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J. L. McK. YARDLEY,* Pittsburgh, Pa. (written dlscussion ?) .-It is interesting to observe how closely Mr. Hansen agrees with other investigators to the effect that the art of electrolytic zinc has left the realm of mystery. In his introduction, lie has said practically what Thomas French said in his paper "The Future of Electrolytic Zinc. "1 The successful electrolysis of zinc from sulphate solutions has not been an easy matter, and it is only within recent years that the difficult problem of depositing high-grade zinc has been satisfactorily: accomplished on a commercial basis. The principal requisite is. that the electrolyte shall be quite free from certain impurities. The methods by which freedom from these impurities is assured are now very well understood, and with experienced superintendents there is little difficulty in obtaining a high efficiency in that part of the process. When certain underlying principles are recognized, the difficulty encountered in dealing with the filtration of the acid and slimy solutions also largely disappears, although it has been a very serious one to the uninitiated. In the dissolving of the zinc from the roasted ore, there is nothing which any competent chemical' engineer cannot undertake, and any other operations connected with the electrolytic process are either of little or no difficulty, or are common to the retort process. Mr. Hansen also agrees with R. G. Hall's statement in " Some Economic Factors in the Production of Electrolytic Zinc:"2

Jan 10, 1918

By Emery C. Olsen

Most coal mining areas of the Western United States are characterized either by thick beds, steep pitches or heavy cover. Individually, each of these may present inherent safety hazards that influence mining. When all are met at one location, the combined effect is to make the safe operation of the mining property a challenge to management. These combined conditions are met in the coal mines of the Columbia-Geneva Steel Div. of the United States Steel Corp., in southeastern Utah. This coal bed measures up to 16 ft in thickness, the pitch is as much as 25 % and mining is under a cover approaching 3000 ft. The Sunnyside coal bed is found in the Book Cliff Mountains, a great escarpment extending from west of Castle Gate, Utah, some 180 miles to Grand Junction, Colo. West of Green River, Utah, the Book Cliffs swing sharply to the north because of the domelike uplift of the San Rafael Swell to the south- west. It is in this northerly extension of the Book Cliffs that the Sunnyside coal in the Blackhawk Formation of the Mesa Verde Group, Upper Cretaceous Age is found. The strata are transected by numerous faults with from a few inches to as much as a hundred feet of displacement. All of these faults have had some effect on the mining operation, either in roof control or, in the case of major faulting, the pattern of mine development.

Jan 10, 1963

By C. M. Loeb, A. M. Gaudin, J. H. Brown

THE object of most size reduction operations in the mineral industry is to liberate the grains of valuable minerals in the ore from those of the gangue. This is usually accomplished by crushing and grinding the entire mass of ore until there is only a small probability that any single particle contains more than one mineral. During this size reduction only limited control exists over size or composition of the particles exposed to the breaking action, and there is no control over the paths followed by cracks generated during the operation. This lack of control usually results in overgrinding and in production of large quantities of very fine material. The first detriment, overgrinding, is costly in itself, but when combined with the second factor it is doubly so. Not only is the fracture of a free particle unnecessary-the fracture of these particles may also make subsequent separation operations difficult, inefficient, and wasteful. It has been pointed out' that if the object of size reduction is to liberate the valuable mineral component of the ore then, ideally, fracture should follow intergranular paths to the exclusion of trans- granular ones. This would result in liberation of the valuable minerals with as little size reduction as possible. This ideal comminution operation is referred to as intergranular comminution, and it was the object of the investigation to determine the extent to which it could be developed by heat treatments.

