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By Robert L. Sundeen, Richard V. Wenberg

INTRODUCTION Shotcrete can be defined as spray-applied concrete with a maximum size aggregate in excess of 9.5 mm (0.375 in.). The concept evolved from guniting, which uses smaller aggregate and generally produces concrete with poorer physical properties. The larger aggregate used in shotcrete requires less water in the mix, while offering larger bonding surfaces, thus imparting greater tensile and compressive strengths. TYPES OF MACHINES Two basic designs of shotcrete machines in general use are the wet or prehydrated zero slump and low slump type, and the dry or nozzle hydrated machines. Fig. 1 shows a typical zero-slump machine in a con¬figuration commonly used for small-volume require¬ments. The prehydrated zero-slump machine mixes exactly proportioned batches in a sealed pressurized chamber. "Slugs" of hydrated shotcrete mix and com¬pressed air are sent through a distribution hose to the nozzle where the wet mix emerges as a spray. The spray is directed onto the rock surface by the nozzle operator. The low-slump machine is similar, except that a thick slurry mix of aggregate is delivered throughout the distribution hose to the nozzle. Fig. 2 shows a typical low-slump shotcrete machine used in moderate-volume applications. The nozzle-hydrated shotcrete machine accepts a premixed "dry" (4 to 6% moisture) batch of aggregate and cement. A constant feed of this mix is directed by compressed air through the distribution hose to the nozzle. At the nozzle, water for hydration is introduced into the emerging spray. The hydrated mixture is di¬rected onto the rock surface by the nozzle operator. Fig. 3 shows a typical dry-mix machine. The major difference between the two basic machine designs is the consistency of the shotcrete quality. Pre¬hydrated machines have high degrees of consistency and produce high-strength concrete, resulting from their ability to produce exact mixtures of zero or low-slump concrete within the machine. Nozzle-hydrated machines tend to produce poorer quality concrete because of the difficulty in controlling the water content at the nozzle. Water input essentially is an art. As such it is not precise, and the shotcrete produced is of variable quality. MATERIALS HANDLING Materials handling presents a problem to either type of shotcrete machine. At times considerable quantities

Jan 1, 1982

By Fred C. Bond

A study of the settling and thickening of finely divided pulps was undertaken with the object of obtaining certain fundamental relationships, with resulting improvements in the design and operation of mechanical equipment. The subject has been treated in two parts: testing and batch thickening, and continuous thickening, including calculations of capacity and dimensions. Part 1. ? Testing and Batch Thickening The usual method of making thickening tests is to agitate the pulp with a plunger in a graduated glass cylinder and let it settle, while recording the time rate of settling. The settling rates corresponding to different pulp dilutions are found, the ultimate dilution obtained is measured, and the necessary thickener area in square feet per ton of dry solids per 24 hours is calculated, for each pulp dilution. The largest area found is used in selecting the proper thickener size.

Jan 1, 1946

By Xiaoping Xu

An albitization granite type tantalum-niobium ore from Jiangxi Province, China was taken as the research object in this paper. The main valuable minerals in this ore are tantalite-columbite and uranmicrolite, and the minerals that can be comprehensively recovered include cassiterite, sulfide minerals, topaz, zinnwaldite, and quartz-feldspar. Based on the research results of process mineralogy, the roughing process of gravity separation for coarse particles combined with flotation for fine particles is proposed. The combined cleaning process of flotation-gravity-magnetic-electric-hydrometallurgical separation is adopted for the rough concentrate of gravity separation while the combined cleaning process of gravity-flotation- hydrometallurgical separation is adopted for the rough concentrate of flotation. High intensity magnetic separation is used to separate and recover zinnwaldite and quartz-feldspar from gravity tailings. By mineral processing for the crude ore containing (TaNb)cassiterite concentrate is 0.0003% with a grade of Sn 63.22% and a recovery of Sn 47.42% while the yield of sulfide concentrate is 0.0783% with a grade of Pb 33.15% and Zn 27.09% which can be separated to get lead and zinc concentrate respectively. The yield of topaz concentrate is 0.1545% and the topaz mainly distributed in the size range of -0.4+0.074mm, which can be made into abrasive products of different particle sizes after classification. The yield of zinnwaldite concentrate is 16.91% with a grade of Liwhiteness of 75%, which is a glass-ceramic material of good quality. 2O5 0.0346%, Sn 0.04%, Pb 0.10% and Zn 0.33%, the tantalum-niobium concentrate with a yield of 0.00278%,a grade of (TaNb)2O5 53.61% and a recovery of (TaNb)2O5 44.49% is obtained. And the yield of 2O 1.34% and Rb2O 0.40%. The yield of quartz-feldspar concentrate is 30.42% with a grade of K2O+Na2O 8.98% and Fe2O3 0.11% and a natural All of tantalum, niobium, cassiterite, topaz, zinnwaldite, quartz, and feldspar are recovered effectively. Keywords: tantalum-niobium ore, gravity separation for coarse particles, flotation for fine particles, comprehensive recovery

