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By B. Simonian

"The Mount Milligan mine, located in central British Columbia, began operation in September 2013 with a design nameplate capacity of 62,500 dry metric tonnes per day, using a conventional SABC grinding circuit followed by bulk sulphide flotation. Over the last few years, many changes have been implemented in order to debottleneck and optimize the comminution circuit to meet and exceed the nameplate design capacity as well as improve the metal recovery of the flotation circuit. This paper discusses changes, grouped into mechanical modifications, projects, and operational changes. The implementation of these changes as well as ongoing challenges and potential solutions will also be discussed.INTRODUCTION The Mount Milligan mine began production in the fall of 2013. It is a conventional truck-shovel open pit gold and copper mine and concentrator with a 62,500 tpd design capacity copper-gold flotation processing plant. The average head grades for the life of mine are 0.18% Cu and 0.39 g/t Au. At full capacity, the mine produces an average 400 dry tonnes per day of copper-gold concentrate containing approximately 21.5% Cu and 50-60 g/t Au. Current mine life is 21 years. This paper will discuss a selection of the operational, engineering, and administrative changes that have been made at the site since the publication of An Update on Reaching Nameplate Throughput and Continuous Improvement at Mount Milligan (Yue, 2017). PLANT FLOWSHEET CONFIGURATION Run-of-mine ore is crushed through a 60-110 gyratory crusher to a top size of seven inches. Up to 100% of the gyratory crusher product is diverted to the secondary crushing circuit by a moveable gate. The material diverted to the secondary crushing circuit is fed to a vibrating double-deck screen. The screen oversize is placed on a surge pile and reclaimed by four vibrating feeders to feed two 1250 kW standard head cone crushers in open circuit. The screen undersize is combined with the crusher discharge and returns to the conveyor feeding the coarse ore stockpile along with primary crusher product that by-passes the diverter gate."

Jan 1, 2019

By M. Sagedahl

The off gas from a smelter is cooled and dust removed in an electrostatic precipitator before approximately 95% of the sulphur dioxide (S02) is converted to sulfuric acid. However, the tail gas may need to be polished to remove the rest S02 to meet demands. A flue gas desulphurization (FGD) system, as usually applied to S02 removal on coal and oil fired Power Station, is suitable for polishing tail gases from copper smelters. The ALSTOM Seawater FGD process makes use of the alkalinity in the seawater to absorb and neutralize S02. Before being returned to the sea, the seawater is treated to comply with environmental regulations. As the ALSTOM Seawater FGD process uses no reagent and produces no byproduct, it is extremely cost-effective for coastal installations. The first SWFGD plant started operation in 1968. Over 60 of these units have been installed worldwide. The ALSTOM Seawater FGD process removes S02 from flue gas flows corresponding to a total of 70,000,000 Nm3 /h. Suitable for thermal power stations, smelters and oil refineries, ALSTOM Seawater FGD plants efficiently treats flue gases in the range of 300,000 Nm3/h to 2, 700,000 Nm3 /h per FGD plant, containing 20 - 6,500 ppm of S02.

