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By J. R. Long, E. T. Hayes, R. S. Dean, F. S. Wartman

THE production of titanium in 15-1b. lots and with a purity sufficient to be consolidated into ductile metal, as described in a previous paper,1 has provided adequate material for a study of the : physical properties of titanium and a more thorough examination of its working qualities. Data on the physical properties reported in that paper were obtained on metal fabricated by a fixed procedure, standardized for the purpose of control of the reduction, and are representative only of material fabricated under those conditions. There are many possible variables in the working schedule, which will have significant effects on the properties of the finished material; and since the previous working methods were not necessarily the best, an investigation of the fabrication of titanium by other methods was undertaken. In this work the consolidation of the powder by pressing and sintering was conducted essentially as outlined in the report cited' and all efforts were centered on fabrication methods for those powders and the properties produced by them. Hardness, density, microstructure, and tensile properties were determined at various stages in the working and annealing; and resistivity measurements were made on a few bars and drawn wire. [ ] CONSOLIDATION OF THE POWDER The screen analysis of the available titanium powder is given in Table I. No attempt was made to alter the size distribution from that noted because this powder, although coarse by normal powder-metallurgy standards, produced acceptable compacts suitable for the present work. Because of their large specific surface, finer powders are more contaminated by oxygen and produce harder compacts, which are difficult to work. The powder as produced is soft, compresses in a normal fashion, and exhibits very little tendency to adhere to the die surfaces. Unlike aluminum and magnesium powders, it can be readily pressed without the use of die lubricants. When compacted at so tons per

Jan 1, 1946

By M. Al-Khawaja, F. Hassani, F. Mucciardi, N. Razavinia

"In today’s economy many industries are becoming aware of the need to recover some of the waste heat they create. Industrial processes release, on a global scale, over 100 tera-Joules (i.e. 1014 J) of waste heat annually. The recovery of waste heat can lead to a reduction of greenhouse gas emissions and it can also provide a financial benefit which can be obtained by converting some of this excess heat to electricity. At McGill, a research program has been initiated so that low grade waste heat (temperature between 100ºC and 300oC) from process off-gases found in pyro-metallurgical industries is captured and concentrated by using heat pipes and then converted to electricity by a mechanical engine. This paper illustrates the 3 C’s process (capture, concentrate and convert waste heat to electricity). It also provides some preliminary experimental data. INTRODUCTIONThe problematic climate change caused by the use of fossil fuels, the rapid depletion of global reserves and the catastrophic consequences of nuclear power generation call for renewable and safe, resources of energy, for both man and the environment. Extensive researches in the production of energy from renewable sources and improvements in efficiency of current technologies can help us to reverse this trend.The greatest advantages of using renewable energies are that they don’t deplete and they also contribute to a green environment. On the other hand the disadvantage of using these resources is that the energy available from renewable sources is much less concentrated than that provided by fossil fuels and nuclear energy. This makes renewable energy less attractive for large scale industrial uses in most cases. A key target for society for the 21st century is the production of energy from renewable sources at a cost that is competitive with fossil fuels. Fossil fuels represent a concentrated form of energy; usually it is referred to as high grade energy. Nonetheless, there is a vast supply of alternative energy. The sun, wind, water and biomass were the first to be explored. While these are all valid options that warrant concerted efforts and large investments, there is another source of energy that typically is produced by manufacturing industries. This energy is often referred to as low grade waste heat. Most of this energy is simply vented to the environment through the stream of off-gases. In the future it will be necessary to capture and convert some of the low grade heat to a valuable form such as electricity if we are to improve on the efficiency of energy usage."

Jan 1, 2012

By Du Sichen, S. Seetharaman, A. Jakobsson

"In the Present paper, the principles of oxygen potential measurements have been discussed along with the design details for oxygen sensors that are used in copper industry. A description of some of commercial probes is presented along with their salient features. The application of these sensors in flash smelting, converter and casting sections of copper production are discussed along with their implications on process optimization.I. IntroductionThe high temperature galvanic cells have come into prominence on account of their numerous applications in both fundamental as well as applied measurements. Since the inception of the oxygen-ion conducting electrolytes like ZrOrCaO·by Kiukkola and Wagner [1], the oxygen concentration cells have been extensively used in laboratories as well as in industries. In metal-production technology, these cells have been used to monitor the oxygen potentials in metallic, slag as well as gas phases and also to control and styr metallurgical processes. The pioneer among the various industrial users of such cells is the copper industry. To-day, high temperature solid electrolyte cells involving oxygen ion conducting electrolytes have become an integral part of copper pyro-refining and continuous casting. In the present paper some of the applications according to the industrial processes are described including the developments that are going on in the European scene."

