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By Wilhelm Rohn

IN discussing the influence of a content of gases on metals and alloys we should probably first consider the physical and chemical conditions under which these gases may be present. By a chemical analysis, such as the total extraction of gases from the liquid metal by melting in a graphite crucible in vacuo, we find only the sum of gaseous chemical elements contained in the metal in any form and no reference is made to the special form under which they have been present previously. CONDITION OF GASES IN METALS In considering gases . in metals we may first turn our attention to gases simply dissolved. Because the solubility of almost any gas decreases suddenly at the freezing point, most of them are released during solidification, developing rise of ingots and blowholes. If only a little gas is dissolved in the molten metal the size of such blowholes may be miscroscopical, or even submicroscopical, resulting in a certain reduction of the notched-bar impact test values. Hydrogen is believed to become less soluble as the temperature is lowered and therefore increasing quantities of this gas may be evolved during cooling between the freezing point and room temperature, leading to unsoundness of the ingot at weak spots; i.e., at the grain boundaries. This gas at the grain boundaries probably is present at high pressure and therefore impairs the mechanical properties to a degree similar to that found in the hydrogen embrittlement of copper. Usually we may trace such gases by observing rising ingots, or at least by the formation of a characteristic pattern of small grooves upon etching.

Jan 1, 1932

By G. W. Jones

THIS paper describes experiments in which eight test samples of gelatin dynamite were fired in three different types of apparatus and the quantity and composition of the gaseous products of detonation determined. The special dynamites were so prepared that the oxygen balance of the samples varied from -35.0 to +6.0 g. per 100 g. of explosive, including the wrapper. By means of this graded series of explosives, the relation between oxygen balance and gaseous products of detonation could be studied explicitly. The effect of varying oxygen balance on explosive strength has-been discussed in another paper.1 The apparatus employed in the work described in the present paper included (1) the Bichel gage, a steel bomb of 15-1 volume; (2) the Crawshaw-Jones confined detonation apparatus, a steel cannon from which the explosive is fired into a pipe of 904 volume; and (3) the Hercules tank, an apparatus in which the explosive is confined in a quartz block which is placed in a steel tank of about 4500-1. volume. A full description of the apparatus is given later. VARIABLES AFFECTING COMPOSITION OF DETONATION PRODUCTS The character of the detonation products of commercial explosives is governed in part by the same factors that affect the combustion products from explosive mixtures of air with gases or vapors. In either case, combustible materials-namely, carbon, hydrogen, and sometimes sulfur-are present and combined variously. In an exploding gas mixture the combustibles are oxidized by oxygen in the admixed air, whereas with explosives the necessary oxygen is provided by oxygen-carrying materials in the explosive ingredients.

Jan 1, 1928

By Magnus Troilius

The method of using the bromine process of determining sulphur in steel, described below, is in successful use at the Midvale Steel Works. Ten grams of drillings are weighed out and put into the 1/2-liter flask A, with long neck. The flask is connected with a wide glass tube C', which, in its turn, is connected with the absorption bulbs B, containing HCI, 1.12 specific gravity, and ahout 5 C.C. of bromine. The wide tnbe C causes the vapor to condense and flow back into the flask A during boiling. The bulbs B connect with a long glass tnbe, which may be made to carry off the bromine fumes through a hole in a window, or, better still, through a flue with powerful draught. The connections being made, 100 C.C. of boiling water are run in through the thistle tube T. The air is thus completely driven out of the flask. 100 C.C. of HC1 (about 1.19 specific gravity) are then run in. When the gas begins to run rattler slowly through B, heat is applied until boiling gradually ensues. The steel being completely dissolved, the apparatus is disconnected, and the contents of B rinsed out into a beaker of 100 C.C. capacity, into which a few C.C. of a concentrated solution of BaCI, have been previously introduced. Heat is then applied (best by means of the hot iron plate) until the bromine is completely driven off and the BaSO, has settled nicely to the bottom. The BaSO4, is then filtered off on a small

