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The present study refers to passive systems for the treatment of acidic liquid effluents emanating from mixed-sulphide mines by means of an-aerobic compost wetlands. An effort was made for the thermodynamic study of the chemical systems that are involved in the reactions during the simulation of this specific system using laboratory columns and a pilot scale application. The substrate used was a mixture of cow manure, a high alkalinity organic substrate and chestnut woodchips, while the synthetic solutions prepared for the laboratory experiments contained the three basic metal contaminants i.e. Fe, Zn and Mn. The precipitation mechanism of the contained metals and the form in which these are precipitated was therefore investigated by constructing the equilibrium phase diagrams (Eh-pH diagrams) of the Me-S-C-H2O systems. Based on the experimental results from laboratory and pilot scale tests the stability conditions of the chemical species taking part in the aqueous solutions were also determined and verified with the thermodynamic data available. The thermodynamic analysis of the system was performed for ambient temperature, which is the prevailing temperature on field constructed compost wetlands. Results were further validated with the results obtained by the application of a five step sequential extraction procedure in the remaining substrate in order to determine the form in which the metals were precipitated.

Jan 1, 2006

By Steven Johnson

The regulatory landscape has changed considerably since the first passage of Oklahoma's land-reclamation requirements in 1968 (Open Cut Reclamation Act of 1968). The Oklahoma Legislature revised the reclamation requirements in 1971 with passage of the Mining Lands Reclamation Act. With the passage of this Act, the Legislature empowered the Oklahoma Department of Mines with jurisdiction for permitting and regulatory authority over non-coal (industrial-minerals) mining operations. This act required all operators to file with the State, through the Department of Mines, a written application for a permit to engage in non-coal mining. Each application consisted of a mining plan, which included location maps of the proposed mining area along with a reclamation plan for the area to be covered. Additionally, a reclamation bond is required prior to issuance of a permit to ensure that the site would be reclaimed. Since 1971, the Act has been amended to include public notification and public participation in the review process of any application. Also, the operator can request that the Department review the mining plan based on the Life Expectancy of the mine, instead of the original one-year plan (HB 1409 in 1993). Even though the operator is granted a mining plan tied to the "Life Expectancy" of the site, the permit is reviewed annually for compliance as required by law.

Jan 1, 1999

By Joseph W. Kupfner

It is a recognized fact that a good maintenance program is a pre-requisite for minimum delay costs and maximum availability of equipment. To develop such a program and to make it effective, one must establish detailed instructions pertaining to inspections, lubrication, servicing, and/or replacing of various parts. A schedule must also be established for these maintenance checks, whether they be weekly, monthly, or whatever period is essential for the equipment. The number of tasks to be performed becomes monumental, and the administration is beyond error-free human capacity. It is for this reason that the computer must be an essential element in any efficient and economical preventive maintenance program. The evolution of a computerized maintenance program began some 18 years ago in the Mining Division of USSteel. It started with a manual system of preparing cards containing preventive maintenance instructions that had to be performed on some regular basis. We were very quickly overtaken by the massive task of administration and distribution of instruction cards to the users. The task became insurmountable as more mines were added to the system, mines that were spread over a large geographic area. It also became evident that the ability to make changes in equipment assignments and in the "what to do" instructions would require more time than had been anticipated.

Jan 1, 1986

By V. Rastogi

Surfactant-based bactericides are able to control acid formation in sulfidic materials such as pyrite and sulfidic ores, thereby helping to abate acid rock drainage. Bactericides are used in the following two ways: as periodic or continuous spray treatments for the prevention of acidification of material actively handled and moved and in controlled-release form for reclamation. Site-specific bactericide treatments are designed for active sites and reclamation. Results from two active coal refuse sites show that acid production can be reduced by 88% or more. Results from reclaimed sites show that bactericide treatment can be more effective than the addition of alkaline materials such as limestone and can reduce acid production from 3,500 to <30 ppm. The controlled-release-pellets treatment outlasts the life of the pellets, as shown by a study of a site now 10 years old A single treatment sets up a change in site microbiology to replace acid-producing Thiobacillus ferrooxidans bacteria with heterotrophic bacteria and creates a stable site without the need for further treatments. A secondary beneficial effect of bactericides is on revegetation, and biomass from treated areas is almost 10 times that from areas not treated with bactericide. Depending on the application, bactericide treatment can be cost effective upfront and certainly long-term, compared to the perpetual water treatment that could be required, even after productive use of the site is completed

