Search Documents

By Paul B. Batten

Shutdown is a generic term for what may be called an Outage, Turn Around (TAR) or Overhaul etc. Running a plant shutdown well has always been key to the financial contribution of a mine. However, something important has changed. The post pandemic reality is that it is harder to retain workers and many of those near retirement just didn’t come back to work. This is creating a shortage of experienced people and a workforce that changes employers easily. We are seeing the impact of this manifested in the erosion of established maintenance and supply chain processes that now struggle to yield the plant runtime that could once be taken for granted. The scope, cost and duration of a shutdown varies widely depending on the nature of the work and the equipment being renewed. The PM of an electric shovel might require a week of downtime and cost $100,000. A gold plant may need to go down for 3 days when its time to change mill liners and cost $500,000. A turnaround in a refinery can take more than a month and cost multi millions. Despite the huge differences.

Jan 1, 2023

By E. Asselin

Electrochemical polarization experiments were conducted on alloy 625 in ammonia solution between 25 and 225°C and the results were compared with those of an oxygen solubility model. Results confirm that corrosion is under oxygen control, Normalized corrosion rates are determined based on the rate of oxygen diffusion to the corroding surface, and the corrosion rate at 200°C (-9.7 µA.cm-2) is roughly 24 times higher than the corrosion rate at 25°C (0.4 nA,cm-2), An oxygen-solubility model for Supercritical Water Oxidation (SCWO) conditions was generated using the Redlich¬Kwong-Soave (RKS) equation of state, Results of the model confirm many of the experimental observations from SCWO reactors which suggest that corrosion is at a maximum at temperatures just short of the critical point, The RKS/oxygen diffusion model predicts that the corrosion rate at 365° C is ?85 times higher than the corrosion rate at 25' C. Given that a normalized corrosion rate is obtained, this type of model could be useful for selection of SCWO reactor materials.

Jan 1, 2005

By S. B. Ballantyne, D. R. Boyle

"Detailed studies have been conducted on the dispersion of uranium in stream waters and sediments around various types of mineralization and hitherto unexplained anomalous areas in the Okanagan Valley and Highland region of south-central British Columbia. These studies were part of the jointly funded and planned Federal-Provincial Uranium Reconnaissance Program of the Geological Survey of Canada and the British Columbia Ministry of Energy, Mines and Petroleum Resources. Statistical analysis of regional data indicates that U in stream waters and sediments varies considerably for different rock types, thus affecting data interpretation. In addition, the data demonstrate a poor correlation between U in stream waters and their associated sediments which can be largely accounted for by variations in climate and water and sediment composition. Regional trends in the distribution of U can be explained in terms of the above secondary factors as well as primary metallization phenomena.Significant correlations between U and F, and U and Mo can be explained by certain magmatic and mineral-forming processes. U shows little correlation with other base metals.The dispersion characteristics of U in the vicinity of Miocene "" basal type "" mineralization ; uraniferous pegmatite terranes, anomalous lineaments in granitic terranes and high-background volcano-sedimentary areas are discussed. Highly anomalous U concentrations in waters and sediments may not always be indicative of mineralization, and guidelines for interpretation require a sound knowledge of the geological and secondary processes operative in the area."

Jan 1, 1980

By Nitin Bhavsar, Kaushik Vakil, Lakshmikanth Reddy, Sanjay Sarkar, Tathavadkar. Vilas, Bhavin Desai, Raghavendra Adiga