Jan 1, 2007

By A. Roy MacLean

"In the Maritimes, there are twelve coal areas. From east to west, these include the Sydney coal field, the St. Rose - Chimney Corner, Inverness, Mabou, Port Hood, Pictou, Colchester - Debert, Springhill, Joggins - Chignecto, Beersville, Lake Stream, and Minto. The first eight are in Nova Scotia while the remaining four are in New Brunswick.In all these areas, the coal was formed during the Carboniferous period, which existed some 300 million years ago. However, within this period not all coal formation took place during the same time. There were three main intervals, which occurred at the time that the Riversdale, Cumberland and Pictou groups were laid down (Hacquebard, 1970). The oldest coals are those of the Riversdale Group. These coals were of rather limited extent, and only a few mineable seams are present, particularly at St. Rose -Chimney Corner and Port Hood. From these two areas only 2 M tons have been extracted, and 'measured' resources of 7 and 9 M tons respectively remain. The Cumberland Group coals are confined to Cumberland County and include the coals of Springhill and Joggins River Herbert -Chignecto. Some 43 M tons have been removed and only 7 M tons of 'measured' coal remain, with an addit10nal 39 M tons of 'inferred' resources. However, there are additional resources at Springhill, which will be discussed in more detail in a later section. The coals of the Pictou Group are the youngest and the most abundant, both in actual number of seams and in regional distnbution. These coals were formed during the Westphalian C and D, a time during which the main coal deposition in Europe also took place. Here belong the coals of the Sydney, Inverness, Mabou, Pictou, Debert, Beersville, Lake Stream and Minto fields. Their total production amounted to 469 M tons or 91 % of the Maritime total of 514 M tons. The remaining resources of all Pictou Group coals have been calculated at 254 M tons of 'measured' coal and 949 M tons of 'inferred' coal. As can readily be seen, the bulk of both past production and remaining resources occur in the Sydney coal field. The Sydney figures represent 73% of total production, and 87% of total 'demonstrated' resources in the Maritime Provinces. Next to Sydney, the Pictou coal field has been the greatest producer, with 59 M tons; it also has the second largest 'measured' resources, amounting to 25 M tons. However in terms of 'inferred' coal resources, the Mabou coal field, ~ith 140 M tons, ranks second to Sydney."

Jan 1, 1985

By Réal Tanguay, Mathieu Piché, Jacques Carignan, Charles Beaudry, André Bonenfant

"Le gisement Isle-Dieu est situé sur le flanc sud de l'anticlinal de Galinée. La stratigraphie locale comprend, de bas en haut, la rhyolite du Groupe du Lac Watson surmontée par le basalte du Groupe de Wabassee. Un horizon repère, siliceux et sulfure, d'origine sédimentaire, appelé ""Tuffite Clef', est présent au sommet du Groupe du Lac Watson et pend à 45° vers le sud.Le gisement Isle-Dieu est constitué par une lentille qui recoupe, en partie, la ""Tuffite Clef"". Elle est séparée en deux trorçons par un dyke de tonalite. Les données obtenues à partir des forages effectues à travers la rhyolite sous-jacente permettent de définir les zonations chimiques et pétrographiques de la cheminée d’altération.Ces transformation minéralogiques et chimiques sont caractérisées par un enrichissement en MgO, Fe2O3, MnO et un appauvrissement en CaO, SiO2 et Na2O. La zonation spatiale de ces altérations permet de mettre en évidence la géométrie et l'extension des conduits hydrothermaux. L'épaisseur maximale des sulfures massifs au sein de la lentille est en étroite relation avec l’importance des zones d'altération. Les patrons de variations chimiques dénotent une orientation préférentielle WNW des conduits hydrothermaux. Les parties les plus altérées et les plus déformées présentent localement de fortes variations positives en Zr, Nb, et terres-rares; ces concentrations sont vraisemblablement imputables a /' enrichissement résultant de la diminution du volume lors de l'altération.L'étude pétrographique montre que la porosité et la perméabilité du milieu ont joué un rôle important dans la circulation des fluides car les roches de la cheminée présentent des phénomènes de dévitrification, de bréchification et de microfracturation très prononces. La nature magnésienne de certaines chlorites et la perméabilité accrue du milieu semblent en accord avec le modelé propose par Roberts et Reardon, ( 1978 )"

Jan 1, 1990

By N. V. Mel'nikov

This paper discusses the reserves of oil, natural gas and coal in the USSR, with particular attention to the future role to be played by coal in supplying the energy fuel resources of the country.

