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By Li Qihou, Li Yuhu, Liu Zhihong, Liu Zhiyong, Yang Xiaofeng

Scorodite samples were synthesized, in adding or without crystal seed respectively by using Atmospheric Scorodite Process (ASP), Hydrothermal Scorodite Process (HSP), and Improved Atmospheric Scorodite Process (IASP) individually; and their crystal structure, crystallinity, morphology, particle size, specific surface area, Fe/As mole ratio, as well as the leaching stability were characterized, aimed to reveal the relationships among the synthesis methods, the compositional and structural properties, and the leaching stabilities of scorodite. The results show that synthesis methods have significant effects on the compositional and structural properties of scorodite. Scorodite samples of high crystallinity, small specific surface area, and low Fe/As mole ratio, possess high leaching stability. The order in the leaching stability of scorodite samples synthesized in this study is as follow: ASP<HSP<IASP. Scorodite particles in the sample synthesized by IASP without crystal seed are in large sizes and of pyramidal morphology enclosed mainly by crystal planes of {111}; and the sample possesses the crystallinity of 84.5%, the particle size (D50) of 28.2 m, the BET specific surface area of 3.72 m2/g, and the Fe/As mole ratio of 1.05; after leaching this sample by using acetate buffer solution of pH 4.95 for 10 days, the total arsenic concentration in the leaching solution is merely 1.14 mg/L.

Jan 1, 2015

By Afshin Sadri, Wai Lai Ying, Brycklin Wilson, Zoe Coull

"Although there have been great steps forward to integrate corrosion engineering into operations, there is still an underlying tendency for maintenance tasks to be performed in a reactive manner. This is especially true when strategies focus on lagging indicators such as visual inspections, RCA (root-cause analysis), and FMECA (failure mode, effects and criticality analysis). This trend to “reactive maintenance” can be avoided by utilizing more inspection and monitoring methods to identify leading indicators of failures. Prevention is generally less costly than repairs; moreover, when paired with appropriate monitoring techniques, intervention of corrosion protection can be more effectively timed and based on more accurate data. Hatch asset reliability studies show nearly 80% of defects are introduced through operations and maintenance. Therefore, proactive corrosion management can provide the necessary feedback to optimize operations and maintenance strategies preventing costly corrosion losses. Understanding corrosion risks gives a clear picture of the benefits of a proactive approach to asset performance. Monitoring techniques (Non-Destructive Testing, field testing, sampling, etc.) by nature are a more effective means of improving maintenance efforts and preventing corrosion losses than other methods (RCA, FMECA). This paper will outline the importance of proactive corrosion management and demonstrate its benefits through industry examples.INTRODUCTION Over the past few decades, with the growth of technology and awareness of sustainable development many studies have shown the benefits of a proactive approach to maintenance strategies. However, in practice there is still an underlying tendency for maintenance tasks to be performed in a “reactive manner”. This is especially true when strategies focus on lagging indicators such as visual inspections, RCA (root-cause analysis), and FMECA (failure mode, effects and criticality analysis). This trend to “reactive maintenance” can be avoided by utilizing more inspection and monitoring methods to identify defects and leading indicators to failures."