Jan 1, 1884

Committee on Reduction and Refining of Copper............ 3 A.I.M.E. Officers and Directors.................... 4 Preface. By C. R. Kuzell....................... 7 Career and Achievements of James Douglas. By Arthur L. Walker. . 9 PAPERS Smelting 1. Reverberatory Smelting Practice History of Reverberatory Smelting in Montana, 1879-1933. By Frederick Laist..............................23 Reverberatory Smelting of Raw Concentrates at the International Smelter, Miami, Arizona. By P. D. I. Honeyman (With Discussion)...... 88 Development of Gun-feed Reverberatory Furnaces at Garfield Plant of American Smelting and Refining Company. By R. A. Wagstaff (With Discussion)........................99 An Experimental Combination of Shaft Roasting and Reverberatory Smelting. By Frederick Laist and J. P. Cooper (With Discussion).... 104 Forms of Copper Found in Reverberatory Slags. By Royal B. Jackman and Carle R. Hayward (With Discussion).............111 2. Converting Practice Development of Copper Converting at Butte and Anaconda. By William Kelly and Frederick Laist...................122 Developments in Converting Lead and Copper Matte at Tooele. By B. L. Sackett.............................132 Messina Stationary Basic Copper Converter. By R. G. Knickerbocker (With Discussion)........................140 Smelting Copper Concentrates in a Converter. By George E. Beavers. 149 Sulfuric Acid from Converter Gases. By George E. Beavers......151 Development of Monolithic Tamped Periclase Converter Linings at United Verde Copper Company Smelter. By F. H. Parsons (With Discussion) . 153 3. Descriptions of Plants The Noranda Smelter. By W. B. Boggs and J. N. Anderson......165 Smelting Operations at Roan Antelope Copper Mines, Limited. By Charles R. Wraith.......................202 4. Waste-heat Boiler Practice Copper-refinery Waste-heat Boilers at Great Falls Reduction Department, Anaconda Copper Mining Company. By E. S. Bardwell......225

Jan 1, 1934

By J. R. Spencer

When supplies of high pressure mercury or other liquids are required in analytical work, it is convenient to have the source of supply at a relatively constant pressure and available in sufficient volume to satisfy the requirements of the apparatus in use. It is also desirable that the pressuring device be as simple and as inexpensive as possible and convenient to operate. This pump combined with a small storage reservoir containing gas under pressure has the attributes of (1) positive control of the maximum output pressure through the use of a regulator in the low pressure air supply; (2) an increasing capacity as the rate of withdrawal of mercury from the pressured system is increased; and (3) simplicity, requiring only the use of a lathe, drill press, and welding unit in its construction. DESCRIPTION Essential parts of the pump are shown in Fig. 1. In appearance the unlt is similar to the usual steam pump in common use in industrial applications although considerably smaller in size. The main differences lie in the area ratio of the air and mercury pistons and in the design of the air valve mechanism. Approximate diameters of these pistons are 4.25 in. to 0.375 in. respectively, giving an area ratio of about 130 to 1. The air piston (2) is attached to the end of shaft (4), with the mercury piston being merely a reduced extension of the shaft. Mercury intake and discharge to the pump are controlled by high pressure check valves that screw into the ports indicated at (6). Air supply is controlled by the valve assembly mounted on top of the

