Search Documents

By Mary Sue Coates

Characterization of the rock mass in which deep underground structures are to be located is of critical importance to the feasibility and design of the structures. The process involves areal studies, subsurface exploration and extensive testing to obtain comprehensive data on the rock units which will enclose the excavated structures. The Illinois Deep Hole Project provides an example of characterization of rock at great depth describing the types and variety of tests and studies which were utilized and the results obtained.

Jan 1, 1984

By Kenneth L. Zonge

Recently, extensive field use has been made of a digital minicomputer incorporated into a modified geophysical prospecting method. This is a generalized induced polarization (IP) system called complex resistivity (CR) and has been successfully used in sulfide mineral exploration. The ease of use, portability and cost effectiveness of this computer-controlled method has provided a viable exploration tool based on a complex data acquisition system. Without the computer, this method would still be relegated to tedious laboratory measurements and theoretical studies.

Jan 1, 1976

By Joseph D. Weeks

FIFTY-eight years and a day, full of labor, of achievement and of honor had been completed when, at Pittsburgh, on the 5th day of May, 1892, the wheels of a life that had but just before lost its inspiration stood still, and the work here of William Powell Shinn was at an end. Born at Burlington, N. J., May 4,1834, he received such an education (and it was. the only school education he ever had) as the public

Jan 1, 1893

By Cleland N. Conwell

Reclaiming mined land in northern regions is less difficult than reclaiming semiarid lands. In 1972, the Usibelli coal mine near Healy, Alaska, initiated experimental plots to determine the proper grasses and amounts of fertilizer. The following spring, approximately 1600 acres of land disturbed by mining were seeded by low-flying aircraft. The reclamation project was evaluated by the State of Alaska and has been adjudged successful. The information gained is being used in reviewing prospecting permits and granting coal leases on state lands.

Jan 1, 1977

By K. A. Natarajan, I. Iwasaki

The influence of dissolved oxygen and the Pt - Pt-O reaction on the measurement of redox potentials in solutions containing ferrous-ferric couple was examined. Current-potential curves were used to illustrate the shift in measured potentials toward the oxygen potential in oxygenated and deoxygenated systems at low concentrations of ferrous and ferric ions. The ranges of concentrations of the ferrous-ferric couple, in which the interference from oxygen and the platinum-oxygen reactions becomes significant, are illustrated through the mixed potential mechanism.

Jan 1, 1975

By E. J. Schmitz

Coming from San Antonio, Texas, and following the Galveston, Harrisburg and San Antonio Railroad westwards, one enters soon the Cretaceous formation, which forms a belt of several hundred miles, extending westwards to the boundary of Arizona and across the Rio Grande into the State of Coahuila, Mexico. The members of this formation are very numerous and in petrographical character very diverse—from a whitish or bluish, slaty, impure limestone to a hard, beautiful blue-and-red striped, and a compact heavy-bedded,

Jan 1, 1885

By John T. Awald

The Bradshaw Mountains of west-central Arizona cover an area of 1600 square miles and contain numerous old mines and prospects. The area has been geochemically sampled on a reconnaissance basis to relate mineralized areas to regional structure and rock types. Copper analyses of stream sediments have been classified and contoured to show the distribution of low and high backgrounds and low, intermediate, and highly anomalous areas. Contoured results are compared to geology and known mines. Several prospecting areas are indicated.

Jan 1, 1972

By J. W. Bolton

PRODUCTION of sound bronze castings is a matter of great practical interest to users and manufacturers of high-grade non-ferrous engineering specialties. Although there has been much excellent research in this field, there still remains some confusion regarding the fundamental principles underlying production of really sound bronze. The literature of the past 20 years on this subject indicates that the prevailing opinion of metallurgists and foundrymen has been that unsoundness in bronze is due generally to oxidation. The following references are typical.