Sep 1, 2012

By J. R. Long, T. R. Graham, R. S. Dean

FOLLOWING the development of elec¬trolytic manganese production by the Bureau of Mines, an extensive program was planned to study the character of this high-purity product and its possible utilization in various alloy combinations. Previous work reported in the literature concerning alloys containing substantial amounts of manganese dealt largely with material prepared from relatively impure grades of the metal, and in many instances the impurities thus introduced did not permit true evaluation of manganese as an alloying element. One phase of the Bureau's program included a general review of the system and the establishment of the physical properties of copper-manganese-zinc alloys, using electrolytic manganese, and with particular emphasis directed to com¬positions within the alpha solid solution area. A number of reports of the work on alloys in this system, giving specific data concerning the equilibrium system and some of its alloys, have already been published. One study1 established the alpha solid solution area at various temperature levels and composition ranges up to 50 pct manganese. Other investigation reports presented the properties of selected alloys; namely, a 65 pct copper, 10 pct manganese, 25 pct zinc alloys' a sensibly white manganese brass composed of 70 pct copper, 20 pct manganese, 10 pct zinc,3 and a series of alloys with a constant copper content of 60 pct and 5 to 25 pct manganese, balance zinc.4 In these reports tensile properties as influenced by cold-working and subsequent annealing were given in detail. Additional data are now available on other alloys of the alpha region up to 50 pct manganese, and these, together with previously published information, are sufficiently complete to establish the relationship between properties and composition for this portion of the ternary system. The present report is a summary of the tensile properties of wrought alloys in the form of sheet and rod stock. The summary is necessarily limited to data for only one condition of cold-work and a single annealing temperature, since a complete exposition of all the data available would be too extensive for this presentation. Nevertheless, it is possible to make a reasonable approximation of the tensile properties in other conditions of cold-working and annealing by a correlation of the data previously presented on specific alloys and the data given here.

Jan 1, 1947

The purpose of this study is to develop designs to facilitate and accelerate auger rotation stoppage (and auger rotation start up so as to promote auger disengagement during auger miner repositioning) and to provide a time delay and warning signal prior to auger start up to permit any miner s near the augers to get away from the augers before they start rotating. In the underground coal mines in the U.S., there are four auger miners that are currently in use. They are the Jeffrey 100L (see Figure 1-1) and 100M (see Figure 1-2), and the Wilcox WCM and the MK20A (see Figure 1-3).

Jan 1, 1974

By Indrajit Paul, Atanu Pal, Kapil Modi, Sanjay Chandra, Chandra Sekhar, Srinivas Dwarapudi

