Search Documents

By M S. Reston

The Tonkolili banded iron formations (BIF), Sierra Leone, host extensive iron ore deposits which are of economic signifi cance to the seaborne iron ore trade. The deposits are dominated by a strategic JORC compliant mineral resource of 11.6 Bt grading 30.1 per cent Fe comprised of primary magnetite mineralisation in the form of a fresh metamorphosed BIF featuring a uniform mineral assemblage of quartz-magnetite ± ferro-silicate minerals. Pilot plant metallurgical test work has demonstrated that the production of a magnetite concentrate is achievable using the established beneficiation techniques of magnetic separation and flotation. The concentrates arehigh-grade, and suitable for blast furnace or direct reduced iron pellet feed. The major challenge facing the development of such magnetite deposits at industry competitive production rates is the significant capital investment required for process plant and associated infrastructure.Two well-developed weathering zones exist within the deposits, and are associated with the progressive development of a tropical weathering profile overprinting the primary BIF. These zones feature a near surface hard indurated duricrust up to 60 m thick, and a soft progressively developed saprolite between duricrust and fresh BIF. These zones have been found to be amenable to producing iron ore products including DSO lump and sinter fines from the duricrust, and concentrate from the saprolite. Mineral resources sufficient to support commercial production of such iron ore products were defined by an intensive exploration program in 2010.African Minerals Limited has developed a three phase production strategy to progressively self fund the development of the Tonkolili strategic magnetite project by:• commencing a Phase I 12 Mt/a DSO operation in Quarter 4 2011,• increasing production in Phase II to 35 Mt/a with the commissioning of a saprolite beneficitation plant and associated infrastructure upgrades, and• developing a 45 Mt/a Phase III operation producing high-grade magnetite concentrate.The comparatively low capital and operating costs of a duricrust DSO lump and sinter fines operation coupled with its proximity to ground surface make it highly attractive for the generation of early cash flow for the Tonkolili project. Revenue from this early production may be used to selffund the subsequent development of phases requiring progressively more significant beneficiation plant and infrastructure.

Jul 11, 2011

By D Espinoza, I Rees, J Pocoe, P Collier

P Collier, I Rees, J Pocoe and D Espinoza

Mar 22, 2022

By D McCoy

Titanium feedstocks are the building blocks of the titanium value chain. They can be mined directly, as is the case for ilmenite, leucoxene and rutile, or manufactured from ilmenite by extracting various quantities of non-TiO2 components from the ore by chemical and/or thermal processes.While feedstocks can be grouped into categories of materials with similar characteristics, they are essentially unique products from very different mining locations around the world. In fact, no two feedstocks are exactly the same. As such, the variations between the available feedstocks, in combination with the permutations in processing technologies to turn the feedstocks into titanium pigment or metal, mean that choices between feedstocks are specific to the location in which they are utilised.In this paper, the authors examine the key requirements of titanium feedstocks to the TiO2 pigment and metal sectors. Apart from the well known differences between feedstock choices for the sulfate and chloride process, the more opaque considerations in feedstock sourcing are examined.

Oct 5, 2011

By S J. Hawke, L A. Dominguez

In non-ferrous metal mining operations, it is generally necessary to crush and grind the ore to a very fine particle size to effectively liberate the contained mineral from the host rock. Fragmentation by blasting is the first stage of this comminution process.Numerous studies and independent modelling of the Mine to Mill process have demonstrated the potential for significant downstream productivity improvements from improved blast fragmentation. However, safety and environmental constraints associated with the blasting process usually limit the extent to which blast energy or powder factor can be increased.An effective blasting solution has been identified that enables the safe utilisation of powder factors several times higher than those used conventionally to provide significant improvements in fragmentation. The solution uses a static ‘blanket’ of broken rock overlying the blast to contain this increased blast energy and control rock movement. To produce this broken layer of rock, the subdrill in each blast is significantly increased to preblast (or precondition) the entire stemming region of subsequent blasts on the next mining bench.The solution has been evaluated at a large open cut poly-metallic mine in Mexico. Results from the application of this technique have shown significant improvement in run-of-mine fragmentation, with subsequent downstream productivity improvement indicated.CITATION:Hawke, S J and Dominguez, L A, 2015. A simple technique for using high energy in blasting, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 321–326 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By A Keogh, P Allen, P Stoker