Jan 1, 1997

By Agus Sasmito, Akash Adhikari, Srivatsan Jayaraman Sridharan, Purushotham Tukkaraja

Previous studies on blast fumes(CO + NO2) clearance and workplace re-entry time have overlooked the effects of toxic gases entrapped in the muckpile. The currently available models forcalculatingthe mine re-entry times assume that all post-blast fumes are emitted upon detonation. However,recentstudies reportedthat as much as 60% to 70% of the fumes or gases produced during an underground development blasting couldremain entrapped in the adjacent rock mass or in the muckpile. Entrapped fumes are slowly released,and when disturbed, high concentrations are released, representing a possible risk during the digging and transportation of the muckpile. This study uses CFD, SC-Flow software to understandthe behaviorof the entrapped fumes and theireffect on mine re-entry time.

Feb 1, 2020

By Orlando Orbegozo

"El objetivo del texto radica en prospectar de forma integral las áreas comprendidas entre las formaciones Nito y San Miguel, así como la mineralización del depósito de Alpamarca hacia el extremo de la mina. El método utilizado fue el pirosulfato de potasio, el cual determina el contenido total del zinc puesto que está presente en cantidades dominantes en todas las formaciones del yacimiento una vez probada la asociación entre la mineralización del zinc y la del plomo. El uso del método permite delimitar la extensión de la mineralización en las diferentes zonas conocidas y de esa forma planificar las exploraciones -desarrollo, a través de los elementos directos y auxiliares de la prospección."

Nov 20, 1972

By G. W. Reimers

Conditions in the underground mine environment can cause self-heating of sulfide ores as a result of exothermic oxidation reactions, which may result in mine fires. This Bureau of Mines report describes thermal analyses of finely ground chalcopyrite, chalcocite, galena, pyrrhotite, marcasite, and arsenopyrite, to characterize their responses under oxidizing conditions. Thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) were used, in the temperature range 1000 to 5000 C. Chalcopyrite showed an initial weight gain, due to formation of sul-fates, a weight loss, caused by ignition of iron sulfide to iron oxide, and a final weight gain, indicating the conversion of copper sulfide to sulfate. Chalcocite did not ignite in the temperature range studied but exhibited a rapid weight gain, because of the rapid conversion of copper sulfide to sulfate. Likewise, galena failed to ignite but underwent a steady weight gain when oxidized in a moist atmosphere, showing conver-sion of lead sulfide to sulfate below the ignition point. Marcasite underwent a rapid weight loss, indicating ignition, at 2000 C. Moisture in the oxidizing atmosphere lowered the ignition point of marcasite and arsenopyrite but not that of pyrrhotite. All the sulfides exhibited exothermic behavior at temperatures below the ignition point.

Jan 1, 1987

By Sanjay Gupta, Sorabh Gupta, Ravi Sundaram

A geotechnical forensic evaluation of piles for an industrial facility in Haryana was performed to assess the quality of the piles and to evaluate piles installed using two different types of rigs. Low strain pile integrity tests were performed on all piles to assess the pile length and possible presence of structural defects. Coring was done through questionable piles for the clinching evidence of concrete quality and pile length. Probe holes adjoining piles helped confirm the bulging of piles at shallow depth. The paper highlights the importance of implementing a well-planned quality assurance program to confirm that all piles installed are of the desired quality.

Sep 1, 2022

By Eugene McAuliffe

AS anthracite is no longer used to a marked extent by the rail- ways of the United States (1,513,000 tons in 1933), that portion of the mining industry engaged in the production of bituminous coal is, and will continue to be, the one chiefly concerned with the future use of its product by the railways. In a period such as the present, when all enter- prise is unsettled, when fundamental principles of industrial management and control are being swept aside or else changed overnight, it is difficult to predict what will happen. The relation between the total production of bituminous coal and the volume consumed by the steam rail- ways of the United States, Classes I,

