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By Renaud Cousin

Supported gold catalysts were prepared by Direct Anionic Exchange on an alumina support and tested during the reaction of CO oxidation and of saturated and unsaturated hydrocarbons (C1 to C3). The catalysts showed high activies over a range of concentrations and temperatures compatible with an application to automotive exhaust cleaning. Furthermore, a complete resistance to thermal ageing at 600°C in the absence or presence of water was observed due to the obtention of strongly anchored nanosized gold particles during the preparation step.

Oct 1, 2003

By J. P. Mogan, E. D. Dainty

Polynuclear aromatic hydrocarbon (PAH) levels were measured in underground mines in the vicinity of diesel vehicles equipped with several types of emission control hardware. In general, the emission control devices appeared to reduce PAH levels, but the companion mutagen study suggested that the reduction might not always be beneficial. All underground PAH concentrations were below the threshold at which a significant impact on health might be expected, but recent animal exposure studies have indicated that PAHs may not be the primary hazard from chronic diesel fume exposure.

Jan 1, 1994

By Eric Pirard

"A mineralogical and trace element analysis was performed on the Küre historical slags in order to evaluate the possible recovery of copper and cobalt. Reflected light microscopy, electron microprobe and image analysis were combined to determine the Cu and Co distribution in the slag.The results indicate that 81% of the total cobalt is chemically combined in the fayalite whereas only 3.4% is in the mechanically entrapped sulphides. The remainder being in hercynite and wiistite. On the other hand, 95% of the total copper is in the sulphide phase.This kind of applied mineralogical investigation gives invaluable information when it is performed preliminary to metallurgical experiments.IntroductionThe recycling of metallurgical slags is a growing business. The operation is directed toward recovering base metals (Cu, Pb, Zn), and by-products (Floyd and Mackey, 1981).Two reasons are invoked to explain metallic losses in slags: (1) mechanical entrapment of matte globules in the silicate melt; and (2) chemically combined metals in the slag-forming phases. Obviously, a chemical analysis of the slag cannot distinguish between those two modes. Grinding and flotation of the liberated sulphides have often been used to evaluate the importance of mechanical entrapment (Mechev, 1970; Imris , 1982).Recent studies in applied mineralogy of pyrometallurgical products (Bérubé et al., 1987; Pignolet et al., 1986) have demonstrated the benefits of quantitative mineralogical analyses of slags. Optical microscopy together with electron microprobe and image analysis offers a powerful and easy way of quantifying the relative importance of mechanical and chemical losses."

Jan 1, 1991

By T. Hidayat

The distributions of minor elements between slag/metal and slag/matte in equilibrium with tridymite in the Cu-Fe-O-S-Si-Al-Ca system have been investigated in the range of conditions of interest to the high- temperature copper production, refining, and recycling processes. An improved experimental methodology has been used involving high temperature equilibration in controlled gas atmospheres, rapid quenching, and quantitative microanalysis techniques using Electron Probe X-ray Microanalysis (EPMA) and Laser Ablation Inductively Coupled Plasma Mass Spectrum (LAICPMS). The effect of oxygen partial pressure on the distributions of minor elements between slag/metal and slag/matte has been accurately measured. The effects of slagging components (Al2O3 and CaO) on the distributions of minor elements between slag/metal have also been experimentally determined. The present study is a part of a larger integrated experimental and thermodynamic modelling research program in the systems relevant to high-temperature copper processing. INTRODUCTION In the high temperature processing of copper, minor elements are distributed between different phases, i.e. liquid slag, liquid matte, and liquid metal. From a processing perspective, it is desired to have the valuable minor elements distribute predominantly in the metal and matte phases rather than in the slag phase, and to have the non-valuable minor elements distribute predominantly in the slag phase rather than in the metal and matte phases. Knowledge of the distributions of minor elements between phases in the smelting, converting, and refining processes is required if the distributions of minor elements between phases in these processes are to be optimized.

