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By Charles L. Kimbell

In overview, 1988 appeared to be the best year for the world's mineral industry since 1980, although the all-important petroleum component suffered severely from low prices. With this notable exception, the traditional statistical measures of mineral industry performance, namely production, trade, and consumption, reflected growth in most elements of the world mineral industry from crude material extraction through the gamut of downstream processing. Moreover, the growth was reasonably well distributed geographically, with many countries sharing in the substantial upturn in activity. World crude mineral output value was estimated at over $1,272 billion in current dollars ($1,090 billion in constant 1983 dollars). The value added by the processing component of the mineral industry raised the total value of the industry's output to an estimated $3,057 billion in current dollars ($2,620 billion in constant 1983 dollars). Less easily assessed was the value of mineral commodities moving in 1988's international world trade, particularly because of the declines in world crude oil and refinery product prices. It remained to be seen if increased volume and value in nonfuel mineral and coal exports, coupled with an increase in the volume of oil exports, would be adequate to offset the drop in oil prices. Whether or not the value of world mineral commodity trade topped the 1987 level of over $498 billion, an increase in the volume of mineral commodity trade was almost assured. Similarly, although comprehensive statistics were not avail-able on consumption of all mineral commodities in all countries, available data on selected major commodities in selected major countries suggested that not only had output of most mineral commodities advanced, but so too had consumption levels for most commodities.

Jan 1, 1990

By H. H. Schrenk

There is a need for a method of determining benzene vapor in air which is simple and accurate and suitable for making industrial hygiene surveys. The most widely used method in this country is the Smyth modification of the Elliott and Dalton procedure. This depends on the nitration of the benzene to m-dinitrobenzene, reduction to phenylenediamine with an excess of standard titanous chloride solution, and back titration with a standard ferric ammonium sulphate solution. This method has the disadvantages of being somewhat time-consuming and cumbersome; it requires considerable apparatus, and a special modification is necessary in the presence of toluene. Recently Cook and Ficklen have published a method based on the oxidation of benzene with hydrogen peroxide in the presence of iron salts. This method requires the use of solid carbon dioxide to freeze out the benzene. The reaction Which produces the color is complex; and only approximate quantitative estimations can be made, except in a very narrow range.

Jan 1, 1935

By J. A. Herdlick

Under authority of the Strategic Materials Act of June 1939, the Federal Bureau of Mines, in cooperation with the Geological Survey, began a broad program of investigation of the strategically important chromite deposits in Sweetgrass, Stillwater, and Carbon Counties, Mont. Extensive occurrences of chromite along the Stillwater Complex in Stillwater County were investigated. The two principal deposits, The Mouat-Sampson and Benbow mines, ultimately were developed and placed in production by the Federal Government. As a part of this general development program, the Carbon County chromite deposits near Red Lodge were examined by Bureau of Mines engineers in 1940, and by the Geological Survey .1-1 1942. The district was examined earlier by Schafer, and the Four Chromes area is mentioned briefly by Westgate. Although the Red Ledge deposits were considered to be of minor importance as compared to those of the Stillwater Complex, several of the ore bodies were adaptable to open-pit mining' methods, and one large deposit on Line Creek Plateau was readily accessible to the Red Lodge-Cooke highway. In 1941, the U. 3. Vanadium Corp. began mining crude lump-chrome ore from the deposit on Line Creek Plateau to supplement national stockpiles, which were being depleted by the rearmament program and the disruption of chrome-ore imports by the European war. Access roads gore constricted to Hellroaring Plateau, and the mining operations were extended to that area. A gravity concentrator with a capacity of 200 tons per day was built and operated at Red Lodge to beneficiate lower-grade ore from the district.

