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By D. J. Bauer

Liquid-liquid extraction techniques were investigated by the Federal Bureau of Mines for the fractionation of rare-earth solutions. Separatory funnel work using tri-n-butyl phosphate (TBP) for extracting ceric nitrate from solutions containing sulfate ion resulted in almost complete extraction. Similar tests using primary amines for splitting trivalent rare-earth pairs and fractions gave promising results. The ceric nitrate extraction procedure was scaled-up by use of pressure-bubbler equipment, a series of spray towers for extraction, washing, and stripping. In this case only 84 percent ceric nitrate extraction efficiency was achieved. This work was done using dilute sulfuric acid for stripping.

Jan 1, 1960

By J. E. Chilton

Regular monitoring for methane gas is required near working faces in gassy underground mines where the potential for methane ignitions is greatest. However, high concentrations of methane can also accumulate outby the face where methane levels are monitored less frequently. Wearing a personal methane monitor equipped with an alarm could protect persons working in these outby areas from injury or death due to methane ignitions. The National Institute for Occupational Safety and Health (NIOSH) has conducted studies to evaluate methanometers that could be used as person-wearable monitors. For the present study, seven different person-wearable monitors that are not currently approved for underground use were evaluated. This paper describes test procedures used to evaluate performance of methane monitors that could be used underground for continuous personal monitoring of methane. The information in this report provides data that allows the reader to make side-by side comparisons of these instruments.

By R. V. Ramani, V. T. Burgos, J. A. McClay

Cost Data Library The data retained in the Cost Data Library is of a semi¬permanent nature in that it is held in storage for immediate use with the program although its contents may require periodic evaluation to maintain it in a current status. The library is composed of six arrays containing both technical and cost data. The following description of the library input system provides the information necessary to maintain an active storage file. Array POWERA: FORMAT (8F10.0) - contains the step groupings of the power rate schedule for power cost computations. Four input data cards are required to fill this storage area. Card Column 1 1 - 10 Demand in Kilowatts for the First Step of the Demand Rate Schedule 11 - 20 Demand in Kilowatts for the Second Step of the Demand Rate Schedule y 41 - 50 Demand in Kilowatts for Fifth Step of the Demand Rate Schedule 51 - 60 Maximum Demand Level for this Rate Schedule 61 - 70 Percent Power Factor for this Rate Schedule 71 - 80 Unassigned 2 1 - 10 First Step Demand Charge, $/Kw 11 - 20 Second Step Demand Charge, $/Kw 4¬ 41 - 50 Fifth Step Demand Charge, $/Kw

Jan 1, 1975

By N. H. Snyder

Coal analyses help to describe the character of coal as it lies in the ground of as it may he delivered to the user Analyses of samples of coal collected from the face of the bed in mines are plentiful, but available analyses of delivered coal are relatively few, and there is a distinct difference between "mine samples" and "delivered samples.” Mine samples are collected actor drag to a standard method. 13 The sampler cuts a channel. 2 by 6 or 3 by 4 inches from roof to, floor in the face of the bed, and excludes from the sample all partings more than 3/8 inch thick, and any lenses or concretions of sulphur or other impurities more than 2 inches in maximum diameter and 2 inch thick. Analyses of mine samples form a permanent and scientific record of the coal bed at the point sampled, they ale important in determining the character of the coal in any given mine or district These analyses, when the samples are taken by a standard method, are valuable to the operator When compared with analyses of delivered coal they show him whether his mine is being worked efficiently or whether the coal is being properly prepared, which involves the ques¬tion ii Nether he has suitable mechanical appliances for separating the impurities sties. In the purchase of coal, mine samples may serve as a sufficient guide for the experienced buyer who has knowledge of the impurities in the bed, and the degree to which these are eliminated in mining and preparing the coal To the average purchaser, however, unacquainted with these details, dependence on mine samples may be misleading The quality of coal indicated by the base samples call rarely, if ever, be attained in the delivered coal Certain impurities that are eliminated from the formally prepared mine sample may not be eliminated by the miner Some of the roof and floor may also be included if these are soft or flaky When coal prices are high and competition is lessened it is easy for the miner and the management to lower the standards of preparation, and a return to rigid stand¬ards is always difficult. In sampling delivered coal the Bureau of Mines follows a definite procedure. 14 A sample of not leas than 1000 pounds is systematically