Jan 1, 1929

By H. C. George

At the annual meeting of the Institute in February, 1927, we had a comprehensive discussion of Petroleum Engineering Education. This discussion covered basic training and prerequisites, laboratories and equipment, graduate courses, availability of lecturers, geological engineering, petroleum production engineering, refinery engineering, transportation engineering and economics and management. However, there are several phases of petroleum engineering education, which many members of the Institute felt should be further discussed at this year's meeting. The first was expressed by me in a letter to those participating in the written discussion, from which I quote as follows: "We fell that the question of handling engineering graduates who enter the petroleum industry should be thoroughly discussed. "During the first five years after graduntion from college, how can these young men be best trained to be of the greatest service to the industry and at the same time do work which will be interesting and of a character which will make them feel that they are accomplishing something and making progress leading toward personal advancement?" Both the written and oral discussion would indicate three groups of opinion; first, those who advocate letting the young engineers go into the industry and take care of themselves without any supervision, direction, or guidance; second, those who advocate the taking of young engineers into the industry and letting them go through all the steps that any laborer or any other mian without a technical education would take, but with some supervision, and third, those who advocate that young cngineers should be given special training for several years after entering the industry. Of course all of these different groups are found in rnost of our industries. The Doherty training school of the Empire Gas & Fuel Co., finds its counterpart in the practice of the Gcneral Electric and Westing-house companies in the electrical industry and the Baldwin and Brooks Locomotive works in mechanical engineering.

Jan 1, 1928

By A. J. Strane

PRACTICALLY all explosives may be classified as those that burn and those that detonate. Explosives of the first class include .black blasting and smokeless powder and are broadly known as low explosives, or propellants, because they merely burn and do that comparatively slowly. Their action is as if some power behind the projectile or other material were exerting a shoving or pushing action. The high, or detonating, explosives produce a smashing or shattering effect upon the material. In using military- explosives of the propellant class, the breach of the gun, or cannon, is proportioned to hold the pressure, so that the projectile will be blown out. Exactly the reverse is true in commercial work; then it is the "breach" or the hole that is to be broken. The projectile and the explosive are therefore chosen that will rupture the largest "breach" possible. With the high explosives, it is easy to break out the breach (that is why they are of no value as military propellants)" but with some of the low explosives it is necessary to plug up the muzzle very carefully before shooting. Doubtless the use of incendiary mixtures of oxidizing and combustible materials led, in the 13th century, to the perfection of the mixture which is practically the same as our commercial black blasting powder of today. About 600 years later, nitroglycerine was discovered, but for years its great potential energy could not be used because, in its liquid state, it could not be safely handled or transported. The accidental discovery that kieselguhr would absorb, and hold fairly well, three times its own weight of nitroglycerine, however, made it available. "Guhr dynamite," as the combination nitroglycerine and kieselguhr was termed, was soon displaced by dynamites having an active base, such as wood pulp and other carbonaceous combustible materials. These do all that kieselguhr will do and, in addition, increase the chemical reaction and add materially to the effectiveness of the blast.

Jan 8, 1920

By Minoru Sasabe, Mayurni Sorneno, Kazuhiro Goto

I) The Object of the Present Experiment. When the oxygen chemical potential in the gas phase is changed, the oxygen chemical potential in the liquid metal or in the liquid oxide phase will be subsequently changed. The object of the present experiment is to develop a method of measuring the change in the chemical potential of oxygen in liquid metals and in liquid oxides with respect to time, when the oxygen potential in the gas phase changes. II) The Experimental Method. The following types of the oxygen concentration cells with the solid electrolyte of Zr0z-CaO are used: KAZUHIRO GOTO, MemberAIME.MINORU SASABE,and MAYUMl SOMENO are Associate Professor, Research Associate, and Professor, respectively, Department of Metallurgical Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo, Japan. Manuscript submitted March 12, 1968, EMD. Igas phase liquid Ag or Pb ZrO2-CaO electrolyte!, The measured reversible electromotive force can be expressed by the next equation, provided that the transference number of the oxygen anion in the electrolyte is unity: E = RT/nF log (at electrode I)/P~ (at electrode 11) where is the electromotive force, R is the gas constant, T is absolute temperature, n is valence of oxygen anion, and Pq is the oxygen pressure at the electrodes. As shown in the previous work1 of the authors, the electromotive force is determined by the difference in the chemical potential of oxygen at the vicinity of the interfaces between the solid electrolyte and the electronic conductors used for the two electrodes. Fig. 1 shows the two kinds of the cell assembly used to measure the change of the chemical potential of oxygen in liquid metals and liquid oxides with respect to time. In both cases, the change of the oxygen pressure in the gas phase is measured by the independent oxygen concentration cell located above the

