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By E. F. Jr. Young, H. E. Steinman, G. C. Smith

Through a progressive laboratory and pilot-plant program Jones & Laughlin Steel Corp has analyzed and corrected mine drainage pollution problems at all of its coal mines. In conducting this program, the company found no "typical" drainage discharge. Each discharge point at each mine was unique, so that varied approaches were needed to eliminate stream pollution. To illustrate the variety of these approaches, the treatment of drainage from foul, discharge points at three mines in Pennsylvania will be considered here. The flows and critical analyses of the drainage sources and treated effluents arc shown in Table I. Hydrated Lime Works at Thompson Borehole The discharge stream from the Thompson bore- hole at the Vesta No. 5 mine flowed into a small branch creek where it created a "yellowboy" deposit and affected aquatic life. Investigation indicated that hydrated lime would neutralize the acid and precipitate ferric iron without aeration. Treatment of the 150.000-gpd flow, however, created about 4000 gpd of wet sludge for which there was no nearby accumulation site. With State approval, this sludge was deposited through an unused borehole into an abandoned section of the Vesta No. 6 mine several miles away.

Jan 1, 1970

I. N. KNAPP, Ardmore, Pa. (written discussion*).-Captain Lucas has made an important contribution to our, knowledge of Belle Isle, especially as to the outline of the sulphur deposit, and the pronounced irregularity of the salt surface. I agree with his view, that the elevation or mound that constitutes Belle Isle may consist of several salt domes formed at different periods. It may be interesting to note the high gas pressure encountered in pockets in the salt by my No. 1 Belle-Isle well. While drilling a dry hole with cable tools, we sometimes struck. pockets of gas which would float the tools, so that drilling had to be suspended sometimes for several hours at a time, until the head of gas was exhausted, and this with a string of tools, 5-in. (127 mm.) stem 36 ft. (10.9 m.) long, that weighed complete about 3500 lb. (1587 kg.). At about 1800 ft. (548 m.), we struck the largest gas pocket and the string of tools was thrown up and nearly out of the hole. When it dropped back it made several loops

Jan 1, 1918

ENGINEERS AVAILABLE (Under this heading will be published notes sent to the Secretary of the Institute by members or other persons introduced by members.) Member, technical graduate, aged 40, member Institute of Mining and Metallurgy 16 years, with varied experience. Actual underground work,. foreman, surveying, milling, mine examination, superintendent, manager, and other positions of trust. Several years' European practice. Familiar with flotation process. Desires responsible position. References furnished. No. 172. Member, aged 40, graduate Massachusetts Institute of Technology. Twenty years' successful experience as blast-furnace superintendent (merchant and steel works), covering operating, remodeling and? building. General superintendent and general manager of proposition comprising blast furnaces, coal and coke, and iron-ore operation, etc. Good organizer and handler of men. Desires position in above line anywhere. No. 173. Member, technical graduate, aged 43, with 20 years' experience in management of gold, silver, and copper properties and also coal and smelting properties in United States, Canada and Mexico. Owing to illness compelled to resign. Now open for engagement. No. 174. Member, technical graduate, with many years' experience with large smelting and refining companies as chemist, metallurgist, and superintendent desires position. No. 175.

Jan 1, 1915

By W. M. Morris

THE volumetric behavior of isobutane at temperatures below its critical temperature has been studied by several investigators. Seibert and Burrell1 measured the vapor pressure of isobutane from the ice point to the critical temperature. Dana and co-workers2 determined among other thermodynamic quantities the density of the saturated liquid and the saturated gas and the vapor pressure from approximately 0° to 130° F. Sage and Lacey3 studied a number of the thermodynamic properties of this hydrocarbon from 70° to 250° F. The specific volume in the gas and liquid region was determined at pressures up to 3000 lb. per sq. in. ? throughout this temperature interval. In addition, the vapor pressures were measured at 30° intervals. These data taken together serve to establish the thermodynamic behavior of isobutane at temperatures between 0° and 250° F. with reasonable accuracy. However, apparently there are no data available at the higher temperatures. For this reason an investigation of the volumetric behavior of isobutane at temperatures between 100° and 460° F. was carried out with apparatus that has been described in another paper (A.I.M.E. Tech. Pub. 1127).

