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By Peter Scales, Ricardo Jeldres, Fernando Concha, Pedro Toledo, Shane Usher, Anthony Stickland

The impact of several electrolytes present in seawater on the rheological properties of flocculated mineral suspensions was assessed using the creep test. Flocculated suspensions were obtained by adding polymer flocculant to a cylinder of mineral suspension and aggregating the suspension using the plunger method. The suspension was allowed to sediment and the supernatant liquid decanted prior to tests for the viscoelastic properties of the resulting sediment. The solid used was alumina AKP-30 both, below and above the isoelectric point. The polymer used was AN934SH, an anionic flocculant with high molecular weight. Salts analyzed were MgCl2, CaCl2 and NaCl, known as water structure makers, and KI and KCl, known as water structure breakers. A high salt concentration of 0.5 M was used to approach the ionic strength of seawater. For both pH’s studied, the sediments demonstrated a viscoelastic non-linear behavior observed as a non-linear relationship between yield strain and applied stress. In the absence of flocculant, it was observed that the viscosity and yield stress of a suspension increase in the presence of structure maker salts for the case of both silica suspensions and alumina suspensions. These results were explained using hypernetted chain statistical mechanics models describing the interaction of ions with solvated surfaces. In contrast, with the presence of flocculant, the shear yield strain of alumina suspensions increases with the breaker character of the salts, however, this result has been explained by an extension of the results from the models. The work has significant implications for the flocculation of mineral suspensions in the presence of seawater.

Jan 1, 2014

By Christopher Robben, Alexander Mosser

"X-ray transmission (XRT) sorting has been introduced into the minerals industry in 2006 and has found various applications in diamonds, industrial minerals and metal ore processing since. The technology offers planar projections of the atomic density of single particles similar to the principle known from airport scanners, but being capable of treating up to 150tph per metre working width. In 2010, a pilot operation using a belt-type sensor-based sorter went into production at the Mittersill mine to treat the fraction 16-28mm. After an optimisation phase, the results were superseding expectations and therefore in 2012 a bigger production plant was set up. Two XRT-based sorters are parallel in operation since. One is treating the fine fraction 16-30mm while the other one is treating the coarser fraction 30-60mm after the secondary crushing stage. The XRT sorters are operated with the objective to reject barren waste before it enters the mill and flotation plant. 105,000tpa of waste material are rejected per year and can be sold as aggregate for road construction. This means that about 22% of the run-of-mine ore are rejected at an early stage with a waste reject grade lower than 0.03wt%WO3. The installation has not only led to lower specific operating costs but also led to reduced tailings disposal in an environmentally sensitive area. This allows the mine to reduce its headgrade which allows for a longer mine life. Alternatively it is possible to produce more tungsten concentrate, which is delivered to the smelter. This article will introduce the technological principle of XRT-based sorting and will discuss the flow-sheet of the Mittersill mine. Experiences that have led to the current plant design are described as well as the impact it has on the operation."

Jan 1, 2014

By Wei Zhang, Jinhong Zhang

"In froth flotation, the adsorption of collector on mineral surface is critical for a successful flotation process. In present work, an atomic force microscopy (AFM) has been applied to study the adsorption of potassium amyl xanthate (PAX) on copper sulfides, i.e., chalcopyrite, chalcocite and bornite. The in-situ collected AFM images show that PAX adsorbs on chalcopyrite mainly in the form of oily dixanthogen; while it strongly adsorbs on chalcocite and bornite in the form of insoluble metal xanthate, which binds strongly with the mineral surface. The information obtained from the AFM study shed lights on the collectivity and therefore the selection of specific collector for different copper sulfide minerals in industrial practice.INTRODUCTIONFroth flotation, which treats the highest throughput in mining industry and produces the maximum economic outcome of any surface chemistry process, has been widely applied for the concentration of copper sulfide minerals, i.e., chalcopyrite, chalcocite and bornite. In flotation, collectors are added into the pulp (mixture of water and fine-grained minerals) to selectively adsorb onto the target mineral and render its surface with high hydrophobicity, which is generally beneficial for a strong mineral-bubble attachment and thus a high flotation recovery. Therefore, the adsorption of collector on mineral surface is vital for a successful flotation process and it has been studied by applying various surface analysis techniques, such as IR (Infrared Spectroscopy), CV (Cyclic Voltammetry) and XPS (X-ray Photoelectron Spectroscopy). (Poling, 1963; Allison et al., 1972; Mielczarski et al., 1984; Leppinen et al., 1989; Kartio et al., 1996) These studies have revealed a lot of information, such as the reaction, product and mechanism, of the adsorption of chemicals on mineral surface. It is also of great interest to directly get the image of adsorbed collectors on mineral surface changing with pulp chemistry, such as pH, redox potential, ionic strength and chemical’s dosage."