Jan 1, 2019

By Bruno Bussière

Acid Mine Drainage (AMD) from mine wastes is one of the most environmental challenge currently facing the mining industry. AMD is the result of the natural oxidation of sulphides exposed to air and water. When mining wastes have the potential to produce AMD, these reactive wastes have to be managed to meet existing environmental regulations. The LTA site (property of Barrick Gold Corp.) contains sulphide tailings that have the potential to generate AMD. The closure option Barrick selected was to construct a multilayered cover with capillary barrier effects (CCBE). The main objective of this CCBE is to prevent the production of Acid Mine Drainage (AMD) from the tailings stack covering an area of approximately 60 ha. Since its construction in 1996, the cover has been monitored to evaluate its performance. Two of the measured parameters are volumetric water content and matrix suction. This paper presents some of the main results from the monitoring program that started seven years ago. The results show that the cover is largely able to maintain a high degree of saturation (greater than 85%) in the moisture-retaining layer. The actual performance of the CCBE on the flat surface of the 60 ha site is even better than expected at the design stage. The area that requires more specific attention with the LTA cover is the influence of slopes that can reduce the performance of the CCBE during dry periods. However, these effects seems to be local and do not significantly affect the overall performance of the CCBE to mitigate the production of AMD at the LTA site.

May 1, 2003

By Malcolm Powell

"Predicting the performance of the whole mining process is surely the holy grail of predictive simulation. This can be named ‘Integrated Process Prediction’.The objective is to be able to predict the response of the processing chain, from mining to concentration, to changes in the ore type. This can apply to greenfields design – selecting processing options to optimise the overall mine performance within the constraints and aspirations of the greater community and environment; expansion and optimisation of existing plant to deal with changes in economic drivers and ore types; and on-line control – predictive reaction to ongoing changes in ore processing types in an operation.In order to achieve this there are several broad key components that are required: ore characteristics based on in-situ rock properties; a reliable 3D map of the ore body by the key processing parameters; prediction of how the rock fragments and the energy requirement to break it; the ability to predict and track progressive mineral liberation of the rock through the reduction process; the response of rock to separation processes as a function of the rock mineralogical properties. This requires the identification of primary rock properties and associating them with the rock particles as they move along the mining process chain to a concentrate or various forms of waste.This paper looks at the value of this integrated approach; the challenges it poses; the technology and capability we require; and how as a mineral processing community we can address the challenges."

Jan 1, 2016

By Y. Qi

A cell-level nonlinear dynamic model of solid oxide fuel cell (SOFC) based on physical diffusion principles is built in this note. It demonstrates that reactant diffusion processes from gas flow bulks to triple phase boundaries (tpbs) play an important role in the dynamic behaviors of SOFC. The simulation shows that under certain condition, the effect of the double layer capacitance may be neglected. The phenomenon of slow rise of voltage in current interrupt experiment may be explained by the dynamic behaviors of partial pressures in the vicinity immediately above tpbs.

Jan 1, 2005

By Premil Agarwal, Alok R. Patnaik, Pulak Dhar, Prakash C. Patnaik

In this study, a physics based model has been presented, considering the growth of the thermally grown oxide (TGO) layer on the bond coating of a thermal barrier coating. Using diffusion equations, a model has been developed to physically describe the oxidation process. The mathematical equations representing the diffusion formulations have been solved numerically. The computed results show the depletion of Al in the bond coating as it diffuses both towards the super-alloy substrate and towards the TGO produced in between the bond coating and the ceramic TBC top layer.

Jan 1, 2004

By Melissa Whellams

?? What is a social risk assessment (SRA)? ?? Why do a SRA? ?? When do you do a SRA? ?? How do you do a SRA? What is a social risk assessment? ?? SIA vs. SRA ? SIAs determine how a company?s project will affect social/cultural conditions in a region ? SRAs determine how social/cultural conditions will affect the risk profile of a company?s project Social risk context includes: ? review of human rights record ? analysis of conflict situation ? analysis of political climate ? stakeholder identification ? stakeholder concern/interest identification ? And so on?