Jan 1, 1950

By Charles E. Wait

In the analysis of a set of interesting furnace-products belonging to the metallurgical cabinet of the School of Mines, I placed in the hands of one of my students a sample of litharge which gave the results quoted below. The collection of specimens from which this was taken, represents the products obtained in the blast-furnace treatment of argentiferous lead ores, also samples from the zinc process, and those from the cupellation of the enriched lead. The sample, when received, was marked "bismuth litharge," and was that obtained during the last stages of cupellation. It gave upon analysis the following : Per cent. Lead,.......85.36 Antimony,.......06 Bismuth ,........20 Copper,.....49 Iron,...... 69 Zinc,......18 Nickel,.....01 Silver,....2.94 Lime,.....36 Magnesia,....03 Silica,.....12 Sulphuric anhydride,. .32 Carbonic anhydride,. 1.25 Water,.....24 Oxygen,..,.7.80 99.95 At present I wish merely to call attention to the large percetage of silver present (equal to 857 ounces Troy per ton of 2000 pounds avoirdupois), and also to note two or three determinations that I have recently made, with a view to ascertain, if possible, the condition in which this silver exists. If I mistake not, it is usually assumed that silver exists in litharge in the metallic state; and it is, indeed, in the analyses of litharge, rarely expressed otherwise. This method of reporting the silver is, no doubt, due to the accepted statements that the oxides of silver are reduced to the metallic state at a temperature of 300' C. or less. The following experiments lead me to believe that silver exists in litharge, not entirely in the metallic state :

Jan 1, 1887

By W. C. Schafer

In tunneling or mining where hydraulic shields, moles, or rock boring equipment is used lasers such as those shown guide the production machine by providing a continuous and visible line and grade reference. In this application the laser may be mounted in the heading, preferably somewhere above spring line. If we view the circular heading as a compass in the vertical plane with 0º referencing at the crown of the heading and 180º on the invert, then it might be said that the laser may be mounted anywhere from 270º through 0º to 90º. The laser is generally mounted 2 to 3 ft off the wall or the crown of the heading by means of a bracket that may be attached directly to the liner plate. In cases where no liner plate is used, then brackets may be bolted directly into the ribs, or grouted directly into the rock. Once the laser is in position the beam is projected to the face. Two points must be surveyed upstream between the laser and the face which define line and grade. Targets may be suspended beneath each of these points approximately 2 to 3 ft. These targets may be circular or rectangular with a surface area which approximates 16 sq in. Each of these two targets should have a ½ to ¾ in. hole drilled directly in their center. When the laser is adjusted so that the beam passes through the holes in each of the two targets, the laser beam itself will parallel the center line of the tunnel and become a visible line and grade reference over the total beam projection.

Jan 1, 1970

By W. J. Schuster

*Original Pages Missing From Book HANNA COAL CO., Division of Pittsburgh Consolidation Coal Co., operates three large under- ground mines in eastern Ohio. The section of Pitts- burgh No. 8 coal seam in which these mines are located varies in thickness from 52 to 64 in. It is immediately overlain by a stratum of shaly material 12 to 15 in. thick locally known as draw slate, which is structurally very weak and which disintegrates rapidly upon exposure to atmosphere. Immediately above the draw slate as it is normally found is a band of extremely high ash material 6 to 12 in. thick known as roof coal or rooster coal, and above this is a stratum of conglomerate material varying from 4 to 10 ft in depth. Overlying the conglomerate is' a relatively thick stratum of limestone, the first stable material above the Pittsburgh coal seam in eastern Ohio. With the method of full-seam mining that has been adopted, draw slate is shot down, loaded with the coal, and removed in the preparation plants. The roof coal then becomes the permanent roof. The major problem in mining the No. 8 seam in eastern Ohio is control of the roof. Since the strata above the draw slate contains no material with a structure firm enough to provide self-support, the roof begins to sag in a relatively short time after the coal and draw slate have been removed. The problem thus becomes one of getting temporary safety posts under this roof as quickly as possible to prevent a break or separation from occurring either in the roof coal or in the conglomerate above it.

Jan 5, 1954

By I. N. Zavarine

THE present paper is a continuation of the work on the relationship between the magnetic and the phase transformations in carbon steels during quenching. An account was given by the author in a previous paper1 of an investigation of this relationship during a continuous quench. The experimental difficulties then encountered prevented a conclusive proof of the existence or absence of such a relationship. The conclusions of the previous paper were derived indirectly. The present paper deals with the same problem, but the method of attack is modified. The technique developed by Davenport and Bain2 in their well-known study of austenite transformation at subcritical temperature was adopted in the present investigation.. They have shown that the austenite to martensite transformation can be caused to proceed at a relatively slow rate by quenching steels into a hot metal bath. Slowing down of the rate of transformation, together with an observation by Lewis3 that a eutectoid steel can be preserved in the nonmagnetic state by such quenching, pointed out a possibility of a study of both transformations .under more favorable conditions than previously described. The preliminary steps were connected with the technique of the hot bath quench. To study this phase of the present work a modification of the apparatus previously described1 was used. The modification consisted in the use of a hot quenching bath instead of brine, and in fixing the secondary and the primary coils of the apparatus in a stationary position in and around the bath. Tubular specimens, as in the previous investigation, were heated in a suitable furnace to a temperature in the austenitic