Jan 1, 1997

By M. D. Attfield

During 1992 a number of papers were published on aspects of respiratory disease in US underground coal miners. These included reports on trends in prevalence of coal workers&apos; pneumoconiosis, the risks of developing coal workers&apos; pneumoconiosis in relation to dust exposure, and the relationship between lung disease other than pneumoconiosis and dust exposure. The intent of this paper is to provide a summary of the essential findings from these investigations. PREVALENCE AND INCIDENCE OF COAL WORKERS&apos; PNEUMOCONIOSIS Coal workers&apos; pneumoconiosis (CWP) is usually detected in living miners through use of the chest x-ray. Deposits of dust in the lung, and the fibrotic tissue reactions to the dust, are manifested on the x-ray as small and large opacities. These abnormalities are quantified into degrees of severity using a standardized classification scheme (the International Classification of Radiographs of the Pneumoconioses of the International Labour Office). For small opacities, the scheme provides for a four-point scale of abnormality (0, 1, 2, 3), reflecting increasing profusion of the opacities on the x-ray. In this report, category 1 or greater small rounded opacities (CWP 1+) represents the earlier radiographic stages of pneumoconiosis. Large opacities, indicate the later and often disabling stage of pneumoconiosis, usually referred to as progressive massive fibrosis (PMF). Information collected in a national surveillance program for underground coal miners (the Coalworkers&apos; X-ray Surveillance Program (CWXSP)) and a large epidemiologic study (National Study of Coalworkers&apos; Pneumoconiosis (NSCWP)) provide a means to assess trends in CWP prevalence over the years following the reduction in dust levels mandated by the 1969 Federal Coal Mine Health and Safety Act (FCMHSA). These programs are operated by the National Institute for Occupational Safety and Health (NIOSH), and are described in detail in Attfield and Althouse (1992) and Attfield and Castellan (1992). Both studies were divided administratively into distinct time periods, and the results shown here reflect that division. Figure 1 shows the prevalence of CWP 1+ as determined from data from the CWXSP, plotted by time period and years in mining. There is evidence of a temporal reduction in prevalence. (The lack of an obvious decline in the early 1970s may be an artifact arising from use of different versions of the standard classification.) Figure 2 provides information in the same format for PMF, and shows a similar trend [ ]

Jan 1, 1993

By R. J. Essex

In support of the Conceptual Design of a Nuclear Waste Repository in Salt, a confined core pillar design method developed by others was reviewed. The method, which was developed for applications in coal, represents the confined strength of the pillar material in terms of a linear failure criterion. However, triaxial compression strength tests conducted on salt samples indicate that a non-linear strength criterion is more appropriate for salt. The rationale behind the confined core method is reviewed. A rederivation of the confined core method is then presented that incorporates a non-linear strength criterion. Benefits of the modified method are that the strength of the confined pillar core can be more accurately represented, and that two contributors of pillar strength, rather than one, can be addressed.

Jan 1, 1988

By M. Pantazidou

Motivated by recent EU legislation already entered into force or in preparation, this article aims at offering glimpses of the future landscape in the area of subsurface protection against contamination from point sources. Towards this end, it discusses the most salient parts of legislation for the protection of water resources. It then presents results from the wide consultation rounds organized by the European Commission in order to both receive input and help make all opinions heard on the issue of soil protection. Finally, it introduces key provisions of the recent legislation on environmental liability. From the above pieces of legislation, this paper highlights the elements that concern specifically the protection of the subsurface against spills of hazardous wastes from point sources and the requirements for subsurface restoration.

Jan 1, 2005

By A. Vargiu, R. Ciccu, G. Massacci

Based on the current results of field practice and on experimental data obtained in the laboratory with a suitable testing apparatus, the industrial operation of diamond wire cutting can be simulated by means of a mathematical model capable of predicting the cutting velocity and the wear rate of the tool, and thence the cost figures, achievable for a variety of conditions (kind of rock, size and shape of the cut, position of the equipment) according to a predetermined setting strategy (peripheral velocity, pull- back force). The paper gives a short outline of the model and discusses the simulation results obtained in a number of cases aiming at singling out the most favourable conditions for a cost-effective use of diamond wire.

Jan 1, 1996

By A. M. Johnson, D. H. Carlson, D. L. Johnson, S. T. Bagley

A biologically assisted ferric iron leaching system was evaluated for in situ recovery of three copper sulfide oresfrorm northern Michigan. Laboratory scale bacterially assisted ferric sulfate leaching tests were run on the three ores. A T. ferrooxidans strain was found that could be adapted to copper in solutions at concentrations as high as 20 g/L. Column leaching of 4.5 to 2 mm (-4 +I0 mesh) material yielded extractions of 80-90% copper from one ore and 70 and 60% from the other ores. The highest copper extractions were from the Mount Bohemia ore deposits located in the Keweenaw Peninsula, which have fracture controlled chalcocite mineralization. The Bohemia ores are apparently well-suited for in situ solution mining.