May 1, 2008

By Ted J. Smith, Stephen E. Kesler

"Zonation patterns are welt developed in the mafic metavolcanic rocks that host epigenetic quartz-carbonate-gold vein mineralization at the Hollinger-McIntyre deposit. Carbonate alteration assemblages are strongly zoned about mineralization. Proceeding inward from background greenschist facies rocks to alteration envelopes enclosing individual veins, the following assemblages are observed:Assemblage I-quartz-albite-chlorite-epidote-actinolite-(calcite)Assemblage II-quartz-albite-chlorite-calcite-epidoteAssemblage III-quartz-ankerite-sericite-(chlorite-calcite)Assemblage IV-quartz-albite-ankerite-sericiteLithogeochemical zoning is equally well developed as variations in whole-rock abundances ofAs, Au, Ba, Rb, and Sb. As and Ba form the most useful zonation patterns, outlining individual ore zones as well as broader trends of mineralization.Gas chromatographic analyses of fluid inclusions in the quartz-carbonate veins indicate that the mineralizing fluid was an H20-C02 mixture. Locally, CH4-rich fluid inclusions are associated with graphitic and/or carbonaceous wallrocks. Fluid inclusions in ore-bearing veins have higher CO2 contents than those in non-ore veins. Extensive sampling and analyses of veins from the area surrounding the deposit reveals a well developed zonation of CO2 contents about the main zone of mineralization. Low CO2 levels (1-2 mole%) in veins are peripheral to the deposit and increase to over 12 mole% in mineralized zones.The observed zoning of the carbonate alteration assemblages is a result of the addition of CO2 to the wallrock, which is consistent with the zoning of CO2 in the fluid inclusions.The zoning patterns delineated in this study are useful in exploration both on a deposit scale and on the scale of individual ore zones."

Jan 1, 1985

By K. Sasaki

Ventilation measurements were carried out in a shallow underground-quarry space with relatively large internal volume of 14,600 m3 in order to evaluate its effective ventilation characteristics. Based on air velocity measurements with an ultrasonic anemometer in the exhaust airway connected to the space, it was found that the space was ventilated by natural ventilation airflow with intermittent changes in direction. It was difficult to measure the ventilation flow with typical methods of flow measurement provided from the intake portal and throughout the mine, because the cross-sectional area and volume of the openings were too large and the flow was variable. In the present study, a tracer gas method was applied to evaluate the effective ventilation airflow rate in the space. A photo-acoustic infra-red gas monitor, highly sensitive to SF6 gas used as a tracer gas, was set in the space to determine air exchange rates from gas concentration-time decay curves. The seasonal variations of airflow and thermal environment in the space were investigated through 13 sets of measurements taken over 15 months. Airborne rock dust concentrations were also measured at same time in the opening. The correlations between the effective ventilation airflow rate, thermal environment and dust concentrations in the opening space were analyzed and are discussed based on the presented measurements taken during year. It is concluded that seasonal variations in effective ventilation flow and the dust concentration are mainly due to differences in air temperature in the space, as affected by the rock?s surface temperature and atmospheric temperature. In summertime, the air temperature and associated air density difference generated lower natural ventilation flows resulting in higher dust concentrations.

Aug 1, 2013

By H. J. Chalmers

"Since the advent of large volume flotation machines, Cominco Ltd. has actively studied possible application of such machines to their various milling operations. A number of installations have been made and more are on the drawing board. This paper gives a description of these units, information as to choice of equipment, and information as to operating experience. Mechanical and operating details of six installations are summarized. Three different types of machines are discussed.Pine PointThe original Pine Point zinc flotation circuit comprised conventional roughing with two stages of cleaning. Over the years with increase in feed tonnage there have developed two adverse conditions; namely, a reduction in zinc concentrate grade coupled with an increase in MgO in the concentrate. This resulted in higher freight payments along with more severe smelter penalties. An intensive test program, in 1971, showed that the concentrate grade could be raised by 1.5 units of zinc along with a reduction in MgO from 0.8% to 0.47.. Subsequently this was done by adding two additional stages of cleaning using 16 cells of Denver 200-V's. The project was completed in January 1973 at a cost of $510,000 to give an estimated annual savings of about $390,000.Selection of the Denver Model 200-V was based on minimum floor space requirement, availability, and favourable operational and maintenance experience with Denver 100’s. As it happens it was possible to ""shoe-horn"" the 16 cells into place with a minimum of plant alteration. Some problems have been encountered with a tendency to ""sand up"" at high pH, particularly at the corners. Otherwise operational service has been very good."