Jan 1, 1972

By R. G. Helberg, S. M. Rebelo

"Copper and cadmium are removed from the zinc sulphate solution in primary purification by cementation reaction followed by filtration. The solids are sent to the cake leach section where zinc and cadmium are recovered from the copper rich slurry. The copper solids from cake leach are filtered, bagged and sold. In order to achieve a lower cadmium copper cake, an altered process flow is suggested. It is proposed the primary purification be split into two steps for individual removal of copper and cadmium. INTRODUCTIONCopper cake is a product of primary purification, also known as copper and cadmium removal. Copper and cadmium are removed by cementation reaction in four stirred reaction tanks. The slurry is then filtered through Shriver manual plate and frame presses with the solution advancing to the next stage of purification, hot zinc purification (HZP). The solids from primary purification are further processed at the cake leach section where zinc and cadmium are separated from the copper rich slurry. Cadmium and zinc are dissolved in the cold cake leach tanks using spent electrolyte. Cadmium is recovered from this cadmium rich solution by cadmium sponging, leaching and electro-winning circuits. The residue from this cold leach step is further leached using spent electrolyte at a temperature of 85°C. The copper rich solids from hot cake leach are filtered on a drum filter and bagged in 1 ton bulk bags for shipping to buyers.Current assays of copper cake are shown in Table 1. The goal is to produce a copper cake product that is below 0.5% cadmium."

Jan 1, 2012

By Charles Camsell

THE Northwest Territories covers a very large area-more than one-third of all Canada-and its most northern point, Cape Columbia in Ellesmere island, is distant only 500 miles from the Pole. Our first knowledge of the Arctic Archipelago, of which Ellesmere island forms a part, resulted from a gold-mining venture in Queen Elizabeth's reign. The English navigators of that time were eager to find a north-westerly and shorter and Jess hazardous route to the riches of China and Japan than that which Magellan had discovered, but they were unaware that the continent then known to bar a direct route extended in great width far to the north. Frobisher was one of these navigators. He reached in 1576 the bay in Baffin island now named after him, convinced that he had found a passage connecting the Atlantic with Asiatic seas. Forced to re-turn after ordeals in which ice, wind, and Eskimos flayed formidable parts, he brought back, among other novelties, a piece o black stone which had been picked up casually by one of his officers, and gave a little of it to the wife of one of the venturers, or financial backers of the enterprise. To quote now from Hakluyt: ? 'She by chance threw and burned it in the fire so long that , at length being taken forth and quenched in a little vinegar, it glistered with a bright marquesset of gold. Whereupon the matter being called in sorne question, it was brought to certain goldminers in London to make assay thereof, who indeed found it to hold gold and that very richly for the quantity." On the strength of this, the venturers, anticipating much profit, launched a second expedition to secure more of this stone, and 143 persons, including 14 miners and finers, set forth in 1577 and returned the same year, with, however, 200 tons of another mineral. Influenced by glowing accounts of veritable mountains of this mineral and by assays made after "additaments"-that is how "salting" in those days was described-the venturers, including Elizabeth, supplied funds for erecting a smelter and refinery at Dartford and outfitting a stilllarger expedition. And so, in 1578, fifteen ships departed with the Queen's blessing, for the same remote shores. After many mishaps, they returned with over 1,000 tons of the mineral, but when it yielded very little of value at the works in Dartford, the? Company of Venturers was forced into liquidation. Though our first prospector and miner was rather inconsiderate of the investors, he proved the existence of an archipelago, hitherto unknown, and secured much information about the new land and its dwellers.

Jan 1, 1938

By G. S. Hume

"THERE HAS BEEN a marked growth in the petroleum industry in Canada since the end of the war. The rate of growth in the demand for oil products has exceeded that in United States, although the per capita consumption is still less. Estimates of the consumption of petroleum and petroleum products in Canada in 1951 are approximately 154,000,000 barrels, which is slightly more than 11 •barrels per capita, whereas the estimated consumption in United States for the same period, according to World Petroleum, is placed at 2,619,- 970,000 barrels. This, on the basis of a population of 154,000,000, would be equivalent to 17 barrels per capita. The increase in consumption of the petroleum and products is world wide. World production in 1951 has been estimated (Oil and Gas Journal) at 11,700,000 barrels a day or more than 41;4, billion barrels for the year. United States production increased 13.7 per cent to 6,143,000 •barrels a day and Canada'.s ,, total production increased about 65 per cent from a total of 29,091,235 •barrels in 1950 to an estimated (Dominion Bureau of Statistics) 48,096,800 barrels in 1951.The trend to use increased amounts of petroleum and petroleum products, particularly in the United States and Canada, has also been supplemented by increased use of natural gas. The rate of expansion of the consumption of natural gas in United States in the past few years has been very rapid, increasing from 2,600 billion cubic feet in 1940 to 5,975 billion in 1950, with the proven reserves in the same period increasing from 85,000 billion to 186,000 billion cubic feet."

