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By G. J. McDougall

After defining activated carbon, the author describes its structure and outlines the physical characteristics distinguishing one type of activated carbon from another. The adsorptive properties of these carbons, the raw materials used, and the manufacturing processes-chemical activation, and physical or thermal activation-are outlined. The high-temperature thermal route (which is the most important for the products employed in gold recovery) using coconut shells or coal as the raw material is then discussed In some detail.

Jan 1, 1991

By A. Morley

It is difficult to evaluate exploration properties in a manner that is transparent, repeatable and easily re-calculated to cater for different geological interpretations, but the risk-based assessment methodology, the Geological Risk Method, developed and described by Lord et al (2001) attempts to satisfy all these criteria. This paper examines a case study example based on valuations of exploration projects conducted by SRK Consulting using this methodology, and describes some of the advantages and limitations of the method.

Jan 1, 2007

By R L. Bowers, D S. Smit

In light of soaring commodity prices, Nkomati has investigated the potential of processing additional low grade nickel ores to add to their reserves. The Chromititic Peridotite Mineralised Zone (PCMZ) was identified as one ore type with the potential of producing a high grade nickel concentrate. In addition to the nickel, copper, cobalt and PGM?s, the ore also contains a significant amount of chromite which adds substantial value to the project. Pyrrhotite, pentlandite, chalcopyrite and chromite are the dominant minerals within the ore, which on average grades around 0.23% Ni and 12% Cr2O3. The PCMZ ore contains excessive amounts of fibrous silicates which makes it a challenging float, with gangue control as the key element to success. Extensive laboratory testwork, which eventually led to a pilot plant campaign, was undertaken with the aim of developing a process route for treating the PCMZ ore. Several flotation circuit configurations were tested and results from the optimal circuit indicated that a nickel concentrate grading at 8.5% is achievable at a recovery of 78%, with substantial recoveries for the copper, cobalt and PGM co-products. The chromite concentrate, grading at 45%, was extracted from the flotation rougher tailings via a spiral plant. These promising results were incorporated into the plant design and are currently being evaluated in a bankable feasibility study, which will see the current 100ktpm MMZ concentrator being upgraded to a 250ktpm PCMZ concentrator as part of Nkomati?s Phase II expansion.

Jan 1, 2007

By P. R. Jochens, D. D. Howat, R. B. Atmore

INTRODUCTION The Miller chlorination process has assumed a preeminent position in the refining of gold bullion, a position it has maintained for over half a century. In the early sixties considerable interest was aroused by the idea of producing a consistently high grade bullion at the mine smelthouses themselves. However, as the use of chlorine in industrial plants is associated with considerable hazards, oxygen was considered a natural alternative, apart from bing less expensive than chlorine. Partial refining at the mine smelthouses would considerably decrease the requirements made on Rand Refinery Limited as well as indicating the possibility of reducing final refining costs. An added factor would be the purer silver chloride obtainable, after prior removal of the base metals by oxygen injection, which would facilitate the production of high-purity silver. The free energies of formation of the oxides of the metals;- silver, copper, lead, zinc, iron and bismuth indicate that, with the exception of silver, these metals should be capable of removal as oxides by oxygen injection. Rose1 had shown that during injection of gold bullion, considerable loss of silver to the boraxsilver slag occurred and, furthermore, that copper removal was not efficient and oxide attack on the refractories was severe. Plant test work2 had confirmed the difficulty of copper removal, but had shown that zinc and lead were almost completely removed. The difficulty of copper removal by oxygen injection warranted further investigation. Also, the high decomposition pressure of silver oxide suggested that by suitable control of the slag composition it might be possible to reduce to very small proportions the silver carried into the slag as oxide. The oxidation of copper by oxygen injection and subsequent dissolution of the oxide in a slag may occur according to the following reactions; Reactions 4 and 5 were considered because of the relatively high solubility of oxygen in molten silver and silver alloys. Thermodynamic data indicate that there is little possibility of any reaction involving the formation of CuO occurring at temperatures above 1 000 °C. To ensure that the operative reactions 1 and 4 take place to the maximum extent, the following factors He significant. (a) an increase in the activity of the copper in the bullion, (b) an increase in the partial pressure of oxygen in the system, (c) an increase in the activity of the oxygen in solution in the metal, (d) a decrease in the activity of cuprous oxide in the slag. From practical considerations, the operative variable most easily susceptible to control is the composition of the slag. SOLUBILITY OF COPPER OXIDES IN BOROSILICATE SLAGS Very scanty information exists on systems containing copper oxides but the indications are that slags containing considerable amounts of boric oxide would possibly prove to be the best solvents for cuprous and cupric oxides. This is attributed to the fact that the activities of copper oxides are much lower in boric oxide slags than in slags in which silica is the main network former. The number of possible slags containing boric oxide was limited by consideration of liquidus temperature, viscosity, corrosive action on refractories, volatilization, and ultimately cost (for industrial application). Slags in the systems soda-boric oxide-silica and lime-boric oxide-silica were selected paying due attention to the above limitations. Additions of 5, 10 and 15 per cent cupric oxide were made to the finely ground, premelted slags. These mixtures were then reground and 2g quantities held in re crystallized alumina crucibles at temperatures of 1150°C and 1 250°C respectively for 30 minutes. The crucibles were removed from the furnace, rapidly cooled, cut in half longitudinally, and a thin section taken from one half was subjected to microscopic examination.

