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By Clarence Karr

In 1955 the Federal Bureau of Mines established a low-temperature tar laboratory at its new Appalachian Experiment Station in Morgantown, W. Va. The objective of the laboratory is to investigate the yields and chemical and physical properties of tars from low-temperature carbonization of coal, to investigate means of economically upgrading these tars, and to make available to industry and the public essential data for increasing coal utilization through the establishment of a new coal-chemical industry, based on the utilization of low-temperature tars. Because of the obvious economic significance of phenols, as well as the relative ease with which they can be separated and analyzed, initial research has centered mainly around this class of tar constituents. It was realized early that no listing of phenols and their physical properties existed that included enough compounds to be practicable. The purpose of this paper is to make such a compilation available.

Jan 1, 1957

By The Staff, Explosives Research Center

The principal activities of the Bureau of Mines Explosives Research Center from July 1, 1962, to June 30, 1963, are described briefly in part 1. Part 2 gives short abstracts of publications that appeared during fiscal year 1963; in general, the research reported in these publications antedates the report period.

Jun 24, 1964

By E. G. King

Many of the existing thermodynamic values for the titanium halides are estimates, including all the entropies and high-temperature heat contents of their crystalline and liquid phases. This report contains the results of low-temperature heat capacity measurents (which lead to entropy values at 298.15° K,) and high-temperature heat-content measurements of four halides - trichloride, tribromide, tetrabromide, and tetraiodide. The new data are combined with selected heat-of-formation values at 298.15° K. to obtain improved values of the heats and free energies of formation of these halides at high temperatures, thus supplementing the previous data of Kelley and Mah.5/ ACKNOWLEDGEMENTS This investigation was conducted under a cooperative arrangement between the Federal Bureau of Mines and the Department of the Navy, Office of Naval Research. The work was done by Bureau of Mines personnel using Bureau of Mines calorimetric equipment. The Office-of Naval Research supplied the supporting funds and arranged for procuring the samples of the titanium halides. The samples were prepared and analyzed by the Inorganic Chemistry Section, Division of Chemistry, National Bureau of Standards.

Jan 1, 1961

By Robert H. Merrill, James V. Williamson, David M. Ropchan, George H. Kruse

In- situ rock stresses were determined by flatjack and borehole - deformation methods . Estimates of the stress distribution around a flatjack were obtained by a combination of flatjack and borehole - gage techniques . The investigations were part of a study , conducted jointly by the State of California and the Federal Bureau of Mines , to determine the stress in rock at the site of an underground powerplant for the Oroville Dam near Oroville , California . The stress distribution around each of three flatjacks was nonsymmetric ; however , stresses obtained from 9 flatjack and 157 borehole measurements are considered reasonably accurate for engineering purposes . The stress near the edge of the openings is between 800 and 1,600 psi ; the stress in the undisturbed rock is approximately 500 psi , nearly hydrostatic .

Jan 1, 1964

By Thomas R. Bur

The strain and pressure gage methods for evaluating the relative performance of explosives in rock were compared. This comparison was based on a study of the responses of strain and pressure gages to explosion-generated seismic waves. Several explosives) representing a wide range of detonation pressures) were used. In general the relative performance of these explosives) as determined from amplitude) impulse parameter) and energy parameter measurements) is the same if the compressive portion of the strain pulse and the comparable portion of the pressure pulse are considered. Other similarities and differences of the two methods are also discussed.

Jan 1, 1967

By Lowell L. Patten

The Federal Bureau of Mines participated with the National Aeronautics and Space Administration and Martin Marietta Aerospace in developing, building, and testing a portable X-ray fluorescence spectrometer for use as an analyzer in mineral-resource investigative work. The prototype battery-powered spectrometer, measuring I1 by 12 by 5 inches and weighing only about 15 pounds, was designed specifically for field use. The spectrometer has two gas-proportional counters and two radioactive sources, 109Cd and 55Fe. Preliminary field and laboratory tests on rock specimens and rock pulps have demonstrated the capability of the spectrometer to detect 33 elements, to date. Characteristics of the system present some limitations, however, and further improvements are recommended.

Jan 1, 1982

By J. W. Paul

A superintendent is one who has the oversight and charge of some organiza- tion or enterprise, with porer of direction. The superintendent of a coal mine is the official who is in general charge of conducting the operation of the nine for the purpose of producing coal; he is accountable to his superiors for all matters that relate to the cost of production and safety in operation, ed under him are all the underground officials and other personnel making up the mine organization. The responsibility of the superintendent covers all the principal phases of mining, purchases of materials, issuance of supplies, accounting, and upkeep of the property and equipriont. In a broad sense, the superintendent must view his job as embraced under four gneral heads: (1) Construction, (2) instruction, (3) supervision; and (4) discipline. The degree of efficiency with which each of these phases of his work is conducted is a measure of the safety factor which the superintendent injects into his job. Injury to workmen and damage to property may be due to neglect of one of these general headings; as for example in the collapse of a scaffold there has been faulty construction which may be found upon investigation to have been the result of faulty instruction or lack of instruction. It may be that the condition of the scaffold was not ascertained in advance of its collapse through faulty supervision, or the discipline of the workmen had been neglected.