Jan 1, 1952

By N. Schmalbein, L. von Ketelhodt, L. Kotelo

"The mining industry continues to remain challenged. Lower commodity prices, increasing labor costs and more importantly diminishing reserves are amongst some of the primary factors contributing to the difficulties faced. Ore sorting technologies have demonstrated their potential to improve the downstream beneficiation performance. The general processing route sees all primary crushed material milled for liberation and then processed in accordance with characteristics of the gold therein, i.e.: refractory golds would require direct leaching or oxidation whilst free gold would follow the conventional cyanidation process, after gravity concentration. Ore dilution increases the associated operating costs within each stage of this process. The opportunity to process the same throughput at a higher grade can only be achieved through pre-concentration. Sensor based sorting has been examined on numerous occasions by various gold producers. Test work carried out on different bulk low grade gold ores has shown the successful applicability of ore sorting to remove waste, whilst maintaining high recovery rates of gold. The results of a combined XRT/Laser sensor sorter have shown grade improvements of over 300% from feed grades of 0,25g/t to 1,15g/t at gold recoveries of 66% and waste ejection rates of 85%. This paper presents some of the results from the work undertaken by STEINERT with respect to gold sulphide ore sorting and presents a modelled financial scenario, which can enable a company to target and reclaim low grade ores.INTRODUCTION The mining and minerals processing industry presents with many different challenges including, volatile commodity prices, increasing labor costs and more importantly diminishing reserves. Conventional processing routes will continue to play a crucial role in the beneficiation process, however innovative methods of reducing operating costs and optimizing on the overall circuit performance is where technologies such as sensor based sorting come into the fore. Sensor based sorting as a dry mechanical process not only reduces water consumption by eliminating unnecessary waste but also reduces the requirements for reagents in the downstream processes. Sensor based sorting under dry conditions presents a highly efficient alternative to wet pre-concentration methods such as dense medium separation (DMS)."

Jan 1, 2017

By P. Cheung, J. Gulyas, R. Clary

Over the past 50 years, the use of autoclaves in the metallurgical industry has evolved from final metal recovery (hydrogen reduction) and purification (sulphide precipitate oxidation) to treating whole ores and concentrates. Recent process developments, such as the use of autoclaves for laterite leaching, have necessitated higher temperature and pressure operations, which in turn have seen marked advancements in technology and manufacturing capabilities to keep in step with process demands. This paper will discuss the advances in technology in terms of design, materials and construction of autoclaves and liners, typical dip tube design and geometric layout. This paper will also address specific auxiliary equipment, such as acid and steam injection systems, and components, such as agitator seal systems.

Jan 1, 2004

By W. Tse, D. Wong

Dense medium separation (DMS) is one of several preconcentration methods used for early waste rejection from run of mine ores at relatively coarse particle sizes prior to additional milling and beneficiation. DMS has been used extensively in the coal, diamond and iron ore industries but lab scale and pilot test work has demonstrated successful separation and upgrading of other minerals such as lead, zinc, copper and lithium based ores using DMS. This paper reviews historical dense media systems, results from the pilot scale Condor DMS system as well as associated laboratory heavy liquid separation (HLS) test work.