National Coal Board. Gate belt conveyors. London, H.M.S.O. (Price 95p.) Although the preface of this handy little book states that it has been written for the guidance of miningoperation trainees, it will prove valuable to the practising engineer as well. NIM reports Report no. 1733 A mineralogical investigation of weathered carbonatite from Salpeterkop. (14th Apr., 1975; re-issued 28th Feb., 1978). Report no. 1823 The recovery of gold and pyrite from a residue dump at Crown Mines. (10th Jul., 1976; re-issued 28th Feb., 1976). Report no. 1829 An investigation of weathered carbonatite from Salpeterkop. (20th Jul., 1976; reissued 28th Feb., 1978). Report no. 1932 A BASIC computer programme for the evaluation of intensity data from the Telsec Lab-X-250 Analyser. (12th Jan., 1978). Report no. 1940 The extraction of the noble metals with n-octylaniline,and its application to the analysis of platinum-bearing materials. (30th Jan., 1978). Report no. 1945 Analyses of the NIMROC reference samples for minor and trace elements. (28th Feb., 1978). International futures conference A conference entitled 'The Road Ahead' is being organized by the 1820 Settlers National Monument Foundation to be held in Grahamstown from 3rd to 7th July, 1978. Conference of metallurgists The technical programme has been established for the 17th Annual Conference of Metallurgists sponsored by the Metallurgical Society of the Canadian Institute of Mining and Metallurgy. This year the Conference will be held in Montreal, Quebec, on 27th to 31st August, 1978, together with the 8th Hydrometallurgy Meeting.