Sep 1, 1930

By R. A. Beall, S. L. Ausmus

The development of a completely water - free expendable graphite mold material , useful for reactive metal castings , has been detailed . Mixing and curing variables have been evaluated both by physical testing of the material itself and by castings of titanium , zirconium , and hafnium . The blend of powdered graphite , cornstarch , dextrin , cereal binder , linseed oil , and Carbowax -4000 is a successful mix when mulled in a carbon dioxide atmosphere , and properly cured and fired . The primary advantage of this material is its adaptability to standard foundry techniques ; i . e . , core blowing and hand ramming . Temperatures in the curing and firing cycles do not exceed 960 ° C , and no vacuum firing is required .

Jan 1, 1964

By Mackenzie Burnett

An inducer-type pump, capable of injecting dry coal into a hydraulic transport pipeline has been developed and installed in a specially designed and fabricated slurry injector vehicle. The full scale prototype injector system can deliver up to 11 ton/min of coal into an 8-in pipeline t pressures up to 95 lb/in2. The Helical Inducer Injector operates on centrifugal principles with flow passing axially through helical pitched conical rotor. Water is delivered to the pump through an annular slot at the atmospheric pressure coal inlet. The spinning rotor maintains an air-core vortex of water which pressurizes the discharge housing. A screw feeds coal through the open inlet into this vortex. The inner radius of the vortex contracts as pressure is increased, giving a limiting maximum pressure which is proportional to the square of the rotor speed. Below this limit, flow rate, discharge pressure, und rotor speed re independent variables. The self-powered, 4 -in high slurry injector vehicle follows and receives ROM coal from a continuous miner, reduces the top size to 3-in, and delivers the sized coal to the injector feed screw for slurry formation and pumps it through a mobile hose attached to the vehicle's outby end.

Jan 1, 1983

By R. E. Mussier

This investigation was made to study new methods to prepare high-purity yttrium metal, Various methods were used to prepare pure intermediate compounds, primarily chlorides, bromides, and iodides, which were subsequently reduced to metal. The process found most suitable for the preparation of pure anhydrous yttrium chloride involved thermal dehydration of a mixture of hydrated yttrium chloride and ammonium chloride while under vacuum. Yttrium bromide and iodide were prepared most effectively by the direct halogenation of yttrim carbide. Yttrim carbide was obtained by reacting and melting yttrium oxide-carbon mixtures in a carbon-arc furnace. Yttrium halides were purified by vacuum distillation and reduced by alkali or alkaline-earth metals. Lithium and sodium proved to be the best reductants from the standpoint of yield (>95 pct) and purity (>99.8 pct) of the yttrium. The product of the reduction step was sponge metal, which was consolidated readily by conventional cold-mold, arc-melting procedure. The purest yttrium obtained in laboratory scale work was prepared by sodium reduction of yttrium chloride and contained only 125 pp oxygen; other impurities did not exceed 1,000 ppm. In larger scale tests yttrium containing only 800 to 1,000 ppm total impurities was obtained by lithium reduction of yttrium chloride. The tensile properties of high-purity yttrium were determined. Mechanical tests showed that yttrium can be forged, extruded, rolled, spot welded, and deep drawn.

Jan 1, 1963

By L. F. Willmott

The Bureau of Mines at Morgantown, W. Va., has been investigating, on a pilot plant scale, various methods of gasifying bituminous coal with oxygen and superheated steam to produce synthesis gas, as part of the broader program of finding new uses for coal. Differences in the pressure gasification methods used have depended on differences in the manner in which the pulverized coal is fed to the gasifier. One of the methods of feeding the coal that was investigated was the continuous, integrated coal-water slurry system. Goal and water were first mixed to produce a slurry; then the slurry was pumped through a heated coil. to evaporate the water fraction; the resulting steam was superheated, and some of it was separated so as to adjust the ratio of the residual steam to the coal fraction and make the resulting mixture suitable for partial combustion with oxygen in a pressure gasifier. Both before and during this reported3 developmental work it was necessary to make an extensive literature search into the technology of aqueous slurries in order to establish design criteria for the pilot plant and to correlate results of various phases of the work with that of other investigators, The pilot work coincided with the commercial development of a long-distance pipeline for the transportation of coal as a coal-water slurry, and this fact tended to broaden the scope of the pilot plant work and the extent of the literature search. This bibliography is the compilation of the material that was collected.