Jan 1, 2018

By A. Prokopiev

The biological stage of reclamation is the third final stage in remediation the damaged mining terrains, which is carried out following the completion of the mining technical stage. The biological stage of reclamation is carried out through restoration of the vegetation layer. The biological reclamation includes all activities related to the introduction into the terrain of vegetation, microorganisms, insects, and animals, with the acceleration of the succession and creating conditions for a sustainable ecosystem close to the natural one. It comprises of all anti erosion and other activities such as the preparation of the land for growing agricultural crops, sowing grass seeds, planting seedlings, amelioration of the soil and further care for the vegetation until its final place on the land. Mineral and organic-mineral ameliorants for biological reclamation were studied. The basic mineral ameliorant is Bulgarian natural zeolites. The zeolitic-rich tuff samples provided from Golobradovo deposit was characterized by their chemical and mineralogical composition and ion exchange properties and X ray analysis. The average content of clinoptilolite was found to be more than 80%. The materials had ion exchange capacity (NH4+) varying from 100 to 110 meq/100g. Chemical modifications of natural clinoptilolites were made in order to form active phases of nitrogen, phosphorus, potassium, and microelements. Slow-acting mineral ameliorant was developed. Organic-zeolite substrate for biological reclamation was developed. This new product is a mechanical mixture of organo-matter and modified zeolites. Agro-chemical parameters of new ameliorants were determined. The substrates including studied overburden dump soil and mineral or organo-mineral ameliorants are produced. The grass growth test was performed. Keywords: biological reclamation, ameliorants, damaged mining terrains

Sep 1, 2012

By Andrew T. McBride, Malcolm S. Powell, Indresan Govender

"Current empirical Semi Autogneous Grinding (SAG) mill models contain assumptions concerning the amount of energy available for particle breakage, how this energy is distributed in the mill media and the rate at which the energy is transferred. Despite these assumptions the JK SAG model is highly functional with a proven track record. DEM provides a numerical framework to greatly improve on these assumptions that were necessary due to a lack of available input data.This paper identifies key outputs of the Discrete Element Method (DEM), such as energy spectra and impact probability distribution. It describes how they can be incorporated into current mill models utilising practical rock breakage data. The rate at which energy is transferred is shown to be dependent on particle position and mill rotational speed and not once per cycle as previously assumed. Based upon this an improved energy transfer methodology is presented. The fundamental outputs of the DEM are validated against experimental three-dimensional particle tracking data, so as to establish whether the DEM produces correct energy transfer predictions on the inter-particle level, which is crucial to this work."

Jan 1, 2003

By Hillary Williams, Ronghao Li, Christopher Marion, Kristian E. Waters, Devin Hundt