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Private equity (PE) firms are comparatively free of mandatory requirements for the level and scope of due diligence applied prior to making investment decisions in minerals projects when compared to listed entities, sovereign funds or financial institutions adopting the Equator Principles (Equator Principles Association, 2013). While this freedom allows for flexibility, agility and innovation in making investment decisions, it can also expose PE firms to material risks that may impact their ability to successfully list the projects or attract later financing.Financial institutions and investors with mandatory due diligence and disclosure standards may refrain from investment in or acquisition of a project if it fails to meet various performance requirements. There are many high-profile projects that have suffered significant write-downs on book value after acquisition because specific non-mining issues were not adequately assessed. Thus, a PE firm may be left with an asset that is difficult to divest and incapable of securing development finance.PE firms can manage this risk by being aware of the growth trend in the adoption of ‘international standards’ in addition to host nation standards and legislative requirements. This paper outlines key issues for PE firms to address to maximise the chances of obtaining funding or successfully taking an exploration or mining project through to listing or divestment. Two steps are required: identification of gaps in performance and priority matters of interest to financial institutions and development of action plans to ensure that the priority requirements are met or capable of being met.A PE firm can set its project for success by understanding the social and environmental performance requirements of international standard financiers and by setting the project on the right path to meeting these requirements, and thus making it an attractive investment.CITATION:Allen, P, Stoker, P and Keogh, A, 2015. Setting for success – private equity exploration and mining project buy-in to listing and divestment , in Proceedings PACRIM 2015 Congress, pp 93–100 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By Laas JJ, Spearing AJS

Considering the capital outlay, running costs and inherent difficulties of backfilling operations at depth the benefits need to be clearly established, quantified and then exploited. Expansion of Vaal Reefs Exploration and Mining Company towards even deeper, highly faulted ground, and the process of establishing codes of practice for the management of rockfalls and rockbursts, required that a sound support strategy be formulated. This paper describes the derivation of an overall backfilling strategy on Vaal Reefs. Use was made of experience gained over some 12 years with backfilling. Numerical modelling was used to estimate potential benefits of backfilling the deepest mining areas still to be extracted. In exploiting a probably unique opportunity, two contiguous mining areas bounded by the same major geological structures, were compared. One was extensively backfilled and the other not at all. Shaft sinking through a backfilled stope added another dimension to the database. Backfilling was introduced in 1985 and several potential spin-offs were expected. These included improved local strata control for fall of ground and rockburst conditions, regional benefits in rock mass stability and mine ventilation optimisation.

Jan 1, 1998

By M Pernechele, U König

Most of the operating steelmaking capacity currently relies on conventional, coal-based steelmaking processes. Currently, direct reduced iron (DRI) is only produced in regions where energy is available at low cost. To align with net-zero emissions goals, steelmaking capacity must transition to loweremissions steelmaking technology. Direct reduction of iron ore will get one of the preferred methods in the future due to its high technology readiness. New reduction technologies include hydrogenbased direct reduction processes. To ensure optimal efficiency during DRI production and to cope with newly developed technologies, processes need to be monitored more frequently and accurate. Traditionally quality control of raw materials and DRI has relied on time consuming physical testing, wet chemistry or the analysis of the elemental composition. The mineralogy of DRI that defines its properties is not frequently monitored. Process monitoring and quality control of DRI is possible by using modern X-ray diffraction (XRD) methods. In addition to the metallic iron content (Femet), metallisation (Metn) and the total carbon content (Ctot), XRD analysis also identifies the overall mineralogical phase composition. This allows additional information about the reduction process and enables fast counteractions on changing raw material mixtures. The benefits of the quantitative determination of the phase composition and the calculation of process critical parameters to produce DRI will be demonstrated with a case study