Jan 1, 2017

By D. Paul Bishop, Kevin P. Plucknett, Hung-wei Liu

"Spark plasma sintering (SPS) process has been evaluated for producing the commercially pure (CP) Ti, TiAl and a TiAl-B4C composite. Comparisons were made between the materials in terms of the sintered density, resultant hardness and microstructures. In the present work, the titanium aluminide powders (Ti-48Al, producing a mixture of y-TiAl/a2-Ti3Al) were synthesised „in-house? using a simple reaction-sintering and mechanical attrition approach. This allowed various size distributions to be generated. The powders were then blended with a fine boron carbide (B4C) powder (up to 6 wt.%), and the resulting mixtures were consolidated using spark plasma sintering (SPS) under vacuum in graphite dies. An applied stress of 50 MPa was used for all SPS runs. The SPS parameters were varied in terms of the ultimate sintering temperature (up to 1300°C) and hold time (up to 10 minutes) for each material. It is demonstrated that high densities can be achieved this approach (exceeding 95% of theoretical, with optimised samples close to full density). Microstructural characterisation was conducted using optical microscopy, scanning electron microscopy, and X-ray diffraction. The B4C additions were seen to partially react with the TiAl to form reinforcements, such as TiCx and TiBx. Preliminary mechanical property assessment will also be briefly discussed.INTRODUCTION Titanium- and titanium aluminide-based alloys possess many unique properties, such as excellent corrosion resistance and high temperature strength, respectively (Cardarelli, 2001; Leyens & Peters, 2003). Compared to many other competing materials (e.g. stainless steel or Ni-based alloys), Ti- and TiAl-based alloys also have relatively low densities (~4.5 and ~3.9-4.1 g/cm3, respectively), which is critical for performance in aviation and automobile applications. However, the manufacturing cost is high, due to the expensive raw Ti material and difficulties in machining. TiAl-based alloys are particularly difficult to produce because of their limited ductility (Lütjering & Williams, 2007). To overcome those problems, powder metallurgy (PM) technologies have shown great potential as near-net shape processes for Ti- and TiAl-based alloys. The general PM process largely avoids laborious post-machining and minimises material use. In industrial production, the PM approach has been successfully utilised to manufacture aluminium- and iron-based alloys (Huo & Heath, 2008)."

Jan 1, 2017

By Henrik Saxén, Mikko Helle

The operation of hot stoves used for preheating the blast in the ironmaking blast furnace has a strong effect on the consumption of reductants, economic performance of and CO2 emissions from the steelmaking site. Generally, it is recommended to maintain as high blast temperature as possible, because this minimizes the rate of reductants in the blast furnace. The blast temperature is affected in a complex way by the time periods of heating and cooling of the stoves, and by the amount of gas combusted in the stoves. Furthermore, as the hot stoves show degraded performance with age, it is a non-trivial task to select optimal operation parameters for the stoves. The paper addresses this computationally by applying a one-dimensional heat-transfer model of the hot stoves for optimization of the performance of the system. The complexity and strong coupling of the decision variables is demonstrated by numerical examples, where the blast temperature is maximized under different constraints.

Jan 1, 2015

By Ming’an Wei, Qifu Duan, Chengtie Wang, Jianmin Wu, Erdenet Mining Corporation, Lusheng Zhou, Wenjian Wu

"The development and industrial applications of magnetic liners have been around for decades. A Swedish company SKEGA first introduced the rubber magnetic liner, and then followed by the Chinese metal magnetic liners. Traditionally, both liners were used in secondary and regrind ball mills, especially for ores containing magnetic materials. Mostly steel balls or equivalent forged balls, usually below 60 mm in diameter, were used as grinding media. With the development of mineral resources over the years, SAG mills and larger ball mills have become the dominating components for comminution circuit design globally. Due to the larger ball mills and thus larger grinding balls (up to 80 mm) especially in non-ferrous metal industry, the application of magnetic liners has been very limited. Based on the new development of materials, the HMR Group Limited has been exploring new designs of magnetic liners which led to the invention of the Nano Steel Magnetic Liner (NSML). Recently, NSML had a successful application in a 5.5m x 6.5m ball mill with 80 mm balls at the Erdenet Copper Mine in Mongolia. Although the first set of liner had a service life of 12 months, the design of the second set was modified and improved to accommodate the operating conditions, which is expected to reach least 24 months service life. The original manganese steel liner only had about 8 months liner life.1. IntroductionMineral processing is an essential operation for the development and utilization of mineral resources. The effective concentration of various useful minerals depends on sufficient liberation of the mineral particles in the ore. The crushing and grinding process such as ball milling are the most common way to achieve proper liberation size. Mill liner is an eternal topic for the operations, not only because it protects the equipment, but also affects the mill grinding efficiency and availability. In recent years, magnetic mill liners have been developed that can easily meet the production targets with numerous benefits, such as zero maintenance, reducing specific energy consumption and improving grinding efficiency."