Jan 1, 2014

By André Chagnon, Yvon Héroux

"Résumé - Cette étude porte sur l'altération de la matière organique et des argiles dans les boues carbonatés dévoniennes du faciès ""F"" de la Formation de Pine Point et ses équivalents stratigraphiques la Formation d'Evie et l'unité bitumineuse de la base de la Formation de Horn River. La matière organique se compose principalement de bitume solide et de quelques fragments de fossiles (organo­ clastes). La majorité des échantillons ne renferment que de l'illite et des interstratifiées illite/smectite.Si on compare les températures d'homogénéïsation (Th = l00°C) des inclusions fluides de la sphalérite et des dolomites associées à la minéralisation aux températures estimées à partir de la réflec­ tance de la collinite (84°C à ll7°C), l'on ne peut pas conclure à la présence d'une anomalie ther­ mique dans le district minier de Pine Point. De plus, la réflectance des organoclastes n'est pas plus élevée dans le district minier de Pine Point que dans les localités plus éloignées des gîtes. L'analyse des minéraux argileux conduit à la même conclusion : aucune anomalie thermique n'est décelable dans les unités échantillonnées à l'intérieur du district minier de Pine Point quelque soit l'indicateur utilisé.La kaolinite et la matière organique altérée, affichant des valeurs anomales de sa réflectance, se trouve essentiellement en présence de soufre et de sulfures. Cela suggère une origine authigène de la kaolinite et une altération de la matière organique reliées au phénomènes de minéralisation.Abstract- The alteration of organic matter and clays is studied in the Devonian Pine Point Formation carbonate muds, ""F"" facies, and its lateral equivalents the Evie Formation and the biturninous unit at the base of the Horn River Formation. The organic matter is mainly composed of solid bitumen with few fossil fragments (organoclasts). Most samples contain only illite and mixed layer illite/smectite.If we compare the Th(l00°C) from fluid inclusions of sphalerite and dolomites associated with mineralization to the temperatures calculated from the reflectanœ (Ro) of the collinite (84°C to 117°C), we cannot detect a thermal anomaly in the Pine Point mining district. This result is based on the reflectance values of organoclasts from the mining district that are not higher than those reflectance values measured on organic matter (OM) away from the ore deposit. A similar conclusion is reached from the clay study: none of the parameters used allow us to identify a thermal anomaly in the samples from the mining district.The kaolinite and the altered OM showing anomalous Ro values mainly occur with sulfides and sulfur. This association suggests an authigenic origin for the kaolinite and an alteration of the OM due to the mineralization events."

Jan 1, 1994

By D J. Murray

This paper outlines the principles of friction hoisting and the components involved, and gives a description of a specific mine hoist. Friction hoisting is compared with conventional drum hoisting, and the depth of shaft at which friction hoists become more economical than drum hoists, with respect to power consumption, is determined. Introduction T HE purpose of this paper is to outline the principles of friction hoisting, to describe the components and to show the advantages of multi-rope friction hoisting. Some calculations are made to show that the power requirements and the initial costs of friction hoists are less than those of conventional drum hoists, once a certain depth of shaft has been reached. The use of multi-rope friction hoists is gradually superseding the employment of the conventional drum hoist in many parts of the world. It results in heavier payloads from deeper levels, an increase in shaft safe-ty and a more compact installation for protection against adverse weather conditions. It was observed that where drums and friction sheaves exceeded 30 feet in diameter, a number of mechanical disadvantages were being experienced;

Jan 1, 1965

By H. W. Parsons

Several low-temperature, dry chlorination processes for the treatment of sulphide minerals are reviewed, in a chronological order. These processes include the following: the Swinburne-Ashcroft, Baker-Burwell, Maim, Comstock-Wescott (Aldermac) and the Mitterburg Mining Process. Dry chlorination investigations at the Canadian Mines Branch (now CANMET) and the U.S. Bureau of Mines are discussed, as is a proposed process by the South Africa National Institute for Metallurgy. The techniques used in the process are discussed, as are the shortcomings, problems and failures of the methods.

Jan 1, 1978

By George P. Demopoulos

For more than 20 years the author had the privilege of working closely on a number of R&D projects with Lucy Rosato and her team at CEZinc. Several of these projects were driven from the sustainability agenda that Lucy Rosato championed as an innovation leader that supported research collaborations. Highlights from this highly rewarding collaboration are to be presented in this paper. In particular we will deal with the following works-topics: (a) iron control via solvent extraction as alternative to jarosite precipitation; (b) production of high-density gypsum by controlled neutralization of simulated zinc plant process/waste waters; (c) selenium removal from weak acid solutions; (d) electrolyte purification by cementation; and (e) manganese control by oxidative precipitation with SO2/O2.