"High alumina content in the Indian iron ore fines (2.5% Al2O3) resulted in poor quality pellets at the recently commissioned 6 MTPA pelletizing plant and a study was under taken to establish suitable pellet chemistry through proper fluxing agents. Limestone fluxed pellets were prepared at varying basicity (0 to 0.8) and pyroxenite fluxed pellets at varying MgO contents (0 to 3%) to study their effect on the metallurgical properties. Fired pellets were tested for their strength, RDI, reducibility and swelling. Microstructural studies, optical and SEM-EDS, were carried out to quantify different phases and their chemistry. Acid pellets exhibited poor quality whereas limestone pellets at 0.8 basicity and pyroxenite pellets at 1.5% MgO exhibited optimum metallurgical quality. Formation of widely distributed silicate melt in limestone pellets and high melting point slag & magnesioferrite in pyroxenite pellets found to improve their quality. However during commercial production of MgO bearing pyroxenite pellets, their room temperature and low temperature properties found to be inferior, but exhibited better high temperature properties, viz. softening-melting behavior. Contrary to this, commercially produced limestone pellets, comprising CaO, exhibited better strength and RDI but showed poor high temperature properties. To yield the benefits of both CaO (for good strength and RDI) and MgO (for low swelling and high softening), a dual flux combination was established by using both limestone and pyroxenite/olivine together that resulted in optimum metallurgical properties. Coke rate at the blast furnaces found to be reduced by 1kg for every1% increase of dual flux pellets in the burden.INTRODUCTION Iron ore agglomerate quality plays a vital role in decreasing the reducing agent consumption and increasing the productivity of blast furnace. In most of the integrated steel works, the burden mix for blast furnace is decided as per the availability of the iron ore agglomerates like sinter and pellets. More attention has been given in recent years to the use of fluxed pellets in blast furnace due to their good strength and improved reducibility, swelling and softening melting characteristics. Generally, quality of pellets is influenced by the nature of ore or concentrate, associated gangue, type and amount of fluxes added and their subsequent treatment to produce pellets. These factors in turn result in the variation of physicochemical properties of the coexisting phases and their distribution during pellet induration. Hence properties of the pellets are largely governed by the form and degree of bonding achieved between ore particles and the stability of these bonding phases during reduction of iron oxides (Panigraphy et al., 1990). It is important to note that conditions and parameters of pelletizing are specific to given ore or concentrate; the present study is undertaken for typical Indian hematite ore fines high in alumina. Except authors earlier work on quality of pellets from Indian iron ore (Dwarapudi et al., 2008, 2010), there is no considerable literature reported on the effect of pellet basicity and MgO content in the basicity range of 0 to 0.8 for Indian hematite ore."

Jan 1, 2018

By R. L. Loofbourow

Reasons for reexamining underground mining include: 1. The assurance that more deep deposits of useful minerals will be found. 2. The existence of deeply covered deposits of industrial minerals near large markets where quarries are becoming depleted or are lacking. 3. Surface property values, zoning and other limitations on open pit mining. 4. Expectation that underground space will be increasingly used for transportation, power plants, storage and similar purposes. 5. The improvements which have been made in underground mining. During the last three or four decades many changes and improvements have been made underground. All underground construction and mining has benefitted to some extent but the effect on the productivity of labor employed with some methods- has changed little and the use of these methods has declined. Productivity of labor in other methods has increased substantially. The relative usefulness of mining methods has changed and a vital industry, bituminous coal, has been returned to health. In this paper, consideration is limited to nine methods used with high productivity during the period under review. These methods are not necessarily better than others but they may be considered the prime methods in the sense that, in our economy, many, low grade ores, coal and the principal industrial minerals could hardly be produced by less productive means.2 Although most of the examples cited are from mining as such., the first four methods discussed can be used for the construction of stable excavations of various' shapes in sound rock.

Jan 1, 1967

By D J. Williams

The majority of surface tailings storage facilities continue to employ sub-aerial tailings slurry deposition. Surface TSFs are typically sized and operated in a way to minimise the initial capital cost of the facility, driven largely by the net present value approach to accounting. This generally leads to too small a storage, too fast a rate of rise of the tailings, and difficulties in managing supernatant water. In turn, this results in wet and soft tailings deposits of high moisture content and low density, and the need for frequent and costly tailings dam raises. Further, such tailings deposits often do not facilitate closure and rehabilitation of the facility. Globally, there are on average over two failures annually of such tailings dams, resulting in loss of life, damage to infrastructure and environmental impact downstream, and the loss of company shareholder value and reputation. Recent high profile tailings dam failures are threatening the mining industry’s financial and social licence to operate.Among the physical processes that tailings undergo on sub-aerial deposition are beaching, hydraulic sorting down the beach according to particle size and specific gravity, settling, consolidation, and desiccation on exposure to the sun and wind. Beaching and hydraulic sorting have proved difficult to test at laboratory scale and difficult to model, and are best assessed in the field. Settling, consolidation and desiccation may be assessed at laboratory scale, but to date there has been an absence of tests to form the basis for the design and management of tailings deposition, and ultimate closure and rehabilitation. The paper describes recent advances in tailings testing methods, including a purpose-built slurry consolidometer that tests the settling and consolidation of tailings from a slurry consistency, simulating increasing tailings depth to about 50 m; and a purpose-built instrumented column that tests the settling, self-weight consolidation and desiccation of a surface layer of tailings, also from a slurry consistency. Selected test results from these two apparatus are presented in the paper, together with brief descriptions of how they may be used to better design tailings slurry deposition. In addition, planned further advances in tailings testing methods are briefly described.CITATION:Williams, D J, 2018. Recent advances in tailings testing methods, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 8–37 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By J. H. Holden, G. R. Strimbeck, L. F. Willmott, W. R. Huff