Jan 1, 1948

By F. R. Cattoir

The Federal Bureau of Mines refined chromium from an aqueous electrolytic process in molten sodium chloride-chromium chloride electrolytes. Oxygen and nitrogen contents were reduced by a factor of 10 to 40, but most other impurities were little changed. The product usually contained a little more iron than the feed. Since iron was entering the bath from the iron pot and the graphite liner at a nearly constant rate, contamination of the chromium deposits by it was more serious at low currents and deposition rates. A few runs in an iron cell with a nickel liner yielded chromium containing one half as much iron as the feed, but up to 1.5 pct. nickel. In all cases the anode feed lay in the bottom of the container, which itself was used as the anode connection. With a 12-in. cell, variations in applied voltage from 0.05 to 1.5, in current from less than 10 to over 100 a., and in initial cathode current densities from less than 100 to over 2,000 a./sq.ft. had little or no effect upon the analysis of the metal produced) except for iron content. Changes in bath analysis from 3 to 11 pct. chromium were also without effect. These changes did bring about large differences in the physical forms of the crystals obtained. The thick heavy crystals produced at low voltage and current contained voids which made them difficult to leach free of chlorides. Easiest to leach were the thin leaf-like crystals obtained at around 1 v.

Jan 1, 1960

By Alan A. Bergeron, J. L. Michels, R. L. Collins

Advanced communication and monitoring systems were developed and demonstrated in three underground mines representing different mining techniques, geographical areas, and material mined. The first mine was a large coal mine in western Pennsylvania that used room and pillar techniques and continuous mining methods. The system developed for this mine provided private telephone channels, environmental monitoring, and control of underground equipment, all on a single coaxial cable, with all system operations under the direction of a minicomputer. Many advanced features were incorporated into the system, such as paging of roving personnel, two-way section wireless, through-the-earth emergency communication, and redundant signal paths. Television was multiplexed into the system for underground equipment surveillance. A hoist radio system completed the complement of equipment at the mine. The second mine was a magnetite ore mine in eastern Pennsylvania that used block caving mining techniques. A radio system was developed that provided two-way communications between trackless vehicles and roving personnel. A unique system of uhf/vhf repeaters combined with a flleaky-feeder" transmission line offered operational and emergency features not previously found in mine communication systems. Evacuation alarming, personnel paging, fan-hole drill operator communications, and maintenance and safety vehicle dispatch were provided. The system required no dispatcher and operated during power failure. A hoist communications/shaft inspection system completed the installation. The third mine was a deep silver mine in the Cour d’Alene district of Idaho. The system developed for this mine utilizes a single wire pair to provide up to 14 voice channels. A unique combination of PBX, telephone carrier system, and intercoms offered private conversations, selective signaling, and emergency backup communications. Two hoist communication systems were installed to provide a voice link and in-cage belling signal between hoistman and cage.

Jan 11, 1981

By J. A. Organiscak

The U.S. Bureau of Mines investigated the relationship of bituminous coal seam parameters and the amount of airborne respirable dust generated at longwalls. Dust and coal samples were obtained from 20 longwalls operating in geographically representative coalfields throughout the United States. Statistical analyses of coal seam parameters and airborne respirable dust measurements indicate a likely causal relationship between seam type and respirable dust. Low-ash, high-volatile coal seams were associated with higher airborne respirable dust levels. A negative linear correlation (significant at the 95-pct confidence level) was observed between the seam's ash content and airborne respirable dust, explaining up to 18 pct (R2 = 0.18) of headgate dust level variation and up to 15 pct of tailgate dust level variation. Volatile matter was found to have a positive linear correlation with tailgate dust level, explaining 16 pct of the variation. Further data examination indicates that these relationships with dust are most likely nonlinear, because of improved R2 values over the linear correlations. However, a notable portion of longwall dust production is influenced by other operational parameters, so additional research under more controlled conditions is needed to determine the seam's causative functions.

Jan 1, 2010

By [F. P. ] Stambaugh

Results of research on the hydrothermal precipitation of zirconium oxide from the Bureau of Mines' zirconyl chloride-sulfate strip liquors indicate that nuclear grade material can be prepared by this process. Greater than 99% of the zirconium value can be precipitated at 250-260°C in short (5-10 minutes) reaction time without consumption of acid value of the liquor. Thus, precipitation of zirconium dioxide on a continuous basis, i.e., the zirconium dioxide is precipitated in a continuous mode of operation by pumping the strip liquor through a heated pressurized reactor and recycle of the acidic (spent) liquor to the process stage are favored. The results of accompanying studies of liquod/solid separation, product washing and dewatering, product purity, and chlorination of the product are presented and discussed.