Jan 1, 1935

By Mowry Bates

The following example of the practical application of engineering geology is of interest in that it demonstrates the advantage of keeping accurate records of all wells, whether drilled by onn's self or by others, together with the advantage gained by gathering such data during the process of development. The fault described was found in the autumn of 1915, during the hurried development caused by the discovery of the famous Gusher Bend pool in Red River Parish, Louisiana. The writer was at the time employed by one of the operating companies as geologist, and the example is a portion of the routine work. Location The oil fields of northern Louisiana and east Texas are located in Caddo, Bossier, De Soto and Red River Parishes, Louisiana, and Marion County, Texas. A very narrow strip of the eastern portion of the latter is productive. The producing oil pools are known as the Caddo Field, in the northern part, and the De Soto-Red River Field, in the southern. The two fields are 60 miles apart. There are several gas fields between them, but no important supply of oil has been found, though there are several producing wells in the Anona chalk, locally called the Chalk Rock, in the Elm Grove gas field in Township 16 North, Range 11 West (see Plate 1). General Geologic and Structural Features The general geology of northern Louisiana has been excellently described by A. C Veatch in Professional Paper No. 46, U. S. Geological Survey; by G. D. Harris, Bulletin No. 429, U. 8. Geological Survey; and later by George C. Matson and Oliver B. Hopkins in Bulletins No. 619 and 661C, U. S. Geological Survey.

Jan 1, 1920

By C. M. Boss

Throughout the Lake Superior Basin each of the great ironranges, from which vast quantities of iron-ore have been, and are now being mined, presents characteristics differing from each and all of the others. One of the most peculiar of these varying features is found in the dikes of the Gogebic range. From an economical standpoint this feature of the dikes has been studied by our practical mining men more than any other geological phenomena in connection with the deposits of merchantable iron-ore. In the greater portion of our mines these dikes appear to form the riffles in the sluice of the ore formation, against which the particles of iron oxide are deposited in the process of concentration out of the quartzose matrix which is termed the ironbearing formation. In composition these dikes are apparently of a dioritic formation, more or less altered and decomposed, comparatively soft, and sometimes almost steatitic. While frequently showing something of a cleavage in the direction of their pitch, they are devoid of parallel laminæ, and when broken assume the form of irregular angular fragments. They are generally of nil ashy grey color, but sometimes at great depth are found to be quite dark, almost black, and of a very hard massive nature, showing radial or fibrous crystallization. Practically all of the dikes thus far discovered in the iron formation are approximately at right-angles with the dip of the formation, and the greater number of them have an average easterly dip of from fifteen to eighteen degrees. Sometimes, however, they are folded in such a manner as to form long synclinal basins; but while their western or initial extremity is fre-

Jan 1, 1898

By E. E. Brownson

THIS paper will be confined to the treatment of methods as applied in the laboratory of the Boston and Montana Reduction Department of the Anaconda Copper Mining Co. at Great Falls, Mont. As the electrolytic plant of this company operates at a current density of approximately 35 to 40 amperes per square foot when running up to capacity, the arsenic and antimony content of the anodes delivered to the, plant is of considerable importance as bearing on the purity of the refined cathodes turned out. Owing to the rather high relative percentage of antimony, it has always been the custom to determine antimony as well as arsenic in all forms of copper. Thus, anodes have been analyzed in which the antimony was about equal to the arsenic although the average shows about 2 parts of arsenic to 1 of antimony. In the refined copper the relative proportions of the two impurities vary considerably, but probably in the average are about equal. In this latter case, the percentage of the two is so small that ordinarily no attempt is made to separate them, the report of analysis showing percentage of As and Sb combined. Although rapid and exceedingly accurate determinations of arsenic may be made by means of various distillation schemes, the determination of antimony, either by itself or together with arsenic, has always been more or less cumbersome and has required a considerable amount of time. By the methods, details of which follow, the determination of arsenic and antimony, either separated as in the case of anodes or together in case of refined copper, is accomplished in 24 hr. from the time the sample is received by the chemist.