Jan 1, 1974

By J. Oliver, B. Wilson, 10

"Red Dog is one of the world’s largest zinc producing mines and a significant producer of lead and silver. While some of the operational challenges relate to the mine’s location in a remote part of Alaska, there are also challenges in the mineral separation process. Recent processing upgrades have included the installation of two M5000 IsaMills to improve the zinc regrind circuit and of one Jameson Cell to improve the pre-flotation circuit. Relatively fine grinding is required to achieve efficient mineral separation at Red Dog, but while fine grinding aids in the production of high grade concentrates, it also creates challenges in the efficient recovery of fine minerals. Over half of the lead lost to the lead circuit tailings, as well as almost half of the zinc lost to the final tailings, is in the finer size fractions (<10 µm). The high pulp density experienced in the pre-flotation and lead rougher circuits also causes significant entrainment loss of lead and zinc to the pre-flotation concentrate and of zinc to the lead concentrate. To help improve fine mineral recovery, Red Dog has recently plant tested and installed magnetic conditioning technology in the flotation circuits. The equipment aggregates fine paramagnetic sulphides and selectively increases their flotation recovery. This paper outlines the testing and positive results at Red Dog.INTRODUCTIONRed Dog is the largest zinc mine in North America and represents approximately 29% of North American zinc concentrate production. The mine is located in northwest Alaska, approximately 100 miles north of the Arctic Circle and 50 miles inland from the Chukchi Sea. The remote location makes the mine accessible only by air or seasonally by ocean-going barges. Red Dog is a partnership between NANA Regional Corporation Inc, the land owner and Teck Alaska Incorporated, the operator of the mine. Red Dog Ore and Mineralogy The Red Dog deposit is a rich sedimentary exhalative (sedex) zinc-lead-silver deposit. The main minerals present in order of abundance are: quartz, sphalerite, pyrite, barite and galena. Production began in 1989 with mining of the Main deposit. Between 1989 and 2012, approximately 55.6 million tonnes of ore with an average grade of 20.5% Zn, 5.6% Pb, and 97 g/t Ag was mined from the Main deposit. Subsequent to the development of the Main pit reserve, two additional open pit deposits were discovered: Aqqaluk and Qanaiyaq. The first blast in Aqqaluk occurred on June 4, 2010. As of December 31, 2014, the Aqqaluk deposit reserve is an estimated 45.7 million tonnes of ore with an average grade of 15.1% Zn, 3.9% Pb and 71 g/t Ag."

Jan 1, 2016

By M. Rigaud, K. Sankaranarayanane, X. Zhou

The effect of varying fine alumina/ultra-fine alumina ratio on the Bingham to dilatancy transition in alumina based, self-flowing refractory castables has been studied in detail employing rheological tests and particle size distribution measurements. Analysis of flow resistance and torque viscosity values has shown that Bingham to dilatancy transition is strongly influenced by fine alumina/ultra-fine alumina ratio in the castable, as well as by the nature of ultra-fine alumina. The calculated values of rheological constants and the viscosity coefficient were found to increase at higher fine alumina/ultra-fine alumina ratios.

Jan 1, 2004

By K. A. Hughes

Under the oxidizing conditions of the McClean Lake Tailings Management Facility (TMF) hydrocarbons entrained on the surface of tailings material from mill processes are gradually converted to soluble bicarbonate ion. This has been observed to be a process occurring over approximately three years likely encouraged by the presence of a microbiological community within the tailings mass and in the water column. A recent tailings sampling campaign has provided evidence that bicarbonate ion is participating in the conversion of gypsum to calcite. In older tailings, equilibrium with calcite appears to be controlling the terminal bicarbonate ion concentration.