Jan 1, 1969

By William P. Blake

IN southern Arizona and in Mexico the word caliche is in general use to denote a calcareous formation of considerable thickness and volume found a few inches, or a few feet, beneath the surface-soil, upon the broad, dry, gravelly plains and mesas. In western South America the same name is applied to the beds of crude soda-niter (Chili saltpeter). While these deposits of South America and of Arizona are totally different in composition, and have nothing in common, except that both occur in layers in the strata near the surface, it is probable that an explanation of the origin of the calcareous beds may equally apply to the accumulation of sodaniter and other deposits of easily soluble minerals. But the name, taken from the Latin, Calx, is more appropriate to the calcareous beds than to those of niter. Caliche has a wide distribution in the arid regions of Arizona and Mexico. It is usually hidden from view by a slight covering of soil; but it is easily found by digging, and is often revealed by a flow of water during heavy rains. It is practically a continuous sheet, from three to fifteen feet thick, of earthy limestone or travertine, through which the smaller plant-roots find their way with difficulty. The presence of this comparatively impervious layer of cemented earth may account for the absence of trees, or of the larger shrubs, over wide areas. The shrubs which gain a foothold are those whose roots do not extend far downwards, and which do not require much water, such as Larrea Mexicana and the [Cactaceoe]. If trees are planted, it is necessary to break up the caliche by blasting, or at least to crack the upper layers. The top of the caliche is more dense and solid than the lower portions. The surface of this top crust, or layer, is comparatively smooth, though undulating, while the lower portions, under the crust, are irregular, cavern-

Jan 1, 1902

By L. C. Morganroth

CARBONIFEROUS CLAYS FROM a geological standpoint, but scant attention has been paid to fire-clay beds. Only within the last few years have they been the subject of individual investigation, prior to this time having been considered only in their relation to coal seams. While the relative importance of coal and fire clay is still immeasurably in favor of coal, yet an industry as large as that of fire clay is entitled to a measure of attention. A discussion of the Carboniferous clays is practically a discussion of the clay beds in the Appalachian basin, since more than 90 per cent. of these clays mined are from this region. The clays are confined to the northern end of the basin, or the States of Pennsylvania, Ohio, Kentucky, Maryland and West Virginia, ranking in importance about in the order named. The clay deposits of the Carboniferous period have been divided into two classes; those found in the Pottsville conglomerate series of rocks, and all those that are found in the formations above, for the reason that the clay beds above the Pottsville series all resemble each other in properties, composition and appearance, and all are distinctly different from the bed found in the Pottsville formation. The bed of clay found in the latter formation is unique in that flint clay is practically restricted to it. (A variety of flint clay is occasionally found in these upper deposits but this is in such small amounts as to be negligible.) Carboniferous clays occur between stratified rocks; sandstones, limestones, etc., in the same manner as coal veins. They are often accompanied by a coal vein although where the clay is of a workable thickness the coal is generally too thin to work. The clay beds are sometimes known by the name of the coal seam at which horizon they occur. Clay beds may be from a few inches up to 20 ft. in thickness. They may consist of all soft clay all flint or both soft and flint.

Jan 2, 1916

By W. A. Barrows

Mesabi ores differ from all other soft hematite-ores of the Lake Superior region in having but little or 110 binder. When exposed to heat, instead of baking into lumpy masses as do the Gogebic, Menominee or Marquette fine ores, they are changed to a sandy powder; and the finer particles, having little or no tendency to adhere together in the furnace, are carried by the ascending gas-currents into the down-comers and gas-mains forming flue-dust of a fine gritty nature. The term " finer particles " is used in this paper to mean ore fine enough to pass through a sieve with 80 meshes to the linear inch. Ore coarser than this is not likely to be carried over except in case of a slip, or an explosion in the furnace. The higher the percentage of fine particles in an ore from this range, therefore, the greater the amount of dust likely to result from its use. This statement, however, does not hold good in case of fine ores from the other ranges, and ores from the older ranges, carrying as high as 20 per cent. of material fine enough to pass through a 100-mesh sieve, have been in successful use for years, and have left no records of their causing trouble in furnace-practice by dust, slips, or explosions, so common since the introduction of Mesabi ores. Mesabi ores containing less than 12 per cent. of material which will pass through an 80-mesh sieve are considered of good structure; from 12 to 18 per cent., fair structure; and more than 18 per cent., poor structure. It was at first supposed that all these fine particles were carried over when the charge was lowered into the furnace, or during a slip, but the presence of partly reduced iron oxides in the flue-dust, even when no slip has occurred, proves that a part of the dust at least must have been low enough in the