Jan 1, 1936

By B. M. Thethwayo

Graphite blocks are currently used in the concentrate - slag zone in primary PGM smelters, and can possibly be extended to the matte zone. This project evaluates the interaction between synthetic matte and graphite blocks on a laboratory scale. Static crucible tests were performed where graphite crucibles (prepared from standard and high-grade graphite) were filled with synthetic matte (27.7 per cent S ? 46.1 per cent Fe ? 17.0 per cent Ni ? 9.2 per cent Cu) and heated to 1550°C for different time periods (1?5 days). Matte penetration was evaluated using a SEM, while graphite dissolution was evaluated by measuring the carbon content of the matte with a LECO carbon analyser. Matte penetrated into standard grade graphite up to approximately 2 mm, while matte infiltration into the high grade graphite was limited to the immediate hot face. The saturation solubility of graphite in the synthetic matte at 1550°C was 0.43 per cent. Copper, iron, nickel, and sulphur were detected in an accretion that formed in the water-cooled part of the furnace. This accretion consists of mainly Cu-S and Cu-Fe-S based phases.

Jan 1, 2012

By \/eena Sahajwalla, Jonathan Dicker, Paul O'Kane, Cath Skidmore, James Dankwah, Magdalena Zaharia, Rita Khanna, David Knights, N Saha-Chaudhury, Somyote Kongkarat

Due to the inherent limitations of current methods of disposal of end of life polymeric materials, avenues are researched towards developing alternative, environmentally friendly and economic recycling processes. Different polymeric materials (i.e. rubber, high density polyethylene (HDPE) and polyethylene therephtalate (PET)), quite distinct in terms of chemical structure and composition, were considered in the present study as carbon resources in EAF steelmaking. Investigations were conducted in both laboratory and industrial scale steelmaking to assess the effectiveness of using these materials as carbon sources for slag foaming in EAF steelmaking. Slag foaming is important because it enhances furnace efficiency.

Jan 1, 2011

By M. S. Badollet, W. C. Streib

"AbstractA commercial method .has been developed for controlling the texture of chrysotile asbestos fibers so that they may possess properties comparable with natural sem1-harsh fibers for use in wet •processes.The physical properties of the soft, silky and slimy fibers are partially altered by a flash-heating process which removes a portion of the molecular water.The heat-treated fibers show an improvement in filterability, an increase in bulk, absorption, and surface area and better electrical properties, such as volume resistivity.IntroductionCHRYSOTILE ASBESTOS fibers are found in nature having varying degrees of texture, referred to as soft, semi-harsh, and harsh. Fibers of each type of texture have inherent characteristics which directly affect their usefulness to industry. Visual differences are apparent under a microscope where it is seen that the soft-textured fibers have a silky, serpentine or wavy appearance, whereas the harsh-textured fibers are coarser and spicular. Semi-harsh fibers, of course, have properties intermediate between these extremes.Fankuchen and Schneider ( l) have shown by the use of low-angle X-ray scattering that the diameter of the harsh type of chrysotile fiber is somewhat greater than tha of the soft variety. Surface area measurements on various chrysotiles of different textures tend to confirm their findings. By nitrogen adsorption methods, it was found that the surface areas of soft types of chrysotile asbestos are approximately 23M2 / g whereas for the harsh types they are as low as 11M2/g."

Jan 1, 1955

By Yazen Khasawneh, Yao Zhang

Upgrading and maintenance programs were proposed at a power generating plant in Indiana. To perform construction activities associated with the proposed upgrading and maintenance, a LR11350 crawler crane with a dead load of 1,500 ton was required in the vicinity of existing plant structures. The contact pressure from the crane tracks for the heaviest lift, maximum reach and angle (worst loading condition) were estimated by the rigging engineer to be on the order of 84 psi. Several concerns were raised regarding the total and differential settlements while the crane is in operation and the induced stresses on existing underground utilities due to crane loads. Three-dimensional finite element simulations were conducted using hardening soil model for the subsurface soils and elastic model for the other structural elements (underground utilities and crane mats) to optimize the configuration of the proposed crane foundation. It was found 1-foot thick engineered steel mats underlain by a 1.5-foot thick crushed stone pad will provide enough support to the crane. It will also control the settlement to the allowable limit and maintain the stresses in the underground utilities within tolerance. INTRODUCTION A LR11350 heavy lift crawler crane was proposed as part of an upgrade program at an existing power plant in the state of Indiana. The proposed crane will be sitting on an open ground in the vicinity of existing plant facilities, with multiple underground utilities going beneath the proposed footprint of the new crane pad. The existing utilities are of diverse kinds, including sanitary sewer corrugated metal pipes, electrical conduits and variable steel water/oil drain pipes. The safety and functionality of these underground utilities are critical to maintain the proper operation of the power plant. Therefore, the design of the new crane pad foundation system is of essential to control the ground settlement and the imposed stresses to the existing utilities (Davie et al., 1998, Scott 2017). To ensure all utility locations and depths are identified, the proposed footprint was thoroughly surveyed. Information in regard to each identified utility was provided by the owner. Subsurface explorations were conducted using geotechnical soil borings and soundings to evaluate the ground conditions and generate soil profiles. Numerical simulation and analysis utilizing finite element method were performed to design the crane pad foundation system and evaluate the responses of the utilities. This paper summarizes project information, geotechnical conditions and then focuses on the finite element analysis in assisting the design of crane pad and the utilities evaluation.