Jan 4, 1958

By F. F. Lines

IT is not the intention of the writer to enter into a discussion of the relative merits of the duplex process as compared with the straight scrap and pig iron process, working under the same conditions, but rather to present in a general way several modifications of the former process, and then describe the method adopted by the Maryland Steel Co., as best suited to local conditions, and also to meet the metallurgical problem presented in the removal from the iron of an unusual constituent-chromium. The principal factors to be considered in deciding whether or not duplexing should be employed are: (1) Chemical constituents of pig iron. (2) Variety and quantity of steel to be produced. (3) Relative cost of pig iron and scrap. (4) Regularity of operation. (5) Capital to be invested. (6) An existing Bessemer plant. Having decided to adopt the duplex process, several combinations may be used, viz.: (1) Acid-lined converter with basic open hearth. (2) Acid-lined converter with electric furnace. (3) Basic-lined converter with basic open hearth. (4) Basic-lined converter with electric furnace. (5) Basic open hearth with electric furnace. The combination of an acid-lined converter with a basic open-hearth furnace is the one most commonly employed, and as it is the one best adapted to the conditions encountered at the plant of the Maryland Steel Co., we will briefly outline the advantages and disadvantages of the different methods of working.

Jan 4, 1915

By H. P. Greenwald

THOSE interested in the early developments and experiments, both in the United States and abroad, that led to modern rock dusting, will find an excellent summary in a paper by George S. Rice,13 published in 1914. The period from 1914 to 1924 was one of intensive experiment on coal-dust explosions in the United States; abroad, war activities and rehabilitation stopped this work over a large part of that decade. Amer-ican findings were published by the Bureau of Mines, particularly in Bulletins 167 and 268. It is convenient to consider that in the United States rock dusting to prevent coal-dust explosions in mines was initiated in 1924 with the publication of tentative specifications.17 This was followed in 1925 by an investigation of methods and costs12 and approval by the American Engineering Standards Committee of a Recommended American Prac-tice.18 Approximately 13 years have elapsed since this approval, and inasmuch as changes in rock-dusting practice in the United States have been evolutionary, it is necessary to consider this entire period as "recent" in some phases of the work. There have been no official changes in the Recommended American Practice since its approval. This paper reviews as briefly as possible knowledge acquired since the issue of the earlier papers mentioned, through experience in mines and experiments conducted by different organizations engaged in the pro-motion of mine safety.

Jan 1, 1938

By L. R. Budrow, R. T. Mishler

The Lucky-Tiger mine is a silver-gold property, situated at El Tigre, in the northeastern part of Sonora, Mexico, at an elevation of 6000 ft. in the Sierra Madre Mountains. It is 30 miles by wagon road from the Esqueda station on the Nacozari railroad. Since its discovery in 1903, the mine has produced forty million ounces of silver. The ore has averaged 40 oz. silver and 0.25 oz. gold per ton. Copper, lead and zinc have been of minor importance, having averaged 0.4 per cent., 1.1 per cent., and 1.5 per cent., respectively. The richness of the ore, combined with its occurrence in narrow veins, required the use of the more expensive methods. of mining. Geology Wall Rock The wall rock is rhyolite and rhyolite tuff, both of Tertiary age. In rare instances, post-mineral andesite dikes have been intruded along the veins. In the upper part of the mine, the walls were fairly solid. On the lower levels, the walls are usually cither kaolinized and soft or silicified and fractured, both conditions requiring closely filled stopes or much timber. Veins The veins have been deposited along fracture planes in the volcanics. There are three principal veins, about 600 ft. apart, all striking nearly north-south and dipping steeply to the west. Table 1 records the approximate dimensions and assay of the veins. Although the average