Jan 1, 2015

By Jeanne B. Percival, Paul Ramaekers, Charles W. Jefferson, Pat A. Hunt, Eric G. Potter, Katherine E. Venance, William Davis, Sean A. Bosman

"A 10-cm thick clay-rich layer near the top of the Manitou Falls Formation of the Athabasca Group is unusual in its breccia texture, alteration, and detrital mineral composition relative to the adjacent overlying and underlying sedimentary beds. This layer is composed of angular quartz grains set in an illite >> kaolinite + dickite matrix. Deformed clay-rich fragments within the layer have very similar mineral assemblages. The presence of euhedral accessory minerals including Ti-oxides and aluminophosphatesulphate minerals points to a diagenetic/hydrothermal origin. The presence of individual grains of Kfeldspar and amphibole is unusual relative to the typical Athabasca quartz arenite; originally, these minerals were probably included in detrital quartz and subsequently liberated during fracturing. The textures and alteration characteristics suggest that this layer is a hydraulically-fractured unit, which has experienced hydrothermal fluid alteration - a possible pathway distally related to uranium mineralization Une couche argileuse de 10 cm d’epaisseur pres du sommet de la Formation de Manitou Falls du Groupe d'Athabasca est remarquable par sa texture brechique, son alteration et la composition de ses mineraux detritiques qui different de ceux des couches sedimentaires sus- et sous-jacente. Cette couche est composee de grains de quartz angulaires dans une matrice composee d’illite >> kaolinite + dickite. Des fragments deformes riches en argile dans cette couche presentent des assemblages mineraux tres similaires. La presence de mineraux accessoires idiomorphes dont des oxydes de titane et des aluminophosphates-sulphates suggere que ces derniers ont une origine diagenetique / hydrothermale. La presence de grains de feldspath-K et d'amphibole est inhabituelle comparativement aux arenites quartziques typiques de l’Athabasca; initialement, ces mineraux constituaient probablement des inclusions dans le quartz detritique qui ont ete subsequemment liberees pendant la fracturation. Les textures et les caracteristiques de l'alteration suggerent que cette unite a subi une fracturation hydraulique et a ete alteree par un fluide hydrothermal - possiblement en lien avec les effets distaux de mise en place de la mineralisation en l'uranium."

Jan 1, 2013

By Harold S. King

TWO summers ago I had the privilege of visiting No. 18 colliery at Glace Bay. Underground, we travelled along the haulage-way behind a powerful electric locomotive. The motor in this locomotive began to smoke badly and a carbon tetrachloride type of extinguisher was used several times during the trip. At the time, I noted a strong odour of phosgene. On my return to Sydney, I spoke to Mr. Harold Gordon, Assistant to the General Manager of the Dominion Steel and Coal Corporation, and warned him of the danger of using this type of fire extinguisher in confined spaces, since it is a well known chemical fact that phosgene, a dangerously toxic gas, is formed by the decomposition of carbon tetrachloride. This danger does not seem to be widely recognized, so it seems advisable that a more general warning be published. Attention was first drawn to the danger by the death of two men in the United States Navy Department subsequent to breathing fumes from carbon tetrachloride used in a fire, and when an employee of the Bureau of Mines also was overcome while fighting a fire with carbon tetrachloride liquid. These accidents led to an investigation of the decomposition products of carbon tetrachloride by a group of workers in the Research Laboratory of the Pittsburgh Experimental Station, U.S. Bureau of Mines, the results of which were published in the October, 1920, number of the Journal of the .Franklin Institute (1). Their experiments were conducted by two methods. The first consisted in applying the liquids to actual fires and -to hot metal in a closed room of 1,000 feet capacity, where the gaseous products, mixed with air, could be retained and analyzed. The second method was to pass the vapour:s in air through heated tubes of iron or quartz, where the humidity of the air and the temperature could be controlled.

