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By Rath M. C, Das R. P

Studies were carried out on dissolution and oxidation of iron powder in ammonia-ammonium carbonate solution using oxygen over pressures. Cobalt and nickel losses during iron oxidation under different conditions were investigated. Regression equations were derived for percent cobalt loss and percent iron oxidation using ammonia, ammonium carbonate and oxygen partial pressure as the variables. The equations were tested for adequacy using Fisher's test. Cobalt losses increased with the increase of initial cobalt concentration and about 400 mg/l of cobalt was lost from a solution containing 500 mg/l cobalt. A maximum of about 80 mg/l nickel was lost from 1 g/l nickel containing solution, and this loss remained the same even when the nickel concentration was increased to 7.5 g/l.

Jan 1, 1992

By Lawson F

A rotating disc geometry has been used to provide a uniformly accessible surface for a kinetic study of the cementation of the metals cadmium, lead and silver from dilute aqueous solutions. This work is an extension of studies carried out on the Cu/Zn and Cu/Fe systems for which the rection rate was found to be completely solution-phase mass-transfer controlled. When the amount of material deposited was greater than 0.2 to 0.4 mg/cm2 there was an apparent enhancement in e which is attributed to the formation of a roughened deposit. This same phenomeon was obseived in the Cu/Zn Cu/Fe systems. Again, the rate of reaction of each system investigated was found to be solution-phase mass ,..~sfer controlled.

Jan 1, 1970

Extensive reserves of kaolin of the type suitable for use as a high quality paper coating exist on the Weipa Peninsula. In 1986 a commercial processing plant was constructed to produce 100 000 tonnes per annum of coating quality kaolin targetted principally for export. A number of processing difficulties have limited the production capability of the plant. The prime area being the pressure filtration operation with achieved cycle times being around 50-60% of design. The rate determining steps being press filling, press unloading and filter cloth washing. This paper details and summarises testwork and results from our attempts at decreasing the filtration cycle time.

Jan 1, 1989

By Crosby N. R

The design of mine openings and the assessment of their reserve are processes ihicl, require the routine manipulation of considerable amounts of data. A number of computer programs have been assembled to operate in a mini computer in order to provide some mechanical assistance for these processes. The system responds to plain language commands. which allows mining engineers to compute the reserves for a number of possible mining outlines, on an interactive basis. Methods of numerical analysis were used in preference to statistical or qeostatistical techniques.

Jan 1, 1977

By Falbo A, Quarestima S, Cozza C, Barbaro M

A new synthetic reagent of the mercaptobenzoxazole class, 5- methyl-2-mercaptobenzoxazole, has been studied. This reagent exhibits powerful selective collecting action towards copper sulphides present in several complex ores, as demonstrated both by laboratory and pilot plant tests. Industrial production is expected to start in the near future. The way this reagent reacts with pure chalcocite has been studied utilising in situ FTIR techniques, adsorption tests, electrokinetic potential measurements and Hallimond cell flotation tests. The FTIR studies have indicated the nature of the surface phase. Adsorption isotherms obtained by the rest method have revealed the quantitative evolution of surface products, permitting the determination of surface coverage at various reagent concentrations. The electrokinetic potential has been utilised to verify the stability of individual species in diverse concentration ranges. Correlation of the results obtained has provided indications on the chemical interaction of this reagent with the surface and on the surface Arrangement.

Jan 1, 1993

An ongoing research program into surface subsidence over Room and Pillar coal mining is described. A subsidence monitoring network has been established for one Room and Pillar mine in the West Moreton Coal Field of South East Queensland, at which pillar extraction is being conducted. The maximum measured subsidence to 28 January 1986 was 638 mm, with movement continuing. Analysis of the monitoring data with view to application of the subsidence pre- diction theory developed by Kowalczyk (1972) is discussed. The Kowalczyk theory provides predictions of subsidence depression, slope of surface, horizontal displacement, surface curvature and horizontal strain, for both the Partial and Total Settlement cases. The development of subsidence with time is also investigated and a preliminary analysis conducted.