Jan 1, 1925

By Richard Franchot

FERROUS metallurgy today, defined as the art of extracting money from iron ores, appears to suffer from a complex of inherited theory. In so far as pig iron costs contribute to inadequate profit margins, this symptom may be diagnosed as due to persistence, despite disproval, of Sir Lowthian Bell's theories of reduction. An attempt to meet the economic situation by reducing costs through improving blast-furnace metallurgy would be inconsistent with Bell's theories. These theories, though refutable on the facts of practice, still prevail and today's metallurgy, as measured by its fuel economy or smelting efficiency ranging between 30 and 40 per cent. is no better than Bell's, showing a specific efficiency of 36 per cent.1 If fair to neglect dry-blast operations, it appears that the advance in furnace practice since Bell's day, as shown by a tenfold increase in individual furnace capacity, has been largely mechanical and that the metallurgy of the process has not been changed materially, since the introduction of blast heat, patented in 1828. It seems fair to attribute, this lack of progress on the strictly metallurgical side to a domination of the industry by false ideas first expressed by Lowthian Bell. What the furnace seems to need first, in the interest of lower costs and of better iron, is some destructive criticism of these ideas, in moderate doses, to be followed by a constructive theoretical treatment; then, research and still more research.

Jan 1, 1929

By Marshall D. Himes

The Pima mine, Pima County, Ariz., a 53,500-tpd copper mine, is located 17 miles south of Tucson, Ariz. The mine is in a sequence of Paleozoic and Mesozoic sediments striking east-north-east and dipping southeasterly. These sediments are intruded by a Tertiary quartz monzonite porphyry. The Paleozoic Permian (?) dolomites, limestones, and sandstones have been altered to calc-silicate skarn, marble, and quartzite. The overlying Mesozoic Triassic (?) clastic sediments have undergone some recrystallization and hydrothermal alteration. The clastic metasediments are divided into three distinct lithologic units: lithic arenite, arkose, and interbedded and overlying black argillite. Three types of hydrothermal alteration in the clastic rocks are propylitic alteration (epidote, chlorite, and quartz, with or without sericite), quartz-sericite alteration, and potassic alteration (K-feldspar, quartz, and sericite, with or without chlorite and calcite). The porphyry has undergone potassic alteration. Dominant structures are an east-west postmineral fault in the western part of the pit, and strong low angle faulting and shearing which truncates the ore body at depth. The two joint sets, one parallel to bedding and the other at right angles to bedding are prominent in the mine. Faulting is in two dominant directions, one striking northwest, dipping northeast, and the other striking northeast, dipping northwest. Economic mineralization is prediminantly disseminated pyrite and chalcopyrite, and molybdenite-quartz veinlets. There are less important amounts of magnetite, hematite, sphalerite, galena, tennantite, and bornite. Mineralization is believed to be both structurally and chemically controlled.