Jan 8, 1913

By Earl Bardwell

IN his paper entitled, Development of Hindered-Settling Apparatus, Dr. Richards has related the history of the development of the hindered-settling classifier and given illustrations of the several types of this apparatus which lie has designed.1 An earlier paper,2 Close Sizing Before Jigging, shows the nature of the hindered-settling phenomenon and the results which it produces. In the first-mentioned paper Dr. Richards describes the method of getting hindered settling and shows the relation that the constriction bears to the classifier. The question of proper ratios between the area of the sorting column and the area of the constriction opening Dr. Richards leaves open, aside from certain statements as to the ratios which have been found to give good results in practice. While working with a hindered-settling classifier of the type now in use at the Boston & Montana Reduction Plant of the Anaconda Copper Mining Co. a number of interesting facts were brought out which have thrown considerable light on the question of proper ratio between the area of the sorting column and the area of the constriction and which will be made the subject of this paper. Free and Hindered Settling. -If a, mineral particle be dropped into a vessel containing still water, the particle will sink in accordance with the laws of free settling in water, which are as follows: 1. Of two grains having the same specific gravity but differing in size, the larger will settle in still water at the greater velocity. 2. Of two grains having the same size but differing in specific gravity, the heavier grain will settle at the greater velocity.

Jan 8, 1913

By Thomas Carnahan

THE mining property of the Utah Copper Co. is situated in the West Mountain mining district, Salt Lake County, Utah, in the Oquirrh Range of mountains. GEOLOGY In a general way the rock formation of the district consists of a series of beds of quartzite and limestone intruded by a body of monzonite porphyry roughly elliptical in shape, with an east-west axis over a mile in length and a north-south axis of about 3,000 ft. This porphyry intrusion, accompanied by strong mineralizing action and fracturing, resulted in the formation of orebodies in the adjacent sedimentary rocks, and was itself sufficiently mineralized to make it one vast orebody. The Utah Copper Co.'s mining property comprises within its boundaries practically the entire outcrop of the monzonite mass, of a commercial grade. GENESIS OF PORPHYRY ORE Following an intricate system of fracturing, mineral solutions circulated freely through the porphyry, depositing small quantities of copper and iron, and resulting in a considerable silicification of the monzonite. The quantity of copper originally deposited was undoubtedly too small to have ever given the porphyry a commercial value, had not secondary enrichment, due to the leaching of the copper from the surface of the mass and re-deposition in the sulphide zone, been active over a long period of years. A large portion of the leached material has probably been .removed by erosion, but there still remains a blanket of leached and oxidized porphyry of varying thickness covering the sulphide ore, known as capping. Over certain sections of the orebody, this capping contains commercial quantities of copper carbonates, but most of it contains little or no copper.