Jan 1, 1928

By Ted C. Briggs

A removable-jacket distortion apparatus was constructed and used to measure distortion coefficients for two high-pressure vessels. The measured distortion coefficients were used to compute distortion coefficients for volumes VI and (V1+V2) of a 1,000-atmosphere Burnett compressibility apparatus for the temperature range 0° to 75° C. Young?s modulus for Armco 17-4 PH stainless steel, heat treated to condition H1150-M, was computed from experimentally determined distortion coefficients. A 10-to 14-percent correction to the values obtained for Young's modulus may be required because pressure vessel end effects were neglected. The distortion coefficients of the compressibility apparatus are believed to be accurate to about 1 percent.

Jan 1, 1970

By Arnulf P. Hagen

This project was designed to explore the suitability of using fluorinated inorganic materials as solvents for the in situ mining of thin seamed, heavily overburdened coal; to build a data base for the selection of an inorganic solvent for use for coal cleaning; to determine if fluorinated solvents will reduce the organic and inorganic sulfur contents of the coal, as well as to lower the ash content. The coal samples have been combined with pure solvent, as well as with aqueous solutions at atmospheric pressure and at increased pressure. The increased pressure experiments are important since they duplicate the conditions anticipated for an in situ cleaning and mining operation. Trifluoroacetic, difluorphosphoric (phosphorodifluoroidic), and trifluoromethanesulfonic acids have been found to be effective for the cleaning of high sulfur, high ash coal at 300°C and at atmospheric pressure. At pressures up to 20,000 psi the effectiveness of these reagents is not decreased.

Jan 1, 1983

By H. E. Sanford

"INTRODUCTION Of the occupations in and about coal mines, those of the haulage crews are among the most hazardous. Statistics indicate that the second largest number of fatalities about coal mines occurs during haulage operations and through the use or misuse of haulage equipment. Despite the fact that relatively few coal-mine employees are engaged continuously at haulage operations, approximately 20 percent of all coal-mine fatalities are attributable to haulage.Most of the hazards in haulage operations could be very greatly reduced if more serious consideration were given to the problems of the haulage crews and if sincere efforts were made to reduce the hazards. Underground haulage is similar in many respects to railroading; yet, railroading is now considered one of the safest of occupations a distinction that has been attained only by honest effort and whole-hearted cooperation on the part of all concerned. Underground haulage is also similar to street and highway operation and has in it some of the difficulties encountered in the reduction of traffic accidents the seriousness of which has not by any means been con¬trolled as yet, notwithstanding the fact that much effort has been expended through a multiplicity of laws, ordinance regulation, etc., as well as by thousands of enforcement agencies and officers.The men working on the locomotives are among the most important members of a coal-mine organization; without skilled haulage employees, the production of coal would be greatly retarded. Their jobs, particularly the job as brakeman, require physical endurance, agility, and mental and physical alertness; in thin coal beds, especially where the roof is not brushed and the coal is loaded into mine cars by hand, the need for these qualifications is greatly increased."

May 1, 1948

By E. D. Gardener, Byron O. Pichard

"Methane, frequently called fire damp or marsh gas, is very well known to coal miners but to thy average gold miner it means nothing, as it is not associated generally with the rock formations in which gold is found.We have recently been conducting a study of mine air in typical gold mines on the Pacific Coast, and out of five California mines in which the air was sampled, three showed methane. Each of these three mines, referred to below as mines A, B, and C, have had accumulations great enough to be ignited. An authentic report from another California, gold mine, which has not yet been sampled, states that recently the superintendent was seriously burned by the ignition of a pocket of gas. This mine is later mentioned as mine D.Mine A is an old mine which had been abandoned for several years and permitted to fill with water. It has been unwaterad recently, and is now being developed at greater depths. During the unwatering, gas bubbles formed on the water and upon being ignited burned freely. It is reported that two men were seriously burned from accidentally igniting the gas. Samples of the bubbles on analysis showed high percentages of methane. Since the mine has been unwatered, no trouble has been experienced through gas being ignited. However, out of a total of six air samples which we took recently in scattered working places, all showed small amounts of methane, the methane content being 0.06, 0.04, 0.05, 0.04, 0.04 and 0.07 per cent, respectively. When these samples were taken methane was not suspected, but its general presence in the mine air indicates that it is being given off constantly."