A pilot - scale fluidized feeder was developed for continuously feeding up to 1 ton of pulverized coal per hour to a pressure gasifier . Fluidization in the 3 - foot - diameter by 34-1 / 2 - foot - high feeder is effected by two streams of inert gas , a technique called zone fluidization . A stream of inert gas through a drilled plate in the base of a central column near the bottom of the feeder fluidizes the coal . Another stream through a drilled plate in the annulus between the central column and feeder wall provides a source of semifluidized coal for the central column . Fluidized coal from the central column discharges through an extraction funnel and discharge line . Zone fluidization provided good fluidization with moderate requirement for fluidizing gas . Instruments were developed for metering and recording the flow rate of fluidized coal . A system was developed for storing , and weighing pulverized coal , and then delivering it in fluidized form at about 1 to 8 tons per hour .

Jan 1, 1964

By Don Painter, Nico Sutmoller, Lori M. K. Kahikina, Brian Dorwart

This paper will address the feasibility of using low-density cellular concrete (LDCC) for an annular fill application where project conditions required pumping the LDCC material for distances of up to 16,000 feet. These conditions occurred during construction of the Kaneohe-Kailua Sewer Tunnel in Oahu, Hawaii, between 2014 and 2018. Located on the island of Oahu, Hawaii, this 13-foot-diameter rock tunnel extends for approximately three miles from the Kaneohe Pre-Treatment Facility to the Kailua Regional Wastewater Treatment Plant. The tunnel was built to convey wastewater and provide temporary storage for peak wet weather flows entering the collection system, thereby reducing the potential for uncontrolled discharges. LDCC was chosen for this project partly due to its environmental benefits, which were essential for an application contiguous to the inland marine and coastal waters of the Pacific Ocean. In order to ensure optimal performance characteristics—compressive strength (with a requirement of 300 psi at 56 days), flowability, and light weight—were achieved, extensive testing of various LDCC products and mix designs was completed. The testing measured the initial set time of the LDCC as well as the compressive strength needed to reduce the quantity of grout lifts required for the project.

Jun 13, 2021

By A. W. Davis

Sapping and mining have constituted an important part of siege operations ever since powder came into general use in Europe. Before this period, famine was the main weapon in the hands of the besiegers, and the history of the middle ages is replete with accounts of sieges lasting two and three years. With the advent of explosives, a position impregnable to assault might be readily won by mining under, and blowing up, its defences. The natural offensive against this method of attack is to countermine and stop the attackers underground before their objective is reached. Thus developed the art of military mining. The French and British, in the Peninsular war, were adepts at this method of warfare, and the explosion of a mine and the formation of a breach were the usual preludes to the general assault of a position. In the Crimea, at Sebastopol, the British and Russians did a lot of underground fighting, as the old maps of their galleries, now in the museum at Chatham, will testify. In the siege of Port Arthur, in still later times, the Japanese and Russians were hard at it as well.

Jan 1, 1926

By James J. Gusek

The Atlantic City iron mine is located in Fremont County in central Wyoming, near the historic gold mining camps of Atlantic City and South Pass City. The mine lies on the southeast flank of the Wind River Mountains at an elevation of about 2,470 m (8,100 ft) above sea level (Fig. 1). An 81-h M2 (200-acre) tailings impoundment at the Atlantic City taconite operation has been a source of blowing dust. The site qualified for reclamation under Wyoming&apos;s Abandoned Mine Land (AML) reclamation program. The ultimate reclamation construction incorporated commercially available organic amendments and fertilizers into a 300-mm- (12-in.-) thick cap of a sterile clay loam cover material. The water level was lowered in an adjacent flooded mine pit that was feeding uncontrolled seeps into the tailings basin. A wide tailings pond spillway was built that allows flood control while minimizing seasonal water-level fluctuations in the pond. Rock berms and rock snow fences were built for wind-erosion control and soil-moisture preservation. Future work includes tree planting in the protective wind/ snow shadows of rock berms and rock snow fences and plugging a decant pipe. US Steel opened the Atlantic City iron mine in August 1962. It closed in 1983. Taconite iron ore was mined by surface methods. The ore was magnetically separated from the waste. The magnetic concentrate was mixed with bentonite, formed into pellets and roasted to produce a blast furnace feed stock for US Steel&apos;s blast furnaces in Geneva, UT. The pellets were hauled by rail to the Geneva Iron Works. The Atlantic City Mine produced three types of wastes. These included waste rock overburden from mining, a coarse-grained (sand to small-gravel sized), nonmagnetic reject rock termed "cobbs" and fine-grained tailings ranging from 600 to 75 µm (28 to <200 mesh). The waste rock has been used as an aggregate/rip rap source by a local contractor and the Wyoming Department of Transportation (WYDOT). WYDOT also