Jan 1, 1939

By Alexander Knoll, Dwight L. Baker

THE work herein reported shows that galena in certain organic solutions of fatty acids becomes coated with lead soaps, and that this coating is not only highly water-repellent but is also repellent to certain organic liquids, particularly those [ ] of high surface tension; i.e., nitrobenzene, diphenylmethane. WETTING PROPERTIES OF GALENA IN NONAQUEOUS FATTY ACID SOLUTIONS When a "captive bubble"1 is withdrawn from a polished, plane galena surface under a nitrobenzene solution of stearic acid, the air bubble shows a decided tendency to "cling" to the mineral surface. The contact angle, therefore, was greater than zero, although it was not large enough to be measured quantitatively by the captive-bubble method.* [ ] When pure nitrobenzene' was substituted for the nitrobenzene-stearic acid solution, no clinging of the bubble was observed; viz., contact angle = zero. Although the contact angle developed in air-galena-nitrobenzene-fatty acid solution was small, the organic solvent repellency of the galena surface was great enough to enable good recovery in a laboratory flotation cell.2 In Table I are given the results of flotation experiments using several different fatty acids dissolved in nitrobenzene.

Jan 1, 1941

Balancing the prodigious iron ore deposits of Western Australia are the equally vast coal resources of the Bowen series of eastern Queensland. The Bowen series is a Permian basin stretching 500 miles in a north-south line. The beginning of what will be large scale mining of the Kianga-Moura coalfields in Dawson Valley was made by the Australian company of Thiess Bros. in July 1961. Then Peabody Coal Co. of St. Louis, Mo., joined Thiess. Later, Mitsui & Co. Ltd. received a 20% interest in the firm Thiess, Peabody, Mitsui Coal Pty. Ltd. Rtitsui was to lend the company money for development. Queensland Parliament, by special act, granted the company exclusive franchise over the Kianga-Moura coalfield, an area of 350 square miles. The rights do not include other minerals. The company is to have a 120-mile railroad completed to Gladstone or some other port in seven years. It must produce at least 500,000 long tons of coal annually until the line is built, after which production is to be upped to 2 million tons. By December 1962, these arrangements were completed.

Jan 10, 1964

By Brandon H. Grove

The Zistersdorf field, near Vienna, continues to be Austria's only producing area. During the year the field was slightly extended by Rohol Gewinnungs A.G. in its Rag 2, which in April came in for an initial 120 tons daily through an 8-mm. (0.315-in.) bean, from the twelfth Sarmat sand at 1447 m. (4747 ft.). The amount of fluid produced by this well has remained essentially constant, but after the first several months water appeared and increased to some 50 per cent of the total. TWO subsequent extension wells, Rag 3 and Rag 5, northeast and west of Rag 2, found only water-bearing sands, and drilled through the main fault and into the Flysch at 1683 and 1401 m. (5522 and 4596 ft.), respectively. At the close of the year preparations were under way to deviate both wells away from the fault to test still deeper sands. Within the previously proven area of the field Erdolproduction's Gosting VII came in flowing a maximum of 440 tons daily, the highest individual production yet recorded. This company's Gosting VIII also yielded an initial production of 20 tons daily, and its Gosting XI, drilling

Jan 1, 1938

By Dwight L. Baker, Alexander Knoll

The work herein reported shows that galena in certain organic solutions of fatty acids becomes coated with lead soaps, and that this coating is not only highly water-repellent but is also repellent to certain organic liquids, particularly those of high surface tension; i.e., nitrobenzene, diphenylmethane. Wetting Properties of Galena in Nonaqueous Fatty Acid Solutions When a "captive bubble"I is withdrawn from a polished, plane galena surface under a nitrobenzene solution of stearic acid, the air bubble shows a decided tendency to "cling" to the mineral surface. The contact angle, therefore, was greater than zero, although it was not large enough to be measured quantitatively by the captive-bubble method." When pure nitrobenzene was substituted for the nitrobenzene-stearic acid solution, no clinging of the bubble was observed; viz., contact angle = zero. Although the contact angle developed in air-galena-nitrobenzene-fatty acid solution was small, the organic solvent repellency of the galena surface was great enough to enable good recovery in a laboratory flotation cell2 In Table I are given the results of flotation experiments using several different fatty acids dissolved in nitrobenzene.