Jan 1, 2019

By Padmavathi V, M. Najamuddin, M. R. Madhav

Granular piles are one of the leading ground improvement techniques, adopted for the betterment of bearing capacity and reduction in settlements of the foundations and also to accelerate consolidation of the surrounding soil. In the recent past, there has been extensive research on the settlement analysis and behavior of granular piles under varied soil conditions. The application of these theoretical solutions to practical problems requires a knowledge of representative values of the deformation parameters of the ground and the granular piles. However, very little information is available on these parameters. The paper presents a new method for the estimation of the modular ratio of granular piles and modulus of deformation of the surrounding in-situ soil from the compression load tests. The load - settlement response obtained from the compression test results are used in the back analysis for estimating the modulus of deformation of the ground. The presence of granular bed, under the rigid plate for load testing, has been given due consideration in quantifying the proportion of load transferred on to the stone column. Based on these considerations a new method is developed to estimate the modulus of deformation of the ground and the modular ratio of the granular pile.

Sep 1, 2022

By Iwu GO, Almond DP, Joasoo _

The gravimetric integral Knudsen effusion method was used to measure cadmium activity values in binary liquid In-Cd alloys in the range 523 to 573 K. The activity measurements together with other studies from the literature indicate that special bonding conditions exist in the melts near a composition corresponding to InCd3. Sound velocities in In-Cd melts were also measured using a precision pulse-echo over- lap method in the range 404 to 953 K. The frac- tional deviation of experimental and ideal isentropic compressibilities at 623K shows a functional dependence on composition with a pronounced maximum near the composition 75 at.%.

Jan 1, 1980

By Shadia Ikhmayies

Thermo-Calc software was used to investigate the phase diagram of the calcium silicon (Ca–Si) system for the range of Si mass percent 0–100, and temperature range T = 200–1800 K. The melting points of Ca and Si deduced from the phase diagram are very close to the values obtained experimentally. Three stable intermediate solid phases were found, which are Ca2Si, CaSi, and CaSi2, where the first one appeared in the Ca rich side of the phase diagram, and the third one in the Si rich side. In addition, three eutectic points were found at Si mass percents of 3.95, 33.00, 62, and temperatures T = 1048.7, 1519.14, 1308.5 K respectively. Atomic Si (Diamond structure) is found mixed with CaSi2 intermediate phase for temperatures less than 1305 K, and mixed with a liquid CaSi for higher temperatures. These results are important for thermodynamic and metallurgic studies of these intermediate phases.

Mar 1, 2018

By H Zhang, A Lawrence

To accommodate the fast growing need for services in Singapore’s Marina Bay downtown area, Marina South, the construction of a common services tunnel (CST) was required. The CST includes various services such as telecom cables, power lines and water pipes. A deep excavation and temporary earth retaining system (TERS) was required to facilitate the construction of the tunnels. Marina Bay is reclaimed land over thick soft marine clay which is likely to be still consolidating. The deep soft marine clay poses a big challenge for deep excavations in downtown areas where highways and sensitive structures are close by. This paper presents a case study of part of the CST Phase 1B and 2 at Marina South, in particular a 26 m deep excavation supported by a 46 m diameter temporary caisson. The construction started in late 2006 and the basic structure was completed in early 2011. The caisson was formed by 1.0 m thick overlapping diaphragm wall panels with a capping beam and three ring beams at different depths. Two-dimensional finite element analyses were conducted to predict the ground settlement, lateral displacement, bending moment and hoop stresses in the diaphragm wall and ring beams during different excavation stages. A comprehensive instrumentation and monitoring scheme was established to verify the design predictions, control excavation safety and trigger the contingency plan to protect public safety. The impact of construction activity, unbalanced temporary stockpiles and adjacent deep excavation for a mole removal will be discussed.CITATION:Zhang, H and Lawrence, A, 2014. A case history of a deep excavation in a big circular shaft in Singapore marine clay, in Proceedings 15th Australasian Tunnelling Conference 2014, pp 581–588 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By C. I. Basilio

