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By H. Leitch

In laboratory experiments, the Bureau of Mines investigated melting, quenching, and sulfuric acid leaching of alumina from mixtures of albite and anorthite, and from anorthosites containing 26 to 32 percent alumina. Variations in pouring temperature, quenching and leaching conditions, were studied with respect to the extraction of alumina and impurities. Virtually all of the alumina was dissolved by leaching melted and quenched California anorthosite in boiling 16-percent sulfuric acid solutions for 15 to 30 minutes. The leach solutions were readily separable from the solid residue by conventional thickening and filtration techniques. Only 2 to 5 grams of SiO2, Fe2O3, or CaO dissolved per 100 grams of alumina. The quantity of SiOz in solution varied inversely with the duration of the leach and with the concentration of the H2SO4 solution used. Melted and quenched Wyoming and Minnesota anorthosites with SiO2:CaO weight ratios of 4.3 and 3.2, respectively, were less amenable to sulfuric acid leaching than California anorthosite with an SiO2:CaO weight ratio of 5.3. However, excellent results were obtained on the Wyoming and Minnesota anorthosites by the addition of SiO2 to these materials before melting, in quantities sufficient to adjust the SiO2:CaO weight ratios of the furnace charges to between 4 and 6.

Jan 1, 1966

By R. J. Leary

The Bureau of Mines experimental blast furnace was blown with oxygen-enriched blast in combination with natural gas injected at the tuyeres. The air blast was augmented with oxygen to form an enriched blast containing 24,8 pct oxygen, and tests were run at natural gas injection rates of 4.5, 6.0, and 8.3 pct of the air blast. Similar enrichment to 26.8 pct oxygen was tested at natural gas rates of 7.2, 9.1, and 11,0 pct of the air blast. At intermediate proportions of natural gas to oxygen, (1) the fuel rate and the replacement ratio of coke by natural gas were unaffected by oxygen injections and (2) the productivity increased about 4 pct for each I pct oxygen added to the blast. The higher proportions of natural gas to oxygen were less efficient; in return for a lower coke rate, the fuel rate increased and productivity declined. A deficiency in reducing gas imposed a limit upon lower than normal proportions of natural gas to oxygen. Beyond this limit the formation of reducing gas was insufficient to support the rate of metal production. When this condition was encountered, the coke rate requirement for specification iron was abnormally high and production fell off badly. Adiabatic flame temperature is discussed as a means for proportioning oxygen and natural gas additions.

Jan 1, 1967

By Mary F. Koehler

Interoxidic compounds, such as vanadates, have not been studied extensively in the field of thermodynamics. This is a report of three vanadates of sodium--metavanadate, pyrovanadate, and orthovanadate. Vanadates of other metals will be considered in future reports. The heats of formation at 298.15° K. of the three sodium vanadates (both from the oxides and from the elements) were derived from the results of sodium hydroxide solution calorimetry. Free energies of formation were obtained by combining heat and entropy values. The results support the conclusion that the three sodium vanadates were stable with respect to all possible decompositions in which vanadium retains its pentavalency.

Jan 1, 1960

By Lawrence G. Houk

In modern warfare mica is truly indispensable. The coordination of combatant units necessitates maintenance of intricate communications equipment, in the construction of which high-grade sheet mica is essential. Scrap, ground, and the poorer qualities of block mica, which are less essential to the military program, are not considered in this paper. Furthermore, as the paper is designed primarily to assist mica miners, mica derivatives such as splittings and films are also excluded from discussion. The paper therefore relates solely to block mica of strategic quality.