Gold and platinum group metals (PGM) do not dissolve in sulfate electrolyte from anode during electro-refining of primary copper. The PGM form solid ‘slimes’ which accumulates at bottom of the electrolytic cell. Typically, 8 to 10 ppm silver is present in copper cathodes, which is equivalent to almost 2% of silver loss during electro-refining. The silver can be cemented with cathode copper as soon as it is dissolved into the electrolyte from anode or during entrapment of slime particles in cathode. Over a period of time, the concentrates grade has deteriorated and change in type & amount of impurities in concentrate has resulted in higher silver loss during refining process. Therefore, an in-depth investigation was carried out in both fire- and electro-refining processes to understand the root causes of higher silver loss in copper cathodes. The detailed characterization and the plant data analysis were carried out. The results of study revealed that higher silver loss in 3rd crop cathodes as compared to 1st and 2nd crop cathodes from same anode. In anode silver was present in two forms, dissolved in copper (solid solution) and in slime phases such as Cu2-xAgxSeTe. SEM-EDX study of anode cross section confirmed higher silver and oxygen content in central region (core) of anode as compared that in both air and mold sides. This is due to non-uniform cooling of anode which was confirmed by the solidification modeling. Higher concentration of oxygen & silver at core of anode rised Ag+ concentration in electrolyte and slime particles during 3rd crop. The results of study were used to optimize the anode cooling process and also electrolyte chemistry to reduce the silver loss. The details of study carried out are discussed in this paper using the results of modeling, characterization and experimental studies. INTRODUCTION In the electrolytic refining of copper, fire refined copper anodes are used as raw material. Anodes contains copper of the range 99.5 to 99.6%, rest being the impurities. Hence, the purpose of the refining is (1) to remove the impurities so that final cathode conforms to the LME specifications and also (2) to recover the precious metal from the anode copper. When anode is dissolved, most of the impurities reports to the anode slime settled at the bottom of the cell, and rest dissolves in the electrolyte. Dissolved impurities remains in electrolyte and are removed during electrolyte recycling. However, sometime dissolved impurities and slime particles get entrapped in cathode due to disturbances in operational conditions. Metals dissolving in the electrolyte are the elements such as Ni, Co, Fe, Zn. The electrode potential of As, Sb and Bi being close to that of copper, these elements partly dissolve in the electrolyte. Noble metals like Ag, Au, Pt and Pd are generally insoluble and are thus expected to report to the anode slime. A small amount of the sliver content from the anode is dissolved in the electrolyte. Because the dissolved silver electroplates on the cathode at a smaller applied potential than copper, the cathode typically contains up to 8 ppm of silver. This is referred to as ‘silver loss’ in cathode (Cooper, 1987). Fortunately, silver is a rather benign impurity in copper due to its electrical conductivity being higher than copper. However, higher silver loss in cathode is loss of revenue for Copper smelter due to significant difference in their LME price.

Jan 1, 2019

The cost benefits of controlling dilution of extracted ore have been very well understood by miners and mining professionals for many years. However, as we strive towards more mechanization, the dilution factor has been compromised in order to fit ?equipment? that is better suited to provide improved safety and productivity. Alternately, the drilling and ground support is accomplished by handheld drilling. In 2007, a short study, commissioned by CAMIRO (Canadian Mining Industry Research Organization) on the safety of hand held drilling vs. mechanized drilling, concluded that the risk of injury with handheld drills was seven times greater than with mechanized drills. Armed with this data, MEDATech Engineering proposed to the CAMIRO group to fund development of a ?MICRO Bolter?.

May 1, 2009

By J. Jankovic

Numerous advantages have been recognized for solid oxide fuel cells (SOFCs) operating at temperatures of 500-700°C. However, there are several issues related to low temperature SOFCs, such as high electrolyte resistance and high electrode polarization. One of the routes to enhance the electrode performance, particularly for the cathode, is to use new materials with optimized microstructure. In this work, the plasma-spraying technique, recognized to have several advantages over presently used deposition techniques, was used to deposit cathode materials onto ceramic and stainless steel substrates to obtain highly porous structures. Cathode materials with composition of Lao 6Sr0.4Co02Fe0 8O3 (LSCF) were employed in the powder form. The LSCF was prepared from powder precursors with different pore formers and binder levels, or from already produced, single-phase LSCF. The (La0.8Sr0.2)0.98MnO3 (LSM) cathode material was also processed for comparison purposes. The deposition process was developed to obtain coatings with good bond strength, porosity, film thickness and residual stresses. The phase and microstructure of deposited materials were characterized using XRD and SEM.