Jan 1, 2016

By S. Jeon, T. H. Kim

"Understanding the frictional properties of discontinuities is crucial to ensure the stability of underground structures. In particular, the frictional behavior at depth depends on the complex interaction among mechanical, hydrological, thermal and chemical characteristics and their coupled effects. In this study, a series of triaxial compression tests were carried out to investigate the behavior of rough shear surface of synthetic rocks. The frictional behavior showed little variation at different confining and water pressures. The test results were analyzed using Coulomb’s failure criterion. In addition, numerical analysis was carried out using PFC2D to simulate the test.INTRODUCTIONUnderstanding coupled behavior of rock at depth is of great importance in design, construction and operation of underground structures such as a disposal facility of radioactive waste, hot dry rock geothermal system and oil reservoir. In particular, many uncertainties are involved in characterizing deep rock mass deformation in the designing process and interactions among fluid flow of groundwater, high temperature and stress disturbance should be considered. Many independent studies have been carried out to investigate the thermal, hydro, mechanical and chemical coupled effects in numerical and experimental methods. They include the researches by Lockner, Summers, Moore and Byerlee (1982), Jafari, Amini Hosseini, Pellet, Boulon and Buzzi (2003), Tembe, Lockner and Wong (2010), Lee, Lee and Jeon (2012), Indraratna, Premadasa, Brown, Gens and Heitor (2014)."

Jan 1, 2015

By P. A. Geusebroek, N. A. Duke

Abstract - The Lupin mine, located in the central Slave province just east of the western boundary of Nunavut Territory, is a world-class example of a Neoarchean-aged banded iron formation (BIF)-hosted lode-gold deposit. At the minesite the gold-mineralized Lupin BIF, separating stratigraphically underlying psammitic wacke and overlying argillaceous turbidite sequences, delineates the Lupin dome, a hammerhead-shaped F2/F3 interference fold structure occurring at the greenschist to amphibolite facies metamorphic transition within the thermal aureole of the Contwoyto batholith. Detailed paragenetic relationships indicate that peak thermal metamorphism coincided with the switch from regional D2 compression to rapid D3 unroofing of the Neoarchean orogenic infrastructure. Gold initially precipitated with pyrrhotite, replacing amphibolitic BIF at the apex of the Lupin deformation zone, separating the east and west lobes of the Contwoyto batholith. Over the course of associated prograde/retrograde metasomatic overprints, gold was further remobilized during garnet and loellingite/arsenopyrite growth in chlorite-altered selvages of late-forming ladder quartz veins. A metamorphic model of ore genesis, with gold being scavenged and transported by metamorphic fluid that was shed and structurally trapped at the amphibolite recrystallization front, is favored over the previously proposed syngenetic and exogenic models of gold concentration that have tended to polarize genetic interpretations to date.

Jan 1, 2004

By V. G. Papangelakis, G. A. Moldoveanu

The use of anhydrite (AH) seed, control of acidity levels and ageing were assessed as means to promote the conversion of freshly produced metastable gypsum generated in-situ to the less soluble anhydrite phase and force deposition of calcium sulphate on seed as opposed to on equipment as scale, while achieving lower terminal aqueous calcium concentration as well. It was found that moderate sulphuric acid levels (0.25M) and ageing in the presence of AH seed accelerated the gypsum-AH conversion, achieving 100% transformation of the metastable gypsum generated in situ to the more stable, less soluble AH in 6-7 days, while lower/nil acidity did not promote more than 30% AH conversion for 10 days, even in the presence of AH seed. These findings indicate that anhydrite seeding, ageing and incomplete neutralization are beneficial for scale control as well as achieving lower calcium levels, thus rendering the resulting solution more amenable for recycling.