Jan 1, 1942

By Frank A. Peters

This Bureau of Mines report is the second of a series of process evaluations planned to determine the relative processing costs of producing metallurgical-grade alumina from low-grade aluminous materials. Included in these evaluations are recommendations for additional research and development to improve the processes and to lower their costs. The design for each process is based on published work. The processes considered in this report are designed to extract alumina as aluminum chloride from calcined clay with 20 percent hydrochloric acid and to remove the silica residue by filtration. Iron is removed by one of the following processes: Isopropyl ether extraction, in which iron chloride is extracted before decomposing the aluminum chloride; gas precipitation, in which the aluminum chloride is precipitated with hydrogen chloride while leaving the iron chloride in solution; gas precipitation-isopropyl ether extraction, in which the aluminum chloride from precipitation is extracted with isopropyl ether, if necessary; caustic purification, in which a crude alumina is produced and then purified by a modified Bayer operation; or sinter purification, in which a crude alumina is produced and then purified by a lime-soda sinter operation. For plants producing 1,000 tons of alumina a day the estimated operating costs per ton of alumina are: [Isopropyl ether extraction process $ 65.09 Gas precipitation process 89.04 Gas precipitation-isopropyl ether extraction process 119.65 Caustic purification process 73.79 Sinter purification process 80.47] The estimated fixed capital costs per annual ton for these plants on a Marshall and Stevens chemical equipment basis of 240.0 are: [Isopropyl ether extraction process $229.03 Gas precipitation process 287.16 Gas precipitation-isopropyl ether extraction process 356.59 Caustic purification process 266.48 Sinter purification process 279.13]

Jan 1, 1962

By Ernest F. Burchard, J. R. Thoenen

"INTRODUCTION Technically speaking, bauxite is not a definite mineral but a mixture of several minerals belonging to a group of partly consolidated material known as laterite, which have been formed by surface weathering of rocks.The term bauxite is applied to the ore of aluminum, although a substantial amount is used for other purposes, such as a base in certain chemical industries and in the manufacture of artificial abrasives, refractories, and certain cements. Although bauxite has not been classed as strategic it now appears that the domestic supply may be insufficient for expanded defense requirements.Until recently, domestic production of metallic aluminum has been ample to meet requirements, but estimates of pyramiding future needs of the defense program have caused serious attention to be directed to the self-sufficiency of this country, both as to the supply of the raw material, bauxite, and the metallurgical capacity available to convert the ore to metallic aluminum.At the request of the Secretary of the interior, representatives of the Bureau of Mines and the Geological Survey recently investigated domestic resources of bauxite.A preliminary study of published literature and a field investigation disclosed that"

Nov 1, 1941

By Ott F. Heizer

This paper describing the mining practices at the mines of Massachusetts, Massachusetts Co., Inc., at Mill City, Nev., is one of a series being prepared by the Bureau of Mines on mining practices, methods, and costs in tie various mining districts of the United States. The author acknowledges the assistance of William C. Vanderburg, associate mining engineer, U. S. Bureau of Mines, in the preparation of this paper.

Jan 1, 1930

By A. T. Iannacchione

Roof-rock instability in advancing sections of underground coal mines is a major contributing factor to accidents resulting in fatalities and injuries. Such roof-rock conditions can also result in loss of production due to additional cleanup time and increased amounts of reject material. The Bureau of Mines is investigating fundamental geologic factors affecting coal mine roof-rock instability in order to develop techniques to predict zones of potential unstable roof-rock. Two distinct directional trends of unstable shale roof-rock in a mine working the Upper Kittanning Coalbed are delineated: one trend is associated with the sandstone-shale transition zone, the other with a fault system. The unstable shale roof-rock associated with the transition zone, a consequence of differential compaction, is comprised of slickensided roof-rock. Whereas, the unstable shale roof-rock associated with the fault system, a consequence of structural deformation of the strata, is comprised of fault planes. These faults, small in comparison to the sandstone-shale transition zone, are difficult to delineate with a standard drilling program. Trends of the transition zone associated with the sedimentary facies change are projected into unmined portions of the coalbed with the aid of exploration core data.

Jan 1, 1981

By E. O. Binyon

"INTRODUCTION The Gibellini manganese—zinc-nickel deposits, are in southeastern Eureka County, Nev, T. 15 N., R. 53 E. M.D.B.M. 27.5 miles south of Eureka, the county seat.The partly explored deposits, locally known as the Black Iron or Gibellini property, were examined in May 1944 by an engineer 3/ of the Bureau of Mines, who recommended that the deposits be explored further by means of core drilling. The proposed program called for drilling six diamond—drill holes, or eight if necessary, and for trenching at two places — 200 feet northeast and 280 feet west of the shaft on the main deposit.In 1946 the project was set up, and In July, of that year diamond drilling as started. Six holes were drilled for a total length of 1,198.5 feet. No trenching or other exploratory work as done. Work on the project was stooped. October 30, 1946.OWNERSHIPAccording to county records, the property comprises a group of 13 unpatented lode claims, and ownership is divided among Louis P. Gibellini,Louis P. Gibellini and wife (both of Eureka, Nev.), and the International Smelting & Refining Co., of Salt Lake City, Utah. Five claims of the group - the Black Iron No. 1, Black Hill No. 2, Manganese No. 3, Flat No. 1, and Flat No. 2 - are owned by Gibellini. Three claims - the Black Hill No. 1, Black Iron No. 3, and Manganese No. 4 are owned jointly by Mr. and Mrs. Gibellini, and the International Smelting & Refining Co. owns the remaining five - the Black Iron No. 4 and No. 5, and Black Hill Nos. 4, 7, and. 9."