Sep 18, 2023

By M Jones, G Corder, A C. Keith

"Sustainable development has become an issue of ever increasing importance to the mining industry. The Ernst & Young (EY) mining industry risk radar regularly shows several sustainability elements in the top ten risks, with social license the number three risk in the 2014/15 survey. This is supported by the Fraser Institute survey results of 2013 showing that 36 per cent of responding companies indicated public opposition had affected their permitting and approvals process.Addressing these issues in a strategic way across a mining business that is then translatable to actions at operational level has remained an elusive goal in the industry. In addition the environment and community issues are commonly viewed as somewhat separate from financial and production issues and as a compliance cost rather than a value add. In their Harvard Business Review paper of 2011, ‘Creating Shared Value’, Porter and Kramer outline changes in thinking required for companies to improve their business sustainably through considering the societal issues impacted by their operations and products. Along the lines of ‘doing more with less’ companies’ value chains can be redefined to reduce energy, transport, water or other resource usage leaving additional resource for societal usage and/or reducing environmental impacts. This paper explores the linking of the holistic Five Capitals-based approach with the creating shared value (CSV) concept to help businesses unleash the benefits of innovation. Previous papers have demonstrated the potential for Five Capitals approach to create strategic value through sustainable development. Building on previous work, this paper provides an overview of the current status of holistic approaches to mine management and presents the application of the CSV concept on an African mine currently undertaking capitals-based strategic planning. The paper also demonstrates the value that has been created through utilising this approach and proposes improvements for changing the way the industry tackles and delivers benefits related to sustainability issues.CITATION:Keith, A C, Corder, G and Jones, M, 2016. Strategic sustainable development – creating shared value in the mining industry, in Proceedings International Mine Management Conference, pp 249-264 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 22, 2016

By B Darlington, L Sandberg, O Vallati

The D47 and D39 Mechanical Dynamic Extra bolts (D47 MDX and D39 MDX) have been developed in response to the ever-increasing demand from the mining industry for rock bolts with high dynamic capacity. To prove such capacity, Sandvik has performed numerous in situ dynamic testing with the unique Dynamic Test Rig (DTR) (Darlington, Rataj and Roach, 2019; Roach, Rataj and Darlington, 2019). To complement the collection of testing data, Sandvik, in collaboration with the Swedish Research Institute for Mining, Metallurgy and Materials (Swerim) have performed additional experiments in laboratory condition using Swerim’s new drop test rig. This rig utilises a momentum transfer method to apply a dynamic load to the bolt. The sample falls together with the mass until the support beam impacts stationary dampers and the momentum energy is transferred to the bolt. Part of the charged energy is released by the dumpers while the remaining portion is absorbed by plastic deformation and/or displacement of the ground support element. The D47 and D39 MDX bolts have been tested at Swerim’s test facility with different levels of input energy. Six tests were performed at the specification energy of 36 kJ and six tests were carried out with the maximum allowable energy from the facility, ie 44 kJ. The bolts confirmed their dynamic performance absorbing the input energy without failure. The D47 MDX bolt absorbed up to 33 kJ with 150 mm displacement while the D39 MDX bolt absorbed up to 35 kJ with 162 mm displacement. This work will present an overview of the drop test rig at Swerim’s facility and a collection of results of the test performed on the D47 and D39 MDX bolts. The test method and results will be analysed and compared to the tests carried out with the in situ DTR.