Jan 1, 1978

By E. B. Viljoen

I. R. M. Chaston* As a gravity concentration man in the midst of so many eminent flotation experts I feel like Daniel. However, I would respectifully disagree with the opening remarks by Mr Viljoen. First, he suggested that gravity concentration of cassiterite was not effective in sizes below 30 microns. In a paper to the Institution of Mining and Metallurgy in 19621, I gave some figures for gravity concentration of deslimed material both for cassiterite and for wolfram which indicated that careful shaking table concentration of fine deslimed material could give recoveries of 75 to 90 percent in the size ranges above 13 micron. These were figures obtained from normal plant operation. It would be interesting to know if any tests were carried out on gravity concentration of the efficiently deslimed feed to this flotation plant to see what the recovery would be. Secondly, Mr Viljoen suggested that gravity concentration plants were expensive. He gives the cost of a flotation plant at R300 000 to treat a feed of 400 t.p.d. to the desliming section or 160 t.p.d. to the flotation cells. From his operating cost figures it would appear that the flotation cost is approximately R2 to R4 per ton of feed to flotation and the total operating cost about R2 per ton of feed. A table plant to treat this tonnage of deslimed feed would consist of about 30 tables and should cost considerably less to install and very much less to operate than the flotation plant. Third, Mr. Viljoen suggests that the concentrate grade from a gravity concentration operation would be unacceptably low. The paper quoted abovel showed that once a primary fine concentrate had been made, giving a suitably deslimed material, further gravity concentration could give concentrates of over 40 per cent Sn with high recoveries. Tailing from this dressing stage was naturally returned to the feed. To give these high grades, sulphides had been removed by flotation but this necessary flotation step is simple and cheap to operate and could be restricted to the final stage when the quantities involved are small. I would agree that flotation has a part to play in fine tin recovery but this role would only seem to become fully effective at sizes below 10 micron and would seem to require, as Mr. Viljoen has suggested, a mechanism for sizing which is effective down to, say, 1 micron. In the meantime it would be interesting to try tabling the flotation tailing to see if it was possible to recover the plus 20 micron cassiterite which is not recovered well by flotation. One point which has been made during discussion is the suggestion that cassiterite particles have a fully hydrated surface at normal pH. I wonder if this layer could materially affect the overall specific gravity of a very small cassiterite particle and, if so, whether gravity concentration of the very fine cassiterite would be improved if carried out in acid conditions, which would inhibit the formation of this hydrated surface. REFERENCES 1. CHASTON, I. R. M. 'Gravity concentration of fine cassiterite'. Trans. Inst. Min. and Met. Vol. 71, p. 4, 1961 and 1962, and discussion of this paper. Dr. R. P. King Mr Viljoen has drawn attention to the difficulties associated with the presence of very fine particles in the flotation pulp and he has indicated that, on the Union Tin plant, they must sacrifice 30 percent of the cassiterite in the minus 7 /Lm material which they separate and lose. He has also indicated that the rate of flotation of cassiterite remained high at these small sizes. The problem arises because the very small particles stabilize the froth making it impossible to handle. These stable froths cannot be easily broken and therefore cannot be pumped and processed. It seems that further fundamental research work on the properties of stabilized froths is urgently required. We have found another difficulty associated with the presence of very fine particles in phoscorite slurries; these particles can be easily floated but with very poor selectivity. We believe that it is possible that a purely physical mechanism such as entrainment is responsible for the collection of fine particles in the froth. We have also demonstrated that the presence of fine particles in the pulp adversely affects the rate of flotation of the larger particles. For esample, we have found an increase in recovery of + 100 um material from 2 percent to 17 percent in a standard laboratory batch flotation test on phoscorite when the - 37 um was removed from the feed. Such interactions between particles are not universally recognised as an important aspect of the complex flotation mechanism. They should appear in any quantitative formulation of the flotation rate process.

By J Taguta, B. McFadzean, P. E. Ngoepe, M. G. Mulaudzi

Computational modelling methods and isothermal titration calorimetry (ITC) were employed to investigate the interaction of a pyrite surface with thiol collectors. Modelling work was conducted in the presence and absence of water. Microcalorimetry was employed to investigate the resultant energy of interaction pyrite as a result of mineral-collector interactions. Sodium ethyl xanthate (SEX), diethyldithiocarbamate (DTC) and diethyl dithiophosphate (DTP) were investigated in this study. The results showed that the calculated surface energies and morphologies for FeS2 showed that (100) and (111) are the most stable surfaces. The morphology also indicated the appearance of the (100) and (111) surface facets and no presence of others. The calculated adsorption energies between thiol collectors and the pyrite surface were always more exothermic than the experimentally determined ones. When comparing different ligand types with the same alkyl chain length, the heat of adsorption of diethyl-DTC was greater than that of ethyl xanthate and diethyl-DTP for pyrite. Experimentally, the diethyl DTP barely adsorbed onto the pyrite surface and this may be due to a different mechanism of action. In computational calculations, water adsorption was found to reduce the reactivity of the Fe atom for the interaction with thiol collectors, and bring the adsorption energies closer to the magnitude of the experimental values. Keywords: Computational modelling, microcalorimetry, experimental and thiol collectors, adsorption energies