Jan 1, 1943

By Alexander Knoll, Dwight L. Baker

THE work herein reported shows that galena in certain organic solutions of fatty acids becomes coated with lead soaps, and that this coating is not only highly water-repellent but is also repellent to certain organic liquids, particularly those [ ] of high surface tension; i.e., nitrobenzene, diphenylmethane. WETTING PROPERTIES OF GALENA IN NONAQUEOUS FATTY ACID SOLUTIONS When a "captive bubble"' is withdrawn from a polished, plane galena surface under a nitrobenzene solution of stearic acid, the air bubble shows a decided tendency to "cling" to the mineral surface. The contact angle, therefore, was greater than zero, although it was not large enough to be measured quantitatively by the captive-bubble method.* [ ] When pure nitrobenzene was substituted for the nitrobenzene-stearic acid solution, no clinging of the bubble was observed; viz., contact angle = zero. Although the contact angle developed in air-galena-nitrobenzene-fatty acid solution was small, the organic solvent repellency of the galena surface was great enough to enable good recovery in a laboratory flotation cell.2 In Table I are given the results of flotation experiments using several different fatty acids dissolved in nitrobenzene.

Jan 1, 1941

By Alexander Knoll, Dwight L. Baker

The work herein reported shows that galena in certain organic solutions of fatty acids becomes coated with lead soaps, and that this coating is not only highly water-repellent but is also repellent to certain organic liquids, particularly those of high surface tension; i.e., nitrobenzene, diphenylmethane. Wetting Properties of Galena in Nonaqueous Fatty Acid Solutions When a "captive bubble"I is withdrawn from a polished, plane galena surface under a nitrobenzene solution of stearic acid, the air bubble shows a decided tendency to "cling" to the mineral surface. The contact angle, therefore, was greater than zero, although it was not large enough to be measured quantitatively by the captive-bubble method." When pure nitrobenzene was substituted for the nitrobenzene-stearic acid solution, no clinging of the bubble was observed; viz., contact angle = zero. Although the contact angle developed in air-galena-nitrobenzene-fatty acid solution was small, the organic solvent repellency of the galena surface was great enough to enable good recovery in a laboratory flotation cell2 In Table I are given the results of flotation experiments using several different fatty acids dissolved in nitrobenzene.

Jan 1, 1943

By R. McEwen, G. W. Hansen, G. F. Lee

The effect of using an anionic collector, Reagent 308, a sodium petroleum sulfonate, with a cationic collector, Armac T, a tallow, fatty acid amine acetate, was studied in a series of monomineralic flotation trials with the alkali feldspars and heavy minerals, ilmenite, rutile, garnet, and monazite. This combination of cationic and anionic collectors is employed to float feldspar and heavy minerals from quartz in the beneficiation of sand in Normanville, South Australia, to produce a suitable quartz sand for glassmaking. In the alkali feldspar trials, Armac T additions were held constant, while the 308 additions were varied. In the heavy mineral trials, the 308 was held constant while the Armac T was varied. Peak enhancement of the feldspar recovery was noted when the 308 additions were between 25% and 150% that of the Armac T additions. At higher 308 addition, depression of feldspar flotation occurred. This appears to be due to a neutralizing effect in the combined collector system and to the formation of a nondissociating complex of both collectors. This variability in flotation response when Armac T is used with 308 suggests that the two collectors do not act independently of each other.

Jan 1, 1977

By Robert A. Haney, Stephen J. Gigliotti, James L. Banfield

A series of investigations were made by the Mine Safety and Health Administration to evaluate the performance of various face ventilation systems as part of a program to reduce frictional ignitions of methane and to develop face ventilation systems that could be used with the line brattice more than 10 feet from the face. Tests were conducted in a full-scale laboratory model of a face area. Systems tested included unassisted blowing and exhaust line brattice, diffuser fan and spray fan systems. Systems were evaluated at air quantities ranging from 1.4 to 7.0 m3/s (3,000 to 15,000 cfm), and brattice-to-face distances from 1.5 to 9 meters (5 to 30 feet.). Tests were designed so that systems could be evaluated for the location of the high-point methane concentration in the face area, methane dilution capacity, and face ventilation index. The methane dilution capacity is the total amount of methane a system can dilute to 1.0 volume-percent. The face ventilation index is the efficiency at which the available face air volume is being used.