Jan 1, 2015

By F. Henríquez, V. Iriarte, L. Vinnett, J. Yianatos, F. Díaz

Metallurgical characterizations of the collective (Cu/Mo) and selective flotation plants were carried out in Minera Los Pelambres, Chile. The selective plant allows the valuable minerals of Cu and Mo to be separated. The evaluation involved two surveys consisting of metallurgical sampling as well as residence time distribution (RTD) measurements to determine load distribution. The RTD data were obtained in real-time by means of the radioactive tracer technique. In addition, metallurgical data was reconciled and supported by effective residence times. In the collective plant, a performance comparison of parallel rougher circuits was carried out, which included a bank of six mechanical cells of 250 m3 and banks of nine mechanical cells of 130 m3. In the selective plant, the Cu and Mo evolution along the plant was evaluated. The results in the selective plant allowed for performance evaluation of mechanical and pneumatic cells in primary flotation. In both plants, mineral losses were evaluated and their relationship with circuit configuration (cell types and circuit layout) was determined. The metallurgical characterization was a powerful tool to evaluate circuit performance and to detect improvement opportunities at industrial scale.

Jan 1, 2015

By Feng Xue, Mi Xujun, Peng Lijun, Yin Xiangqian, Liu Dongmei, Xie Haofeng, Huang Guojie, Yang Zhen

The Age-hardening Cu-Cr alloys are extensively used in integrated circuit lead frame, railway contact wire, resistance welding electrode and continuous casting mold copper plate, owing to having an excellent combination of high electrical or thermal conductivity and high strength. High temperature performance is very important during the service process. Effect of Magnesium and Zirconium on softening behavior of Cr-Cr alloy are investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). During the softening process in the Cu-Cr alloy, the recrystallization process, grain growth and Cr precipitates coarsening are observed. The addition of Mg or Zr to the Cu-Cr alloy, the resistance to elevated temperature can be significantly improved, owing to being restrained the growth of the precipitates by segregating along precipitates surface. INTRODUCTION Age-hardening Cu-Cr system alloys can be widely uesed in many fileds such as electrodes for spot welding (Hatakeyama et al., 2008; Cheng, Shen & Yu, 2013; Zhou et al., 2016; Chbihi, Sauvage & Blavette, 2012), intergrated circuit lead frame (Hatakeyama et al., 2008; Cheng, Shen & Yu, 2013; Zhou et al., 2016; Liu et al., 2006; Pang et al., Xia et al., 2012; Wang et al., 2009; Huang et al., 2003; Cheng, Yu & Shen, 2014; Zhang et al., 2016; Li et al., 2007) and railway contact wire (Cheng, Shen & Yu, 2013; Zhou et al., 2016; Chbihi, Sauvage & Blavette, 2012; Liu et al., 2006; Pang et al., Xia et al., 2012; Wang et al., 2009; Huang et al., 2003), because it has high strength, good electrical and thermal conductivity. The precipitation behavior of binary or ternary Cu-Cr alloys had been investigated by many researchers (Chbihi, Sauvage & Blavette, 2012; Peng et al., 2017; Batra et al., 2002). In addition, to obtain additional mechanical properties without much deterioration in electrical conductivity, trace addition of alloying elements like Zr, Ag, rare metals (Y and Ce) and Mg are added into Cu-Cr alloy. The addition Mg to Cu-Cr alloy accelerated the process of precipitates nucleation and restrained the growth of the precipitates by segregating along precipitates surface during aging, which enhanced the stability of the deformation microstructure and improved the mechanical properties of the alloy (Zhao et al., 2018). Additional zirconium in Cu-Cr alloy enhances the strength by the decrease in inter-precipitate spacing of Cr precipitates and the formation of Cu5Zr phase (Chihiro, Ryoichi & Kazue, 2008). Owing to the decrease in inter-precipitation spacing of Cr precipitates and to the Ag-atom-drag effect on dislocation motion, the addition of Ag can increase in strength, stress relaxation resistance and without much deterioration in electrical conductivity (Chihiro, Ryoichi & Kazue, 2008). The enhance in strength and electrical conductivity of the Cu-Cr-Zr alloy by adding Ce and Y elements are attributed to removing oxygen and sulfur from as-cast alloy (Li et al., 2006). However, the effect of Mg or Zr element on microstructure and properties of Cu-Cr alloy during the softening process are not clear. Therefore, Microstructure evolution and properties of a Cu-Cr systems alloy were investigated in detail by OM and TEM. The Relationship between microstructure and properties of Cu-Cr systems alloy was also discussed.