Dec 1, 1921

Develop a method to evaluate the effectiveness of coal scam fire surface seals so that potential problems may be corrected at an early stage, before the integrity of the surface seal is lost. Background Surface seals are the primary coal seam fire abatement method being used in the western United States. Surface seals smother a fire by denying it oxygen. The seal is usually constructed by placing a mantle of soil, four to ton feet thick, over a coal scam fire area to exclude air from the fire. The soil is compacted to increase effectiveness, and a soil cement may be used to augment the soil. In some cases, burning coal may be excavated and separately smothered or otherwise extinguished in another area; in other cases, a trench maybe excavated and backfilled with incombustible material to isolate a fire. More often, a surface seal is simply applied over and around the entire known burning area. In the 1950's, the Bureau of Mines administered a large program to treat numerous coal seam Fires across the western United States. Methods used in this program were described in Bureau of Mines Information Circular (IC) 7932, dated 1959. More recently however, various coal seam fires have been treated with surface seals under the direction of state Abandoned Mine Land Reclamation authorities. It has frequently taken years to evaluate the effectiveness of surface seals. By the time problems become evident, it has often been too late to take corrective action within the scope of the original abatement project. For this reason, the Bureau of Mines developed a means for tracking temperature trends at coal seam fire projects to obtain a better and earlier handle on the effectiveness of surface seals.

Jan 1, 1991

By R. V. Ramani, A. S. C. Owili-eger

The Federal Coal Mine Health and Safety Act of 1969 (sec. 303 (b)) stipulates that no working section of the mine shall contain more than 0.5 percent carbon dioxide and no harmful quantities of other noxious or poisonous gases such as the oxides of nitrogen. The concentration of methane should at all times be maintained below one percent. A split of air returning from any working section shall contain no more than 1.5 percent of methane (sec. 303 (i) (2)) and air that has passed by an opening of any abandoned area shall not be used to ventilate any working place in the coal mine if such air contains more than 0.25 percent of methane (sec. 303 (j)). Methane concentration in the returns from the bleeder entries should not exceed 2.0 percent (sec. 303 (i) (3)), and no air that has passed through an opening which is inaccessible for examination shall be used to ventilate any active areas. While the air quantity requirements alone can easily be met, the governing condition in most mines is the dilution requirements for quality control. A sufficient quantity of air is required to render harmless and carry away noxious and respirable pollutants. In recent years, changes in coal extraction methods, rates of advance, location of available reserves, position of prominent methane sources and horizons, and geological sequences have contributed sig¬nificantly to alterations in rates, patterns and character of numerous methane emissions. Gas production of 10 to 15 million standard cubic feet per day is not uncommon from deep mines (Cervik, 1969). Thus, because of the large capital outlay involved in the instal¬lation and subsequent remedial actions of methane drainage systems, knowledge of gaseous flow patterns and storage characteristics of the