Jan 1, 1980

By G. M. Potter

During investigation of the occurrence of manganese deposits in the western United States, the Bureau of Mines collected 2-ton samples of 4 ores from 3 properties in northeastern Nevada. Laboratory tests were made to determine the amenability of these ores to ore-dressing methods of concentration. The Caviglia-Vietti property is situated 11 miles southeast of Ely, White Pine County, Nev. The ore deposits are lenticular veins and irregular masses found in limestone fracture zones and along the contact of limestone and underlying shale. Two samples, of the ore were tested: Lot A, from the Vietti shaft, and lot B, from the. Caviglia shaft.

Jan 1, 1954

By William J. Campbell

One of the principal objectives of the Bureau of Mines program for developing super refractory materials is to obtain fundamental data on the physical properties of refractory oxides. This particular investigation obtained accurate thermal expansion coefficients for alpha alumina and evaluated, critically, those coefficients with other published values. High-temperature X-ray diffractometer measurements, by the Bureau, showed that alpha alumina expands anisotropically with expansion parallel to the c axis approximately 10 percent greater than parallel to the a axis. Thermal expansion characteristics of four different alumina samples were determined up to 1,200° C.; the results are presented in both tabular and graphical form. The combined random and systematic errors in the measurements are considered less than 3 percent above 500° C, and approximately 2 percent at 1,000° C. No differences in expansion were observed between the samples or between the heating or cooling cycles.

Jan 1, 1961

By J. S. Dunning

The objective of this research by the U.S. Bureau of Mines was to determine the effects of AI additions on the sulfidation resistance of Fe-Cr-Ni alloys. A series of Fe-Cr-Ni alloys with and without -additions of 4 pet AI were tested in a wet S vapor atmosphere at 677 C. A study of the morphology and composition of corrosion scales indicated a different corrosion mechanism for AI-free alloys compared with AI-containing alloys. Aluminum-containing alloys formed a compact, tightly adherent layer at the metal-scale interface that reduced corrosion rates by a factor of 3 to 10 compared with that of AI-free alloys. The thin, adherent AI-containing scale limited inward diffusion of 0 and S to the base metal and outward diffusion of Ni from the base metal. Aluminum-containing alloys formed a three-layer scale in oxidizing-S environments, while AI-free alloys formed a less protective two-layer scale.

Jan 1, 1989

By W. R. Gilliland, G. W. Jones

"One-phase of the accident prevention program of the Bureau of Mines is the determination of the explosion hazards of various combustible gases and vapors encountered,mining and allied industries and the development of means and methods of eliminating them.Gasoline is foremost among the combustible-liquid's as to quantity used and variety of applications in industry, It is a chief contributor to the causes of fires and explosions, taking an enormous yearly toll in property damage and considerable loss of lives.The results presented in this report evaluate the effect of various gaseous inert substances, which owing to their chemical composition, should be of considerable value in the prevention of gasoline fires and explosions. The substances investigated are as follows: Nitrogen (N2), automobile exhaust gas (85 percent N2 + 15 percent CO2), carbon dioxide(CO2), dichlorodifluoromethane (CCl2F2-Freon-12), trichloremenofluoromethane (CC13F-Freon-11), and dichloromonofluoromethane (CHCl2F-Freon-21).The general term ""gasoline"" designates a combustible liquid of such characteristics as to give satisfactory operation without preheating in spark-ignition-type internal-combustion engine. It comprises a complex hydrocarbon mixture having a limiting distillation range and produced commercially by distilling or ""cracking"" crude petroleum or other various petroleum stocks. Small proportions of other substances may be incorporated in the gasoline to enhance its antiknock properties or operating characteristics in internal-combustion engines and to increase its stability during storage, transportation, and use.It is thus seen that gasoline may have rather wide variations of chemical and physical properties, and it would: appear that the results of any investigation dealing with one particular gasoline might not be applicable to other types. However, as indicated by the results given in this report, the inflammable properties of different gasolines at normal atmospheric temperatures are influenced largely the mars volatile hydrocarbons containing 5, 6, 7 carbon atoms- in the molecule, and that the heavier constituent of higher molecular weight have a minor influence on the inflammable properties at ordinary temperatures."