"Zircon is an important mineral for ceramic, foundry, casting, and refractory applications; and it is the worlds primary source for zirconium. Zircon can also contain large and valuable proportions of other valuable metals, such as rare earth elements and hafnium. The Nechalcho deposit (Northwest Territories, Canad), is a hard rock REE deposit, which looks to recover zircon for its Zr and REE content. In this deposit, zircon is finely disseminated and associated with predominately silicate gangue minerals. Most of the work to date has focused on the beneficiation of mineral sand deposit, which typically remove silicate gangue minerals through physical separation steps. Therefore, the separation of zircon from silicate gangue, such as quartz, by flotation, has received little attention. This work used zeta potential measurements and microflotation experiments to understand the interaction between zircon and six different collectors (sodium oleate, sodium dodecyl sulphate, dodecylamine, SM 15, K-octyl hydroxamate and Florrea 7510). The results were compared with those of quartz. This study indicated that selective separation of zircon from quartz without the use of selective depressants or activators is likely challenging. The findings suggested sodium oleate and SM 15 only offered selective flotation of zircon in highly acidic conditions. Separation by the flotation of quartz is possible using sodium dodecyl sulphate, dodecylamine and K-octylhydroxamate. However, selective separation is highly dependant on collector dosage, for dodecylamine, and the selective activation of quartz, for sodium dodecyl sulphate and K-octyl hydroximate. Florrea 7510 offered poor recoveries for both zircon and quartz.INTRODUCTIONZircon (ZrSiO2) is a nesosilicate mineral which has a wide variety of applications, due to its hardness, opaqueness and resistance to heat and corrosion. Its major end uses are in ceramic, foundry, casting, and refractory applications (Bedinger, 2017). Zircon is also the most abundant zirconium (Zr) bearing mineral in the earths crust and is the principal economic source of Zr (primarily used in alloys for heat and corrosion resistance) and zirconia (ZrO2) (primarily used in ceramics) (Bedinger, 2017; Milnes and Fitzpatrick, 1989). Zircon forms in silicate melts and can often contain large proportions of other valuable metals such as rare earth elements (REE), and hafnium (zircon is the primary source of hafnium) (Bedinger, 2017; Belousova et al., 2002; Orlova, 2007). A common chemical formula showing the range of substitution in zircon is (Zr,Hf,Th,U,REE,Ca,Fe,Nb,Ta)(Si,P)O4 (Orlova, 2007)."

Jan 1, 2018

By Kang N. Zhong, Hui H. Luo, Yi H. Wei, Yu L. Wang

"More than 85% of phosphorous reserves in China occur as middle-low grade phosphate of sedimentary origin. The main gangues are dolomite, quartz, silicates, and clays. The characteristics of minerals are finely disseminated. Flotation results have shown that the floatability of apatite of this kind of ore is much worse than that of igneous and metasedimentary origin because of its high specific surface area. Although some effective depressants, such as naphthalene sulfonate and phenanthrene sulfonate, are used to decrease the MgO content in the P2O5 concentrate, its presence is still high (about 2%) in the Chinese concentrates. Meanwhile, the wastewater may cause some environmental problems. Batch flotation results and measurements of specific surface area and CO3 2- have revealed that there is a relationship between the floatability of apatite and the surface area.A two-stage flotation flowsheet, which includes a combination of direct and reverse flotation, was developed for beneficiating sedimentary phosphate ores. The direct flotation was conducted in an alkaline medium and most of the apatite and carbonate minerals floated leaving quartz and siliceous gangue in the sink. In the reverse flotation circuit, the floated product was further beneficiated in an acidic medium to eliminate the carbonate as a float product. Apart from the high quality of concentrate, the two-stage flotation also facilitated the treatment and the recycling of wastewater. A wastewater recycling procedure was developed and tested in a continuous flotation process. The key factor was the careful selection of effective and non-toxic reagents."

Jan 1, 2003

By Amir Hajizadeh Omran, Mehdi Irannajad, Sima Mohammadnejad, Fardis Nakhaei

"This study presents an experimental program performed to investigate the effects of flotation variables including gas flow rate, froth depth, slurry solids percent, frother/collector dosage and pH on the froth bubble size during desulfurization of an iron ore. These conditions were varied using a central composite design (CCD). Image analysis techniques have been developed and used successfully to characterize the froth bubble size. Results of the CCD experiments showed that the flotation variables have different effects on the froth bubble size. The froth height, air flowrate, pH and solid content had the most important influence on the froth bubble size. The interaction between the collector-frother, pH-collector, frother-air flowrate, solid content-froth height, pH-froth height and solid content-pH were also significant. Process state can be accurately deduced from the froth surface appearance, providing a convenient way to quantify the parameters as a function of the process control. INTRODUCTION Flotation processes are subjected to a wide variety of process disturbances, some of which are made by the change in mineral features and others to variation in operating procedures. Feed and air flow rates, densities, size distributions and shapes of particles, surface properties, and reagent dosages and compositions can all change, often with significant effect on the performance of the plant (Moolman et al., 1996a). Flotation process efficiency is governed by the wettability of the solid as well as the surface tension at the liquid-gas. Both of these properties are influenced by operational conditions encountering in a flotation process. The structure of froths developed on the pulp surfaces of flotation cells has a remarkable effect on both the grade and recovery of minerals in the concentrate (Shean and Cilliers, 2011)."