Jan 1, 1982

By G. K. N. S. Subasinghe

An attempt has been made to explain the behavior of a pinched sluice in terms of the established theories of fluid mechanics and mineral processing. A method has been developed to calculate the underflow discharge by assuming a logarithmic velocity distribution and free gravity fall through the discharge slot. The concentration profile of solids over the depth of flow has been shown to comply with Bagnold's theory of dispersive shear, rather than turbulent sediment transfer. Even although the results can be explained qualitatively by the Bagnold theory, their complete quantitative analysis will not be possible until more work is done. Consequently, an empirical equation has been developed to predict underflow pulp densities. It has been shown that the process of the segregation of the heavier mineral beneath the lighter can be described by a first order law. From the results obtained, a computer model of the pinched sluice has been developed. This predicts the underflow grade, pulp density and flow rate in terms of the feed and operating conditions. The model can also be used to determine the effect of a change in operating conditions, and for the optimization of rougher, cleaner, and scavenger circuits.

Jan 1, 1984

By H. Reginald Hardy, Gary L. Mowrey

Field studies were conducted over a longwall coal mining operation to investigate the feasibility of using microseismic techniques to detect and to locate any areas of instability in the vicinity of the longwall. An array of geophones buried at depths of 3 to 8 m from surface were positioned approximately 130 m above the active area of the longwall panel. A mobile microseismic monitoring facility amplified, filtered, and recorded the microseismic activity sensed by the geophones. Microseismic events were detected at depths of at least 130 m and at horizontal distances in excess of 250 m from the source. Most events, which resembled decaying sinusoidal transients, had frequencies of 10 to 100 Hz, and particle velocities of 1 to 8 pm/s. Source locations for the 150 largest events were computed using a least-square travel-time-difference method. Both isotropic and unique wave propagation velocity models were considered when evaluating the source locations. Most of the events were computed to be within ± 30 m vertically of the coal seam and ± 15 m horizontally of the longwall face, when the unique velocity model was employed.

Jan 1, 1980

By Edwin H. McKee

Eruption of rhyolitic ash-flow tuffs in the area of the McDermitt (Cordero) caldera began about 17.4 million yr (m.y.) ago and continued for about 1.5 m.y. During this period of silicic eruptions, a circular area about 30 km in diameter collapsed to form a caldera that subsequently filled with sedimentary and volcanic rocks. A total of more than 200 km30f silicic rocks was erupted from the volcano. The final phase of igneous activity, about 15.0 m.y. ago, included resurgent doming and intrusion in the south-central part of the caldera. Three to 4 m.y. later (-1 2 m.y. ago), hydrothermal solutions using the northern part of the caldera ring fractures as conduits deposited silica, cinnabar, pyrite, alunite, and other minerals in tuffaceous lake beds and volcanic rocks accumulated within the caldera. The ore-forming solutions may have been a residuum from the silicic magma, or connate water, or ground water heated by the still-hot resurgent magma in the central part of the caldera. The source of the mercury and other elements has not been identified.

Jan 1, 1977

By Harry V. Warren

There are two topics which may be considered as opening gambits in any conversation in any part of the world, weather and health. Nothing much can be done about the former, and it would appear that no great changes can be anticipated in the immediate future. With respect to health, a great deal has been achieved in the past 150 years, curiously enough not all of it by medical men. It would appear that the time is now appropriate for geologists to come to the assistance of medical men. During the past few decades, medical science has mastered many of the diseases commonly associated with childhood. As a man tends to live longer, those diseases usually associated with middle and old age become more prominent. Thus we must realize when we say that today more people are dying of cancer and coronary disease, absolutely and relatively to other diseases, this should not suggest that these diseases did not exist a hundred years ago; it does suggest that more people are living to an age where death from these diseases is apt to become more common.