Apr 1, 1946

By Doyle A. Ellerbruch

An FM-CW microwave system was investigated for measuring coal layer thickness. Measurements were made in three different mines near Pittsburgh, Pennsylvania, near Fairview, West Virginia, and near Coffeen, Illinois. Microwave frequencies in the range 1-2 GHz were used to measure samples up to 55 cm thick. All samples were backed with a naturally occurring shale. Measurements were also made on coal and shale samples compounded in the laboratory at the Bureau of Mines Pittsburgh Mining and Safety Research Center near Bruceton, Pennsylvania. The results indicate that layer thickness can be determined in most cases, although large anomalies may, in some cases, produce misleading results. Many anomalies that were detected with the FM-CW system were verified visually by drilling into the coal layer. The dielectric constant of coal apparently varies significantly within a coal seam. The form of the output signals from the FM-CW system seem to simplify the data interpretation and analysis process as compared to the manually swept microwave system used previously. It appears that this technique has the potential of measuring changes in the dielectric constant of a coal seam and providing an output that can be used for real-time corrections in layer thickness; measurement.

Jan 1, 1976

By C. F. Jackson

This paper describing the mining practices at a mine in the Southeast Missouri district is one of a series being prepared by the Bureau of Mines on mining practices, methods, and costs in the various mining districts of the United States. The conditions, operating methods, and practice described in the following pages arc those obtaining at a property in the Southeastern Missouri lead belt, St. Francois County, Mo. This property is the eldest in the county and is a consolidation of a number of separate mines originally opened up as individual operations many years ago. Present-day operations have necessarily to be adapted to suit the older levels, stones, and pillars, and also the recovery of ore from worked over areas which was considered too low grade to mine in the earlier days constitutes a different problem than that of development and mining in virgin ground.

Jan 1, 1929

By D. W. Bridges, R. O. Dannenberg, Laird Crocker

Preliminary solvent extraction studies , reported by the Bureau of Mines (5) , have been continued and expanded to improve on the previous estimate of process requirements . The solvent extraction portion of the process was examined at a scale large enough to enable meaningful extrapolation of the results to geometrically similar equipment of plant size . About 82 pct of the beryllium was recovered from approximately 0.5 pct beryllium oxide (Be0) Spor Mountain , Utah , ore by a process involving ( 1 ) sulfuric acid leaching , ( 2 ) counter current decantation (CCD ) washing , (3 ) iron ( III) reduction by sodium hydrosulfide ( NaHS ) , ( 4 ) beryllium solvent extraction by di - 2- ethylhexyl phosphoric acid ( EHPA) , ( 5 ) caustic stripping of beryllium- bearing EHPA, (6 ) hydrolysis of sodium beryllate - caustic strip liquor , and (7 ) calcination of beryllium hydroxide (Be ( OH ) 2 ) formed in step (6 ) . The resulting beryllia assayed 98 to 99 pct Be0 and was suitable for most nonnuclear uses . Best overall results were obtained by using pH 2 , 1.6 grams of BeO per liter of leach liquor as feed and 0.25 N EHPA in kerosine containing 2 wt vol pct (grams per 100 ml of solution ) isodecanol ( IDA ) as solvent . Analysis of the data indicated that a commercial plant would achieve 95- pct overall extraction operating at 45 ° C with 20 hp per 1,000 gal of dispersion in each of seven mixer- settlers , having 290 gal per ton of ore hourly mixer capacity and 90 gal per ton of ore hourly settler capacity . At least 79 lb H2SO4 , 13 lb sodium hydroxide (NaOH ) , 3 lb NaHS , 0.25 lb kerosine , 0.07 lb polyacrylic flocculant , 0.03 lb EHPA , and 0.007 lb IDA would be required in H2SO4 leaching and subsequent processing to recover 1 lb BeO .