Jan 1, 2019

By Sylvain Castonguay, Sylvain Pilon

"Operator competency is an important factor in the safe and successful operation of today’s complex processes. Competent process unit operators deliver superior performance and results. In greenfield projects, operator competency is particularly critical, as the lack of specific operations experience must be offset with proven practical knowledge and skills to avoid mistakes that can cost millions in terms of start-up delays, production losses and equipment damage. It is, therefore, important to know precisely what competencies are required for a project or site, and what any gaps in operator competency need to be addressed and improved. The success of plant commissioning, start-up and sustainable operations is directly tied to operator competency. The significant investments required for new projects, the exploitation of more challenging ore bodies, and the increasing complexity of plant operations have placed renewed emphasis on the need for competent operators. Furthermore, many large capital projects are being developed in remote regions, often with ties to the delivery of social benefits for the local population in terms of jobs, training and other development opportunities. While automation and processing technologies have helped do more with less, indicators now point to a bottleneck in human performance limiting operational results.Automation industry development in managing abnormal situations, including solutions for simulation and operator training, has produced applications to provide customized and flexible training methods. This paper will discuss tools to automate the operator competency process in order to guide trainers to effectively teach, measure, control, provide feedback, and monitor operator skills. Today’s competency management solutions can be effectively applied throughout the course of an operator’s professional life, as a guide to hiring new operators, for developing competencies to support operations, and also to develop and refine best practices and share lessons learned."

Jan 1, 2016

By D. Nower

"The supply of copper is expected to be at a large deficit in 2012. To recover from these deficits mining companies are required to maximize production and there is no better way to accomplish this than to optimize the use of their mobile mining equipment fleets. To optimize these fleets, each equipment type has to be monitored in its own unique way. Automation would not only improve production, but also minimize the safety risks and eliminate planning errors. The automated vibration monitoring of multiple systems on the shovel can determine the machine’s condition at all times. This reduces unplanned downtime and keeps critical shovels in production. This paper will discuss the details of how shovels can be successfully monitored, continuously. INTRODUCTIONP&H Mining, part of Joy Global, is the world’s largest manufacturer of above-ground mining equipment. Its electric rope shovels, such as Figure 1, with capacities up to 115 tons (104.3 metric tons), are used for high production loading in surface mines; its draglines, such as Figure 2, have bucket capacities to 160 cubic yards (122 cubic meters). P&H also produces blasthole drills, mobile mining crushers and other essential mining equipment. Headquartered in Milwaukee, WI, the company does business on every continent, except Antarctica. ECONOMIC FACTORSDue to the global demands for metals and power, mines are required to operate at full capacity. Mine operations cannot afford any critical assets to shutdown unexpectedly; depending on the ore type and quality, downtime for a single shovel can be as much as $300,000 per hour.Electric rope shovels are one of the most critical assets in open pit mining. They are very large, complex machines with DC or AC motors, multiple reduction gearboxes (some of them complex planetary) and multiple large rolling element bearings. This complexity, combined with the tough 24/7 service, results in too much unplanned shovel downtime, which can affect the entire downstream process."