Jan 1, 1916

By L. R. Jackson, W. T. Lankford, K. F. Smith

COMMERCIAL steel sheet is prepared by a combination of hot and cold rolling and annealing. This treatment usually results in more or less pronounced anisotropy. The [ ] anisotropy may manifest itself both as preferred orientation and in the manner in which impurities, segregations, and the like, are aligned in the sheet. The type of preferred orientation and the organization of impurities or segregations may affect the elastic moduli, the yield strength, the tensile strength, and almost always the amount of ductility in different directions. In any case, the most important directions concerned in the anisotropy are along the rolling direction, along the width direction, and along the thickness direction. Considerable data exist on the anisotropy of sheet steel as demonstrated by conventional tensile tests; however, few attempts have been made to measure the constants of plastic anisotropy and use them to describe the flow of anisotropic sheet under combined stresses. [ ] In this paper, evidence is presented indicating that plastic flow in anisotropic sheet can be described by the shear-strain energy flow theory provided that the anisotropy is properly taken into account. MATERIALS USED IN THE INVESTIGATION Table I lists the sheet materials used in this investigation and describes the condition in which materials were tested. DESCRIPTION OF TESTS AND TEST METHODS Two types of tests were run-tensile tests and hydraulic-bulge tests. Characteristic parameters of anisotropy were determined from the tension tests by methods which will be described later. In all cases, the tensile test pieces were cut from the same quarter line and adjacent to the bulge test pieces in the sheet in order to minimize

Jan 1, 1948

By F. E. Calkins

THE following presentation of the more important accumulated facts and probabilities involved in copper ore deposition is based on my experience in examination work and study of the extensive litera-ture of the subject; to make personal mention of all sources of information would require the naming of a small army of able geologists and other investigators who have contributed to, building up the science. I have tried to present the salient features of the subject in logical order and condensed form, and to point out the relative importance of processes involved. Doubt-less many geologists could suggest some changes and many additions. ORIGINAL SOURCE The original source of all copper was in the earth's interior; it has been brought to the outer part of the earth, within reach of man, in three ways: (1) By intrusions and flows of basic igneous rocks containing copper in minute quantities, presumably as silicate or sulfide. No orebodies have been formed by this method. (2) As segregations within intrusive igneous rocks, the copper minerals having solidified at the same time as the rock itself. The few deposits known to have been formed in this manner have been of little or no importance. The oft quoted Sudbury nickel-copper deposits are now known to belong to the class following. (3) By gaseous or liquid aqueous emanations from ,large deep-seated masses of intrusive molten rock. These emanations, or mineral solutions, ascended through zones of connected openings in the earth's crust and dropped their load at points far above their source. Deposits formed in this manner were the primary source of nearly all, if not all, of the world's copper production.

Jan 10, 1923

By David W. Brunton

The list of our past-Presidents comprises the names of many who, in their official addresses, have sketched the current progress of the arts and professions with which they were familiar. Such addresses are, in my judgment, highly useful, setting forth the results of our own work as a society, and recalling to our minds the particular lines in which discussion would prove most fruitful. Following this course with some hesitation, I venture to offer an outline of the recent improvements and the present situation in mining and metallurgy in the Western United States. The wonderful advances in mechanics, chemistry, and electricity have all combined to aid these arts to such an extent that progress during the last decade has undeniably been more rapid than ever before in the history of the profession. In all mining countries improved transportation-facilities, in many instances called into existence by the traffic created by the mines themselves, have done much to enlarge the field of operations by the reduction of freight-, operating- and living-expenses, thereby bringing lower-grade properties into the producing class. Under normal conditions, as the age of a district increases, all these different factors should combine to off-set the augmented costs attendant on deep mining, and greatly tend to prolong the profitable life of the mines. The more recent and important improvements in our Western mining-practice which have contributed most towards the advancement of the art may be briefly summarized as follows; but, before beginning this portion of my address, I wish to thank most heartily the many engineering friends who have so