Jan 1, 2018

By M. Saghaeian, R. Hejazi, H. Abedini, M. Zare

Water recovery in mineral processing plants is one of the most important subjects because water supply is a critical matter economically and environmentally, especially in desert areas. In this paper, the filtration behaviour of two iron ore tailing sample has been investigated using laboratory scale vacuum and pressure filtration units. These samples including tailing from Sirjan and Zarand concentrate production plants with the d80 of 94 and 41 micron, respectively. The results show that by using vacuum filtration the cake moisture content of Sirjan sample would be about 24%. But the filtration time is too long and vacuum belt filter cannot be used in industrial scale. Adding about 40 g/ton of flocculant would decrease the filtration time by about 30% and make the vacuum belt filter appropriate for dewatering of this sample. For Zarand tailing sample, the vacuum filtration would produce a wet cake by about 31% moisture content. Filtration time is too long and adding flocculant would not improve the results very much. So pressure filtration must be used for dewatering of this sample. The results of laboratory tests show that using pressure filter would reduce the cake moisture content to 21%. The filtration time is logical, so this process can be used for Zarand tailing dewatering.

Jan 1, 2014

By S. A. Kondratyev

"The present research work aims at disclosing the dependence of flotation concentrate recovery and its grade on the physically adsorbed collecting reagent properties, viz., surface pressure in the reagent film at gas-liquid interface, velocity of reagent species spreading over the said interface, relation between interaction energies of collector molecules within a film and with water dipoles.When using a single collecting reagent it is possible to improve the flotation concentrate grade in two ways, namely, by reducing collector consumption rate or using a weaker reagent. According to the proposed mechanism, a decrease in the physically sorbed species of the collector leads to a decrease in the rate of removal of the kinetic restriction of a flotation contact formation. As a result, the recovery of the useful component is reduced and the content of valuable components in the flotation concentrate is increased. The relationship between the spreading velocity of physically sorbed species at the gas-liquid interface and the recovery and quality of the flotation concentrate has been experimentally proved. Reduction in collector consumption lowered the valuable component recovery at a higher grade of the concentrate.The reasons were established for a rise of valuable content in the flotation concentrate if a weaker collector was used. It is justified that the use of a weaker collecting reagent with a shorter hydrocarbon fragment declines physically sorbed species of collector. The spreading velocity of collector derivatives at gas-liquid interface tends to lower along with less participation physically sorbed species of collector in formation of a flotation aggregate. The spreading velocity is determined for products of interaction between butyl-and ethyl-xanthates and lead nitrate at gas-liquid interface. It is found that the spreading velocity of butyl-xanthate derivatives is higher than that of ethylxanthate derivatives.The research work gets insight into the nature of relation between useful component content in the flotation concentrate and the useful component recovery. It is pointed out that adjusting the collecting activity of a collector makes it possible to influence a useful component content in the froth product thus gaining a compromise between wanted grade and recovery parameters."

Jan 1, 2018

By R. D. van der Weijden, W. F. C. van Wageningen

"Copper(II) can be recovered or removed from acidic copper sulfate solutions as cuprite or metallic copper powder by reduction with carbohydrates (van der Weijden et al., 2001, 2002). In order to make this process suitable for a commercial scale pipe reactor, process conditions and reactor configuration need to guarantee proper throughput of the dilute suspension. This is where crystal engineering also comes into view. Copper powder characteristics, such as size and shape of particles, influence the tendency to adhere to reactor walls and to agglomerate, which in turn influence the throughput. Furthermore, separation, drying, packaging and product quality, are dependent on the powder characteristics.In this paper the effect of both chemical and physical parameters on the shape and size of particles were systematically studied in a number of autoclave experiments. These parameters include mixing, Cu(II) concentration, pH, temperature, seeding, use of additives and reactor materials. Additionally, Monte Carlo simulations of copper growth inside a Kenics static mixer were made. Results show that the use of additives, and the use of static mixers influence particle characteristics the most."