Jan 1, 2005

By D. Maddocks

"IntroductionThe greater part of the iron ore industry in Canada is located along the Labrador-Quebec border on a geological formation known as the Labrador trough. The Labrador trough is a 700 · mile long geosynclinal segment composed of folded and faulted Proterozoic sediments, volcanics and intrusives, extending from Gagnon, Quebec, to the north west tip of Ungava Bay. This geosyncline can be divided into three parts (Fig. 1).The northern unmined part, extending from southern to northern Ungava Bay, is a low grade metamorphosed iron formation.The iron deposits of the central region, represented by Schefferville, are hematite-limonite ores formed by oxidation and leaching of an unmetamorphosed taconite formation. Average iron content of the ore is greater than 540Jo for direct shipping and 50% for plant feed.The deposits of the southern section (Carol Lake, Wabush, Mt. Wright, Gagnon) extend from just north of Carol Lake to Gagnon and is a metamorphosed silica-iron oxide (specular hematite and magnetite) formation averaging plus 30% iron.The mineral wealth of this area was first observed by Father Louis Babel about 1870 and again by Dr. A.P. Low of the Geological Survey of Canada in 1894. However, the remote location hindered development until after 1945. First production of direct shipping ore from Schefferville was in 1954. Production at Carol Lake commenced in 1962.This area now accounts for sixty million long tons (61 Mt) per year of processed iron ore products as follows:This chapter will concentrate on pelletizing and agglomeration as experienced at the Iron Ore Company's Carol Lake operation. However, whenever possible, reference will be made to alternate methods, procedures, equipment, etc."

Jan 1, 1989

By C. A. Sosa-Blanco

Minera Sabinas in central Mexico treats a complex sulfide ore containing galena, chalcopyrite, sphalerite and argentite as valuable minerals, and in some cases important amounts of non-magnetic pyrrhotite. For high pyrrhotite ores, results obtained by selective flotation showed good grades and recoveries in the lead-copper circuit, but a commercial zinc concentrate could not be produced due to the high floatability of pyrrhotite. When this is the case, an alternative method was proposed to produce a bulk concentrate by flotation which is then leached to recover copper and zinc from liquor in a SX-EW circuit. Leaching was conducted in an autoclave in order to study the effect of temperature and pressure, but bioleaching tests were also conducted. Leaching lead-silver residues were treated by cyanidation in order to recover silver values. The results obtained by selective flotation and by bulk flotation with leaching of the bulk concentrate showed that the latter alternative increased zinc recovery by 30 % with similar recoveries of the other metals.

Jan 1, 2007

By Robert B. Parsons

"On February 15, 1984 Finance Minister Lalonde presented to Parliament a budget heavily flavoured with the current consultative mood of the Government. Notably absent from the budget was the typically long list of tax changes of immediate effect. Instead, the bulk of the budget papers consisted of a wide variety of white papers on significant topics that would have a far reaching impact on the future of all Canadians.This month. Tax Notes examines the highlights of Mr. Lalonde's budget.IntroductionThe mining industry need not feel slighted in Finance Minister Lalonde's budget of February 15, 1984: the budget offered very little that would have an immediate impact of significance on any sector of the economy. Apart from some welcome announcements for the oil and gas industry to postpone the implementation of certain negative tax changes, the budget was surprisingly scant in terms of definitive tax proposals.While massive revisions in the rules relating to pensions, small businesses, commodity taxation and profit-sharing were brought forward, many of these proposals are set out in White Papers or other documents to be implemented into legislation only after further consultation. Canadians will accordingly have to wait for such promised benefits as increased RRSP and other pension contribution limits."

Jan 1, 1984

By T. Niedoba

Coal as an energetic raw material is characterized by many features that determine its quality. The data concerning coal are usually treated as independent values, despite the fact that this kind of approach is not always appropriate. In the paper the dependencies between sulfur contents and volatile components in coal and particle size and density were analyzed. The method of ordinary kriging is applied to experimental data to describe this relationship; this method can be used for particles of any size and density. An example of the application of this technique is presented for energetic coal Type 31, originating from one of the Polish hard coal mines in Upper Silesia. Results from ordinary kriging are in good agreement with experimental results. Similar analyses can be performed for other properties of coal material, such as ash content, Roga number, and moisture. On the basis of the data obtained by ordinary kriging, a more comprehensive multidimensional model is described, which can characterize certain deposits or strata from which the analyzed materials originate. This is superior to basing the model only on experimental data, which often is limited by size of the sample. The results obtained by ordinary kriging applied to various types of coal would allow more precise analysis of individual properties of the studied materials and increase the ability to determine significant differences between them. This method can be also applied to other types of mineral raw materials, such as copper ore.