Jan 1, 1963

By R. L. Thorne

The Snettisham Peninsula, 30 miles southeast of Juneau, Alaska, was studied by the Bureau of Hines to obtain basic information about the size, grade, and metallurgical characteristics of a large basic intrusive containing titaniferous magnetite. The investigation, which was part of a continuing program to determine the potential reserves of iron and titanium ores in Alaska, included transit and magnetometer surveys, followed by diamond core drilling and metallurgical testing. The magnetic attraction of a part of the Snettisharn Peninsula is noted on early navigational charts prepared by the Coast and Geodetic Survey. Reconnaissance examinations by the Geological Survey and a preliminary dip needle survey by the Territorial Department of Mines indicated the general nature of the basic intrusive, but little was known as to the grade and extent of the magnetite mineralization. The detailed survey by the Bureau of Mines proved an area of approximately 390 acres in which generally high magnetic anomalies with exceptionally high localized anomalies occur. Subsequent drilling across B representative section of the deposit yielded core samples, which assayed from 11 percent to over 45 percent total iron. A large sample of core composited to represent the drilled portion of the de-posit assayed 18.9 percent Fe, 2.6 percent Ti02, and 0.29 percent S, 0.32 percent P, and 0.05 percent v.

Jan 1, 1956

By J. A. Kost

A dust-control manual was prepared for use by mine operations personnel. The manual documents state-of-the-art control techniques, dust sampling, and use of personal protective devices. Content addresses advantages/disadvantages of control techniques, design and operating specifications, and implementation and maintenance guidelines. An indexed list of selected references is also included. In addition to the completed manual, this report documents work performed in the course of its preparation.

Jan 1, 1981

By E. T. Bowers

Pneumatic conveying of coal underground is not widely used in the United States, although it is becoming increasingly popular in Great Britain, the Federal Republic of Germany, and South Africa. The question of safety has been raised repeatedly: Will the system be prone to dust or gas explosions, and, if so, can it withstand such occurrences safely? The work reported here was done under a Bureau of Mines contract and deals with the safety aspects of pneumatic transport of underground coal, as well as the hazards inherent in more conventional haulage systems. Included are three designs for different applications of pneumatic haulage: off-loading a continuous-mining machine on a room- and-pillar section, vertical hoisting through a 1,200-ft shaft, and off-loading a tunnel-boring machine driving a 2,000-ft tunnel.

Jan 1, 1985

By W. F. Watts

In 1980 the Bureau of Mines developed the Mine Inspection Data Analysis System (MIDAS). MIDAS is a computerized, industrial hygiene data base capable of statistically analyzing environmental data collected in coal and noncoal mines and mills by Mine Safety and Health Administration (MSHA) inspectors or mine operators. The objectives of this report are to describe the current contents of MIDAS, to report analyses of coal and noncoal mine respirable dust samples collected by MSHA inspectors and to evaluate the proposed change in the metal and nonmetal respirable dust standard from a formula based upon the percentage of quartz identified in the sample to 100 µg/m3 of respirable quartz. Based on samples collected by MSHA inspectors, changing the noncoal respirable dust standard would result in 4 pct fewer samples with dust concentrations exceeding the standard. Analysis of respirable coal dust data collected by MSHA inspectors showed that mines with longwall plows or shears had the highest geometric mean concentrations (1.64 and 1.29 mg/m3, respectively). Mine operations using continuous rippers out-numbered longwall mine operations about 10 to 1 and had a geometric mean concentration of 0.66 mg/m3.

Jan 1, 1987

By Edwin A. Clarke

[For almost 2 decades the Bureau of Mines has been Interested in converting solid fuels to liquid fuels. Small-scale laboratory investigations were carried on for a number of years.4/ This work wad expanded substantially under authority of Public Law 290, approved by the 78th Congress on May 5, 1945. As part of the. broadened program, coal-hydrogenation demonstration plant was designed and erected at Louisiana, Mo., where: hydrogen-manufacturing and compression equipment, shoes, electric power, and other utilities and facilities were available from a discontinued wartime ammonia works . The plant uses the direct -hydrogenation or Bergius process, but the process differs from prewar European practices in many respects. Many noteworthy improvements h eve bean made, particularly by substituting automatic instruments for manual control of process variable's, in line with modern American processing practices. The over-all objective of the demonstration plant is to bridge the gap between laboratory end commercial-scale operation by furnishing cost and engineering data to develop a synthetic liquid-fuels industry when it proves technically and economically justified. Fitting into the over-all program, specific objectives o early runs were to (1) train personnel who had no experience with this type of operation, (2) break in the installed equipment, (3) obtain successfully integrated operation of the entire plant, and (4) work towards obtaining data on the hydrogenation of coal-tar oil and a typical low-ash coal. In beginning fan integrated operation, it is common practice to operate and obtain reaonably smooth performance of each unit before the over-all operation is undertaken. The first part of the plant completed was the refinery, consisting of several fractionating systems, a stabilizer, and a chemical treater.]