Jan 1, 1987

By Graham Andrews

Experiment shows that the microbial degradation of pyrite does not necessarily proceed stoichiometrically. Under some conditions sulfur is oxidized preferentially leaving something approaching iron in composition; under others, the pyrite is converted almost to elemental sulfur. A kinetic model for the process based on three elementary biochemical reactions can explain these observations. The diffusion of sulfur along grain boundaries and dislocations in the solid pyrite uncouples the oxidation rates of sulfur and iron from the requirements of stoichiometry. This mechanism also explains qualitatively why bacteria adsorb preferentially at dislocation sites on pyrite surfaces, why they form "pits" at these sites, and why amorphous pyrite is more readily degraded than pure crystals. The rate-limiting step for pyrite oxidation is discussed

Jan 1, 1989

By J. H. Tylczak, R. Blickensderfer, D. J. Singleton

As part of its research on wear of mining and mineral processing equipment, the US Bureau of Mines evaluated the erosion-corrosion characteristics of 12 alloys in phosphoric acid waste water. Tests were conducted on 2- and 5-cm-diam specimen8 in 12- and 60-cm-diam ball mills by grinding phosphate rock in gypsum pond water with an initial pH of 1.6. For comparison, grinding tests also were conducted in tap water. Static corrosion tests in gypsum pond water also were carried out. For all alloys tested, the wear by erosion-corrosion was greater than the sum of erosion plus static corrosion. A low-alloy, high-carbon steel and a high-manganese, nitrided stainless steel were the most cost-effective materials

Jan 1, 1987

The declining grades of surface deposits have re-confirmed the need for greater production rates. Large scale production requires increased investments in expensive and sophisticated equipment. The key to successful operations can depend entirely on proper equipment utilisation and in this program of research at the Department of Mining and Metallurgical Engineering, University of Queensland, much emphasis has been placed on the analysis and improvement of this aspect of a load-haul-dump operation. For a model to be successfully integrated into a mine engineering function and readily accepted by mine operating personnel, it has to offer more than just results. The concepts used in its design and construction must include sufficient detail to enable engineers to apply it usefully and with confidence.

Jan 1, 1979

By John R. Marks

In April 1990, the Homestake Gold Mine embarked on a five year, $US 23 million underground drifting and drilling program to explore promising ore targets north of the current mine. This paper describes the ventilation and air-conditioning system that was installed for the 4m x 4m x 5.2 km (ultimately) drift, which is being driven at about 8m per day in 48OC (118.5 F) crystalline rock. Design parameters are described first. Differences in South African, Canadian and U.S. drift ventilation and civil tunneling techniques proved interesting. Details are then given on equipment selection, installation and performance. Costs are included. Special note is made of safety considerations for a long, dead-end drift.

Jan 1, 1991

By James L. Crowe

Electric-power-generating plants fired by fossil fuels are faced with increasingly stringent requirements for control of sulfur emissions. Several approaches for limiting these emissions, or for operating such facilities in an environmentally acceptable manner, are being pursued. Some of the approaches are based on the use of naturally occurring carbonate rocks or of materials derived from them. This paper discusses primarily the carbonate-rock-based processes being developed for control of sulfur dioxide emissions from fossil-fueled electric-power-generating plants. It includes a discussion of the role of carbonate rock materials in removal of sulfur dioxide from stack gases after combustion, capture of gaseous SO2 during the combustion process, and removal of sulfur from fuel prior to complete combustion. Materials derived from carbon- ate rocks are generally used in processes which convert the sulfur to a throwaway product, but there are also proposed processes in which the sulfur is converted to a useful product and the absorbent is regenerated for reuse.

Jan 1, 1974

By Michael G. Nelson

Underground coal mining practice often requires that some coal be left in place at the seam boundaries after mining, for purposes of ground control, quality control, machine guidance, or good operating practice. Many methods for measuring the thickness of boundary coal have been developed, but only the natural % R gamma background method as bee used in routine operations. Use of this method is constrained by the level and consistency of the natural gamma background in the bordering strata, the accuracy of the gamma detection instrument, and the elevation profile of the seam boundary being detected. Computer simulations for three commercially available gamma detection instruments, designed for mine use, showed that measurement of boundary coal thickness by the natural gamma method can provide satisfactory input for horizon control systems when the gamma detector is large, when the sensor is mounted on the mining machine, and when the elevation profile of the seam boundary does not change rapidly in the direction of advance.