Aug 1, 2013

By Robert MacPhail, Louis Racine, Bret G. Cousins

"Sodium Isopropyl Xanthate is employed in a wide variety of sulphide flotation procedures due to the specificity over other xanthates and the cost savings over other sulphide collectors such as thionocarbamates, xanthogen formates and dithiophosphates. An investigation carried out by Tennants Research Technology Applications (TRTA), has produced a chemically enhanced SIPX that has shown all the advantages of normal SIPX along with improved recoveries.Currently, FLEX 31 is manufactured at the Prospec Chemicals xanthate plant in Fort Saskatchewan, Alberta, Canada. Prospec, founded in 1983, produces approximately 4500 tonnes of xanthates per year and is presently undergoing expansion to produce approximately 6000 tonnes. The proprietary process for FLEX 31 is a new addition to plant operations that include the production of xanthates, thionocarbamates and xanthogen formates.This paper will cover the testwork on the zinc flotation circuit at the Louvicourt Mine in Val d'Or, Quebec. This testwork indicated that FLEX 31 could replace SIPX due to the ability of the FLEX to improve zinc flotation kinetics without adversely affecting final concentrate grade. FLEX has presently replaced SIPX in the zinc circuit at Louvicourt.BackgroundThe Louvicourt deposit is hosted by greenschist facies Archean volcanic rocks located in the southeast portion of the Abitibi Greenstone Belt. In the Val d'Or area, the volcanic rocks form an east-west striking, steeply dipping and south-facing sequence composed of thick mafic and ultramafic flows of the Lower Malartic Group.The joint venture has three partners-Aur Louvicourt Inc. (30%), Novicourt Inc. (45%) and Teck Corp (25%). Aur Resources holds 30% interest through Aur Louvicourt, a wholly owned subsidiary and is the operator of the project. Novicourt Inc. is 60.9% held by Noranda.Approximately 75% to 85% of Louvicourt's revenue comes from the sale of copper; 10% from gold (in the copper concentrate); 7% from zinc and 3% from silver (also in the copper concentrate) The copper at Louvicourt is fairly ""fast floating"". About 60% of the copper in the ore can be concentrated in the first flotation cells with feed grades of approximately 4% copper.The initial testwork and pilot trials had indicated that it would be difficult to achieve zinc grades over 52% and recoveries would have to be kept at a level amenable to salable concentrate grades. The actual mill results, with a fine regrind, achieved zinc grades of 55% to 56% at about 75% recovery."

Jan 1, 1996

By Mehmet F. Taner

"Abstract - The East Sullivan Stock (ESS) is a small, composite felsic alkaline pluton of presumed late Archean age in the Val d’Or mining district. Three main facies have been distinguished: monzonite sensu stricto, porphyritic monzonite, and green trachytic porphyry. This monzonitic group of rocks is of relatively homogeneous composition with high abundances of Na2O, K2O, Ba, Sr, Rb, Zr, Mo and LREE. The alkaline ESS is distinguished from other igneous units in the Val d’Or mining district, such as the Bourlamaque Batholith, by relatively high concentrations of Ba, Sr, Rb, Mo, Cu and Au. The ESS hosts many base (Cu, Mo) and precious (Au) metal occurrences, including: (1) porphyry style Cu-Au-Mo disseminated sulfide deposits, (2) Cu-Au deposits in volcanic rocks near the ESS contact, and (3) pyritic gold mineralization in east-west trending shear zones. The ESS is well defined by concentrical zoning on the aeromagnetic vertical gradient color map, and displays four linear trends, which are assumed to be structural lineaments, at 035°-055°, 320°-300°, eastwest, and north-south. The main mineral occurrences related to the stock display a preferred spatial association with the east-west linear magnetic trends.The ESS is preferentially located along a major structure and was emplaced late in the evolution of the Abitibi subprovince like other felsic alkaline plutons. This stock is similar to late-tectonic mineralized felsic alkaline intrusions of the Kirkland Lake and Larder Lake mining districts in Ontario, and to the Allard stock in the U.S.A. which is associated with gold and base metal mineralization. Similarities also exist with younger alkaline plutons associated with Cu-Mo-Au porphyry deposits in the Canadian Cordillera, which formed in tensional tectonic environments. The felsic alkaline magma may have formed by partial melting of deeply buried supracrustal rocks, concomitant with the development of deep fractures such as the Cadillac Fault. In such an environment, hydrothermal solutions carrying remobilized metals from deep supracrustal rocks may have deposited gold and base metals in structural traps. Plutons similar to the ESS should be good targets for mineral exploration. Résumé - Le Stock de East Sullivan (SES) est une intrusion composite alcaline d’âge tardiarchéen, situé dans le camp minier de Val d’Or. Trois principaux faciès ont été identifiés: une monzonite sensu stricto, une monzonite porphyrique et un porphyre trachytique vert. Les données chimiques montrent que ce groupe des roches monzonitiques est relativement homogène en composition avec des concentrations élevées de Na2O, K2O, Ba, Sr, Rb, Zr, Mo et ETRL, définissant une suite alcaline typique. Cet alkalin stock peut être facilement distingué des autres unités géologiques de la région de Val d’Or, tel le batholite de Bourlamaque, par une concentration élevée de Ba, Sr, Rb, Mo, Cu et d’Au. Le SES contient plusieurs importants prospects de métal précieux (Au) et de métaux de base (Cu, Mo), incluant: (1) une minéralisation disséminée de type porphyre Cu-Mo-Au, (2) une minéralisation de Cu-Au dans les roches volcaniques encaissantes hôtesses près du contact et (3) une minéralisation d’or pyritique dans une zone de cisaillement de direction est-nordest. Le SES est bien défini sur la carte aéromagnétique en couleurs du gradient vertical par des zonages concentriques, où quatre linéaments structuraux ont été reconnus: 035°-55°, 320°-300°, est-ouest, et nord-sud. Les principales zones minéralisées spatialement associées au stock sont généralement situées soit près des linéaments magnétiques est-ouest, soit le long de ceux-ci.Le SES semble s’être mis en place le long d’une structure majeure, développée tardivement dans l’évolution de la Sous-province abitibienne, comme les autres plutons alcalins felsiques. Ce stock est similaire à la suite tardi-tectonique d’intrusions alcalines minéralisées des camps miniers de Kirkland Lake et de Larder Lake en Ontario, ou"