Nov 29, 2022

By D Tucker, K Harney

Hatch forecasts that an increasing share of seaborne traded iron ore will be ultrafine, being either concentrate or pellet feed. This provides several challenges for the iron and steel industries, but the principal concern is: how much ultrafine iron ore can be consumed on sinter strands and with a minimal effect on productivity?This paper will identify new supply by project through 2020. Demand will be estimated for sinter production and practical steps will be identified to increase ultrafine consumption in sinter strands. The long-term iron ore price will be forecast to balance supply and demand. The paper will conclude by assessing how the pricing of ultrafine ore will develop relative to the Chinese iron ore indices.CITATION:Tucker, D and Harney, K, 2015. Iron ore ultrafines challenges and opportunities, in Proceedings Iron Ore 2015, pp 501–504 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By D Capstick, M B. Ebell

This paper describes the test work, process design, commissioning and operation of a processing system at the Ergo gold operation that improves the extraction efficiency from gold tailings material. The improvement in recovery is derived from the separation of the gold contained within the sulfides of the tailings material and a dedicated process stream to recover that gold.The sulfides are separated by means of a flotation circuit and that resulting concentrate is subjected to a regrind of below 20 ¦m to enable a greater liberation of the gold. The ultra-fine material is then subjected to a dedicated leach circuit to recover the now exposed gold particles.The case study is an example of the challenges of introducing new technology and methodologies to a well-established operation and thereby attaining improved efficiencies and tangible business benefits.CITATION:Ebell, M B and Capstick, D, 2013. Improving extraction efficiency from Witwatersrand gold tailings using flotation and ultra-fine grinding of concentrates, in Proceedings World Gold 2013 , pp 301-306 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By M Zlatev, S Silge

Producers of primary resources such as iron ore face the challenge of processing crude materials with increasing levels of impurities, which may result in the requirement for wet processing. This results in a significant increase in water usage, power consumption and operating costs. Given the remote locations of most operations in Australia (Stewart et al, 2013; Prosser, Wolf and Littleboy, 2011), the required volumes of power and fresh water for wet processing can be very difficult to achieve.HAVER&TYLER is renowned across the world for their screening technology in wet and dry processes. Its innovative Hydro-Clean® system represents a cost-effective and eco-sensitive way to clean any crude materials and material blends with a grain size distribution of 0–150 mm that are contaminated with adhesive clay, slit and other impurities.CITATION:Silge, S and Zlatev, M, 2015. Iron ore washing – achieve more with fewer resources, in Proceedings Iron Ore 2015, pp 519–528 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

Magmatism and mineralization are features of the New England Orogen in late Palaeozoic- Mesozoic time. Voluminous silicic and mafic magmatism, both orogenic and post-orogenic in association, was accompanied by abundant mineralization in the earlier phases. Later activity passed transitionally into less vol- uminous felsic to mafic intraplate basaltic volcanism, with possible migratory hot spot activity through the flanking Oxley and Sydney Basins. Only minor mineralization took place at this stage. A new inerpretation links these magmatic and mineralizing events to a major thermal cycle. A New England hot spot(?) complex evolved in latest Carboniferous/early Permian time. Its activity was partly obscured by orogenic magmatism as Australia moved slowly over magma sources in the deep lithosphere. In Triassic time Australia's movement changed direction and faster drift over the waning hot spot complex produced multiple migratory intraplateòactivity. The volume of magma and hence abundance of ancillary mineralization was related to age of the hot spot, speed of the continental movement over thermal sources and extent of accompanying orogenic activity. The New Eng- land Orogen hot spot(?) possibly existed for 165 Ma, with mineralization changing over this Period.