Jan 1, 1964

By B. C. Parks

This is the first of a series of reports on the relation between microscopic composition and chemical and physical properties of banded bituminous coals. It describes the relation between microscopic composition and behavior during thermal decomposition of a heterogeneous, high-volatile A bituminous coal from the Chilton bed in West Virginia. The standard free-swelling test was used as a simple means of studying the effect of heat on the coal. Although swelling indexes are not precise indicators of coal behavior in the coke oven and have limited value in caking investigations, they are reliable for predicting expansion of coal in a fuel bed and have practical value in the study of fuels. The swelling test also supplements other useful laboratory tests for determining the plastic and expansion properties of coal.

Jan 1, 1957

By F. H. Nehl

The U.S. Bureau of Mines investigated the selective electrowinning of Ag and Au from cyanide solutions contaminated with Cu with the goal of decreasing the amount of Cu codeposited. Decreasing Cu codeposited will reduce refinery costs. Direct current was applied to the cell in pulsed and square wave voltages at 0.070 A?h per 150 mL of solution. Times tested for each cycle ranged from 1 to 10,000 ms. Graphite, lead, and stainless steel were evaluated as electrode materials. Square wave electrowinning at 70° C gave the best separation of Ag and Au from Cu. Applying 2.5 V during the duty cycle, 0.0 V the rest of the period, a duty cycle of 10 to 30 pct, and a period of 100 to 1,000 ms gave the following results: Ag concentrations decreased from 34 to 0.1µg/mL, Au concentrations decreased from 54 to 0.2 µg/mL, and Cu concentrations remained almost constant at 560 µg/mL.

Jan 1, 2010

By J. A. Eisele

The Bureau of Mines is investigating the recovery of alumina from domestic nonbauxitic resources, including anorthosite. The United States has large reserves of anorthosite, but its aluminum content is less than 50 pct soluble in acid, unless a source of fluoride is added to the acid. A flowsheet that includes leaching with HCl and fluoride followed by crystallization of AlC13.6H20 from the pregnant liquor by HCl gas injection was designed. Approximately 90 pct of the aluminum values were recovered from the anorthosite when a ratio of 0.14 mole of fluorine per mole of aluminum was used. Sodium chloride is cocrystallized with the A1C13.6H20 but is removed by water washing of the Al203 product. A material balance is given based on results of laboratory studies of the unit operations.

Jan 1, 1983

By S. M. Shelton

The widespread occurrence of domestic manganese deposits and the shortage of ferromanganese-grade ore have been sources of much speculation and investigative effort for many years. The present emergency has intensified the search by the Bureau of Mines for methods of producing ferromanganese-grade concentrates4/ from low-grade ores.

Jan 1, 1941

By S. M. Shelton

[The widespread occurrence of domestic manganese deposits and the shortage of ferromanganese-grade ore have been sources of much speculation and investigative effort for many years. The present emergency has intensified the search by the Bureau of Mines for methods of producing ferromanganese-grade concentrates4/ from low-grade ores.]

Jan 1, 1941

By Edward Roberts

This is a progress report of an investigation by personnel of the Bureau of Mines from June to September 1951 to introduce preservative chemicals into growing timber. It also describes in detail the impregnation process, known as the collar method, developed by the United States Department of Agriculture2/ Twenty-eight trees were treated by this method, and a complete record was kept of each individual tree and of each timber cut from it. These timbers have been placed in a coal mine, and their tendency to decay is compared to that of adjacent untreated sets. Although several years will be required before final conclusions can be drawn, this report explains the appearance and encouraging results of the treated timber to date. Also included are some comparative costs of untreated timber, treated timber by the commercial pressure method, and treated timber by the collar method. INTRODUCTION In the hope of increasing the useful life of cut timber, experiments to impregnate growing trees with wood-preservative chemicals by utilizing the natural flow of sap have been carried on for centuries. None of the various methods used in these experiments has ever gained any widespread use because they have been commercially impractical.

Jan 1, 1953