Jan 1, 2003

By Weiguo Xie, Malcolm Powell, Lian Liu, Ping Yu

"In order to develop a common mathematical and simulation platform for tumbling mills, a review of existing mechanistic models was made identifying the key aspects of grinding and slurry transport which are common to all tumbling mills. A mill model structure has been developed for all types of tumbling mills based on the population balance framework by incorporating breakage characteristics, slurry and solids transport, product classification and discharge, and energy consumption. A size-dependant breakage model developed by the JKMRC is applied. Transport is separated from breakage events and treated as a main sub-model in the new model structure. The model structure is based on dynamic time-stepping technique to enable dynamic simulation capability for non-steady-state simulation and control modelling. It is envisaged that the new model will cover a full range of milling conditions. It should enable a smooth transition between different mill types, such as from AG (Autogenous Grinding) to SAG to ball mill. The dynamic mill model structure developed here is the first step towards mechanistic modelling of grinding mills and provides great potential for the optimization of the comminution process."

Jan 1, 2014

By D. Vega, P. R. Brito-Parada

"Small diameter (10 mm) hydrocyclones have been applied successfully for the separation of particle suspensions in the micron size range. These hydrocyclones are attractive because they show a bypass fraction larger that the water recovery, resulting in a high particle recovery to the underflow as well as low water recovery. However, this is a disadvantage when the purpose of the hydrocyclone is classification because of the large amount of fine particles that are misplaced in the underflow. The aim of this study is to explore, experimentally and computationally, the influence of design parameters on the classification process. In this work, a full factorial experimental design was defined to carry out comprehensive experimental tests using glass beads (0-20 µm) as the particulate system. We show that the dimensions of spigot and vortex finder diameter can be effectively manipulated to change the separation performance of the system and the energy consumption. A CFD model was developed that is able to predict particle size distribution. The numerical results for the partition curves showed very good agreement with the experimental data. INTRODUCTION Small diameter hydrocyclones are a very attractive separation technology for fine particle suspensions. Since the hydrocyclone diameter is directly proportional to the cutsize that can be achieved, 10mm hydrocyclones have been shown to be very effective in collecting particles in the micron-size range. In addition, while in large hydrocyclones the bypass, i.e. the fraction of particles that report to the underflow without classification, is similar to the water recovery, in 10mm hydrocyclones the bypass fraction is considerably larger than the water recovery. Its high particle recovery and low water recovery makes small hydrocyclones ideal for ultrafine particle classification and dewatering applications in mineral processing. The separation of mineral suspensions achieved using small hydrocyclones has been the focus of various studies. Pasquier and Cilliers (2000) derived a general classification model from experimental data of fine silica concentration in 10mm hydrocyclones; the model was able to describe the fish-hook partition curve. The effect of operating conditions has also received some attention in the literature. Cilliers et al. (2004) showed that an increase in temperature positively effects the recovery of fine silica particles in small hydrocyclones, by increasing the bypass and decreasing the cutsize. Neese et al. (2015) showed that the cutsize in 10mm hydrocyclones can be further decreased by operating at higher pressure, which also trebled the throughput."

Jan 1, 2018

By Juan Pablo Segovia, Alonso Pereira, Fernando Concha, Daniel Sbarbaro, Samuel Vergara

A robust theory of sedimentation-consolidation evolved and was accepted by researchers worldwide in the last two decades of the 20th century. This theory provides a reliable method of thickener design, simulation and control. However, a process model, simple or sophisticated, empirical or phenomenological, is useful only if it is possible to determine, in an objective way, its experimental parameters. Although it is important for a mineral processing plant to perform periodical laboratory test to determine thickening parameters, and in this way adjust the operation, not always these tests represent the behavior of the material in the process. It is important to be able to determine these parameters directly in the thickeners. Research workers at the University of Concepción developed new instrumentation, algorithms and software for the determination of thickening parameters. In this paper, two new instruments for the on-line determination of the settling velocity and the compressibility of the sediment are presented and results of tests in a major mineral processing plant in Chile are described.