Jan 1, 1974

By C. S. Sivaramakrishnan, Manjit Singh, Rajendra Kumar

Regarding liquid nzetals structurally as a suspm-sion of clusters , having derivated solid-state coordination, in truly liquid atoms, the recently developed Kuvlar-Samarin technique of centrifuging- in liquid state enabled the determination of the cluster sizes inAl-Cu mid Pb-Sn systems. It is shown that the colutne fraction of the clusters does not exceed 9 pct and the energy of their formation in Al-Cu is about 5.5 kcal per g-atom and in Pb-Sn eutectic alloys about 25 kcal per y-atoni. STRUCTURAL investigations of liquid state have principally followed the following three courses: i) studies with X-ray, electron, or neutron diffraction; these investigations have shown that there is a certain amount of regularity in the structure of liquid metals which can be defined by a coordination number and that the structure is a derived function of that in the solid state; ii) thermodynamical investigations which are based on the concept of ideal behavior; these describe the liquid state in terms of free-energy values and other thermodynamic functions; although these investigations are of help in the study of the general effects of alloying, they do not provide any structural insight into the precise atomic distribution in liquid state; iii) measurements of surface tension and viscosity; although it is natural to expect that the viscosity is related to the structure in liquid state, these investigations have so far only provided information which can be used by the foundry technologists and has been little utilized in formulating models of the structure of liquid state. As it happens, investigators in the three groups have worked almost independently of each other and there is practically no structural correlation between the results of one group with those of another. The purpose of the present paper is to indicate that the experimentally measured parameters of these three groups of research are closely related to the structure in the liquid state. STRUCTURE OF LIQUID METALS Although atomic distribution in solid and gaseous states is rigorously known, that of the liquid state is only appreciated on the fringes. There is no universal model of atomic distribution in liquid state, but two diverse models are at present hotly contested. The first, largely expounded by ~ildebrand,' regards the liquids as condensed gas since many of their properties and much of their behavior can be adequately described by regarding them as fluids. The second mode12j3 considers that some form of near-solid as- sociation of large number of atoms exists in the liquid state. On the other hand, ~ernal' was able to predict rather precisely the radial distribution functions in liquids on the basis of statistical geometric approach which considered that liquids are "homogeneous, coherent, and essentially irregular assemblage of molecules containing no crystalline regions or holes large enough to admit another molecule". He introduced the concept of pseudonuclei in the otherwise random structure as aggregates of closely packed tetrahedra which gradually merge into irregularity and continually replace each other. To what extent the pseudonuclei can be regarded as regions of near-solid association is indefinite but Bernal suggested that the concept of pseudonuclei can be compromised with the latter model if the near-solid associations are regarded as extremely dense and not necessarily crystalline. The difficulty in projecting the structure of liquid metals arises because they exhibit duplicity of character as some of their properties are closer to those of crystalline solids and others to fluids. There is an increasing tendency to discuss the structure of liquid metals in terms of the second concept according to which the structure of liquid metals may be conceived as consisting of i) clusters of atoms where the aggregation is a close derivative of that in the crystalline state, ii) individual atoms which behave like true liquids in respect to degrees of freedom and iii) excess number of vacancies. It is noteworthy that the introduction of only 5 pct vacancies is sufficient to transform crystalline matter into the liquid state. At any instant of time thermodynamic equilibrium exists between i, ii, and iii, but the relative proportion of the clusters and random atoms is not known. That this is so can be appreciated by the fact that, when liquid metal is rapidly cooled, liquid state vacancies may condense in the form of dislocation loops and vacancies in excess of their equilibrium number in solid state. These dislocation loops have been observed in thin foils of aluminum prepared from rapid cooled aluminum. As temperature increases above melting point the number and volume fraction of clusters decrease but those of vacancies and random atoms increase. Clusters are transient in nature. In pure metals the cluster is an aggregation of the metal itself. In alloys, however, the nature of the cluster largely depends on the interaction between solvent and solute atoms. If the interaction between unlike atoms is greater than between like atoms: the clusters are then aggregates of unlike atoms. Examples of this kind of system are A1-Cu, Mg-Pb, and so forth, i.e., systems which exhibit negative departures from the Raoult's law. In systems where the interaction between unlike atoms is smaller than be-

Jan 1, 1968

Jan 1, 1903

By E. A. Lawrence

The experiences of Canex Placer Ltd. in establishing vegetation on a lead-zinc tailing pond are presented, hoping others with similar challenges will be benefited. History The tailing ponds are the result of 23 years of mining and milling operations, which ceased in August 1970. Roughly 7.9 million tons of lead-zinc ore were removed in that time. The ponds are located between Salmo River and B.C. Highway 3, about 8 miles north of Nelway near the Canada-U.S. border.

Jan 1, 1975

Societies, Boards, Etc , on Which Institute Has Representation United Engineering Society WILLIAM L SAUNDERS, President GEORGE H PEGRAM, 1st Vice-president ALFRED D FLINN, Secretary J V W REYNDERS, 2d Vice-president JACOB S LANGTHORN, Treasurer HENRY A LARDNER, Assistant Treasurer Finance Committee GEORGE H PEGRAM Chairman J VIPOND DAVIES BANCROFT GHERARDI W F M GOSS WILLIAM L SAUNDERS, ex-officio House Committee ALFRED D FLINN, Chairman FREDERICK F SHARPLESS' GEORGE T SEABURYO F L HUTCHINSON CALVIN W RICE

Jan 1, 1923

By A. Wahab Khair, Nagendra P. Reddy

This paper attempts to evaluate the effectiveness of rock reinforcement on underground coal mine entries using analytical technique. A two dimensional finite element analysis has been carried out to see the difference in the 4-entry stability with and without rock reinforcement. A total of eight models with different thicknesses of the immediate roof layer, different material properties, and different anchorage horizons of the bolts were considered in the analysis to see how the safety factors of these entries can be improved.