Jan 1, 1948

By J. E. Murphy

A method is being developed by the Federal Bureau of Mines for recovering lead metal from galena without the generation of SO2. Lead chloride is obtained by leaching lead concentrate at a temperature of approximately 100° C with FeCl3 solution: PbS + 2FeCl. " PbC1 2 + 2FeC1 2 + S. Electrolysis of the PbCI 2 product in a fused-salt bath results in deposition of molten lead metal at the cathode and evolution of chlorine at the anode. The chlorine can then be absorbed in the spent leach solution to regenerate FeCl3 for recycling. Optimum electrolyte composition was a PbC12-LiCl eutectic containing 7.6 wt-pct LiCl. The PbCl2-NaCl eutectic also proved satisfactory. Electrolysis in the PbCl2-LiCl bath at 450° C yielded 99 pct current efficiency at a current density of 5 amp/in2 with an energy requirement of only 0.24 kW-hr/lb metal produced. This compares with 98 pct current effi¬ciency and 0.26 kW-hr/lb metal produced for the PbCI2-NaCI bath. A typical lead deposit contained less than 100 ppm total detectable metallic impurities. At the low temperature employed for electrolysis, there was essentially no vaporization of Pb or FbC12.

Jan 1, 1974

By J. B. Gayle

A 1/2-ton experimental coke oven was installed ac the Bureau of Mines Southern Experiment Station, Tuscaloosa, Ala., in 1948. Designated as the Tuscaloosa oven, this unit features a 17-inch carbonizing chamber, globar heating elements, and silica-brick walls designed to simulate as closely as possible the carbonizing conditions for commercial slot-type ovens. Because of the small force exerted on the oven walls in most tests conducted to date (probably owing to the practice of charging coals and blends at a moisture content approximating that normal to commercial plants operating in this district), little information has been obtained about expansion properties. Two sole-heated ovens have therefore been constructed and used as supplementary equipment for determining the expansion properties of coals tested in the Tuscaloosa oven. The reasons for constructing the Tuscaloosa oven, the details of design, the operating, characteristics of the oven and the reproducibility of results have been discussed in previous publications. 3 4 5/ The present report deals with the effects of substituting various high- and low-volatile coals for components of a selected base blend carbonized under conditions similar to those normally used for producing foundry coke. Results of tests of 11 coals and 14 blends indicate that several blends tested rave cokes having physical properties very similar to those produced from the reference blend.

Jan 1, 1957

By Edward Kline

A review and synthesis of literature pertaining to biological consequences of submarine mine-tailings disposal (STD) was conducted. STD can result in massive sea floor sediment deposition. STD may also increase suspended sediment, trace metals, and residual milling reagents in receiving waters. These perturbations, which are highly site dependent, invariably smother benthic organisms, and could potentially affect or alter fish, plankton, and benthos through acute and chronic toxicity, bioaccumulation, behavioral changes, smothering, derived secondary effects, and habitat alteration. Much of the available information concerning STD is unpublished and limited to a restricted number of sites. From this information and related research, it appears that benthic smothering is the only major consequence of a properly designed STD system. There have been cases of metal bioaccumulation due to inadequate preliminary evaluation, Also, shallow water habitat alteration has resulted from STD. Reductions in biological production are likely due to benthic smothering. The rate of ecological recovery after termination of an STD operation varies and is difficult to assess, The consequences of STD are site specific. Additional research is needed concerning possible consequences of milling reagents and the broad implications of benthic smothering. Also, methodologies are needed to allow better prediction of benthic recolonization and ecological implications of metal bioaccumulation.