Jan 1, 2012

By O. A. Ojo, N. Esmaeili

"The effects of brazing and use of composite powder mixture as interlayer material on hot corrosion resistance of brazed IN738 superalloy were studied. Brazing was observed to result in significant reduction in the hot corrosion resistance of the superalloy. However, application of composite powder mixture, which consists of additive superalloy powder, enhanced the hot corrosion resistance of brazed samples. It is also found that although the use of composite powder mixture increased hot corrosion resistance of brazed alloy, if the additive powder completely melts, which is possible during brazing, it can significantly reduce the hot corrosion resistance of the brazed joint. Elemental micro-segregation during solidification of the joint with completely melted powder mixture produces chromium depleted zones and consequently reduces hot corrosion resistance, since a uniform distribution and adequate chromium concentration is necessary to combat hot corrosion. This has not been previously reported in the literature and it is crucial to the use of composite powder mixture for enhancing the properties of brazed superalloys.INTRODUCTION Superalloys have been developed in response to the increasing demand for materials with higher resistance to corrosion and creep and also with higher mechanical strength at higher temperatures (Smith, 1981). Ni-base superalloys are predominantly used in manufacturing hot sections of gas turbine engine components. This is due to their high strength and corrosion resistance in extremely high temperature service environments which is typical for hot sections of gas turbine engines (Miglietti, 2009). The continuous demand for higher efficiency and output has resulted in the use of higher operating temperatures and gas pressure in modern gas turbine engines (Jahnke & Demny, 1983). Consequently, this has caused thermal and mechanical stresses which result in severe degradation and damage of gas turbine engine components due to creep, fatigue and hot corrosion (Zhang, Feng, & He, 2006). The decision to replace or repair damaged parts depends on the overall repair cost and expected life of the repaired components (Jahnke & Demny, 1983). However, in most cases, it is more cost effective to repair damaged parts rather than use a full replacement."

Jan 1, 2017

By D. Beneteau

Plotting sets of data collected over time using a frequency-magnitude distribution is common with both earthquake and mining seismology. A Time-Between-Events (TBE) analysis technique simply makes use of the inter-event times and b-values (slopes of the best fit lines on the frequency-magnitude charts) from the same set of data. Four distinct patterns in TBE versus Event Magnitude have been found which suggest whether there are constant seismic sources causing populations of data, or if the smaller and larger events, within the population represent varying seismic sources. Different rates of events, identified as TBE-rates in this study, may suggest whether the events are blast induced, or not. This study was done using actual seismic datasets from hardrock mines in Canada and Australia. This was to verify the applicability of the method to multiple mining environments and to determine the practicality and implications of this methodology to enhance the interpretation of seismic source mechanisms The results of the TBE technique and other proven techniques are combined into a Seismic Mechanism Assessment Worksheet. This is a tool that allows operators to compare trends within seismic datasets with assessments of in-situ rock conditions. The goal is to enhance the understanding of rockmass failure mechanisms.

Nov 1, 2011

By O. Neves, C. G. González Beca, M. C. Sol Pereira, H. Sousa Vale, R. A. Guedes de Carvalho, M. N. Sampaio

"As sulphide ores are usually concentrated by flotation , the material is very finely ground <37um), wet and impregnated with the chemicals used in flotation. These conditions are favourable to the development ofchemical reactions which are largely influenced by atmospheric conditions (temperature, humidity, wind, etc.) as well as by the geometry of the piles.Physical and chemical properties of a chalcopyrite concentrate were determined by laboratory tests. The knowledge of these properties was considered necessary in order to establish a correct design of the storage and handling operations of the sulphide ore concentrates obtained by flotation.The properties studied in this work were: transportable moisture limit, flowability, effects of vibration, hygroscopicity, ""caking"", chemical alterations by humidity, oxidation and self-heating (auto-ignition, dry and wet oxidation, self-heating by humidification and its prevention).INTRODUCTIONIn order that the handling and the transport of a powdered material may be carried out correctly, it is necessary to know certain physico-chemical characteristics. Transportable moisture limit (TML), apparent density (both aerated and compacted), compressibility, angle of repose, angle of spatula, cohesion and angle of slide(l-4) are characteristics (among the flowability parameters) worth knowing.Moisture content of the powdered material is fundamental, because if this is too low heavy losses will occur when the product&apos;s particle size is very small, if it is too high, separations between solid and liquid phases may occur. In the latter case, the centre of gravity of the system may change suddenly and cause accidents, mainly if transport is by sea or by river."