Jan 1, 1983

By D. M. Deason, G. Y. Onoda

Phosphate clay wastes, as currently produced, leave montmorillonite clay in a highly dispersed and disintegrated form. Alternative processing, where the extent of swelling and self-disintegration of such clays is controlled or limited, may result in improved settling and consolidation behavior. In this study, a method to control montmorillonite dispersion, through preservation of clay tactoids, was examined. Through this process, significant improvements in settling rates and sediment solids concentrations were achieved in both pure clay systems and on simulated phosphate clay wastes.

Jan 1, 1985

By Frank L. Bazzanella, Paul A. Weyler

A brief introduction to gravity concentration is presented, including some discussion on the more common minerals currently recovered. The important considerations in basic design of a gravity plant are mentioned and four currently operating flowsheets are presented. The plants discussed in detail include the Climax Molybdenum Co. By-Product Plant and the Canada Tungsten Ltd. Plant. Plants briefly highlighted include the Palabora Mining Co. Uranium Recovery Facility and the Bridge Hill Ridge Heavy Mineral Recovery Plant of Mineral Deposits Ltd.

Jan 1, 1978

By R. P. Ehrlich, D. A. Dahlstrom

In the hydrometallurgical circuit, many phase separation steps are usually necessary. Typical steps are pregnant liquor - leach residue separation by counter- current decantation or continuous vacuum filtration, clarification of liquids prior to precipitation, ion exchange or solvent extraction, dewatering of final product, etc. The paper discusses the more recent advances in these areas and considers general operating parameters and cost factors. In addition, emphasis is placed on future needs because of the growing importance and necessity of hydrometallurgical processing of minerals.

Jan 1, 1973

By N. A. Hasenack

A full description of tests and test results of potgrate--as well as industrial tests is given. It is concluded that the favorable effects of magnetite ores on the pelletizing-plant results can almost be obtained by replacing the magnetites by hematites with coke breeze. The amount of coke breeze to be added should be about 30% above the theoretical value which is derived from the transition heat of the magnetite. The total amount of coke breeze should be limited to 1.5%.

Jan 1, 1977

Those in charge of the Second Pan-American Financial Conference say that the engineering profession will be well represented at the Janu-ary conference in Washington. Latin American engineers are more closely connected with important industrial projects and have a greater command in matters pertaining to the developments on which they are working than is the case in the United States. Our own engineering profession may. therefore do well to study the Latin-American plan of cooperation between capital and the engineers.

Jan 11, 1919

By J. A. Gay

BRITISH success in extracting significant quantities of germanium from gas works flue dusts has been one of the prime forces in promoting similar research in the United States. Pittsburgh Consolidation Coal Co. and Pennsylvania Coal & Coke Co. are two of the larger U. S. firms with germanium from flue dust research programs. British interest in germanium started in 1933 when V. M. Goldschmidt reported that some coals from the Yard Seam of Northumberland and Durham contained 30 to 50 ppm of germanium.

Jan 8, 1953

By C. A. Mezger

These districts are limited approximately on the north by the railroad from Salisbury to Ashville, and comprises the counties of Alexander, Catawba, Burke, Rutherford, McDowell, Cleveland, Lincoln, Polk and Henderson in North Carolina, and Greenville, Spartanburg, Union and York in South Carolina. The occurrence of monazite at Amelia Court House, in Virginia, belongs evidently to the same geological system, as its distance from the Alleghenies corresponds with that of the above-mentioned districts, and all the stratification runs parallel with those mountains.

Jan 1, 1896