Jan 1, 1987

By P Thompson, B W. Atkinson

Water treatment is not æcore businessÆ for mining companies.Just as mineral ores and coals are unique, each requiring detailed characterisation and pilot-testing to determine their optimum beneficiation route, so too are mine waters, each requiring careful assessment to determine the most appropriate treatment. There are many cases of æregret capitalÆ expenditure, whereby mines have installed off-the-shelf equipment only to find it inadequate for their purposes or grossly expensive and labour intensive to operate.Water may be required for potable purposes, ore processing, dust control and/or irrigation. A major driver will frequently be environmental constraints for off-site discharge. Mine water projects can become very complex, and detailed models need to be prepared and optimised to properly consider the raw water sources, the on-site storages, the on-site uses and the off-site discharges, as well as handling the residuals (by-products) of water treatment. By-products may be in the form of concentrated backwash streams or streams of elevated salt content. Careful management of the by-products is required to avoid recontamination of the source water.Regulators often drive mine owners toward reverse osmosis (RO) so that their discharges can be considered as æzero dischargeÆ in terms of potential pollutants. Such decisions need to be based on site-specific information rather than any form of æblanketÆ requirement. An analogy is that many humans like to consume mineral water rather than ænormalÆ tap water. Receiving environments also accommodate or even prefer their æmineralsÆ and so RO is neither warranted nor sustainable in many cases.This paper presents two case studies for operating mine sites, both of which have a significant excess of water requiring environmental discharge. The examples demonstrate a sensible balance between treatment type, environmental constraints, process implementation and residuals management. LIMN« æthe flow sheet processorÆ was used to model one of the case studies due to the complexity of the water system on that site.CITATION:Atkinson, B W and Thompson, P, 2013. Mine water - optimising for site and environment, in Proceedings Water in Mining 2013 , pp 9-14 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By S McKnight, L Koroznikova, S Hall

Mineral sands represent an important new resource being developed in the Murray Basin, including parts of western Victoria. This paper will outline a simple methodology for mineral sands characterisation, developed as part of the AMIRA-managed project P777 æThe Development of Heavy Suspension Techniques for High Density Separations (Replacement of ClericiÆs Solution)Æ. This project is currently sponsored by three multinational mining companies (De Beers Consolidated Mines, Iluka Resources Limited and Rio Tinto Limited) and is developing an innovative laboratory mineral characterisation procedure that will allow the replacement of the currently employed highly-toxic chemicals.Mineral sand resources almost always contain more than one valuable (and relatively heavy) mineral. Titanium minerals are found with a large range of titanium contents, giving rise to density variation and often subjective mineralogical descriptions. Companies tend to rely on laboratory heavy liquid separation in the evaluation of samples arising from exploration, mining or metallurgical processes. Unfortunately, there are only a limited number of high density (æheavyÆ) liquids and these tend to be more toxic as their density increases. Low-toxicity inorganic solutions, based on tungsten compounds, have been developed that can be utilised at relative densities (RD) up to 3.0. However, beyond this value currently only organic liquids can be used. Diiodomethane (methylene iodide) having a relative density of 3.31 is commonly used; however, this presents significant health and safety hazards. Mixtures of thallium formate and thallium malonate were found in the early 1900s by Clerici to provide liquids having specific gravities between 4.0 and 5.0, hence æClericiÆs solutionÆ. For the characterisation of the heavy components of mineral sand deposits (eg anatase sg 3.9, rutile sg 4.2, ilmenite sg 4.4 û 4.7 and zircon sg 4.6 û 4.8) there is currently no heavy liquid alternative to ClericiÆs solution. ClericiÆs solution is highly toxic and testing is now conducted by very few laboratories worldwide with costs reflecting the chemical costs (though extensive efforts are made to recover and reuse the liquid, plus the requirement of its removal from the mineral samples), the infrastructure costs and health and safety regimes (eg blood testing of exposed staff, inventory management). A simple laboratory technique of density fractionation is being developed, employing suspensions of fine tungsten carbide particles in lithium heteropolytungstate (LST) solutions, that can replace ClericiÆs solution in the evaluation of fine mineral sands samples (eg -250+150 microns). The developing methodology that can achieve low-cost, low-toxic separations at relative densities above 5.0 will be outlined and the comparison of results with ClericiÆs solution presented.

Jan 1, 2006

By U König

The use of high speed detectors made X-ray diffraction (XRD) an important tool for quality and process control in the mining industries. Besides knowledge about the mineralogy of a sample it provides useful information in terms of quantification of the crystalline phases and the amorphous content. Cluster analysis of XRD data can facilitate multi-dimensional mapping of ore deposits and drill cores, identifying regions of favourable mineral compositions. The studies of this paper demonstrate how XRD and data clustering can be used for grade control, process optimisation and quality control of iron ores and iron ore sinters. These new developments have an enormous potential as an inexpensive, reliable tool, useful in the characterisation of iron and sinter materials implemented in an industrial environment.