Jan 1, 1989

By S. M. Chentouf, M. Jahazi, N. Bombardier, T. Belhadj

The main limiting factor in the commercial expansion of superplastic forming (SPF) of thin sheet aluminum alloys is the extent of cavitation phenomenon that takes place during the processing. The severity of the cavitation process is mainly dependent on the uniformity of deformation (i.e. level of local thinning) during processing. In the present paper, correlations are made between thickness variations in several formed sheets and the characteristics of the cavities observed in the material. The 1.4 mm thick 5083 aluminum alloy sheets were hot pre-formed at around 450°C for 4 min and then air-cooled. Opto-digital and Scanning Electron Microscopy were used to examine the microstructure and analyse the cavities. Also, grain size measurements were carried out for different location in the SPF formed piece. The surface and volume fractions of the cavities were measured with the aid of metallography image processing (MIPTM) on as-polished samples prior to etching. The results are analyzed in terms of the influence of applied strain and microstructure conditions on the propensity to cavitation of the alloy.

Jan 1, 2015

By M. Kawata, T. Amano, T. Miyamoto, K. Shibayama

"The High Pressure Acid Leach (HPAL) plant of Taganito HPAL Nickel Corporation (THPAL), located in Taganito, Philippines, with a nameplate capacity of 30,000 Ni-t/year started commercial operation on October 2013. The plant load was smoothly ramped up and it achieved monthly production equivalent to 33,000 Ni-t/year in 2016. Partial improvement of the plant capacity for the achievement of 36,000 Ni-t/year, as evaluated from the current operation progress of each system is planned for 2017. In this paper, aside from presenting the progress of the plant ramp-up, research and development activities such as the reduction of nickel loss and the improvement of filtration capacity which was achieved by particle size control of ZnS precipitates in the Zinc Removal system are also discussed.INTRODUCTION Taganito HPAL Plant Project History of THPAL Taganito HPAL Nickel Corporation (THPAL) was incorporated in August 2008, as a joint venture of three (3) companies, namely Mitsui Corporation with 15% share, Nickel Asia Corporation (NAC) with 10% share and Sumitomo Metal Mining Corporation (SMM) with a controlling stake of 75%. Aside from its capital share, NAC’s Taganito Mining Corporation (TMC) supplies the ore for the HPAL plant located in Taganito, Claver, Mindanao, Philippines. The objective of THPAL is to produce 30,000 MT of nickel and 2,600 MT of cobalt as mixed (Ni/Co) sulfide by treating nickel laterite ore in the Philippines and exporting to Japan as raw material for SMM’s Niihama Nickel Refinery (NNR) for the next 30 years. In other words, 1.15 wt% of nickel in ore is refined to 99.99 wt% nickel in electrolytic nickel. The mixed (Ni/Co) sulfide is shipped to NNR and SMM provides the technology and management personnel to THPAL plant as well as sulfuric acid which is the main reagent for HPAL process. Figure 1 shows the location of THPAL and current relationship between the stake holders.The Characteristics of THPAL Plant In terms of plant design, a 2-train system is applied for the HPAL circuit considering the reliability of the process, facility and avoidance of whole plant shutdown due to HPAL troubles. The technical data, operation know-how and improvements gained from the successful operation of Coral Bay Nickel Corporation (CBNC) which was established in April 2002 were reflected in THPAL’s plant design. As for the H2S plant, a more economical design was considered which is different from CBNC."