Jan 1, 1986

By Fiedler VA, Threadingham GM, Leckenby DF, Clarkson CJ

The Utah Development Company Research and Development Laboratory has embarked upon a programme of optimisation of the company's coal preparation plants. This goal is being accomplished in a three-fold manner - use of pilot plant equipment for optimisation and modelling of the various unit operations, evaluation or development of on-stream ash analysis for process control, and evaluation or development of alternative processes. In each of these areas, digital data acquisition- and at a later stage, process control feedback, is being extensively utilised, based largely upon the use of the HP85 and HP9915 desktop computers. A variety of input/output configurations such as HPIB, BCD, GPIO are used, and at times supplemented by microprocessors such as the Intel 80/05 to assist in data transfer. This paper will discuss a number of specific projects, especially in relation to the manner in which the variables are monitored, and the data later retrieved and analysed.

Jan 1, 1983

Soil improvement technologies have been widely employed over the recent decades to overcome tunnelling problems in difficult grounds, their range of application growing proportionally to the technological development. The constant advancement in the different mechanical (flexible and more powerful equipment) and electronic (enhanced reliability and direct quality control) aspects of these technologies, fostered the confidence of engineers and tunnellers and, ultimately, allowed the entire tunnel industry to approach difficult excavations in a safer and cost effective manner.This paper outlines the main features of commercially available soil improvement techniques, with particular emphasis on permeation grouting and jet grouting. These two technologies, developed concurrently in Europe and Japan, and there customarily adopted in the design of underground structures, have known extensive and extreme applications worldwide in recent years. Case histories and current practice of soil improvement techniques, as they apply to tunnelling, are also rendered.

Jan 1, 1999

By Johnson G. D

The typical management systems used to address the issue of operating risk centre around technologies that identify, analyse and evaluate the risk factors. These logical systems such as HAZOPs, Fault Tree Analyses, etc rely heavily on technical considerations and process flow analysis. However, several research projects, across industries and countries have clearly shown that up to 80 per cent `operating risk' is determined by the actions of workers, supervisors and managers. Yet, most of the focus of risk management is on technical and procedural issues. This suggests that a significant imbalance exists in our management systems and that industries are unlikely to show significant improvement on current levels of safety performance. Effective risk management must include the intangible element of the organisation psychology towards risk. A practical and theoretically sound approach had been researched and developed in and for the mining industry. This paper describes the approach and methodologies applied at the Cosmo Howley Gold Mine in the Northern Territory, where an inclusive approach to managing financial and operating risk was followed. The Cosmo Howley Mine showed a dramatic reduction in lost time injuries and improvements in financial indices - providing conclusive evidence of the link between management effectiveness, safety and productivity. This `triangle' has often been the subject of speculation and theory. It is demonstrated in this paper how the management team of Cosmo Howley focused their practices and systems on the improvement of organisational dynamics, ensured tangible and clear focus on parameters of costs and safety and how the improvement process was managed. It is concluded that the improvement process did not require a `major re-engineering' of the organisation. The organisation culture changes that occurred were incremental, planned and effective. It entailed the implementation of sound risk management methodologies, and ensured that a significant emphasis was placed on an aspect that is defined as `organisational dynamics'.

Jan 1, 1994

By Cutmore NG

The moisture content of iron ore is important in handling, stockpiling, transport and further processing operations. Typically these ores contain both `free' and `bound' moisture, the latter being moisture that is not removed in a conventional laboratory determination of moisture by air drying at 105¦C, and it is the free moisture that is important in dust control and ore handling. The CSIRO Division of Mineral and Process Engineering has previously developed and commercialised gauges, based on capacitance and microwave techniques, for the on-belt determination of moisture in coal and minerals. However, these gauges determine total moisture, and have a different sensitivity to free and bound moisture in the material analysed. Consequently, the accuracy of determining total or free moisture alone may be significantly affected by variations in the bound moisture content. An investigation has been carried out on the simultaneous determination of free and bound moisture in iron ore fines (

Jan 1, 1993

The discovery of bauxite in 1955 at Weipa on the NW coast of Queensland's Cape York Pen- insula enabled Australia to join the Caribbean and West Africa as one of the major world sources of bauxite. Weipa, today, is the largest bauxite mining operation in the world and holds a significant position on the world bauxite scene as the operation 1. supplies 15 per cent of the Western World's metallurgical grade bauxite requirements, Z. produces 50 per cent of the world's demand for abrasive grade calcined bauxite, and 3. is the world's largest bauxite shipp ing port.