Jan 1, 1994

By W. L. Parker, W. A. Selvig

"Introduction.Powdered or pulverized coal is extensively used as a fuel, the total annual consumption*** in the United States being about 12.000,000 tons, and growing steadily. As the coal is usually pulverized so that 70 per cent or more parses through a 200-mesh sieve, it presents difficulties in sieving, because such finely divided material tends to clog the meshes. A fineness test is desirable in order to judge the efficiency of the pulverizing apparatus, and as an indication of the particle size of the coal being burned.Committee D-5 on Coal and Coke, American Society for Testing Materials, has recognized the desirability' of a standard method for determination of fineness of powdered coal. The Bureau of Mines, in co-operation with this Committee, conducted sieving tests on two standard samples of powdered coal, which are described in this paper. As a result of this work a method for making fineness tests, by band sieving, is recommended as a standard method, while a rapid method, by machine sieving, is given for routine tests.Outline of Investigation.Preliminary trial tests were made by the bureau and tentative methods were formulated for making the sieving tests both by band and by machine.Each of two samples of powdered coal was carefully mixed, and portions were sent to the twelve laboratories mentioned later. These were requested to make duplicate sieving tests on the two standard samples, by the hand-sieving and machine-sieving methods, and to follow the tentative procedure exactly as outlined. All of the laboratories made sieving tests by hand shaking and eight of them made tests by machine shaking."

Nov 1, 1923

By D. S. Harper, C. O. Carman

A German coal planer was put in operation in the Keystone mine of the Eastern Associated Coal Corp. , Keystone , W. Va . , in August 1960 . At present , the planer is mining in the fourth panel . The blocks of coal mined were 340 by 1,900 feet in panel 1 , 340 by 1,660 feet in panel 2 , 590 by 1,900 feet in panel 3 , and panel 4 , currently being mined , is 590 by 1,900 feet . Almost one- half million tons of coal have been mined from these four panels . An 11 - man crew handles the complete planer operation and produces an average of 500 tons of clean coal per shift . Self - advancing hydraulic props are used to support the roof over the entire face . Roof control and action on all of the panels has been highly satisfactory . During periods of extreme pressure , some additional support is required in the tail entry where evidence of weight from the retreating longwall extends about 200 feet outby the face . The time lost from production by moving equipment between panels has been reduced steadily . The move from panel 3 to panel 4 required 5 days , but it is believed that even that time could be reduced .

Jan 1, 1963

By O. M. Bishop

"SUMMARYAs a result of the increased demand for fluorspar during the war, the Bureau of Mines investigated numerous fluorspar properties in the southern Illinois field, which is centered in Rosiclare. Among these the J. J. Shelby 40-acre tract on the western edge of the district presented favorable factors that caused it to be chosen /or exploration.H. G. Spiller, formen lessee of the property, had explored the Shelby vein by means of an adit level and winze, and showed it to contain goad values in zinc and fluorspar at the depth explored. A diamond-drill hole with which Spiller explored the vein 78 feet southwest of the winze, however, failed to cut ore. After studying the field evidence, the Bureau concluded that the vein merited further exploration, particularly at a depth of about 440 feet, where the Fredonia limestone would form the foot-wall of the vein and the hanging wall would be the competent Cypress sandstone.Between October 17, 1944, and March 26, 1945, three diamond-drill holes were bored for a total inclined depth of 1,592 feet. Holes 1 and spaced approximately 500 feet apart, explored the vein at 440 feet 4 below the surface. The economic mineralization existed in the vein where cut. Hole 3 cut the fault at approximately 300 feet below the outcrop but failed to find any vein matter except stringers of calcite with small amounts of pyrite."