Jul 11, 2011

By E Cunha, D Roldao, TáTamantini, J F. C L Costa, T Webber, C Monteiro

The main problem of geostatistical simulations is to reproduce the real characteristics of the mineral deposit when there are few conditioning data. In this case, the geological interpretation, based on structures, geophysics and geological maps, plays the major role in terms of resource evaluation.The paper investigates the use of principal component analysis (PCA) to help classify multiple geostatistical categorical simulations considering the similarity among them and the interpreted model, herein referred as training image (TI).An iron deposit with four lithological facies, in a specific horizontal plane, was used as case study for two-dimensional (2D) simulations. Sequential indicator simulations (SIS) was used to obtain ten equally probable 2D images, which were generated and compared against the interpreted model (TI).In this study, 11 random variables are comprised by the vector of ten SIS realisations plus the training image (TI). The similarity between the TI and each SIS realisation is measured using the angle between the TI and SIS vectors projected in the new coordinate systems (PCA factors). It is possible to order the SIS realisations from the highest to the lowest PCA factor taking into account the TI similarity.The visual analysis of the images shows coherence in the PCA results as a method to measure similarity. This methodology can be used as a post-processing tool to rank simulation results and to select the ones which better represent the prior known geology or to compare the quality of different methods of simulation.

Sep 26, 2011

By R E. McIvor, K M. Bartholomew

Classification system efficiency (CSE) is a simple, powerful metric that provides a comprehensive measure of classification system performance. CSE directly quantifies the amount of coarse solids in the mill, and as a result, also directly quantifies the percentage of mill power being used effectively. In this manner, it is an effective, practical grinding energy efficiency metric.Three independent variables drive CSE: circulating load ratio, sharpness of classification, and classifier bypass. Due to practical downstream constrains on per cent solids, improvements realised by increasing circulating load reach diminishing returns as sharpness of classification and bypass deteriorate in the most commonly used classification device, the hydrocyclone. This combination of effects leads to the use of CSE, and its relationship to operational economics, as an objective circuit optimisation criterion.Its simplicity in measurement makes CSE a useful tool for the plant metallurgist, and it is not subject to a great amount of experimental error. CSE provides the plant operator a fast, simple, and effective means to evaluate the performance of the plant classification system. Improvements in CSE relate directly to circuit throughput and energy efficiency. This paper, through description and plant case studies demonstrates the power and utility of this emerging grinding system optimisation metric.CITATION:Bartholomew, K M and McIvor, R E, 2013. Classification system efficiency - a comprehensive closed-circuit grinding optimisation metric, in Proceedings World Gold 2013 , pp 389-394 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By T Rohde, P Defferrard

In 2010 a store and release cover (the cover) was constructed on the south waste rock dump (SWRD) at Century mine. This also included aerial seeding of province native trees and shrub seeds. The purpose of the cover is to reduce percolation into the potentially acid-forming (PAF) waste rock by maintaining a compacted reduced permeability layer (RPL) at near-saturated conditions. This is achieved by overlaying the RPL with a 1.5 to 2 m thickness of soil-mulch. The soil-mulch has a hummocky final surface that captures rainfall, so it does not runoff, allowing it in part to infiltrate, with excess water removed by evaporation and transpiration. The RPL is the trafficked surface of the SWRD.The unsaturated behaviour of the cover is being monitored by instrumentation including volumetric water content and matric suction sensors and a weather station capable of estimating evapotranspiration. The instrumentation allows for direct measurement of infiltration into the cover, storage of rainfall, percolation through the base of the cover and in situ soil water characteristic curves (SWCC).The key functions used to describe the unsaturated behaviour of the cover materials is the SWCC and the unsaturated hydraulic conductivity function. The SWCC is a plot of soil water versus soil suction. It provides the loci of moisture states of a soil from the saturated to the dry state.The paper presents the results of five years of monitoring. It shows that total infiltration into the top of the SWRD was about 1.6 – 3.7% of cumulative rainfall over five years, with most of the infiltration going into storage within the cover. Runoff from the top of the dump is not allowed therefore, the remaining 95% of the total rainfall was lost to evaporation or as lateral flow when infiltration reached the RPL. The paper presents some simple analyses of the wetting by rainfall infiltration of the cover, leading to breakthrough at the base. Field data are used to support the analyses.Presentation of the SWRD water balance is also included in the paper using SVFLUX™GE which is a finite element model that simulates water transport through a saturated or unsaturated medium.CITATION:Defferrard, P and Rohde, T, 2018. Five years of cover performance monitoring and modelling for a store and release cover at Century Mine, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 179–189 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By P Mulvey, M Stuckey