Jan 1, 2017

By K. M. Deen, E. Asselin

Hydrometallurgical processes, i.e., Cu extraction from a mineral concentrate and Zn electrowinning, are coupled in a battery-like system. A naturally-sourced CuFeS2 concentrate mixed with activated carbon is used as a positive slurry electrode separated by a membrane from the negative compartment. The Zn is deposited on the negative Al current collector from the circulating solution containing 100 g L–1 Zn2+ in 0.2 M H2SO4. In this battery-like system, both CuFeS2 oxidation and Zn deposition are possible during the charging cycle. The additional benefit of this setup is the energy storage if discharged by re-dissolving the Zn in the negative compartment. Cyclic charge/discharge testing revealed oxidation of the mineral concentrate supported by the Zn2+/Zn redox reaction. The coulombic and energy efficiencies increased monotonically to 95.6% and 43%, respectively, with approximately 7% Cu extraction during the first 10 charge/discharge cycles (completed in 2.4 hours). The discharge energy density also increased from 2.7 to 36.2 mWh L–1. In the following 90 cycles, the low energy (~14%) and coulombic (~33%) efficiencies that were obtained confirmed the progress of irreversible reactions e.g. Cu extraction from the mineral concentrate. Overall, approximately 16% Cu was extracted from the mineral concentrate over 100 charge/discharge cycles (or about 12.2 hours). INTRODUCTION Chalcopyrite (CuFeS2) is the main economic copper-bearing mineral, which is generally processed through pyro-metallurgical methods to produce Cu. However, environmental challenges with smelting, depletion of high-grade ores and a large number of impurities (some toxic) have resulted in continued research aimed at the development of hydrometallurgical technologies to process CuFeS2. There are a number of different proposed hydrometallurgical routes in the literature to treat CuFeS2 concentrates, but only a few have attained commercial acceptance (Dreisinger, 2006). Zn is another commercially important metal that is mainly produced via acid leaching of roasted sphalerite (ZnS). The pregnant leach solution is rigorously purified to remove all the soluble metal impurities, particularly those that are electrochemically more noble than Zn and present large kinetic activity towards H2 evolution (Hu & Piron, 1992; Mackinnon, Brannen, & Fenn, 1987; Mureşan, Maurin, Oniciu, & Gaga, 1996). Metal impurities such as Cu, Co, Ni, Cd, Pb, Sb, As, Ge and Fe etc., if they exist in the leach liquor beyond the tolerance limits, can decrease the current efficiency during electrowinning and deteriorate the deposit quality (Alfantazi & Dreisinger, 2001). A complete flow sheet, describing the process steps of Zn metal production from mine site to pure metal is presented elsewhere (Brown, Meisenhelder, & Yao, 1983).

Jan 1, 2019

By Joe Price

Canada?s energy future will increasingly depend on a supply of light, sweet crude oil derived from the Athabasca oil sands deposit of North-eastern Alberta. Billions of dollars are being spent on the construction of new and expanded mine and bitumen extraction plants, in situ recovery facilities, pipelines, upgrading installations and all the infrastructure needed to support these projects. The success of the existing operators has also inspired new players, anxious for ?a piece of the action? to come forward with exciting project proposals of their own. None of this investment and spin-off economic activity would be taking place today if events had unfolded differently in this part of the world some one hundred million years ago. The accumulation of sand in rivers, estuaries and in the near-shore marine environment created the great reservoirs that host the enormous oil deposits these projects are designed to exploit. Mine operators of all stripes will likely agree that there are few good ?geological surprises?. With specific reference to oil sand deposits, the geological history determines the distribution of sand, silt and clay bodies, which in turn controls the ore grade. Important design factors including everything from stable pit slope angles to tailings properties reflects events that took place millions of years before. An understanding of the sequence of events that resulted in deposition and preservation of the sediment and oil are important to sound design for both mining and in situ facilities. A geological history of the region is described. Site-specific examples from Syncrude?s operating mines are used to illustrate some of the geological factors that can present design challenges.

May 1, 2003

By W. D. Freeborn

Slim-hole drilling and completion techniques were first used in the Cynthia area of the Pembina field, Alberta, by the Texaco Exploration Company in the summer of 1957. Prior to that time, eighty-eight wells had been drilled and completed in this area in a conventional manner. Subsequent to the initial four-well evaluation programme, twenty-one additional wells have been drilled using slim-hole techniques. No difficulty was encountered in the drilling and completion of slim-hole wells, or in obtaining production from them. A comparison of drilling and completion economics and practices has been made for slim-hole and conventionally completed wells. Penetration rates for both bit sizes (614 in. and 9 in.) were relatively equal. The shorter life of the smaller bits required the use of 15 per cent more bits per well, but the total trip time to change bits was similar for both hole sizes because of the higher hoisting speeds possible with the lighter drilling strings used in the slim holes and better hole conditions. Completion costs of the slim holes were reduced by 37 per cent as compared to the costs of conventional-type completions. This was made possible through the use of smaller well equipment, the elimination of tubing, and a reduction in rig time for completion operations.

Jan 1, 1958