is within a metre of surface to the south side near the tailings dam, where it is approximately 10 m below surface. When they were deposited during the period from 1957 to 1968, the tailings contained pore water at a pH of about 8 resulting from neutralization treatment in the mill. At the three piezometer nests, the pH increases from 3 near the water table to 7 near the bottom of the tailings. The pore water in the tailings is gradually becoming acidic because of oxidation of pyrite in the zone above the water table. The concentrations of Fe, Mn, Ni, Co, Zn and Pb are high in the shallow acidic zone and much lower in the deeper neutral zone. Concentrations of 226Ra range from 30 to 230 pCi/L. At the three sites concentrations of major ions in the permeable sand a short interval beneath the tailings indicate 226Ra presence of tailings seepage, but Ra concentrations are only 2 to 8 pCi/L. Greater downward penetration of 226Ra probably occurs in the area closer to the tailings dam. Monitoring of a network of multilevel bundle piezometers installed in permeable sand that extends southward from beneath the tailings indicates the occurrence of a plume of tailingsderived water containing high concentrations of Ca, Mg, Fe and S04 that extend 400 m downgradient from the tailings dam. The total dissolved solids decline from 20,000 at the dam to less than 500 mg/L at the identifiable downgradient periphery of the plume. A much smaller but distinct plume of water with high heavy metal concentrations and 226Ra in the range of 10 to 130 pCi/L extends from beneath the dam for a distance of 15 m. The pH of the groundwater in this heavy metal-radium plume is 4 to 5, whereas elsewhere in zone of groundwater with high dissolved solids, the pH is above 6. The results of this investigat, suggest that the heavy metals an 226 Ra are relatively immobile in the perme-

Jan 1, 1980

By E. R. Reeves

The mining industry has recognized the importance of engineering controls as a primary means of preventing hearing loss. The noise control treatments most commonly observed on drills and bolters during this study were windshields, sound absorbing material, and hydraulic motor covers. These controls were evaluated on machines at underground metal mines to determine the amount of noise reduction achieved by each control. The results indicate that absorbing material has very little effect on the noise level. The noise reduction attributable to the motor covers was dependent on the material used to create the cover. Properly installed windshields were the most consistent control.

Jan 1, 2004