The mechanisms involved in the adsorption of modified thiol-type collectors on sulfide minerals have been investigated in the present work. These collectors belong to the broad classes of thionocarbamates, thioureas, thiophosphates and thiophosphinates. They differ significantly from the traditionally used thiol-type collectors, such as xanthates and dithiophosphates, in terms of structural features that involve either the introduction of an additional oxygen donor or the alteration of electron densities on donor atoms. Electrochemical studies suggest that the adsorption of these classes of collectors is probably the result of a coupled reaction of the EC-type, involving an initial electron transfer step (E), followed immediately by a chemical reaction (C). Thus, the overall adsorption process is controlled by both the E, and pK of the system. The role of structural features in changing the interaction of the donor atoms with sulfide minerals is also discussed.

Jan 1, 1991

By Greg Colzani, Emily Thompson

The 3RPORT Project, includes a 5-mile tunnel excavated by a 19-foot diameter slurry Tunnel Boring Machine below the city of Fort Wayne, IN. The Geotechnical Baseline Report (GBR) indicated vuggy to massive argillaceous dolomite within the tunnel alignment. During excavation of the first reach, the TBM encountered zones of cohesive clay and sandstone presented in full face and mixed face conditions. The occurrence of Sandstone was not a “Baselined Condition” described in the GBR for this reach of the alignment. This paper will discuss the methodology to investigate, mitigate and evaluate the DSC impacts on TBM performance.

Dec 1, 2022

The primary steel industry of the Prairie Provinces consists essentially of three companies whose total annual melting capacity, as of January 1, 1963, was 333,000 net tons. These companies have steel rolling facilities. In addition, there are five other companies producing steel castings by melting scrap in electric furnaces which, with the plants having rolling facilities, gives a total annual furnace melting capacity of 380,000 tons. Since 1954, the annual production of steel ingots and castings has ranged from a low of 66,588 tons, in 1954, to a high of 211,138 tons in 1961. The present facilities on the Prairies for making steel ingots from scrap, and rolling them to produce light merchant mill products, appear to be sufficient for many years ahead. Steel scrap, as electric furnace feed to make steel ingots for the present line of products, will probably continue to be available at reasonable prices either on the Prairies or from the north-central United States. It is recognized, however, that residual elements in scrap may be-come of greater significance and necessitate more rigid control of scrap quality.

Jan 1, 1963

By Cang Daqiang, Li Yu, Liu Xiaoming, Zong Yanbin

"Utilization of high-quality heat in melting slag is a great challenge for iron and steel industry. In the paper, a new method is put forward to concurrently utilize heat and slag by converting the melting slag directly into high valued materials, slag glass-ceramic. A glassceramic with a higher basicity of 0.7 than traditional basicity of 0.45 was prepared from steelmaking slag in order to utilize more hot melting slag. Effects of Alz03 on its crystallization processes were researched by XRF, DTA, XRD and SEM. Results show that Alz03 in glassceramic would have great effected on its property. When the Alz03 content ranges within 12%-15%, glass-ceramics with basicity of0.7 could reach the best performances. The change of dominant phase in glass ceramics from akermanite and wollastonite to akermanite and gehlenite would significantly degrade its mechanical property. An increase of Al2O3 content leads to a rise of the viscosity and crystallization activation energy of the glass, while results in increasing sintering temperature and crystallization temperature of glass, which contributed to its fully crystallization and densification process.IntroductionSteel slag is a by-product under a process of converting iron to steel at above 1600°C, and 0.1-0.15 ton molten steel slag would be discharged for producing per ton of steel in the process. The discharged steel slag at 1600°C has heat of 68 kgce/t. In 2012, China's steel output reached 716 million tons, and produces about 100 million tons of steel slag and 68,000 tee of heat in it [1,2]. But at present, utilization of both slag and its heat at 1600°C is a great challenge for iron and steel industry.Dry granulation of melting steel slag by air and then recovering the heat of the hot air are a traditional technology which have not yet been put into practice for very low heat conductivity of the slag and low efficient of heat exchange among the different processes [3,4]. Therefore, a new method for high efficient utilization of both steel slag and its high temperature sensible heat is put forward [5,6], which is on-line reducing and extracting iron from molten steel slag and then directly preparing glass-ceramic by use of the residual molten slag."

Jan 1, 2014