Jan 1, 1996

By T. Marolt, J. Likar, E. Grøv, J. Žarn

"Underground structures are an integral part of the infrastructure of modern society and are used for a wide range of applications, including subways and railways, highways, not at least nuclear facilities. When the wider area is subject to earthquake activity, underground constructions should be analyzed on seismic and static loading. Observations showed that the underground structures have significantly less seismic risk than surface structures. Available methods allowed analyzing the magnitude of risk for different input parameters of seismic loads in different ground environment. Simulation of earthquake loading on underground structures, in the present paper is given the various aspects of analyzing the potential damage and instability of underground facilities. INTRODUCTIONThe development of methods and computing resources used for para-seismic engineering has finetuned the evaluation of the seismic strength of buildings and equipment. Reinforcements may therefore be decided, not simply on the basis of a reassessment of the hazard, which constitutes input data for the calculation of structures and equipment, but also on the basis of developments in para-seismic engineering. Underground facilities are an integral part of the infrastructure of modern society and are used for a wide range of applications, including subways and railways, highways, material storage, and sewage and water transport and not at least nuclear facilities. Although in the past showed that the underground structures are significantly less seismic risk than on the surface, the professional researches and their results are accessible. Seismic resistance of underground structures is analyzed from several aspects. The currently available methods allowed analyzing the magnitude of risk for different input parameters of seismic loads in different ground environment. For better interpretation of earthquake loading on underground structures, are given below the various aspects of analyzing the potential damage and instability of underground facilities in rock. One of the early studies which covered this are of investigation were prepared by Dowding and Rozen (1978). They grouped damages due to earthquakes in underground structures into three main categories:- damage from ground shaking- damage from fault dislocation- damage by earthquake-induced ground failures (e.g. liquefaction and landslides)."

Jan 1, 2015

By Lawrence Melis

Fission Uranium Corp.’s Triple R Uranium Deposit at its Patterson Lake South Project is located in northwest Saskatchewan in Canada’s Athabasca Basin. As part of pre-feasibility studies for the project a detailed metallurgical test program was completed to provide process design criteria. The testwork program encompassed preparation and analysis of test composites, comminution testing, uranium acid leaching, liquid-solid separation, solvent extraction of uranium, precipitation of uranium yellowcake products, tailings and effluent treatment, tailings physical and chemical characterization, and environmental testing of prepared tailings, as well as investigations of gold and silver recovery from the mineralization. The paper provides mineralogical information, testwork methodologies and test results which were used to arrive at process design criteria and the selection of the process flowsheet for the project.