Jan 1, 2020

By N. B. Strydom

The data on heat stroke cases reported during the past five years were examined to determine the influence of age on the incidence of heat stroke. Relating the age distribution of these cases to that of the total number of Bantu mine workers showed clearly that the older men run a significantly higher risk of developing heat stroke than the younger men. Although the number of Bantu over 40 years of age in the industry is less than 10 per cent of the total they nevertheless accounted for 50 per cent of the fatal heat stroke and 25 per cent of the nonfatal heat stroke cases during the period under review. Age must, therefore, be recognised as a causal factor in heat stroke and the worker over 40 years of age should be allocated to work on surface, or in cool areas or to non-strenuous and supervisory tasks in hot areas.

It is a great honour to officiate at the celebration of the centenary of the South African Institute of Mining and Metalurgy. Tonight's festivities bring back happy memories of my association with South Africa's mining industry during my tenure of office as Minister of Mineral and Energy Affairs. They also remind me of the illustrious personalities who have preceded me on this podium. The Pioneers They include Sir Percy Fitzpatrick, who spoke in 1909 on the eve of the Union, General Smuts, and, on many occasions during the 1920s and 1930, Jan H. Hofmeyr. The basic issues addressed by them continue to enjoy the Institute's attention today, namely the optimal and safe exploitation of our country's mineral resources and cost-effective extraction of minerals from their ores. Translated into the Institute's key objective it reads: To initiate and give effect to the means whereby the requirements for technology and scientific knowledge if the minerals and metals section if the South African economy is satisfied.

Jan 1, 1994

By J. R. de Wet

The behaviour of mild steel in aqueous cyanide solutions similar to caustic cyanide elution solutions was investigated at high temperature in electrochemical experiments. The anodic polarization diagrams of mild steel indicated that steel may undergo active dissolution under these conditions. The rare occurrence of gold plating in practice is the result of the limiting of the anodic dissolution of the steel by the presence of a passive layer on the steel. This passive layer is stable only in a certain potential range, and the free corrosion potential attained determines whether the steel will be passive or active. For conditions typical of elution columns, several corrosion potentials are possible, depending primarily on the initial condition of the steel and the concentration of oxygen in the solution. If these conditions result in the formation of a passive layer on the steel, changes in concentration and temperature will not necessarily result in plating since the layer may exist in a metastable form.

Jan 1, 1993

By Y. C. Kim

The estimation of local recoverable reserves using the widely spaced exploration drill hole information in an open-pit mine is probably one of the most difficult tasks in ore reserve estimation. The difficulty of this problem is magnified if the grade distribution is highly skewed, such as in a gold deposit. This paper describes the results of performance comparison of three different kriging techniques in an open-pit gold - silver deposit. The three different kriging techniques compared in their local recoverable reserve estimation capabilities are: (1) lognormal kriging, (2) indicator kriging, and (3) probability kriging. For performance comparison, the predictions are compared with the actual recoverable reserves determined from blast hole information. Based on the results from one test bench, both indicator and probability kriging performed better than lognormal kriging, perhaps owing to samples not being truly lognormal. Between indicator and probability kriging, probability kriging results were definitely superior to indicator kriging results.

Jan 1, 1987

By D. D. Marsden

The paper briefly outlines the history of the successful development of vegetating techniques for mine-residue deposits. It seeks to place on record the major roles played by M.J. Mrost, who initiated and systematically developed the concept, and W.H. Cook, who continued the trials and successfully directed a stupendous large-scale project. The vegetating techniques currently practised are outlined, and it is concluded that vegetating is still the only surface-stabilizing technique of any significance that is employed throughout the world.