Jan 1, 1905

By C. W. Washburne

THE waters of many oil fields have been regarded as buried sea water which has been retained in the sediments since the time of their deposition. The preservation of connate water through geological time has seemed improbable to only a few geologists, but there is room for doubt that buried sea water could remain in the strata during their periods of deformation and during the many subsequent epochs of. the circulation of meteoric ground-water. Some have even suggested that the calcium chloride water in the deep mines of the Lake Superior region is ancient sea water buried in the Algonkian lavas, but it is hard to understand how such water could be derived from the highly sodic and sulphatic water of the sea. It would seem more plausible to connect the calcium chloride with the highly calcic magmas of the greenstones in which it is found. Chemical analyses of waters associated with oil differ widely from the composition of sea water, requiring extensive alteration of the latter, if the former is truly its derivative. The first notable difference is the general absence of sulphates from oil-field waters, but this has been explained satisfactorily through reduction by hydrocarbons and organic matter. Oil reduces sulphates with the production of hydrogen sulphide (or sulphur), water, and carbonates (or carbon dioxide). The second striking difference is in the high ratio of chlorine to sodium. An examination of the analyses of chloride waters from oil fields shows that they contain a large relative excess of chlorine over that in sea water. Moreover, there is difficulty in finding chemical reactions that are probable in nature, by which sea water could be converted into anything like the chloride waters of oil fields. In the latter a large part of the chlorine occurs as calcium acid magnesium chloride. This condition might be produced by the removal of sodium carbonate, which; however, cannot be precipitated in the presence of much calcium or, magnesium.

Jan 3, 1914

By Lyndon L. Foley

The proper spacing of oil wells is a problem of vital importance to the oil industry. Conservation demands a maximum recovery, while economic considerations attach primary importance to profitable extraction of oil. Formulas have been evolved,1-4 which attempt to solve the spacing problem mathematically, using reservoir characteristics as factors. Comparisons have been made of fields producing from supposedly similar sands, which have been drilled to varying densitiesl5,6 and also of different leases in the same field. 5-8 Intermediate wells have been drilled in old, depleted fields to test the efficiency of drainage by the original operation.9-11 Intermediate wells have been drilled also to obtain cores of the depleted sand for analysis, from which to learn the degree of efficiency of extraction. The problem is being attacked by many students, and along several different lines. Unfortunately, the fields now depleted were produced generally without restriction, and conclusions drawn from them may not apply to fields operated under restricted production. Reservoir conditions in a restricted field, especially reservoir pressures and pressure gradients within the reservoir, are quite different from those in a field produced to capacity. Many people have held the idea that the closer the spacing, the greater the recovery. This general statement is not always true, as other factors than well spacing enter into the recovery problem. Cutler,5 who has been quoted frequently by advocates of close spacing, limited his conclusions to gas-drive fields, and to the particular fields and spac-ings that he investigated. Hill and Sutton7 analyzed four tracts in the Powell field; the tract most closely drilled had the third largest recovery per acre-foot, and the tract with the widest spacing had the second largest recovery per acre-foot. A search of the references to well spacing in the publications of the U. S. Bureau of Mines5,13-19 discloses repeated condemnations of the wastefulness of the practice of town-lot drilling.

Jan 1, 1938

T. W. ROBINSON, Pueblo, Colo.: Mr. Potter's review is a striking testimony to the important part played by science in this branch of practice. But, the question arises, In which department has science effected most ? The available raw material, the size of furnaces, the general design and equipment of the plant, and the daily management, are particulars, each of which contributes to the general result, while the effect of each merges into that of the others. The following notes concerning the operations of the furnace-plant of the Colorado Fuel and Iron Company (formerly the Colorado Coal and Iron Company), at Pueblo, may throw some light upon the question of their relative importance. This company operates three stacks, and when the plant first came under my observation, about nine months ago, the furnaces were constructed, equipped,and run as stated below: Raw Materials.—The main sources of ore-supply were, as they still are, the Orient and Calumet mines of the company. The Brecce and Morning Glory ores, mentioned below, were formerly brought from Leadville, but are practically now no longer used. The Orient ore is a porous brown hematite, easily reducible in the furnace. The Calumet is a magnetite, very refractory in character, requiring preliminary roasting. Both are fairly uniform in composition. The Breece and Morning Glory are red hematites, resembling in appearance the soft ores of the Vermilion range, Lake Superior. The coke here used is made of coal from the company's mines in southern Colorado, and is distinct from that produced by the company in the western part of the State. The structure is similar to that of Alabama coke. The limestone employed is a calcite. The analyses are given in Table I. I would note, parenthetically, that I know of no section of the country presenting harder conditions for furnace-practice than these materials impose. Results cannot be measured by the more