Jan 1, 1939

By H. C. Gunning

SOME small vanadium-bearing deposits on the west coast of British Columbia about 100 miles north of Vancouver are of interest for several reasons. They are of a type that is, so far as we know, unique. They are difficult to identify as being vanadiferous so that, unless they are described, other similar deposits could easily pass unrecognized. Furthermore, although none of them has as yet been proven to be of commercial proportions, no good reason is apparent why larger, and therefore valuable, deposits should not occur under similar geological conditions. The original discovery on Quadra island was made in 1932 and has been recorded by H. V. Ellsworth and H. C. Gunning (l). Since 1932, prospecting in the area has revealed other similar deposits, one about a mile south of the original and another some ten miles to the east, near Menzies bay on Vancouver island. The Quadra Island showings are a mile and a half north of the head of Gowland harbour, a small inlet that is easily reached by gas boat from Campbell river, about four miles to the southeast on Vancouver island. The deposits were examined by the writers in the spring of 1943 in connection with field work sponsored by the Department of Geology, University of British Columbia. We are indebted to Mr. G. A. Dirom and Mr. Lothrop, of Vancouver, for helpful data on the Menzies Bay deposits, and to Dr. V. Dolmage for making a brief trip to Gowland harbour and discussing the deposits.

Jan 1, 1944

By Beaumier. M., J. -P. Lalonde

"Les réultats obtenus dans les sols sur quatorze aires d'essai et six cheminements régionaux dans I'A bitibi-Témiscamingue indiquent clairement qu'il existe des variations régionales importantes dans les teneurs en éléments traces de l'horizon A1 formé sur l’épais recouvrement glacio-lacustre de cette région. Les anomalies obtenues correspondent à celles qui ont été décelées lors de précédents levés des eaux souterraines et du till de base.Selon les critères d'évaluation utilisés, treize des quatorze aires d'essai ressortent comme anomales dans Ie contexte abitibien; dix de celles-ci sont tres anomales. Ceci suggère fortement qu'un levé régional de sols, fondé sur une approche multi-éléments, identifierait entre 70 et 90 % des cibles géochimiques reconnues par des échantillonnages en profondeur. Les résultats d'un échantillonnage systématique effectué sur une région de 1000km2 viennent aussi appuyer cette hypothèse. Conséquemment, les sols formes sur les sédiments glacio-lacustres sont un médium très utile pour inventorier de grandes regions recouvertes par ce typ e de sédiments.L 'horizon A1 est Ie plus utile pour ce type de levé parce qu'i1 est facil e d échantillonner, qu 'it assure une plus grande constance du typ e de matériel échantillonne et qu'il contient des teneurs accrues.De multiples mécanismes de dispersion géochimique ont joué des rôles d 'importance variable pendant et après la mise en place des sédiments glacio-Iacustres. Les plus importants sont la pression hydrostatique, la diffusion chimique et électrochimique ainsi que la bio-accumulation. Si on veut progresser dans la connaissance de ce milieu complexe, on devra adopter une approche plus systemique tenant compte de I'interaction des mécanismes agissant dans l'environnement global avant, durant et apres Ie depôt du mort-terrain."

Jan 1, 1984

By M. A. Rabah

This study aims to recover europium, yttrium metals, some valuable salts or oxides from the white powder (apatite) coating the inner surface of spent florescent lamps (SFLs). Pressure leaching using sulphuric/nitric acid successfully dissolved the metals of interest. Europium or yttrium metals were obtained by hydrogen reduction of their oxides. Addition of potassium thiocyanate converted the dissolved sulphates to thiocyanates. Selective separation of Eu and Y was then carried out by solvent extraction from the thiocyanate solution. The used solvent was trimethyl-benzylammonium chloride. N-trihutylphosphate in 1 M nitric acid was used to strip the metal loaded in the organic phase. Results showed that the quality of the cleaned glass tubes of the SFL met the standard requirement for the lamp manufacture. The white powder (WP) is composed of calcium sulphate 35.2%, phosphate 61.5% and oxides of europium and yttrium 1.65%wt. respectively. Autoclave digestion of the WP for 4 h at 120°C and 500 kPa in sulphuric acid/nitric acid mixture dissolved 96.4% of yttrium and 92.8% of europium. The conversion rate of sulphate to thiocyanate was favoured at low temperature. Stripping of Eu and Y from the loaded organic phase behaved in an opposite way. A metal separation factor of 9.4 was obtained. ate recovered europium and yttrium salts were selectively separated using ethyl alcohol or dilute nitric acid. Yttrium was very soluble while europium was not. Europium and yttrium metals were obtained by hydrogen gas reduction at 850°C and 1575°C respectively.

Jan 1, 2004