Aug 1, 2010

By R. J. Bowell

Mineralogical controls exert significant control over the extraction of uranium from its ores. Uranium speciation, associated mineralogy, deportment and uranium mineral availability are all factors of consideration when assessing leachibility. This study presents data from laboratory uranium extractions undertaken on several contrasting uranium ores from a wide range of orebodies. The results provide insight into the mineralogical factors of importance when considering uranium extraction. These results are presented within the wider context of geometallurgy and demonstrate how geometallurgical assessment, even at an early stage of mine development, can greatly assist in the design of a suitable extraction scheme.

Aug 1, 2010

By George P. Demopoulos, Amani Al-Othman, Terry C. Cheng

One critical issue in chloride hydrometallurgy is the regeneration of the lixiviant HCl that is currently achieved by pyrohydrolysis. In this paper, a low temperature HCl regeneration process was investigated which regenerates HCl and produces saleable gypsum. This process promises to reduce the generation of wastes by the reaction of spent calcium chloride leach liquors with sulfuric acid solution at low temperature. Experiments were performed to determine the optimum conditions of the reaction in terms of temperature, reagent concentrations, rate of reagent addition, mixing and seeding/recycling to produce marketable gypsum and HCl with practical strength.

Jan 1, 2004

World copper electrowinning tankhouse plant practices have been surveyed. This survey is a supplement to previous surveys that have been carried out in 1995, 1999, 2001, 2002 and 2003. On a world basis, process technology trends include the further installation of automated electrode handling systems including permanent cathode systems, automated cathode handling machines, fully automatic cranes and polymer concrete cells. Designs also have included larger electrode sizes and higher electrolyte flows and current densities. Overall these trends have further resulted in optimized tank house productivities and improved electrowon cathode purity. Most greenfield copper electrowinning projects are occurring in South America and Central Africa.

Jan 1, 2007

By Colin P. Skidmore

Long touted as Australia?s fourth uranium mine the sediment-hosted Honeymoon Uranium Project is close to commercial production using insitu-leach mining methods. Uranium mineralisation occurs as pitchblende coatings on unconsolidated quartz sand and gravels within a stacked aquifer system in a buried palaeochannel located in the Curnamona Region of South Australia. A final NI43-101 Feasibility Study is close to completion which has included extensive delineation drilling using PFN technology to accurately measure uranium grade and distribution. This data integrated with a detailed 3D sedimentalogical model is being used to optimise wellfield and plant design.

May 1, 2006

By Xu Feng, Han Shufeng, Zhu Bin, Wang Mingming

Due to urban subway tunnels mostly built in the cities with highly density buildings, the geological and construction conditions is complex, especially certain sections of the subway tunnel will pass through from the foundation of the overpass, therefore the stability and surface deformation control of that section’s tunnel excavation is particularly important. Taking Xi'an Metro Line Three interval tunnel as a research object, we have used FLAC3D simulation to analyze the tunnel’s surrounding soil deformation and tunnel lining stress distribution under bridge foundation with shallow buried covered excavation method. Analysis results show: (1) After the excavation of the tunnel right line, due to the bias of the upper bridge foundation the right of the tunnel showed relatively large deformation. In order to ensure the construction safety, we recommended using the grouting anchor reinforcement on the right side wall to further control the deformation zone. (2) The maximum vertical displacement of the ground occurred in the right wall of the tunnel portion which was due to the intensity of soil outside the grouting range of the arch is low, as a result the deformation is larger; this position requires special attention, strengthening the monitoring measurements of this part is necessary to avoid the large deformation and other adverse effects of the upper portion of bridge foundation. (3) The maximum vertical force area of the initial lining of the tunnel is in the middle of the side wall, while the second lining in this part of forces is smaller, thus at the beginning of the construction of the liner, attention should be paid to this area. On-site grouting or steel bracing reinforce support may be used if necessary.

Jan 1, 2015