Jan 1, 1993

By M. D. Flavel, J. C. Motz, G. V. Jergensen

Introduction Compared to the gyratory crusher, the cone crusher is character¬ized by its higher speed and a flat crushing chamber design which is intended to give a high capacity and reduction ratio for materials suitable to this type of processing. The aim is to retain material longer in the crushing chamber to do more work on material as it is being processed. A concept of how a piece of stone might flow through a secondary crushing chamber is shown in Fig. 45. The number of times material will be nipped during crushing will depend on material size, friability, and the geometry of the crushing chamber as well as its speed and eccentric throw. Cone crushers are usually specified in terms of closed-side setting (CSS) and a given quantity of material passing a particular square-mesh screen size. A criterion of product passing closed-side setting is often available. This value will vary according to the particular crusher design and the details of its applica¬tion. Essentially, cone crushers can be classified into distinct types, depending on their duty. Crusher sizes for all duties are described by terms arising out of common industry usage, such as 3-ft, 7-ft, etc., which refer to the crushing-head (mantle) diameter. At present the range of sizes available varies from approximately 2 to 10 ft diam. Weights vary in the range of 5 to 200 tons, and connected horsepowers range from 10 through 700. There are so many variations that specifics should be obtained from machine manufacturers. The crushing chambers that are fitted to various machines are also often referred to by terms arising out of common usage, such as standard for secondary crushers, and short head for tertiary crush¬ers, which refer specifically to the Symons design. Also used are more specific but equally vague descriptions, such as coarse, intermedi¬ate, and fine chambers. Some manufacturers such as Allis-Chalmers with their Hydrocone crushers refer to the model number of the machine by the feed opening and the diameter of the mantle. For example, a Model 10-84 Hydrocone crusher has an 84-in. diam man¬tle, and is capable of accepting a 10-in. diam sphere at the feed point to the crushing chamber. Rexnord and Telsmith define crushing cavi¬ties in their capacity tables as feed openings at minimum recommended discharge settings (closed-side settings). Each practice offers guidelines which should be carefully defined for the specific crushing problem. The utilization of a cone crusher depends on how well it is controlled and the features of the circuit in which it operates. Normally, it will operate in the range of 75 to 85% of the peak capacity. It is likely that industry pressures will call for a standarized de¬ applied crushing power. Experience has shown that the crushing process is more controllable if certain reduction ratios are adhered to for each stage. Technically, this is defined as that size of feed (in. or mm) of which 80% will pass, divided by the size of the product (in. or mm) which 80% will pass. Secondary Crushers These are the cone crushers which accept suitable feed size material either prepared by a primary crusher or occurring naturally, and reduce it to a size suitable for marketing in one stage, or make feed for subsequent crushing or grinding stages. Secondary crushers have feed openings of 4 to 25 in. in the larger (7-ft) models down to a 2&apos;/a to 4 in. in the smallest 24-in. models. Reduction ratios normally range between 3:1 and seldom more than 5:1. In the 7-ft models, the cone crusher typically makes a product all passing 2 in., but this is dependent on the machine design and properties of the material being treated. Secondary crushers most commonly operate in open circuit. They also are operated in closed circuit with a vibrating screen, depending upon product requirements and conditions where the reduction ratio does not cause excessive power draw and build-up of circulating load. Screening ahead of secondary crushers is generally recommended, especially where the feed contains more than 25% material smaller than the desired closed-side setting. Tertiary Crushers These are cone crushers that normally take secondary crusher product and reduce it to a marketable product or make it suitable for subsequent comminution steps. The reduction achieved is a func¬tion of the crusher design and the properties of the material to be treated. The reduction ratio is normally in the range between 1.5 and 2 to 1, and seldom more than 3 to 1. The tertiary crusher normally operates in closed circuit with a vibrating screen and makes a product smaller than all passing &apos;h or 5/8 in. Fine Crushers Sometimes these machines are called sand crushers and are called by various manufacturer brand names, such as Gyradisc, Hydrofine, V.F.C., and others. A cross section of a Symons Gyradisc crusher is shown in Fig. 46. Essentially, these crushers would be used in a fourth-stage crushing operation, but could be called on to reduce a screened feed size fraction from a secondary or primary crushing operation. This type of crusher normally receives feed no coarser than 1&apos;h in. that is scalped of all over-sized material and operates in closed circuit with a vibrating screen. For average materials, typical product is &apos;/e in. top size, although a -10 mesh product can be produced on those materials having suitable characteristics. The crusher is nor¬mally operated in a separate circuit from the main crushing plant because of the variations in output rates that are caused by varying physical properties in the feed. The reduction ratio is generally less than 2:1, and circulating loads are generally high. More interparticle crushing takes place in these machines than with conventional cone crushers and capacities can be more sensitive to changes in moisture content, feed size graduation, and other physical properties. Design Features For the various applications, crusher manufacturers normally have a range of crushers of different sizes and power ratings to select from.