Jan 1, 1894

By Owen Rice

CHANGES in coke hardness affect the working of the blast furnace, for soft coke is an obstacle to proper furnace operation. Soft coke is due to a low hydrogen-oxygen ratio in the coal charged; increasing this ratio increases the hardness of the coke. The best means of determining the hardness of coke is the combined tumbler and ball-mill. Soft coke is a great hindrance to proper blast-furnace operation and changes in coke hardness affect the working of the furnace. The best method of determining the hardness of coke is by using a combination tumbler-ball-mill. Soft coke is due to a low hydrogen-oxygen ratio in the coal charged. An increase of this ratio improves the hardness of the resulting coke. WHAT IS GOOD COKE? It is not always appreciated that the correct answer may be such a reliable forecast to the physical condition of the blast furnace, and incidentally its entire operation, that among the ordinary variations in other raw materials and also in operating conditions, it assumes a position of primary significance. Inasmuch as coke forms two-thirds of the total bulk of material charged, this assertion will not seem exaggerated, and in the subsequent discussion its applicability will be presented. Coke is the ideal blast-furnace fuel because it is strong and hard enough to resist the crushing and grinding effects of the furnace burden, and its porosity allows the ready passage of gas upward through the charge, and rapid combustion before the tuyeres. Coke deprived of its strength and with a cell structure physically frail and chemically susceptible to solution by carbon dioxide, has its chief asset eliminated. When the melting zones are approached the fluid cinder trickling toward the hearth will envelope the small pieces of coke and form a sticky mass that will retard the free passage of gas. Blast pressure will then rise, driving

Jan 1, 1921

By Ira B. Joralemon

The sampling of disseminated copper deposits has been describeu often but the method of combining assays to give the true shape and value of the orebody as it will be mined has received less attention. As the ore mined during five or ten years at several of the great disseminated properties has averaged materially lower in grade than the published estimates, the question of the sampling and estimating of these orebodies seems timely. In this paper, attention is given particularly to factors that may cause errors in the final estimate. Sampling of diamond-drill holes, churn-drill holes, and underground workings is briefly described in the first part of the paper; then the method of combining assays to give the average grade and tonnage that will be mined is taken up in some detail. The necessity of study of the geology of the deposit and of probable costs is emphasized. Finally, the methods of calculating tonnages are outlined. DlAMOND-DRILL SAMPLING There are three main requisites for accurate diamond-drill sampling. First, the core should be removed and the hole cleaned out at the beginning of every sampling interval, usually 5 ft. (1.5 m.). After the rods are let down, water should be run through them until it becomes clear. The water must be clear before drilling starts. 'In this way the material knocked down from the sides of the hole by the descending rods is washed away, instead of being left to salt the sludge sample. The second requisite is to save all the sludge and all the core from every sampling interval. Where the material is uniformly heavy, the cuttings will settle suffciently in a box, through which the sludge flows s1owly.l Where part of the material is too light to settle readily, the sludge should be run into barrels, and allowed to settle until the water becomes clear. Then the clear water is siphoned off, and the sludge evaporated to dryness over a slow fire, sacked, and assayed.2 To obtain

Jan 1, 1925

By R. R. Hawkins

PEoperly designed tubing strings make it possible to continue the flowing life of wells beyond the stage where ordinarily they would be put to pumping. Wells no longer able to flow through 2-in. tubing can be made to produce through smaller tubing if conditions within the well are carefully studied and correctly designed strings are installed. In this way, pumping expense may be postponed and in some pools it is within reason that the entire recovery may be obtained by natural flow if maintenance of pressure is practiced. Infrequent tubing changes would be necessary but their cost would be much less than that of installing and maintaining pumping equipment. If small wells are to be made to flow naturally, careful consideration must be given the actual lifting mechanics within the string, so that fairly accurate knowledge of reservoir conditions, especially pressure, is essential. Wells producing between 5 and 25 bbl. daily are classified here as "small wells." Exponential Flow A maximum of the energy contained in the expanding gas must be employed to do useful work if natural flow is to be continued. It is evident that adiabatic expansion would defeat this purpose, therefore the velocity of the gas must be held down to a minimum in order that isothermal expansion may be approached. Of course, true isothermal expansion would not be obtainable in an oil well, hence the use of the term "exponential." 1 Obviously the closer the approach to isothermal expansion, the more efficient the lift. Experiments by the U. 8. Bureau of Mines² have shown that for isothermal expansion to take place in a gas well where water is being produced, a definite relationship exists between the depth of the well and the minimum operating pressure. The latter must be such that the tubing fill-up, if static conditions prevailed, would be equivalent to 14 per cent of the distance between the top of the fluid inside the tubing and the tubing head. It has been observed that variations in this essential ratio

Jan 1, 1932