Apr 1, 1947

By D. Harrington

We Americans pride ourselves that ours is the greatest, most advanced and most civilized nation in the world, yet statistics indicate that apparently we have little appreciation for the lives and limbs of the people whose efforts give us whatever greatness we possess. The latest available statistics indicate that the annual accident death rate per 100,000 of population is nearly 80 or far higher than that of any other country in the world except Chile; is more than double the rate in Hungary, Netherlands, Ireland, Belgium, Denmark, Italy, Germany, Norway, Sweden, and Finland; is nearly double that of England, Wales, the Union of South Africa, New Zealand, Japan, Australia, and Scotland; and is 25 to 40 percent greater than Switzerland, France and Canada. To make matters worse, from the viewpoint of mining; the latest available statistics give mining by all adds the worst accident rate of the major industrial occupations in the United States, the accident severity rate for mining in 1935 being listed by the National Safety Council as 10.14, the next highest rate being 4.52 for construction, and the average rate for 30 main industries being 1.58. IMPROVEMENT IN SAFETY RECORDS Offsetting to a slight extent this rather dark picture is the fact that starting about 1930 the mine-accident rate in both coal and metal mining began to fall, reaching an all-time "low" in metal mining in 1932 and in coal mining in 1933. It now appears probable that the year 1936 has again lowered the accident rate in coal mining and this, together with the fact that the years 1933, 1934, 193 5, and 1936 all set much lover accident rates in coal mining than ware achieved for any similar previous period, gives hope that the trend is definitely in the right direction, though from the above figures mine-accident severity has a long, tedious road to travel before it becomes as low as the severity rate of all other major industries in the United States.

Jan 1, 1937

By Sumner M. Anderson

THE importance of the mineral industries of the Latin American area in 1964 may be evaluated in respect to a number of points of reference, a few of which are measurable and appropriate for examination. With regard to the region's contribution to total world production, it accounted for total 1964 world output of natural nitrates (from Chile), and about 97 percent of the optical and electrical grades of quartz crystal (from Brazil). The region supplied over 20 percent of world output of 7 other mineral commodities and accounted for 4 percent or more of world output of 19 other mineral products. Among major commodities, the area, occupying 15 percent of the earth's land surface, supplied within 3 percent of that proportion of the world's output of copper, lead, tin, zinc, barite, and crude petroleum. Incomplete compilation of production data, particularly that of nonmetallic minerals, precludes production estimates on some items for the area ass whole, and therefore the importance of Latin America as a world producer of some additional commodities may not be clearly assessed. For example, most of the countries of the area collect only incomplete data or no data at all on the production of clays and other ceramic materials, sand and gravel, dimension and crushed stone, lime, ornamental and precious stones, perlite, vermiculite, carbon black, coal tar products, and petrochemicals. In the case of many countries of the area, the value of production of one or more of these commodities greatly exceeded that of other mineral industry products that are carefully reported.

Jan 1, 1966

A preliminary research and development program dated April 25, 1974, was prepared for Development Engineering, Inc. (DEI) for laboratory, field and other engineering studies on the disposal of retorted oil shale. This program was revised and published as a final document dated December 17, 1974. The document included discussions on the peculiarities of retorted shale materials to be investigated and discussions of the various laboratory and field tests which would need to be conducted to define their physical and chemical properties. The proposed research and development program was divided into eight work phases as follows: I Program Development. II Exploratory Laboratory Tests on Old U.S.B.M. Retorted Shale. III Laboratory Tests on Pilot Plant Retorted Shales. IV Laboratory Tests on Retorted Shales from the Semi-Works Plant.

Jan 1, 1976

By S. H. Ash

As part of the work done at the Washington coal mines during the year 1929 , a study was made of the safety practices in and about the mines . Inasmuch as electrical blasting has made considerable headway it is interesting to note the manner in which it is done and the reasons why it was discarded at some of the mines . Blasting is done at the mines in the State by means of capped fuse , electric blasting " caps , " and in some instances by electric delay detonators . Black blasting powder with fuse is used at most of the open- light mines . The use of squibs was discontinued several years ago because the coal operators , without exception , recognized the dangers incidental to their use . Permissible explosive and dynamite are also used at some of the open- light mines . With the exception of some rock work and the driving of level work in gangways and air courses the explosive is detonated by means of capped fuse .

Apr 1, 1930

By Stephen A. Swan

Bureau of Mines research has not included analyses of mining dredge safety since 1948. Because of the increasing use of dredges, 63 fatal accidents and several hundred nonfatal injury accidents involving dredges were examined. Also, 31 working dredges and 3 dredge manufacturers were visited to acquire qualitative information. Drowning accidents represented 59 pct of the fatalities and are delineated in detail. Also, countermeasures against other hazards are discussed.

Jan 1, 1985