Jan 1, 1985

By S. G. Malghan, V. K. Pujari

Detailed characterization of all the powder constituents during powder processing is necessary for the reproducible manufacture of ceramic components that will perform reliably in intended applications. In this paper, selected physical and surface chemical techniques for characterization of silicon nitride powder are evaluated. The characterization data are discussed in the context of how these data, through their influence on powder processing unit operations, can affect the final microstructure. In the forming of ceramics, some of the major variables of injection molding are evaluated. Accurate measurement and control of these variables is emphasized for manufacture of Si3N4 ceramics with a high degree of reliability.

Jan 1, 1990

By N. Santa, V. Salinas

"Printed circuit boards are potentially recyclable materials. Developing suitable methodologies for proper disposal and better utilization, brings major environmental and economic benefits. A methodology for copper recovery using heat treatment before conventional leaching is carried out. A comparison between conventional methodology and the one that includes incineration treatment is presented. It concludes about results and differences in terms of the percentage of copper leached over time. INTRODUCTION The rapid proliferation of electronic devices in the past two decades, has forced researchers to find a solution for one of the most toxic and hazardous materials, the printed circuit boards (Ghosh et al, 2015). For this, countless techniques have been developed, the methodologies includes hydrometallurgy, pirometallurgy, electrometallurgy or a combination between all of them. The amount of precious and base metals in its composition are very attractive and usable to implement methodologies that allow maximum recovery and recycling. This subject has been extensively studied and researched in order to provide solutions to the great problems generated by incorrect final disposal of this waste. Over 150 articles have been widely published in the last 15 years, covering large areas such as characterization of discarded printed circuit boards, health risks associated with processing and different routes of recycling have been analyzed to provide an overview understanding this issue (Ghosh et al, 2015). (Oh et al, 2003) performed a selective leaching of valuable metals from waste printed circuit boards by size reduction, magnetic and electrostatic separation, also leaching with sulfuric acid and hydrogen peroxide, achieving 95 \% of copper extraction. (Chaverra Arias, 2014) proposed a similar methodology to extract copper from electrical and electronic waste, performing similar processes and applying metallic copper electrowining as well as copper oxychloride precipitation. (Silvas et al, 2015) used hydrometallurgical processes for recycling printed circuit boards applying physical processing and copper extraction by selective leaching. (Kumar et al. 2014) conducted a leaching of metals from waste printed circuit boards using sulfuric and nitric acids. Also there have been proposed various methods for recovery of different metals including applying multiple metallurgical techniques that involve both living organisms and high temperature processes such as pyrometallurgical. The printed circuit boards are a very important source of copper, according to several authors mentioned above, the amount of copper on a printed circuit board can reach about 20 \%, because copper is responsible of establishing a conductive layer that will enable the connection between electrical and electronic components. This document proposes a methodology for recycling printed circuit boards and extract copper by selective leaching. The process that is carried out consist in a preliminary characterization and mechanical separation which will condition the material for further hydrometallurgical treatment that includes leaching in nitric acid media 3M."

Jan 1, 2017

By J. F. Whelan, B. D. Marshall, Z. E. Peterman, J. B. Paces, L. A. Neymark

Observations of calcite and opal in cavities in the unsaturated zone at Yucca Mountain indicate that: 1) seeps are not regularly spaced in underground workings and not all fractures sustain flow, 2) many cavities represent sites of seepage that have remained stable for millions of years, 3) typically there is no evidence (such as dripstone) for seepage dripping into cavities from their ceilings, and 4) seepage is not likely to be greater than about 1 liter of water per year (per 5-m-long drift) based on calcite abundances observed in the ESF. This estimate of seepage is significantly lower than that used for performance assessment.

Jan 1, 2000

By R. Hogg

The various sub-processes which, together, make up the unit operation of froth flotation all depend on the characteristics of the feed solids, the solution phase, the air bubbles and the mechanical/hydrodynamic action of the machine. Characterization is obviously necessary for evaluation and process control, but the relationships between characteristics and process response are often unclear. A model-based characterization scheme is proposed in which material and system characteristics are evaluated in the context of simplified models for the individual subprocesses. The general basis for such an approach is discussed using the process of particle attachment and the influence of mineral liberation as examples.

Jan 1, 1989