Jan 1, 1987

By J. S. Freer

Integrated Environmental Management (IEM) involves the integration of environmental factors Into project planning, execution, and operation from inception to final closure and after-care. The objective IS to develop the most cost effective, environmentally acceptable manner in which the project can proceed, and to gain the approval of the authorities and the support of the interested and affected parties (I & APs) for the benefit of the developer, the economy, the people of South Africa and the environment on which they depend.

Jan 1, 1993

By M. Thurston

This case study shows that for a set of lognormal data with a low coefficient of variation the semi-variogram of the logs has almost the same shape as the semi-variogram of the raw data. This means that the variogram of the logs, which is numerically more stable, can be used to krige the raw data. This technique is tested on samples from a sedimentary gold deposit and the results compared to those obtained from ordinary and simple lognormal kriging.

Jan 1, 1987

By K. Moxham, B. McKeown

The South African gold and platinum deposits were formed in very different ways and yet both have many similarities. They are flat dipping tabular orebodies, extremely narrow and located in hard abrasive country rock. The mining methods employed are also similar. Primary access is via shafts or declines; secondary access is via haulages and cross-cuts; and tertiary access is from raises. The proposed solution for rapid access described in this paper is focused on the haulages and cross-cuts.

Jan 1, 2006

The aspect ratio (mill diameter/mill length) of autogenous and semi autogenous mills varies widely and can be as high as three or as low as 0.5. The literature on the subject of what effect aspect ratio has on grinding mill performance or energy efficiency is almost non-existent. However, at the design stage of many grinding circuits the subject is often vigorously debated amongst metallurgists. In this paper the performance characteristics of mills with different aspect ratios are examined to determine whether process performance characteristics are a function of aspect ratio and whether high aspect ratio mills are any more or less energy efficient than low aspect ratio units. Data from both pilot and full-scale mills are used for this purpose in open and closed circuit configurations.

Jan 1, 2007

By N. A. Barcza

Pointing out that South Africa needs to utilize its wealth-creating activities, together with local and international investment, to further develop its industries, the address asserts that the mining and minerals industries, especially in the manufacture of beneficiated products, offer the greatest potential for South Africa to achieve its goal. As many mineral-beneficiation processes are based on pyrometallurgical routes, the address goes on to describe some historical - pyrometallurgical operations and to indicate probable developments in the future. These include growth in the fields of both precious and base metals. After discussing environmental and recycling matters, together with manpower requirements, the address concludes that the major growth in the mining and minerals industries will occur in the manufacture of steel, stainless steel, ferro-alloys (particularly ferrochromium), aluminium, and titania slag.

Jan 1, 1996

The role of research and development In the South African gold-mining industry Presidential Address given by M. D. G. SALAMON, Fellow, Dipl. Eng. (Mining) (Hungary), Ph.D. (Durham) The decision of the gold-mining industry in 1974 to embark on a major ten-year research and development programme was widely publicized at the time. In choosing a subject for this address, I felt almost obliged to use this opportunity to give an account of the progress of this undertaking. On reflection, however, I felt that a simple progress report would not suffice. It seemed important that the programme should be shown in persepective, and that its aims should be outlined to the mining and metallurgical engineering community, many of whom are vitally concerned with the well-being of the gold-mining industry.