Jan 1, 1978

Degussa's PAL-system (peroxide assisted leach) has been proven to be more economical than the conventional cyanidation technique. Significant in- creases in the gold recovery have been reported, accompanied by savings in cyanide. Accelerated extraction kinetics and modified reagent demands necessitate a redesign of the conventional cyanidation plant. The South African Osprey Mine is presented as an example of a successful PAL-application. Based on the plant and laboratory data it is shown that the redesign of the flowsheet can be an important factor for the effectiveness of a metallurgical plant. In the case of the Osprey Mine, the PAL-technology all ows a modification of the current preoxidation-ClPcircuit to two separate CIL-plants to treat run-of-mine ore and old tailings dumps. A doubling of the throughput is possible without enlargement of the plant. This innovation in the field of gold extraction, the combination of the PAL-process with a redesign of the metallurgical plant, can be considered as a basis for a more profitable gold mine.

Jan 1, 1991

By Jena, Anand S, Das R. P

Leaching studies were carried out on Indian Ocean manganese nodules using sulphuric acid as the lixiviant. By leaching the nodules with 8 per cent sulphuric acid for 12h at 100°C, copper and nickel could be completely extracted along with 50 per cent cobalt and 6.2 per cent manganese.94.2 per cent of the iron was also dissolved. To increase manganese and cobalt extraction, charcoal was used as a reductant. The role of charcoal was to reduce the manganese dioxide and render it soluble as manganese sulphate as well as to facilitate solution of the cobalt minerals associated with the manganese dioxide. Various leaching parameters were studied including acid concentration, amount of reductant, leach time, pulp density and leach temperature. It was found that by leaching the nodules with 10 per cent sulphuric acid at 100°C for 4h using 5 wt/wt per cent charcoal (0.05g of charcoal per g of nodule) almost complete extraction of copper, nickel, cobalt and manganese could be achieved. However, under these conditions all the iron present in the nodules was also leached.

Jan 1, 1989

The objective in design of an excavation in a jointed rock mass is to achieve a prescribed degree of control of rock mass displacement around the excavation. Any excavation in jointed rock usually involves slip and separation along discontinuities as well as translation and ro- tation of constituent rock blocks. Thus, any acceptable model of behavior around an excava- tion must be capable of simulating the force displacement paths followed by the constituent elements, including rigid body translation and rotation. The distinct element method models such behavior by simulating the rock mass as an assemblage of rock blocks which interact through corner and edge contacts. Discontinuities are regarded as boundary interactions between blocks with joint behavior prescribed for these inter- actions. Introduction of structural element logic allows a variety of installed support sys- tems to be modeled. The response of the support to axial, transverse, and flexural loads is based on explicit algorithms similar to those used in the distinct element formulation. This allows large displacements and rotations and general non-linear constitutive behavior for both the support elements and the interface with the rock. This paper describes both the distinct element and structural element formulations and demonstrates several applications involving sup- port interaction with jointed rock.

Jan 1, 1987

By Leach B. G

A geostatistical study was made of diamond drill hole intersections within 18CC stope block at the C.S.A. Mine, Cobar, N.S.W. The stope block is located in 18CC orebody which is a massive sulphide - multiple vein, Copper-Zinc type, lacking clear definition on gangue mineralogy, base-metal assays and total sulphide considerations. Of the variograms constructed for inter- section width and copper, lead and zinc grades and accumulations, only zinc displayed behaviour amenable to model fitting and kriging procedures. Zinc grades were calcu- lated for sub-blocks comprising the total stope block and comparison with equivalent grades determined by traditional methods showed them to be generally less extreme in the highest and lowest grade sub-blocks. The total-block grades derived by the two methods were almost the same. It is suggested that the failure of copper to show variogram continuity might reflect the difficulty in defining the actual 18CC orebody, a proposition which is supported by the poor continuity in the variogram of horizontal width. In the case of lead the poor continuity may be due to the frequent manner of occurrence of galena as coarse grained patches of limited extent. The results of the study, did not provide a convincing reason to depart from the traditi- onal methods of grade estimation at the C.S.A. Mine.