Jan 1, 1910

By Henry Mulryan

DIATOMS are microscopic aquatic plants of the order Bacillariaceae. They are unicellular plants with skeletons made up of amorphous opaline silica. The skeletons show highly ornate, complicated geometrical designs. Diatoms live in water virtually everywhere. They are found in clean sea water, brackish water, and fresh-water lakes and ponds. When conditions are right, diatoms propagate by subdivision in huge numbers. Alkalinity, temperature, and the presence of high concentrations of silica in the water largely control diatom life. When the diatoms die the skeletons drop to the bottom of their habitat to form oozes of varying thicknesses. DIATOMITES Diatomite, or diatomaceous earth, is composed essentially of the siliceous remains of the diatoms, although other organic skeletons are also present, especially in sea-water deposits where radiolaria, sponges and silico-flagellates are common. Impurities are generally carbonaceous material, fine-grained silt, volcanic ash and dust, and occasional coarse grains of sand. Diatomites are marine, brackish, or fresh-water, depending upon types of diatoms and their method of deposition. DIATOMS More than 8000 species of diatoms have been named and classified. Some are definitely classified as to their habitat; some are so well recognized as to their living conditions that they can be stated to be diagnostic types, and when encountered in a deposit determine the origin of the deposit. Some of the commoner types of diatoms found in the fresh-water diatomites on the Pacific Coast are: [Cymbella lanceolata Agardh Fragilaria virescens Ralfs Encyonema prostratum Ralf s Diatoma vulgare Bory Surirella biseriata Brebison Eunotia major Ehrenberg Amphipleura pellucida Kutaing Stictodiscus niagarae Ehrenberg Gomphonema geminatum Lynberg Melosira granulata Ehrenberg]

Jan 1, 1939

By Robert L. Akright

LOCATION AND HISTORY The Candelaria silver mine is located in an arid, isolated desert setting in Sections 3 and 4, T.3N., R.35E., and Section 33, T.4N., R.35E., Mineral County, Nevada (Fig. 1). Silver was discovered in 1863 by Mexican explorers, and high grade silver veins were mined from the early 1870s through the 1880s. Essentially all mining had ended by 1890. The veins were mined by underground methods typical of the period. As is the case in many mining districts, Candelaria was studied and explored by a number of companies. All these efforts were terminated short of mine development because of low silver prices and difficult metallurgy. On March 1, 1976, Occidental Minerals (Oxymin) entered into a Limited Partnership agreement, known as Candelaria Partners, as General Partner with Congdon and Carey Ltd. No. 4. Prior to the agreement, Congdon and Carey had acquired the candelaria properties as part of a bullish silver program and did considerable exploration which indicated the possibility of a large reserve of shallow silver mineralization. GEOLOGY AND ORE DEPOSITS Silver and gold mineralization in the Candelaria district occurs in high-grade fissure veins with silver values ranging from 0.6 to 7.8 kg/t (20 to 250 oz per st). These veins, combined with the low grade disseminated mineralization in the intervening material between the veins, form Manto- like deposits 15 to 46 m (50 to 150 ft) thick. Three such deposits are found in the Candelaria district: the Lucky Hill, Mount Diablo, and Northern Belle deposits (Figs. 2 and 3). The average ore grade of the Lucky Hill and Mount Diablo [ ]

Jan 1, 1985

By J. G. Thompson

OXYGEN, nitrogen and hydrogen are present in practically all metals in one or more of the following forms: (1) molecular gas in blowholes or blisters, (2) combined in nonmetallic inclusions such as nitrides, oxides or silicates, and (3) in solid solution in the metal. Gaseous elements, in some of these forms, are encountered in practically all metals and alloys but possibly have received most publicity in connection with iron and steel. In fact, the entire steel industry depends upon the control of the oxygen content during the refining process, as well as in the finished material, and it was only after the adoption of the use of efficient deoxidizers such as manganese that the production of good steel with a low carbon content became possible. In normally clean, sound steel the amount of hydrogen is negligible and the amounts of oxygen and nitrogen vary from a few thousandths to a few hundredths per cent. However, many of the effects attributed(27,31,40.41,53,54,55,56,62) ? to the presence of these elements are important and at first glance appear to be out of proportion to the amounts of impurities involved. The presence of oxygen is believed to affect the solubility of carbon in austenite and ferrite and thereby to affect the structure of the iron or steel. Such properties as strength, hardness, ductility, elastic limit, impact resistance, magnetic permeability, tendency toward caustic embrittlement, irregularity in carburization, the cutting life of tools, certain corrosion phenomena, the presence of flakes, seams, bands, ghost lines and hair cracks, and the tendency to age-harden, all have been attributed to the presence of oxygen.

Jan 1, 1932