Jan 7, 1962

By Olav Idelgeland

FROM indirect evidence point defects have been believed to influence the fatigue behavior of metals and alloys.1,2 Measurements of changes in resistivity made after cyclicstressing at low temperatures indicate that a very high density of defects is present, part of which may be removed by room-temperature annealing.3'4 These results are consistent with the generation of a high number of point defects at low temperatures. Corresponding measurements made after room-temperature stressing did not show any recovery effects.3 This was attributed to a stabilization of the dislocation network after a few thousand cycles without generation of vacancies. In this laboratory resistance measurements of copper single crystals, shaped as normal fatigue specimens ,5 have been made with a Kelvin double bridge at room temperature during and after cyclic stressing at 80 cps by comparing with a dummy at a close and constant temperature. Temperature differences were measured to ±0.025°C with fine thermocouples taped onto the gage lengths. Potential leads were tin-soldered into small holes in the gage length to give stable values. Corrections for differences in temperature and changes in mean length of the specimen were made according to the formula:

Jan 1, 1968

By A. W. Edelen

THE Teziutlan copper-zinc deposit is supposed to be of late Cambrian or early Paleozoic age. The country rocks are a series of schists or phyllites, flat lying and in the form of a plunging anticline. The ore deposit occupies a single horizon in the schist for a known horizontal extent of 1200 meters. Along its strike occur four large lenses or ore bodies. These ore bodies occupy positions along the flank and extend to the crest of the anticline. The primary mineralization is in the form of quartz, pyrite, sphalerite, chalcopyrite and galena, with a few scattered silver anti-monides. Quartz and pyrite form the mineralization between the ore lenses. In the ore lenses the sulphides appear as a massive, very fine-grained intergrowth of minerals. The intergrowth suggests a contemporaneous deposition of the heavy sulphides. The grain size, usually under 0.09 mm., makes the separation difficult and fine grinding important. The ore bodies were formed at great depth by solutions probably originating in the same basic magma that gave rise to the dolerite sills that are so common in their vicinity.

Jan 1, 1937

By Douglas Semmes

THE possible oil territory of Alabama can be readily divided into two regions, the Paleozoic area of the north, and the Coastal Plain province of Cretaceous and younger formations lying to the south. This latter area has received much attention in the last few years and has been described by a number of writers.1 Although the possibilities of the Cretaceous series have been much emphasized by recent writers, the fact remains that the two or, possibly, three localities where oil or as have been found in, anything like paying quantities are confined o the area of Carboniferous rocks. Moreover, almost all of the oil seeps and a good percentage of the gas seeps are confined to this area .2 Topographically, as well as structurally, the Paleozoic area can be divided into three rather well defined provinces: (1) The broad, open Coosa Valley lying adjacent to the crystalline oldland, with comparatively little relief, except for occasional longitudinal ridges and rather intense folding; (2) the plateau region of horizontal or gently warped Pennsylvanian strata broken by occasional anticlinal valleys aligned northeast and southwest, outliers of the Coosa Valley proper, in which

Jan 3, 1920

By J. M. Toguri, H. Flood

The application of the mass action law to the thermodynamic treatment of metal-slag equilibria is discussed. The consideration of the reactions essentially as ionic exchange equilibria is shown to be both an advantage and an aid for the elucidation of the theoretical treatment. This is illustrated by several examples. In general two different methods of application of the mass action law to metal-slag equilibria have been used by different groups of investigators. These could be called the oxide reaction and the ionic reaction approach respectively. At the recent discussion in the metallurgical section of the I.U.P.A.C. Congress in Montreal, 1961,' divergent opinions prevailed regarding the most rational way of applying the mass action law to metal-slag equilibria. This question is of fundamental importance in the treatment and understanding of theoretical chemical metallurgy. Consequently, the following is an attempt to contribute towards its clarification. As an example, the distribution of iron and manganese between molten iron and slag will be considered. I) THE OXIDE EXCHANGE REACTION APPROACH The equilibrium between iron and manganese between molten iron and slag is frequently formulated as an oxide metal exchange reaction as follows:

Jan 1, 1963