Jan 1, 1974

Only limited work has been reported in the literature about the use of latex in soil. Unisol 91 2,3 (a 9:l oil-latex emulsion made b International Synthetic Rubber Company) and Phil1ips Petroset4 geotechnic emulsions are surface soil stabilizers which penetrate a maximum of two inches, but do not reduce permeability. Diamond Alkali 5 found that styrene-butadiene rubber latex as a one percent latex-soil mixture reduced permeability to 0.7 from 21 feet per year under a head of twenty feet of brine. We have found no literature reference for use of latex as sealant at depth in the soil, although asphalt has been applied at depth using civil engineering methods6,7. Most of the materials investigated as soil sealants in the present work were latexes, although some studies were also conducted with a variety of inorganic and organic chemicals. Of the latexes tested, most were rubber but a few were plastic, e.g. polyvinyl chloride. Sealants examined in this investigation are listed individually in Table I with supplier, code number, and other pertinent information. The materials consisted of the following general classes with additional details as indicated: 1.Anionic latexes: a. styrene-butadiene copolymers and terpolymers (SBR) b. butadiene-acrylonitrile copolymer (Paracrils®) c. polyvinyl chloride homopolymers and copolymers (WC) d. ethylene-propylene terpolymer e. vinyl acetate homopolymers and copolymers (VA) f. acrylics (acrylate copolymers) g. 2-chlorobutadiene homopolymer (chloroprene) (prepared specially as cationic material coagulated by soil). 2. Water Soluble polymers: a. polyvinyl ether b. methylcellulose c. polyethyleneimines d. polyacrylic acid homopolymer e. copolymers and terpolymers with acrylic acid types (water soluble as sodium or ammonium salts) f. alginates g. monomers (for polymerization in soil, e.g. acrylamide)

Jan 1, 1972

By R. A. Keaens, L. C. IlsLey

For the purpose of this paper a junction box is defined as " a fused switch, inclosed in an explosion-proof compartment, provided with a ready means of connecting or disconnecting a trailing cable without exterior arcing." Junction boxes are intended for use 'at the end of trailing cables and are usually placed outby the last open break through in a coal mine. Where it is not safe to supply current through nips or a trolley, junction boxes suitably spaced along an entry permit tramming and movement of machines with safety, although not with any considerable speed. Junction boxes serve a threefold purpose: (1) They prevent dangerous arcing at the outby end of trailing cables; (2) they afford a safe, practical means of fusing or otherwise protecting the trailing cable; and (3) they provide an efficient means of transmitting power from the power circuit to the trailing cable. The first purpose is the most important from a safety standpoint. Dangerous arcing-that is, arcing capable of igniting gas-frequently takes place where trailing cab1c.s are attached to the power circuit. At either 250 or 500 volts only a very small arc is required to ignite mine gas. The usual method of connecting the trailing cable to the power circuit by cable nips or trolley taps does not make a good electrical connection; hence arcing may be expected at any time. Furthermore, junction boxes eliminate the personal hazard attendant upon the use of trolley taps by removing the possibility of accidental contact with trolley hooks or wire and the liability to injury due to manipulation of the device. In the general scheme of mine ventilation it is assumed that gas will not accumulate where junction boxes are placed, an assumption based on the normal operation of the ventilating system. In many

Jan 1, 1929

By R. E. Mussler

As part of an overall goal to develop technology that can maintain an adequate supply of minerals to meet national economic and strategic needs, the Bureau of Mines is evaluating a method for selectively extracting nickel and cobalt from low-grade domestic laterites. The method involves electrowinning to recover the metals in pure form; therefore, preliminary laboratory-scale electrowinning tests were conducted in both a nondiaphragm and a diaphragm cell to determine the effect of variables on energy efficiency under controlled conditions. Electrolytes were generally reagent-grade sulfate solutions that were prepared to simulate electrolyte that could be obtained by stripping nickel-and cobalt-rich solvent extraction reagents. Limited tests were conducted with electrolyte generated from laterite leach solutions. Electrical energy consumption in a nondiaphragm cell was 2.06 kwhr/lb Ni with the cell operated at 50° C, a cell feed of 90 g/l Ni, a pH of 3.5, an extraction of 3.2 g/l, and a cathode current density of 20 amp/ft2. The energy requirement decreased with increasing concentration and temperature, and increased with increasing. extraction and current density. At 50° C, energy consumption in the nondiaphragm cell was 21 pct greater than in the diaphragm cell, but it was only 5 pet greater at 65° C. For this reason and because of overall cost considerations, operation at 65° C with the nondiaphragm cell was preferred. Smooth sheets of cobalt were obtained by electrowinning in a nondiaphragm cell at selected temperatures from 50° to 85° C and with cobalt concentrations from 55 to 87 g/l. The energy consumption (1.48 kwhr/lb) was 22 pet lower with a cobalt concentration of 75 g/l and a cell temperature of 65° C than with a cobalt concentration of 55 g/l and a cell temperature of 50° C.