Jan 1, 2020

By V. A. G. Preto, W. H. White, J. E. Harakal

Potassium-argon age dating performed recently on intrusive rocks from Copper Mountain indicates that the satellite Smelter Lakes and Voigt stocks have radio-metric ages which are indistinguishable from that of the Copper Mountain stock, as determined by Sinclair and White (1967). The complex of intrusive rocks known as the Lost Horse Intrusions also yields essentially the same radiometric age, as do biotite-sulphide-pegmatite veins on Copper Mountain.

Jan 1, 1971

By James D. Hall

THIS essay deals with the materials and methods used in the waste filling of scopes in Canadian mines, with especial reference co the methods used at the Sullivan mine, Kimberley, B.C. The author would like to thank members of the staff of the Sullivan mine for information obtained, and acknowledges material from the following publications: Waste Filling of Stopes: Information Circular 6816, U.S. Bureau of Mines. Mining Methods and Practices at Lake Shore, by Leslie S. Weldon; Trans., C.I.M. & M., Vol. XXXIX, 1936, pp. 142-202. Development and Mining (at the Mcintyre Mine), by D. E. Keeley; Eng. & Min. Journal, November, 1933. INTRODUCTION Although mining in Canada is a relatively youthful industry, many of our mines have reached a stage of extraction which requires waste filling, both as a means of support and co make possible the winning of ore that would otherwise have co be left in the mine. Fill may be used at regular intervals as one of the cycle of operations, as in cur-and-fill and square-set scoping; or it may be introduced into a completed stope co provide permanent support for overlying rock formations, and co permit mining of pillars of valuable ore. Waste fill is sorted in resuing, which is a form of cut-and-fill scoping employed in narrow veins.

Jan 1, 1937

By Denni Nikols

"Planning for coal beneficiation in the electric utility industry is relatively complex, involving the coordination of experts and specialists in a broad range of fields, as well as compliance with a wide variety of government regulations.This paper examines the role of the planner, reviews possible benefits of coal beneficiation, identifies potential problems and illustrates a typical planning schedule.The steps involved in the planning process are:Step I-Bench- and pilot- washability studyStep 2- Wash plant designStep 3- Power plant and boiler designStep 4-Mine designStep 5-Major environmental and technical problems to address.IntroductionElectrical utilities and coal have a long and intimate relationship . Cleaned coal is becoming an increasingly popular fuel with the utilities for a variety of reasons. Generally, the greatest impetus to burn a cleaned or prepared coal fuel comes from the need to control airborne pollutants.Long-range planning is a standard practice for electric utilities, forecasts of demand must be made well into the future. Since the lead time required to provide new facilities is often as long as 10 years and the cost very high , planning becomes an important task.For a utility that owns and directs the operation of its coal mines, the mine planning or fuel acquisition planning takes on the magnitude of other corporate planning functions. It is from this perspective that a utility would view coal preparation. Except for the interaction of a coal-fi red plant on the actual mine design the planning considerations o f a beneficiating facility for a captive mine or a contract raw coal supply are about the same. Because TransAlta Utilities is currently supplied from captive mines, this discussion will tend to focus in that direction.It is the role of a planner to plan. This is easy to say but it is not always easy to do. Often we are working within a context that resembles the geological time scale. Frequently the objectives are not clearly defined when we begin and ultimately our plans are tested in the waters of government regulations and cost benefit analyses .Planning for beneficiation of Plains coal, or any coal, provides just such a test. The planner's role in this endeavour requires a wide vision. While parts of the process may be amenable to classical methods of project scheduling, the broad range of subjects and interaction of seemingly unrelated tasks is sure to obscure some of the considerations that must be made. Therefore, the planner's chief role is coordinating the work of many experts and specialists toward the final objective.Among the specialists are combustion , geo technical, mining, civil , and mineral processing engineers , geologists, hydrogeologists, soil, and reclamation experts to list a few.When one considers coal beneficiation, the planning part o f that consideration is probably more complex than any other single engineering function. Due to the company's location in the Alberta Plains and the proximity o f the mine to the thermal generating station, this paper will tend to emphasize that situation.Beneficiation may offer some advantages over run-of-mine coal to the power plant opeator. Some of these advantages are: removal of a contaminant, power plant efficiency gains , lower plant capital costs (for new plants), possible lower mining costs."