"Inter-aquifer leakage due to fractures caused by coal seam gas extractions or longwall mining is an important issue for both the gas and coal industries. Currently, predicting stress induced macro-porosity associated with hydraulic fracturing, depressurisation via dewatering or collapse of overlying seams to infill a void left by longwall mining, is problematic. If fractures can be located the fracture can be sealed. Locating fractures is difficult. The non-geophysical approaches to locate fractures has been to consider the mixing of different waters, particularly that of more recent shallower groundwater with older deeper groundwater, via differences in radio-isotopes integrated with geochemical models to predict likely mixing of waters. This approach is applicable under appropriately complex settings; however, it is an expensive technique and is based on the assumption that the daughter isotopes are equally non-reactive which may not always be the case.Potentially a cheaper and faster technique is to consider integrating geochemistry (mineral weathering) and hydrogeology. The chemistry of groundwater, controlled by the weathering of primary rock?minerals and?formation of secondary minerals, can not only be differentiated between geological strata but also within strata as different stages in weathering results in differing impacts on water quality (ie different reactants).Field analysis of pH, electrolytic conductivity (EC), oxidation reduction potential (ORP) and dissolved carbon dioxide together with laboratory analysis of dissolved constituents characterise the chemistry of the water. Collection of rock samples at the time of drilling for bore installation can provide the (only) opportunity to assess the media in which the groundwater resides and migrates through. An assessment of aquifer matrix chemical makeup, via bulk sample chemical analysis, X-ray diffraction (XRD) and petrographic analysis can achieve this.The chemistry of groundwater is dependent on the water velocity. Water at deposition and post-diagenesis dissolution of minerals by hydrolysis and oxidation will result in equilibria of the dissolved phase with the solid phase. Post-depositional fractures caused by either tectonic activity or weathering alter the rate of weathering and thereby the geochemistry. Slow water flow in microfractures results in water in equilibrium with the rock minerals. Faster flow in larger fractures results in water being in disequilibria with rock minerals.Fractures can alter groundwater chemistry by two pathways: changing groundwater velocity, which changes the rate of hydrolysis or oxidation mixing water from different geological strata.Both pathways cause subtle changes in the water chemistry.It is however, the dissolved phase chemical data, which can be observed over time at individual locations and/or at a point in time along a flow path, which allows the hydrogeologist to ælook up-gradientÆ and locate the zone of leakage. Hence, influences on rock/groundwater chemistry, from anthropogenic sources to natural mixing of waters, can be assessed via appropriate interpretation of geochemistry, hydrogeochemistry and flow data.This paper will use the example of the geochemical and hydrogeological characterisation of aquifers within the Hawkesbury and Bulgo Sandstone of the Southern Coalfields to the south of Sydney in New South Wales to demonstrate this approach.CITATION:Stuckey, M and Mulvey, P, 2013. Looking for fractures - integrating geochemistry with hydrogeology to find inter-aquifer leakage above dewatered or collapsed coal seams, in Proceedings Water in Mining 2013, pp 99-108 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 26, 2013