Jan 1, 2014

By Smuts. E. M.

This paper describes a methodology used to develop a numerical model for the study of particulate suspension rheology. Initially, Computational Fluid Dynamics (CFD) models of different rheometer geometries were tested with both a Newtonian fluid (water), and a non-Newtonian Herschel-Bulkley slurry. Rheograms were reproduced from these models and compared to experimental values. Once a single-phase model had been validated, a coupled model combining CFD and the Discrete Element Method (DEM) was created. Two open source software packages were chosen. CFD is implemented using Open FOAM®, and DEM using LIGGGHTS. These two different codes were coupled via another program called CFDEM. This coupled model is currently capable of modeling spherical particles in a suspending liquid. DLVO forces have been included in some models to account for inter-particle forces due to the surface charge on the particles. The coupled model is currently being validated. Preliminary results show good qualitative behavior of the model. Keywords: rheology, cfd, dem, suspensions, modeling

Sep 1, 2012

By Graeme J. Jameson

In conventional flotation machines, the recovery is strongly related to particle size. As particle size increases, the recovery also increases, reaching a maximum in the range 20 to 120µm. Beyond this range however, the recovery declines quite quickly. The reason for the decline in recovery observed with coarse particles can be traced to the effect of turbulence. Bubbles trapped in turbulent eddies rotate rapidly, and when the centrifugal force on a particle exceeds the retaining forces due to surface tension, the particle detaches. Since the centrifugal force varies as the cube of the diameter of the particle, and the attachment force varies simply as the diameter, being proportional to the length of the contact line, it is clear that detachment forces will predominate as the particle size increases. The corollary is that the recovery of coarse particles can be improved if the level of the turbulence in the cell can be reduced to a minimum. In this paper, a new type of flotation machine will be described, in which the particles to be floated are suspended in a fluidized bed. An up flow of fluidizing water is provided, by recycling liquid from the top of the cell. The recycle stream is aerated in a high-energy device that disperses the air into fine bubbles that capture the fines and ultrafines. Results are presented for several minerals and coarse coal. Keyword: fluidized bed flotation

Sep 1, 2012

By Kwang Soon Moon

Liquid ? liquid reactions such as solvent extraction in hydrometallurgy and BTX extraction in petrochemical industry has long suffered from the long retention time mainly due to the limited interfacial area caused by the immiscibility between water and oil phase, requiring typically very large perfect mixer type reactors and tall adsorption towers. A novel spray reactor for immiscible liquids; that is the KISEI Nozzle Reactor (KNR) was introduced, enabling the drastic increase in the interfacial area between the reacting immiscible liquids. Various spray mechanisms were applied in materials processing, e.g. spray drying, powder metallurgy, and aerosol industry, but not in hydrometallurgy. The KISEI Nozzle Reactor(KNR) was fully developed and used in production of biodiesel from the immiscible triglycerides and methanol. An experience with a full production plant facility is briefly discussed in the current paper. With the fog-like methanol spray in oil medium, the trans esterification reaction was almost instantaneous, and transformed the traditional batch trans esterification process into a continuous production process. And above all, with no moving parts in the KISEI Nozzle Reactor (KNR), the process requires minimal operation and maintenance costs. Keywords: immiscible liquids reaction, nozzle spray reactor, continuous biodiesel reactor, hydrometallurgy, organic extraction, micro emulsion