Jan 1, 1953

By Arno C. Fieldner

In view of the widespread interest in the production of synthetic liquid fuels from solid and gaseous fuels to supplement declining reserves of petroleum, and the many requests that are now being received for information on the subject, this bibliography of Bureau of Mines contributions has been compiled. In addition to the publications issued by the Government in printed or mimeographed form, references are included to articles written by the Bureau staff for the technical press and to cooperative reports of work done jointly with States, colleges, and industries. References are given under each section in chronological order. Bureau of Mines bulletins, technical papers, and Minerals Yearbooks are printed and are obtainable at the prices indicated from the Superintendent of Documents, Government Printing Office, Washington 25, D. C. If no price is given, the publication is out of print. The price of entire volumes of the Minerals Yearbook or of reprints of certain chanters may be obtained upon request. Any orders or remittances in payment for these publications should be cent directly to the Superintendent of Documents and not

Jan 1, 1945

By C. E. Wicks, F. E. Block, F. D. Stevenson

The vapor pressures of tungsten (VI ) chloride ( WC1 ) and hafnium ( IV ) iodide ( HFI ) were measured by a metal diaphragm technique . Vapor pressure values were obtained to permit calculation of the thermodynamic properties of the vaporization processes of the compounds . The vapor pressure data of WC16 are represented by the following equations for the liquid , B - solid , and a- solid over the temperature intervals indicated : - log P = 8.194 3,253 /T Liquid , 281.5 ° to 325 ° C : B - solid 230.0 ° to 281.5 ° C : log P a - solid 185.0 ° to 230.0 ° C : log Pam *** = 8.794 - 3,588 / T = 9.615 - 3,996 /T where T is the absolute temperature in degrees Kelvin . The heats of vaporization and sublimation are 14.9 , 16.4 , and 18.3 kcal / g mole , respectively . The entropy of vaporization at the normal boiling point , 330 ° C , was 24.3 eu . The fusion temperature , 281.5 ° C , and transition temperatures , 230.0 ° and 185 ° C , were found by thermal analysis .

Jan 1, 1964

Approximately half of all the fuel energy used in the United States is now pro-vided by oil and natural gas. A persistent and rapid growth in energy demand during the last 3 decades has been absorbed largely by the liquid and gaseous rather than solid fuels. In 1948 the energy provided by coal was substantially the same as in 1920. Meanwhile, the use of oil and natural gas each had increased fivefold. On a per capita basis, the change is more significant. Coal consumption has dropped from about 6 tons per person to 4-1/2 tons, while oil has increased from 4-1/3 barrels to 14-1/3, and natural gas from 7,500 cubic feet to about 35,000. These facts would have only academic interest if the United States had unlimited supplies of all fuels. However, while the Nation's reserves of coal are adequate to meet our needs for centuries, those of oil and natural gas appear limited. It is obvious, therefore, that the security of our liquid-fuel position would be greatly enhanced if the supply could be based in an increasing degree on solid fuels, such as coal/and oil shale, which make up more than 95 percent of our fuel reserves, instead of natural oil and gas. In addition, this would create new employment and help to stabilize the market for coal, which may be facing comparatively bleak prospects in the near future unless its position with respect to other fuels is improved.

Jan 1, 1950

By G. J. Slavens

The U.S. Bureau of Mines conducted research on preparing submicrometer titanium nitride (TiN) powder as a substitute for tungsten carbide (WC) in cutting tools and wear-resistant parts. Earlier research on a small scale was expanded to include a larger reactor. The TiN powder was produced by contacting titanium tetrachloride (TiCI4) with anhydrous ammonia (NH3) in the presence of Mg at 1,100° C. The powder was collected in an electrostatic precipitator (ESP) filled with ultra-high-purity (UHP) Ar. All collected powder was thermal vacuum distilled to remove Mg and magnesium chloride (MgCl2), leaving the purified TiN. Powder handling and purification procedures were conducted to assure low oxygen content in the powder product. Oxygen content in the distilled TiN powder product was as low as 0.40 wt pct. Nitrogen averaged near 22.0 wt pet with a high of 22.4 wt pct. The purified powder product had an average median particle diameter of 0.14 µm with a standard deviation of 0.09 µm.

Jan 1, 2010