Jan 1, 1981

By W. N. Poundstone, W. M. Merritts, B. A. Light

A joint investigation by the Bureau of Mines and the Christopher Coal Co. at the Humphrey No. 7 mine, operating in the Pittsburgh coalbed in northern West Virginia, was undertaken to gain more insight concerning the hazardous emission of methane gas in mining. This report describes the equipment, procedure, and results. Horizontal bleeder holes drilled in the faces drained large quantities of methane, eliminating downtime of mining equipment. Also, larger quantities of methane were removed by forcing 14 to 25 g,.p.m. water at 25 to 200 p.s.i. 5 pressure into the bleeder holes. In one infusion test a fluorescein dye was added to the infusion water; in later mining operations, the infusion water was traced for a distance of 1,500 feet. With vacuum pump applied to the horizontal hole the gas-flow rate increased, and the methane content decreased. Tests indicated that methane and water infused in bleeder holes traveled along the bedding planes of the Pittsburgh coalbed at a faster rate than across the planes. Methane associated with coalbeds is produced by the slow decomposition of carbonaceous material in the absence of air and the presence of water. It is lighter than air and, depending on its concentration, forms an inflammable or explosive mixture with air. It is believed that methane is entrapped in and around the pores of the coal and adjacent strata--often under great pressure. In many cases where the strata have been disturbed by geologic movements the

Jan 1, 1962

By Kenneth L. Cashdollar

This paper is an overview of and introduction to the subject of dust explosions. The purpose is to provide information on the explosibility and ignitability properties of dust clouds that can be used to improve safety in industries that generate, process, use, or transport combustible dusts. The requirements for a dust explosion are: a combustible dust, dispersed in air, a concentration above the flammable limit, the presence of a sufficiently energetic ignition source, and some confinement. An explosion of a fuel in air involves the rapid oxidation of combustible material, leading to a rapid increase in temperature and pressure. The violence of an explosion is related to the rate of energy release due to chemical reactions relative to the degree of confinement and heat losses. The combustion properties of a dust depend on its chemical and physical characteristics, especially its particle size distribution. In this paper, the explosion characteristics of combustible dusts will be compared and contrasted with those of flammable gases using methane as an example. These characteristics include minimum explosible concentration, maximum explosion pressure, maximum rate of pressure rise, limiting oxygen concentration, ignition temperature, and amount of inert dust necessary to prevent flame propagation. The parameters considered include the effects of dust volatility, dust particle size, turbulence, initial pressure, initial temperature, and oxygen concentration. Both carbonaceous and metal dusts will be used as examples. The goal of this research is to better understand the fundamental aspects of dust explosions.

By Richard A. Thomas, Charles D. Litton, Kenneth E. Mura, Harry C. Verakis

Experiments were undertaken to evaluate the flammability of typical noise abatement materials used to line the cab interior of mobile mining equipment. The experiments were conducted using three different experimental configurations: 1. A ventilated tunnel test. 2. A full-size cab test where the interior surfaces were lined with the sample material and then ignited near the floor using a methane-air burner. 3. Standard ASTM E-162 tests using a radiant panel test apparatus. This paper describes the tests and presents the results obtained for 15 to 20 different materials of various chemical compositions and thickness. With one exception, materials that did not exhibit flame spread in the tunnel test also performed well in the full-scale cab test. All materials that had passed only a small-scale flammability test, such as SAE J369, failed dramatically in all three of the above test configurations. With one exception, all materials that performed well in the full-scale cab test had flame spread indices < 25, based upon the ASTM E-162 results. The lone exception had an ASTM E-162 flame spread index of 68. With regard to samples that failed the full-scale cab test, the carbon monoxide levels within the cab reached lethal concentrations in the range of 1.8% to 3.8% within 2 minutes from ignition of the sample—dramatically illustrating the severe fire environment that can result within the cab space.