Jan 1, 1984

By F. Dubuc

"The Adams Mine of Jones & Laughlin Steel Corporation is situated on the Boston Township iron range near Kirkland Lake, Ontario. Eight different orebodies have been outlined, with a total open-pit crude tonnage of. about 100,000,000 tons or the equivalent of 30,000,000 tons of concentrate. The ore consists of fine-grained, well-bedded Early Precambrian iron-formation composed essentially of alternating layers of chert and magnetite. Grade averages about 22 per cent magnetic Fe.The iron range varies in width from 3,000 to 4,000 feet and is made up of several horizons of iron-formation, cherty ""quartzite"" and volcanic rocks. The latter consist mostly of basic lava flows and minor amounts of tuff. Dips are rarely Jess than 50 degrees, and the range is believed to represent an overturned limb of a major synclinal structure. Dykes of syenite and lam prophyre, along with local younger diabase, intrude the rocks of the iron range."

Jan 1, 1966

By K. S. Raja, B. McNall, B. Pesic

"High-level radioactive wastes are stored in large underground storage tanks made of low-carbon steel. The wastes consist of concentrated solutions of sodium nitrate (NaNO3) and sodium hydroxide (NaOH), and the radionuclides 137Cs, 99Tc, and 90Sr. The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV), which in turn modifies the kinetics of corrosion of the storage tank. To understand the influence of technetate ions on the corrosion of steel, electrochemical polarization studies of A 537 steel samples were carried out in 1 M NaNO3 + 0 .05 M S r(NO3)2 + 0.1 M NaOH with and without addition of HReO4 at different temperatures (24 – 85 °C). The concentration of HReO4 was varied from 0.014 – 0.04 M.INTRODUCTIONAqueous processing of spent nuclear materials generates a large amount of high-level radioactive wastes. The wastes are primarily salt solutions of sodium hydroxide and sodium nitrate which also contain fission products such as 137Cs, 99Tc, and 90Sr. Among the high level radioactive fission products, Tc-99 is of great importance because of its high concentration, long half-life (2.1 x 105 years), high solubility in geologic waters as technetate, and rapid diffusivity through the geologic systems. The solubility of technetate ions varies depending on the oxidizing conditions prevailing in the storage containers. High level radioactive wastes are stored in single shell or double shell tanks made of low carbon steels such as ASTM type A15, A516-70 and A537. Most of the available literature on corrosion of steel in simulated radio active waste environments pertains to nitrate induced stress corrosion cracking (Subramanian & Mickalonis, 2005). The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV). Corrosion of steel and formation of Fe(II) and Fe(III) will affect adsorption and reduction of Tc species. The radioactive species can irreversibly be sorbed on the steel surface by oxidation of Fe(II) to more stable Fe(III) and fixed as less soluble Tc(IV)/Fe(III). The solubility of Tc species is also affected by other factors such as dissolved oxygen, local pH, temperature etc. How the corrosion behavior of steel will be affected in the presence of Tc species is not clearly understood.Cartledge (Cartledge, 1960) demonstrated that passivation of iron can be achieved in the presence of oxygen along with suitable inhibitor ions/molecules of the general formula XO4 n-, such as pertechnetate (TcO4 -). The pertechnetate ion is univalent. Since it is derived from a strong acid, no buffering action can be expected from this ion. The redox potential of the reaction (1) is 0.738 VSHE (Pourbaix, 1974)."

Jan 1, 2012

By Edward R. T. Tiekink

Metal complexes continue to find therapeutic applications for the treatment of a wide variety of human ailments. Amongst these, gold(I) thiolates are used to treat rheutmatoid arthritis but, usually in combination with other treatment or as a last resort. New therapeutic uses of gold, both as gold(I) and gold(III), are being sought, including against cancer, the focus of the present contribution. It will be demonstrated that certain gold(I) complexes show exciting cytotoxicity profiles, rivalling those of cisplatin and standard chemotherapeutic agents. More importantly, anti-tumour activity is demonstrated in vivo, albeit in a mouse model. The presentation will give a brief overview of ?metals in medicine? with a focus on gold and will summarise some recent advances in the development of goldbased anti-tumour agents.

Oct 1, 2003