Sep 1, 2012

By J. Roth

The increasing demand of the filler industry regarding fineness and better delaminated products led to the development of a series of different grinding machines, which differentiate basically by the grinding mechanism as well as the kind of classification. Spiral jetmills grind, as it is well known preferably by delamination, therefore a spiral jetmill with integrated dynamic classifier has been developed. Especially the enhancement of the functional properties of the used industrial mineral fillers is a factor of highly increasing importance. These properties are very often bound to the platy shape of the minerals expressed by the aspect ratio. The developed Spiral Jetmill shows sufficient ability for such delamination and therefore increases in aspect ratio. In a series of comparative tests the suitability and advantages of this system regarding achievable fineness down to the submicron range as well as the conservation or even improvement of the aspect ratio of different minerals has been studied. As an emphasis on the results application tests with certain materials in the plastics field have been conducted. Due to the fact that in this range the required specific energy for achieving the necessary fineness increases exponentially another target is to optimize the grinding efficiency. A special feed control system provides on one hand a sufficient load inside the mill to obtain maximum utilization of the applied energy and on the other hand to prevent the mill from overfilling and coming with this a poor classification. The integrated classifier is a combination of a high speed motor with directly attached classifier wheels. This unit on one hand grants the necessary high circumferential speed of up to 190 m/s for providing an exact top cut of the ultrafine products and on the other hand gives the required operational reliability for continuous operation. Hard grindable impurities, which enrich inside the mill chamber, can be rejected from the process leading to an even cleaner product. Comparative tests on a talc product with certain free quartz impurities showed a significant improvement of the final product with respectively low loss on rejected material. This effect again had a beneficiary impact on the suitability of the final product when used in plastics application.

Jan 1, 2014

By Regis Texeira, Leopoldo Gutierrez, Vicente Hernandez, Caludia Vidal, Lina Uribe

"Molybdenum is currently the most important by-product of Chile´s copper mining industry. This mineral has gained international relevance over the years, because of its price. At mining deposits in Chile, copper and molybdenum are extracted together and then separated in a concentration process consisting of several flotation steps using sodium hydrosulfide (NaHS) as copper depressant. However, there are environmental issues related to the potential emisions of toxic hydrosulfide gas and bad odours, which affects nearby communities and suppose a risk for operators. This problem has led to the need for development of new technologies to eliminate the use of NaHS in the process of selective flotation of Cu and Mo minerals. In this work, results of flotation tests in which lignin derivatives reagents are used to obtain the selective separation of Cu and Mo minerals by flotation are presented. In this technology molybdenite is depressed by the action of lignin derivatives (lignosulfonates), while copper sulfides remain hydrophobic and float. The use of lignin derivatives in the selective flotation of copper molybdenum minerals represents a non-toxic alternative to NaHS.INTRODUCTIONSeparation of copper sulfides from molybdenite is commonly achieved through a two-stage flotation process. In the first stage the collective flotation of copper sulfides and molybdenite is promoted to generate a collective concentrate which is then treated in a second stage with sodium hydrosulfide (2.5-3.0 kg/t NaSH) to depress copper sulfides flotation without affecting the flotation of molybdenite. As a result a copper concentrate with 30-35% Cu, and a molybdenum concentrate with 50-52% Mo are generated. Although this process is widely used at industrial level, environmental issues related to the risk of H2S generation and bad odors have always been a concern. Thus there is a need in the industry for a more environmentally friendly process to separate copper sulfides and molybdenite."

Jan 1, 2018

By V. Panayotov

Slag and by-products of metallurgy bear valuable components and their processing raises an in-creasing interest. Coke and iron have to be separated and other components have to be depressed, in order to obtain sellable high quality copper concentrates. Use of classical mineral processing technologies, such as magnetic separation, sulphidization, hydrometallurgy, etc. yields copper concentrates with grade of 4%~6% Cu. Copper is lost in tailings and the whole technological cycle is low profitable. Technology proposed applies an electrochemical treatment of the industrial water entering the flotation cycle. Iron and iron compounds that do not bear Cu, coke and gangue materials are depressed during the copper flotation. Copper concentrate of grade of 9.8%~10% Cu is obtained at simultaneous increase of Ag recovery by 8%~10%. As a result company profitableness is increased. Technology proposed is easy to implement, it does not require changes in the existing technology flow-sheet, and additional investment is low. The flotation process can be aided by a specially developed system for real-time analysis of the obtained copper concentrate which allows in-time corrections in the flotation parameters and entire process control. Applied flotation schemes, technological parameters and results obtained are described.

Jan 1, 2014