Improve underground mine roof bolt support systems by alleviating problems associated with certain ground support systems currently being used. Approach Convert a passive resin-grouted roof bolt system into a uniform, tensionable roof bolting system. Background Resin-grouted roof bolts are one of the most common forms of ground support in U.S. underground coal mines. These support systems can be installed with a full-column of grout and be loaded with subsequent roof movements after installation. This is called a "passive" support system. An alternative to the passive support system is the mechanically-anchored, tensioned roof bolt system. This system is installed with resin grout. This system is designed to load or tension the support during installation by using a mechanical anchor, coupling, or threaded nut after the resin has properly cured. It is called an "active" support system and is used extensively for improved strata control in a laminated geologic deposition or in difficult ground conditions. To ensure that active bolts have been properly installed, the bolt loads must be checked by using a torque wrench or other suitable equipment. Unfortunately, this practice presents potential safety hazards and has limited accuracy. Laboratory and field experiments also reveal that the torque-to-tension ratio developed on active support systems can vary by 50% from bolt-to-bolt. Variations in bolt load installations can induce stress concentrations and lead to roof degradation or failure.

Jan 1, 1991

Enhance coal mine worker safety and productivity by developing a means to control and predict coal mine mountain bumps. Approach The Bureau of Mines has been engaged in extensive research to understand coal mine mountain bumps and their effect on underground coal mining in the United States. Information was collected on the geologic conditions, mining techniques, and engineering parameters at five mountain-bump-prone mines. Although research has not yet evolved to the point where mountain bumps can be effectively predicted or controlled, such studies are invaluable for providing clues that can lead to the development of mountain bump mitigation technology. Case Study Results and Recommendations Mountain bumps in coal mines are explosions of the coalbed that violently release the strain energy stored within it into openings created by mining. Such an event is not only dangerous to mine workers, but can cause substantial amounts of damage to mine equipment, resulting in productivity loss and downtime. In a coal mine, the occurrence may cause coal to be expelled violently from the coal face or coal pillars or cause the mine floor to heave suddenly. Coal bumps are usually accompanied by a very loud noise and tremors or vibrations. Such ground failure:; usually occur in the vicinity of an active gob line in an active retreating room-and-pillar panel, or at or near the face in an advancing or retreating longwall mining panel.

Jan 1, 1989

Control dust generated during undercutting in salt mines without causing ore-solubility problems that result from excessive water use. Approach A foam generator was developed to provide a reliable foam to control dust on cutting machines used in mining water-soluble ores. The system was designed to keep total foaming agent/water mixture flowrates below the flow-rates characteristic of water-only systems. The foam generator consists of a reservoir to hold the premixed agent and water, a metering pump, and a small compressor to aerate the mixture. The system is compatible with all cutting machines. How It Works One of the current wet-bar techniques, the through-the-bar trickle system, pumps water through a pipe in the cut-ting bar to its tip placing the water behind the kerf. If the pipe conducted foam effectively the foam would be released in the kerf where it would mix with the cuttings and the dust produced by the chain. For improved foam delivery, however, it is recommended that the pipe be replaced with an external channel welded along the top of the bar. This provides excellent dust control while avoiding the accumulation of copious quantities of foam in the heading. The system is very simple. The foam generator is a 50-gallon tank filled with a mixture of water and foaming agent. The mixture is pumped through a wye fitting to a second line where it is mixed with compressed air, (300

Jan 1, 1984

By Neil B. Young

Analytical results for nahcolite, dawsonite, total extractable alumina, and oil yield are presented for samples representing Green River Formation oil shales in the saline section of two cores from Colorado&apos;s Piceance Creek basin. Analyses are also reported for samples extending the analyzed section of Colorado corehole No. 3 beyond that reported previously. These data permit evaluation of the deposit for possible production of three coproducts--shale oil, alumina, and sodium carbonates--from the saline section of the formation at these sampled points.

Jan 1, 1970