Jan 10, 1976

By M. Arnesen

Mining professionals recognize the need to continuously evaluate and refine mine planning standards and scheduling. We must examine our current reality, and evaluate the following: •How well do our planning standards represent the actual mining process? •To what extent do they support the requirements of the downstream mining activities? •How we apply them to operational management and control? In most operations, mine-planning standards are global averages. Little differentiation is madein quantifying key planning variables. Often standards used in the long-term, are applied to the short-term, and the standards and scheduling precedents are only reviewed occasionally. Mine-planning standards applied to production schedules are often only focused on the management of functional mining performance, and play no role in managing the requirements of down stream processing. Many mining operations are characterized by high levels of fluctuation, and typically incorporate a wide range of factors and adjustments to compensate for deviations from performance targets, in mining operations as well as for the other business areas. The reason for using global averages is because of a lack of understanding of the causes of deviations that occur through the process, and the impact that they may have on the performance of the business as a whole. Average standards and factors are often used to quantify the variability in a system. From these average values, measurement standards and performance targets are derived for the planning and execution environments. During the execution of a plan/schedule there will be deviation in actual performance and the planned ‘average’ standards. In reality the ‘average’ conditions seldom occur and the impact of variability and interdependency are seldom constant or predictable. The predictability of variability and interdependency is further complicated by the fact that mining conditions have a role to play in the actual production performance, and they too are variable. By developing the throughput knowledge of our production systems, we can better understand the nature of variability and the interdependency within the systems as well as the impact of interdependency between the links in our production chains. With this knowledge, planning standards and scheduling precedents can be better defined and sensibly differentiated. This will improve planning and management of ore utilization, mining production and the effectiveness of processing. As a result the business will be more stable and predictable and business performance will be improved. The purpose of this paper is to describe: •At a high level, the scope for refining and differentiation in mine planning standards, and incorporating geological and plant parameters into mine scheduling. This will improve planning and scheduling and the overall performance of the mine. Given our current level of scientific knowledge and the technological tools at our disposal we should be able to plan and schedule production so that we can manage pro-actively and improve business performance. In doing so we can also improve reconciliation and value tracking through mining and processing •The flexibility and functionality of the XPAC planning and scheduling tool that will enable a throughput management approach.

Jan 1, 2003

By D. Lunt

This paper describes and sets in context the commercially proven uranium extraction processes. It also discusses some of the technologies that are currently being pursued with the aim of reducing costs and overcoming a number of technical issues that are faced by process designers and operators. In doing so, opportunities for the transfer of extraction technology from other industries/commodities are identified. The key processing areas that are examined include: ?The influence of mineralogy. The type of uranium mineralization and the nature of its association within a particular deposit will have a major impact on process route selection. Uranium minerals are classified according to their influence on extractive metallurgy. As the uranium price has risen in recent times, so opportunities are increasing for the recovery of uranium from less conventional resources such as phosphates and fossil fuels. ?The opportunities for employing techniques aimed at reducing the capital and operating costs of the overall process such as heap leach and beneficiation. Preconcentration by screening, gravity separation and radiometric sorting can potentially reduce the mass flow to the downstream leach and recovery plants. ?Purification or separation of uranium in carbonate systems. While it is possible to directly precipitate uranium from clarified leachate, the presence of impurities such as vanadium, molybdenum and others may dictate that ion exchange or selective precipitation is employed. Advances have been made in other industries in terms of improved ion exchange equipment aimed at reducing resin inventories and hence costs. ?Separation in acid leach systems. Earlier developments included the use of combined SX-IX systems (Eluex or Bufflex) and the introduction of continuous countercurrention exchange (CCIX). Column SX has found a ready application to uranium in view of the rapid extraction kinetics. With the renewed interest in uranium processing, efforts are being redirected towards further development of resin-in-pulp (RIP) as a means of driving down capital and operating costs. ?Extraction in a chloride environment. Australia and Namibia are desert countries where good quality water comes at a cost. However, both have access to saline water from either the ocean or subterranean aquifers. The issues associated with operating a uranium extraction operation in such environments is discussed. ?Extraction from less conventional sources. Recent price increases for U3O8 have resulted in a number of companies examining the recovery of uranium from sources such as fossil fuels and phosphate deposits. Both of these areas were examined in the 1970s and 1980s and a number of approaches were commercialized. The paper reviews the extraction options.

Jan 1, 2007