Jan 1, 1998

By Leonard Obert

This Bur of Mines investigation considers the deformational behavior (creep) of pillars made from three quasi-plastic rocks--salt, trona, and potash ore. The first phase of this study considers the design of a model pillar suitable for creep tests; in the second phase, six model pillars prepared from salt from two sources, from trona, and from potash ore. The pillars in each group were subjected to a different but constant axial stress, and the axial strain was measured for 1,000 hours.

Jan 1, 1965

By B. D. Harden

FOR over fifty years the Spanish mine, 21 miles northeast of Nevada City, in Nevada County, California, has been one of the Bradley properties. Between 1883 and 1889 it was operated by the late Frederick W. Bradley and P. R. Bradley. The ore averaged only about $1 a ton at that time but the mine was credited with a production of about $900,000 in that period. The property was then closed down until 1922, when the Bradley interests reopened it and continued development for the next nine years, when a 50-ton mill was built. This began operation in April, 1931. This was a selective flotation plant, with the tailing treated on Wilfley tables, and operated on ore from the No. 4 and No. 16 tunnel stopes. This ran from $3 to $6 in gold, 2 to 3 oz. of silver, copper 0.6 per cent, lead 1.5,

Jan 1, 1935

By Eugene Frey

"INTRODUCTION The Blue Bell fluorite deposits were examined in August and November 1944 by an engineer 3/ of the Bureau of Mines, and an underground project was set up. The Bureau of Mines began development of fluorite here February 10, 1945, and completed its survey on June 21, 1946.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepared the final report. The Metallurgical Branch, C. C. Ralston, chief, analyzes samples and perform beneficiaticn tests. The exploratory project was under the direction of Paul T. Allsman, chief, Salt Lake City Division, Mining Branch. Acknow¬ledgment is due R. Thurston of the Federal Geological Survey for mapping the topography of the area, and to F. H. Gunnell and W. A. Young of the divisional office for detailed mapping of the surface and underground development and interpretation of the results.The chemical analyses included in this report was performed under the direction of H. E. Peterson, analytical chemist; the petrographic studies on the ore were written by LaMar Evans, petrographer; and the beneficiaticn section was written by C. H. Schack, metallurgist, under the direction of S. R. Zimmerley, chief, Salt Lake City Division, Metallurgical Branch."

Jul 1, 1947

By Moore A. J

This paper describes the use of a wavefront reinforcement model which has been developed to supplement established charge mass scaling methods. The model allows for the time taken for blast vibration wavefronts to travel from each blasthole, and has been successfully used to explain the reason for directional increases in both air and ground vibration in certain situations. The model has been used to identify wavefront reinforcement due to the propagation of air vibration and ground vibrations in certain situations. The paper includes a throw (or cast) blasting case history which provides multi-station evidence of the strong directional nature of wavefront reinforcement.

Jan 1, 1995

By Clarence Hall, J. J. Rutledge

Many of the fatal accidents in coal mines have resulted from the Explosives used in Use of explosives for breaking down the coal. These accidents have resulted both from the use of explo- sives that were not suitable and from the careless or improper use of suitable explosives. Investigation has shown that one of the commonest causes of dis- astrous explosions in the coal mines in this country has been a blown- out shot of black blasting powder or dynamite. The dangers that attend the use of these explosives were perceived several years ago, and in consequence the attention of powder manufacturers was directed to the production of explosives that would be less liable to ignite inflammable gas or dust. The manufacturers have been so successful in their efforts that it is now possible to obtain explosives which yield much shorter and quicker flames than black blasting powder or dynamite, and hence are much less dangerous to use in fiery or dusty coal mines. of explosives. To find out which of the many grades of short-flame explosives Government tests have the qualities that render an explosive most effective and least dangerous for mining coal, the United States Government established a testing station at Pitts- burgh, Pa., in 1908. This station is now under the charge of the Federal Bureau of Mines. Before the station was opened a state- ment of the requirements that the explosives in question would have to satisfy was drawn up and sent to manufacturers. A number of these sent explosives to be tested, and on May 15, 1909, a list of the explosives that had passed the tests was published. Since that date other brands of explosives have been tested and three more lists have been issued. The latest list, published in Miners' Cir- cular 2, Bureau of Mines, contained the names of no less than 71 explosives that had passed the tests prior to January 1, 1911.