Jan 1, 1979

By Osborn G

The bulk flotation behaviour of an industrial rougher bank has been determined with a view to characterising the size iepend ent behaviour of the identifiable nineral groups present. A relatively simple flotation model, based on first order kinetics and the assumption of perfect mixers in series ias been used to provide a fit to the operation of the cells. The adequacy of the model is discussed in relation to the characteristics of the ore and the size iependancy of the parameters. It is shown that improved fits are possible if the model accounts explicitly for this size dependancy and demonstrated how the model may be of use in prediction of the grade recovery relationships for different operating conditions as an aid to plant optimisation.

Jan 1, 1986

By Rosmus P

Improper use of auxiliary ven- tilation units during heading operations may often result in the appearance of hazardous methane accumulations. This is the case especially when roadways are ventilated by a combined system with a short sucking pipe at face end performing as the dedusting installation. Uniform air inflow to the face end facilitates sucking off the dust clouds and creates conditions favourable for formation of local methane accumulations. The highest methane concentration occurs in the cutting zone between the rock cut and the pipe inlet, under the roof and by, the sidewalls. Permanent monitoring of methane concentration at face end employs methane sensors. The most important are: one on the road- header's boom behind the cutting head, and one at the air outlet from the dedusting installation.

Jan 1, 1988

By X Liu

The crystal chemistry of carbonate in Ca apatites, including Na-free and Na-bearing hydroxylapatite (CHAP) and Na-bearing fluorapatite (CFAP) and chlorapatite (CCLAP), has been investigated by Fourier transform infrared (FTIR) spectroscopy and single-crystal X-ray structure, using crystals synthesised from carbonate-rich melts at 1 GPa, 1400 - 1000¦C. The carbonate ion substitutes for both the X (OH, F, Cl) anion species in the apatite channel (type A carbonate) and the phosphate group (type B carbonate). The type A carbonate ion is oriented in the channel with two oxygen atoms close to the c-axis, and the type B carbonate ion is located close to the sloping faces of the substituted phosphate tetrahedron, with details varying with composition series. Sodium promotes the uptake of type B carbonate and also has a profound effect on FTIR spectra. Crystal compositions correspond approximately to the substitution formula Ca10-(y+z)Nay z[(PO4)6-(y+2z)(CO3)y+2z][X2-2x(CO3)x], with x + y up to 1.0 and z + 0.0 for CHAP, x + y + 4z + 0.4 for CCLAP, and x + y + 2z + 0.1 for CFAP, for equivalent conditions of synthesis. The sodium cation and A and B carbonate ion defects are locally coupled in all three composition series to facilitate charge compensation and minimise the effects of spatial accommodation. Synthetic Na-bearing type A-B CHAP with x + y + 0.5 has a similar chemical composition and FTIR spectrum to biological apatite.

Jan 1, 2008

When lying over 200-250m depth, many seams and surrounding strata are gassy enough to create mining difficulties , particularly in highly productive longwalls as well as in their development headings. In addition to the gassiness of seams or stra- ta in the outgassing volume around working, the shape expansion and limits of this one influences much the intensity of gas emission. These charac- teristics of outgassing volume differ very much ac- cording to the permeabilities of the seams and strata encountered by their fracturation due to mi- ning. Moreover, the shape of the outgassing volume is very much modified by the rate of advance of the face. In nearly impermeable deposits, gas flows from a limited outgassing volume. When the rates of advance of a face are medium or low, the shape and dimensions of this volume do not change very much and outgassing volume is translated progressi- vely with the face advance. This explains why, in the past, it was observed that there was for each seam an average steady specific emission of gas, round which the volume of gas evolved per mined ton or per mined unit area, calculated over a cer- tain time, was oscillating. Combined with a statisti- cal irregularity coefficient, this allowed prediction gas of emission and thus to take decisions for air ventilation, drainage, and eventually production.

Jan 1, 1988

Comminution Kinetics equations are developed to take into account difference of grindability of mineral components. The equations describing both batch and closed circuit grinding or crushing processes are given. These equations are applied to industrial data to derive comminution kinetic and classification characteristics of the component minerals in a multi-mineral ore. Control strategy based on these concepts is presented.

Jan 1, 1985