Jan 1, 1912

By Sir Albert E. Kitson

The manganese ore deposits of the Gold Coast, British West Africa, occur in very ancient rocks, of both sedimentary and metamorphic types. In certain respects they have a strong resemblance to those of India and Brazil, as contrasted with those of Tertiary age in Georgia, but in this paper no careful comparison with them can be made. Viewed from the present condition of the manganiferous rocks, the oldest deposits are in the sediments. Later than these are the progressively metamorphosed representatives of these sediments. Youngest are the products of decay and degradation with the concentration of manganese oxide in the rocks of both groups. The oldest occurrences are in argillaceous and siliceous phyllites and slates, which show only a moderate degree of metamorphism. They belong to a series which also includes mudstones, sandstones, grits, conglomerates and subordinate limestones, with tuffs and lava-flows, largely of basic types. This has been named the Birrim System. Its age is unknown, for no definite fossils have been discovered in it. Since these non-fossiliferous strata at many plaees are of a character which in many parts of the world are suitable for the preservation of fossils, and which contain them, it is assumed that the Gold Coast deposits are pre-Cambrian. These rocks of the Birrim System have normally a northeast-southwest strike, and are folded, but not to any very great degree except in certain belts. From the Eastern Province of the Gold Coast they may be traversed diagonally across their strike for upwards of 600 miles, to the extreme northwestern corner of the Northern Territories. Thence they probably extend much farther into French territory.

Jan 1, 1927

By R. J. Pugh

In addition to directly analyzing the surfaces of minerals using high vacuum instrumentation methods, some important surface properties of mineral fillers can be determined indirectly by using reactive chemical probe molecules. This technique enables the strength and the number of the surface reactive sites to evaluation and this type of information is useful in predicting interfacial behaviour of minerals. One method of classifying these surface sites is by using Lewis acid/base theory and this type of approach could enable one to predict the adsorption of functional groups in dispersants, thickeners, pigments, etc. Also the adhesion of polymer matrices to the filler surface may be improved.

Jan 1, 1992

By H. H. Li

Reverse flotation is usually used for hematite/silica or bauxite/clay flotation separation in which the silica or clay is floated and rejected. Some properties of these silicate minerals such as particle size and surface characteristics have significant effect on their flotation behaviours. Firstly, the silicate mineral particles (especially clay minerals) generally have fine particle size (< 5 microns) in their natural states or due to overgrinding and they display poor flotation kinetics, consequently having low flotation recovery. Secondly, the wettability difference on different particle basal planes influences the affinity for adsorptions of different types of chemicals such as collectors or macro-molecule. Common polyacrylamide (PAM) flocculants can be used to minimize the exposure of the most hydrophilic planes of clay particles via hydrogen bonding but they can not efficiently enhance the overall particle surface floatability due to the hydrophilic properties of this type of macromolecules. A novel method to improve both flotation kinetics and surface wettability of silicate minerals has been developed and studied. That is to use a temperature-sensitive polymer, poly (N-isopropyl acrylamide) (PNIPAM), as a process aid in the flotation of silicate minerals. Unlike PAM polymers, PNIPAM can induce a hydrophilic/hydrophobic transition on the particle surface when the temperature is changed to be lower or higher than its critical solution temperature (CST). At a lower temperature, the PNIPAM adsorbs on the particle surface via hydrogen bond similar to PAM. It induces strong hydrophobic aggregation when the temperature is increased above the CST. Thus, both floc size and mineral floatability are greatly increased. The flotation results show very good flotation performance and the addition of conventional flotation collector was no more required because the increased particle surface hydrophobicity induced by PNIPAM. Contact angle measurements explained the role of PNIPAM in manipulating particle surface hydrophilic/hydrophobic transition.

Jan 1, 2014